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Coarsening droplets for frosting delay on hydrophilic slippery liquid-infused porous surfaces 在亲水性滑液注入多孔表面上粗化液滴以延迟结霜时间
Pub Date : 2024-02-17 DOI: 10.1002/dro2.106
Jyotirmoy Sarma, Deepak Monga, Zongqi Guo, Fangying Chen, Xianming Dai

Frosting occurs due to the freezing of condensed water droplets on a supercooled surface. The nucleated frost propagates through interdroplet bridges and covers the entire surface, resulting from the deposition of highly supersaturated vapor surrounding tiny droplets. While inhibition of the formation of frost bridges is not possible, the propagation of frost can be delayed by effectively removing tiny droplets. Passive technologies, such as superhydrophobic surfaces (SHS) and hydrophobic slippery liquid-infused porous surfaces (SLIPS), rely on static growth and direct contact with densely distributed droplets. However, use of these approaches in delaying frost propagation involves challenges, as the interdroplet distance remains small. Here, we report a new approach of spontaneous droplet movement on hydrophilic SLIPS to delay the formation of interdroplet frost bridges. Surface tension forces generated by the hydrophilic oil meniscus of a large water droplet efficiently pull neighboring droplets with a diameter of less than 20 μm from all directions. This causes a dynamic separation between water droplets and an adjacent frozen droplet. Such a process delays the formation and propagation of interdroplet frost bridges. Consequently, there is significant delay in frosting on hydrophilic SLIPS compared to those on SHS and hydrophobic SLIPS.

结霜是由于过冷表面上的冷凝水滴冻结而产生的。由于小水滴周围沉积了高度过饱和的水蒸气,成核的霜通过水滴间的桥传播并覆盖整个表面。虽然无法抑制霜桥的形成,但可以通过有效清除微小水滴来延缓霜的传播。被动技术,如超疏水表面(SHS)和疏水性滑液注入多孔表面(SLIPS),依赖于静态生长和与密集分布的水滴直接接触。然而,由于液滴间的距离仍然很小,因此使用这些方法来延迟霜冻的传播是一项挑战。在此,我们报告了一种在亲水性 SLIPS 上实现液滴自发运动以延迟液滴间霜桥形成的新方法。大水滴的亲水性油半月板产生的表面张力能有效地从各个方向拉动直径小于 20 μm 的相邻水滴。这就造成了水滴与相邻冻结水滴之间的动态分离。这一过程会延迟水滴间霜桥的形成和传播。因此,与 SHS 和疏水性 SLIPS 相比,亲水性 SLIPS 上的结霜时间明显延迟。
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引用次数: 0
Back Cover, Volume 3, Number 1, January 2024 封底,第 3 卷,第 1 号,2024 年 1 月
Pub Date : 2024-01-24 DOI: 10.1002/dro2.114
Xi Zhao, Mengwen Qiao, Yingxin Zhou, Jing Liu

Back Cover: The cover image is based on the Review Article Liquid metal droplet dynamics by Zhao et al.

Gallium-based liquid metal droplets are newly intriguing research targets in diverse areas due to their unique properties which combine the dual merits of both liquids and metals. This review summarizes the latest progress and presents an overview on basic findings related to liquid metal macro-droplet dynamics, including droplet types, fabrication methods, different dynamic behaviors, main challenges, and future perspectives. (DOI: 10.1002/dro2.104)

封底:镓基液态金属液滴因其兼具液体和金属双重优点的独特性质,成为各领域新的引人入胜的研究目标。这篇综述总结了最新进展,并概述了与液态金属宏观液滴动力学相关的基本发现,包括液滴类型、制造方法、不同的动态行为、主要挑战和未来展望。(DOI: 10.1002/dro2.104)
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引用次数: 0
Front Cover, Volume 3, Number 1, January 2024 封面,第 3 卷,第 1 号,2024 年 1 月
Pub Date : 2024-01-24 DOI: 10.1002/dro2.115
Yanchen Wu, Joaquin E. Urrutia Gomez, Hongmin Zhang, Fei Wang, Pavel A. Levkin, Anna A. Popova, Britta Nestler

Front Cover: The cover image is based on the Research Article Digital twin of a droplet microarray platform: Evaporation behavior for multiple droplets on patterned chips for cell culture by Wu et al.

