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Rare earth elements in rift-hosted ferromanganese nodules, Malawi, Central Africa 中非马拉维裂谷型锰铁结核中的稀土元素
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90108-3
T.M. Williams

Ferromanganese nodules from Lake Malawi have been analysed for 13 rare earth elements by ICP mass spectrometry. Total REE levels are considerably higher than previously reported for lacustrine or continental margin nodules and shale-normalised profiles display many characteristics commonly associated with deep ocean concretions. While shale-normalised REE values for the nodules exceed 1.0 across the entire REE spectrum, the surrounding lake muds are enriched only in LREE. Significant fractionation, involving the preferential assimilation of HREE during nodule growth is thus inferred. The nodules are also characterised by positive Ce and negative Tb anomalies, generally consistent with REE incorporation through redox-mediated exchange processes.

用ICP质谱法对马拉维湖锰铁结核中的13种稀土元素进行了分析。湖泊或大陆边缘结核的总稀土水平远高于先前报道的水平,页岩正态化剖面显示出许多通常与深海结核相关的特征。在整个稀土谱上,结核的页岩归一化稀土值均超过1.0,而周围的湖泥只富集低稀土元素。由此推断,在结核生长过程中,稀土元素的优先同化是重要的分馏作用。结核还具有Ce阳性和Tb阴性异常的特征,通常与氧化还原介导的交换过程中REE的结合一致。
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引用次数: 2
Editorial: Software survey section 编辑:软件调查部分
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90111-3
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引用次数: 0
Un exemple de volcanisme du Protérozoïque inférieur en Côte d'Ivoire: zone de subduction ou zone de cisaillement? 科特迪瓦下元古代火山活动的一个例子:俯冲带还是剪切带?
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90102-V
Koffi Ble Pothin

The study of lava and pyroclastic formations from Odienné showed the calco-alkaline character of the volcanism in that region and revealed the structural context of its origin. It appears that, contrary to the general idea which links the calco-alkaline volcanism to the subduction zones, the Odienné volcanism is associated with the shearing constraints along Sassandra fault. The intensity of those constraints was such that it met the temperature and pressure conditions of a subduction zone.

对奥甸纳斯火山岩和火山碎屑地层的研究显示了该地区火山活动的钙碱性特征,揭示了其起源的构造背景。与将钙碱性火山作用与俯冲带联系在一起的一般观点相反,odienn火山作用似乎与Sassandra断裂的剪切约束有关。这些约束的强度使其符合俯冲带的温度和压力条件。
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引用次数: 7
Planktonic foraminifera and chronostratigraphy of the Oligo-Miocene in some wells in the isthmus of Suez and the North-Eastern reach of the Nile Delta, Egypt 埃及苏伊士地峡和尼罗河三角洲东北段部分井的浮游有孔虫和渐新世至中新世的年代地层
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90107-2
O.H. Cherif , H. El-Sheikh , S. Mohamed

The lithofacies and planktic foraminiferal content of the Oligo-Miocene interval penetrated by four wells (El-Temsah-2, Boughaz-1, Mallaha-1X and San El-Hagar-1) drilled in the Isthmus of Suez and in the eastern reach of the Nile Delta enable to clarify the chronostratigraphy and sedimentological and tectonic history of the studied sequence.

The Oligocene is represented by the Qantara Formation which is conformably overlain by the Aquitanian-Burdigalian (early Miocene) Rudeis Formation. The early Miocene is separated from the middle Miocene (Langhian-early Serravallian Kareem Formation) by a hiatus, probably reflecting the mid-Clysmic tectonic event that affected the Gulf of Suez region.

A stratigraphic gap between the early and late Serravallian Kareem and Serravallian to Tortonian Sidi Salim Formations may have been caused by the uplift of the isthmus of Suez which induced the beginning of evaporite sedimentation in restricted basins in the southern part of the Gulf of Suez. The Messinian is either represented by a regressive sequence of coarse siliciclastics known as the Qawasim Formation or by evaporites.

苏伊士地峡和尼罗河三角洲东段4口井(El-Temsah-2、boughaz1、mallahaa - 1x和San El-Hagar-1)钻探的渐新世-中新世段的岩相和有孔虫含量有助于阐明所研究层序的年代地层、沉积学和构造史。渐新世以Qantara组为代表,该组被早中新世的阿基坦- burdigian Rudeis组整合覆盖。早中新世与中中新世(langhian -早Serravallian Kareem组)隔了一段间断,可能反映了影响苏伊士湾地区的中纪构造事件。苏伊士地峡隆升导致了苏伊士湾南部局限盆地蒸发岩沉积的开始,在早、晚期的Serravallian Kareem组和Serravallian至Tortonian Sidi Salim组之间形成了地层间隙。墨西尼亚期的代表要么是被称为卡瓦西姆组的粗硅塑料的退退序列,要么是蒸发岩。
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引用次数: 11
The geology of Libya 利比亚的地质情况
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90110-C
J.R. Vail
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引用次数: 1
First heat flow density determinations from Southeastern Zaïre (Central Africa) 来自东南部Zaïre(中非)的首次热流密度测定
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90100-5
M.N. Sebagenzi , G. Vasseur , P. Louis