This cover highlights evaporation phenomenon of multiple droplets on patterned surfaces, affected by humidity, temperature, and droplet distribution. We establish a digital twin system and propose a theoretical method to detect volumes and pH variation on evaporating droplets onto patterned substrates. The proposed strategy allows us to achieve an active maneuver of the collective evaporation of droplets on patterned surfaces. (DOI: 10.1002/dro2.94)

封面:封面图片取材于研究文章《液滴微阵列平台的数字孪生》(Digital twin of a droplet microarray platform):本封面重点介绍了多液滴在图案化表面上的蒸发现象,它受到湿度、温度和液滴分布的影响。我们建立了一个数字孪生系统,并提出了一种理论方法来检测图案化基底上蒸发液滴的体积和 pH 值变化。所提出的策略使我们能够实现对图案化表面上液滴集体蒸发的主动操纵。(DOI: 10.1002/dro2.94)
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引用次数: 0
Inside Front Cover, Volume 3, Number 1, January 2024 封面内页,第 3 卷第 1 号,2024 年 1 月
Pub Date : 2024-01-24 DOI: 10.1002/dro2.113
Diego Sánchez-Saldaña, Maria Fernandino, Carlos A. Dorao

Inside Front Cover: The cover image is based on the Research Article Acoustic micro-beam vortex generator for flow actuation inside droplets by Sánchez-Saldaña et al.

A micro-size spiral IDT placed at the base of the droplet leads to an acoustic vortex that induces a poloidal flow inside the droplet with an ascendent flow in the centre and descendent flow in the periphery. This paper shows that the micro-size spiral IDT can control the scale of the flow actuation inside the droplet which in turn can be used for facilitating the operations on particles. (DOI: 10.1002/dro2.96)

封面内页:封面图片来自 Sánchez-Saldaña 等人撰写的研究文章《用于液滴内部流动驱动的声学微束涡流发生器》。在液滴底部放置一个微型螺旋 IDT 会产生一个声学涡流,从而在液滴内部诱发极性流动,中心为上升流,外围为下降流。本文表明,微小尺寸的螺旋 IDT 可以控制液滴内部流动驱动的尺度,这反过来又可用于促进对粒子的操作。(DOI: 10.1002/dro2.96)
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引用次数: 0
Inside Back Cover, Volume 3, Number 1, January 2024 封底内页,第 3 卷第 1 号,2024 年 1 月
Pub Date : 2024-01-24 DOI: 10.1002/dro2.112
Jingyu Shi, Yu Zhang, Yadi Fan, Yi Liu, Mo Yang

Inside Back Cover: The cover image is based on the Review Article Recent advances in droplet-based microfluidics in liquid biopsy for cancer diagnosis by Shi et al.

Droplet-based microfluidics with high throughput, low contamination, high sensitivity, and single-cell/single-molecule/single-exosome analysis capabilities have shown great potential in the field of liquid biopsy. This review aims to summarize the recent development in droplet-based microfluidics in liquid biopsy for cancer diagnosis. (DOI: 10.1002/dro2.92)

封底内页:封面图片根据 Shi 等人撰写的综述文章《基于液滴的微流控技术在用于癌症诊断的液体活检中的最新进展》绘制。基于液滴的微流控技术具有高通量、低污染、高灵敏度和单细胞/单分子/单外显子分析能力,在液体活检领域显示出巨大的潜力。本综述旨在总结基于液滴的微流控技术在用于癌症诊断的液体活检中的最新发展。(DOI: 10.1002/dro2.92)
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引用次数: 0
Frontispiece, Volume 3, Number 1, January 2024 插图,第 3 卷第 1 号,2024 年 1 月
Pub Date : 2024-01-24 DOI: 10.1002/dro2.111
Kenta Goto, Kyoka Nakanishi, Fumito Tani, Satoru Tokuda

Frontispiece: The cover image is based on the Research Article Chemical reaction in a liquid–liquid phase-separated multiple droplet: Synchronization of color change dynamics with droplet movement by Goto et al. (This cover image is licensed under CC BY-NC-ND 4.0.)

Exemplifying self-similarity, a large Matryoshka doll holds a smaller one within. The shape is repeated at different reduced-scales to generate a nested structure. The smallest doll hosts a micro-channel, which formed nested droplets through liquid-liquid phase separation when oil-rich and aqueous alcohol liquids were mixed. (DOI: 10.1002/dro2.93)

封面插图:封面图像基于 Goto 等人的研究文章《液-液相分离的多液滴中的化学反应:该封面图片采用 CC BY-NC-ND 4.0 版授权。)作为自相似性的例证,一个大的马特里奥什卡娃娃内部有一个较小的娃娃。这种形状在不同的缩小尺度上重复出现,形成嵌套结构。最小的娃娃内有一个微通道,当富含油脂的液体和含水酒精液体混合时,微通道通过液-液相分离形成嵌套液滴。(DOI: 10.1002/dro2.93)
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引用次数: 0
New insights into suspended drops: When soft matter meets acoustic levitation 悬浮水滴的新发现当软物质遇到声悬浮
Pub Date : 2024-01-17 DOI: 10.1002/dro2.95
Hongyue Chen, Zhenyu Hong, Duyang Zang

Acoustic levitation has developed into a popular but elegant tool for the study of drops as well as soft matter due to its exceptional levitation capabilities to a variety of liquid samples. The acoustically levitated drops offer opportunities for the investigation of a wide range of fundamental issues related to liquid drops. In this review, the unique physics/chemical processes involved in acoustically levitated drops are dealt with. We first introduce the dynamics of the acoustically levitated drops, including drop oscillation, coalescence, and the associated capillary phenomena. The bubble formation and stability are also discussed. Depending on the inhibition of solid surfaces and the nonlinear effects of ultrasound, the self-assembly of colloidal particles at the air–liquid interface as well as granular matter in air is reviewed. In particular, the exploration of biological drops by using acoustic levitation is also highlighted. In the end, the concept of acoustic-levitation-fluidics and possible potential topics are proposed.

声学悬浮因其对各种液体样品的特殊悬浮能力,已发展成为研究液滴和软物质的一种流行而优雅的工具。声学悬浮液滴为研究与液滴有关的各种基本问题提供了机会。本综述将讨论声学悬浮液滴所涉及的独特物理/化学过程。我们首先介绍了声悬浮液滴的动力学,包括液滴振荡、凝聚和相关的毛细现象。我们还讨论了气泡的形成和稳定性。根据固体表面的抑制作用和超声波的非线性效应,我们回顾了气液界面胶体颗粒以及空气中颗粒物质的自组装。还特别强调了利用声学悬浮对生物滴的探索。最后,提出了声悬浮流体学的概念和可能的潜在主题。
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引用次数: 0
Liquid metal droplet dynamics 液态金属液滴动力学
Pub Date : 2024-01-16 DOI: 10.1002/dro2.104
Xi Zhao, Mengwen Qiao, Yingxin Zhou, Jing Liu

The unique properties to combine the dual merits of both liquids and metals together make the gallium-based liquid metal (LM) droplets a class of unconventional substitute which possess great potential for a group of newly emerging areas, such as stretchable electronics, soft devices, micro sensors and actuators. In addition, LM droplets are undoubtedly an intriguing target worth of pursuing in fundamental hydrodynamic investigations due to their extremely high surface tension nature compared to classical nonmetallic fluids. Since the discovery of the diverse transformation phenomena and self-fueled droplet mollusks of LM that can move automatically in solution via single electricity or even without any external energy supply, tremendous attentions were attracted to this special fluidic object of LM droplets. Over the past decade, there has been a proliferation of explorations on LM droplet dynamics, while the involved contents are heterogeneous due to the interfacial physical/chemical activity of the LM and the diversity of the kinetic behaviors. To better understand and manipulate the droplet behavior and to promote further development of the LMs, this review is dedicated to summarize the latest progress and presents an overview on basic findings related to LM macro-droplet dynamics. Firstly, the extended definition of LM droplets and the corresponding fabrication methods are given. Then, typical works on LM droplet dynamics are systematically interpreted based on their different behavior categories. Finally, the perspectives, main obstacles and challenges restricting the development of LM droplet dynamics are pointed out.

镓基液态金属(LM)液滴具有将液体和金属的双重优点结合在一起的独特特性,是一类非常规替代品,在可拉伸电子器件、软器件、微型传感器和致动器等新兴领域具有巨大潜力。此外,与传统非金属流体相比,液态金属液滴具有极高的表面张力,因此无疑是流体力学基础研究中值得探究的目标。自从发现了 LM 的各种转化现象和自燃液滴软体动物,它们可以在溶液中通过单电甚至不需要任何外部能源供应就能自动运动以来,LM 液滴这一特殊的流体物体就吸引了人们的极大关注。在过去的十年中,有关 LM 液滴动力学的探索层出不穷,而由于 LM 的界面物理/化学活性和动力学行为的多样性,所涉及的内容也是异构的。为了更好地理解和操纵液滴行为,促进 LM 的进一步发展,本综述致力于总结最新进展,并概述与 LM 宏观液滴动力学相关的基本发现。首先,给出了 LM 液滴的扩展定义和相应的制造方法。然后,根据 LM 液滴的不同行为类别,系统地解释了有关 LM 液滴动力学的典型研究成果。最后,指出了制约 LM 液滴动力学发展的前景、主要障碍和挑战。
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引用次数: 0
Water droplet energy harvesting 水滴能量收集
Pub Date : 2024-01-12 DOI: 10.1002/dro2.97
Zhiming Lin, Zhengbao Yang

Harnessing abundant kinetic water energy in diverse forms of river flows, ocean waves, tidal currents, raindrops, and others, is highly attractive to ease the energy crisis and satisfy the demands of scattered sensor network nodes in the Internet of things. Among them, raindrops, widely and ubiquitously distributed in nature and ambient living life, have been extensively explored and regarded as significant renewable energy carriers. Extensive efforts have been made to investigate droplet-based electricity nanogenerators in fundamental mechanism, performance, and applications for achieving sustainable energy demands of the rapidly developing society over the past decade. In this review, we introduce the remarkable progress in this field and discuss the fundamental mechanisms of droplet energy harvesting technology for achieving high-power generation. More significantly, a systematic review of droplet energy harvesting in different two-phase interfaces, including liquid–solid, liquid–liquid, and liquid–gas interfaces, is provided. Finally, this survey reveals that droplet-based electricity generators present vast potential in the power supply. At the same time, several development challenges and prospective solutions are discussed to spur future technological advancements.

利用河流、海浪、潮汐流、雨滴等各种形式的丰富水动能,对缓解能源危机和满足物联网中分散的传感器网络节点的需求具有极大的吸引力。其中,雨滴广泛而普遍地分布于自然界和人们的生活中,已被广泛探索并视为重要的可再生能源载体。近十年来,人们在研究基于雨滴的纳米发电装置的基本机理、性能和应用方面做出了大量努力,以满足快速发展的社会对可持续能源的需求。在这篇综述中,我们介绍了这一领域的显著进展,并讨论了液滴能量收集技术实现大功率发电的基本机制。更重要的是,我们对不同两相界面(包括液-固、液-液和液-气界面)中的液滴能量收集进行了系统综述。最后,这项研究揭示了液滴发电装置在电力供应方面的巨大潜力。同时,还讨论了若干发展挑战和前瞻性解决方案,以推动未来的技术进步。
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引用次数: 0
Chemically robust superhydrophobic surfaces with a self-replenishing nanoscale liquid coating 具有自补强纳米级液体涂层的强化学性超疏水性表面
Pub Date : 2024-01-02 DOI: 10.1002/dro2.103
Xiaoteng Zhou, Pranav Sudersan, Diego Diaz, Benjamin Leibauer, Chirag Hinduja, Fahimeh Darvish, Pravash Bista, Lukas Hauer, Manfred Wagner, Werner Steffen, Jie Liu, Michael Kappl, Hans-Jürgen Butt

Due to poor chemical robustness, superhydrophobic surfaces become susceptible to failure, especially in a highly oxidative environment. To ensure the long-term efficacy of these surfaces, a more stable and environmentally friendly coating is required to replace the conventional salinization layers. Here, soot-templated surfaces with re-entrant nanostructures are precoated with polydimethylsiloxane (PDMS) brushes. An additional nanometer-thick lubricant layer of PDMS was then applied to increase chemical stability. The surface is superhydrophobic with a nanoscale liquid coating. Since the lubricant layer is thin, ridge formation is suppressed, which leads to low drop sliding friction and fast drop shedding. By introducing a bottom “reservoir” of a free lubricant as an oil source for self-replenishing to the upper layer, the superhydrophobic surface becomes more stable and heals spontaneously in response to alkali erosion and O2 plasma exposure. This design also leads to a higher icing delay time and faster removal of impacting cooled water drops than for uncoated surfaces, preventing icing at low temperatures.

由于化学稳定性差,超疏水表面很容易失效,尤其是在高度氧化的环境中。为了确保这些表面的长期功效,需要一种更稳定、更环保的涂层来取代传统的盐化层。在这里,带有再入式纳米结构的烟灰模板表面预涂了聚二甲基硅氧烷(PDMS)刷。然后再额外涂上一层纳米厚的 PDMS 润滑层,以提高化学稳定性。表面是超疏水的纳米级液体涂层。由于润滑层很薄,脊的形成受到抑制,因此液滴滑动摩擦小,液滴脱落快。通过在底部引入一个自由润滑剂 "储库",作为上层自我补充的油源,超疏水表面变得更加稳定,并能在碱侵蚀和氧气等离子暴露下自发愈合。与无涂层表面相比,这种设计还能延长结冰延迟时间,更快地去除撞击冷却的水滴,从而防止低温结冰。
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引用次数: 0
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