First heat flow density determinations from southeastern Zaïre are presented. Sites are located in the late Proterozoic metasedimentary cover of the Pan-African belt (600 Ma.). For each individual boreholes, heat flow ranges between 48 and 72 mWm−2. The average value of 62 mW m−2 for the sites is similar to that of 66 mW m−2 observed in Zambia. Both values are higher than what is expected for Pan-African terranes. These heat flow determinations in Shaba province of southeastern Zaïre, together with gravity and seismological observations, support the hypothesis of lithospheric thinning for this area. As already suggested for Zambia, this lithospheric thinning may be associated with a southwestern extension of the East African Rift System from Tanganyika across the central African plateau.

首先介绍了Zaïre东南部地区的热流密度测定。遗址位于泛非带(600 Ma.)晚元古代变质沉积层。对于每个单独的钻孔,热流范围在48到72 mWm−2之间。这些站点的平均值为62 mW m−2,与赞比亚观测到的66 mW m−2相似。这两个值都高于泛非地形的预期值。这些在Zaïre东南部沙坝省的热流测定,加上重力和地震观测,支持该地区岩石圈变薄的假设。正如已经对赞比亚提出的那样,这种岩石圈变薄可能与东非裂谷系统从坦噶尼喀向西南延伸到中非高原有关。
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引用次数: 16
The mineralogy and geochemistry of some cassiterite from the Younger Granite province of the Jos Plateau, Nigeria 尼日利亚乔斯高原新花岗岩省一些锡石的矿物学和地球化学特征
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90104-X
M.I. Ogunbajo

Cassiterite from four different alluvial mining localities on the Jos Plateau were investigated from the point of view of their mineralogy, colour variety and chemistry. The optical properties of each of the colour varieties as revealed by the incident light microscopic studies coupled with the variation in their chemical composition as revealed by the electron microprobe analyses indicate that the cassiterites crystallized under different physicochemical conditions. Some (black varieties) are high temperature forms, whereas others, i.e., the red and white varieties are low temperature forms. Furthermore, the chemistry of these cassiterites tends to support the age migration of the Younger Granites whereby the northern cassiterites tend to be older, richer in SnO2 and poorer in the elements Fe, Nb and Ta than the southern cassiterites.

从矿物学、颜色变化和化学角度对乔斯高原四个不同冲积矿区的锡石进行了研究。入射光显微研究显示的每种颜色的光学性质,加上电子探针分析显示的化学成分的变化,表明锡石是在不同的物理化学条件下结晶的。有些品种(黑色品种)是高温品种,而其他品种,即红色和白色品种是低温品种。此外,这些锡石的化学成分倾向于支持年轻花岗岩的年龄迁移,即北部锡石比南部锡石更古老,SnO2含量更丰富,Fe、Nb和Ta元素含量更低。
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引用次数: 0
Implications of whole-rock PbPb and zircon evaporation dates for the early metamorphic history of the Kasaï craton, Southern Zaïre 全岩Pb()和锆石蒸发日期对南部Kasaï克拉通早期变质史的意义Zaïre
Pub Date : 1993-05-01 DOI: 10.1016/0899-5362(93)90098-B
F. Walraven , B.T. Rumvegeri

A whole-rock PbPb date of 3021 + 47–49 Ma, found for granodioritic granitoid occurring within biotite gneiss in the Sandoa-Kapanga region of the Kasaï Craton, southern Zaïre, in reflected in single zircon evaporation data (centered around 3014 ± 2.3 Ma) obtained from the biotite gneiss itself. Other zircon evaporation dates found in the biotite gneiss range from ca. 3.0 Ga to 3.09 Ga and are interpreted as minimum ages of discordant zircon phases overprinted during one or more metamorphic events. Anomalously high Pb initial ratios characterise the granitoid and consequently its ca. 3.02 Ga age, taken together with the corresponding zircon date, is considered to reflect a metamorphic event during which anatectic melting took place to produce the granodioritic magma. During the same event, overgrowths formed on older zircon cores. The ca. 3.02 Ga date is the oldest yet recognised in the southern Kasaï Craton and a correlation is suggested with the D2 metamorphic event of this region. Additionally a prehistory back to at least 3.09 Ga is indicated by the other zircon dates in the biotite gneiss.

在Zaïre南部Kasaï克拉通Sandoa-Kapanga地区的黑云母片麻岩中发现的花岗闪长花岗岩类的全岩Pb()Pb年龄为3021 + 47 ~ 49 Ma,反映在黑云母片麻岩本身的单锆石蒸发数据中(中心约为3014±2.3 Ma)。在黑云母片麻岩中发现的其他锆石蒸发年代在约3.0 Ga至3.09 Ga之间,被解释为在一次或多次变质事件中叠加的不一致锆石相的最小年龄。异常高的Pb初始比值是花岗岩的特征,因此其约3.02 Ga的年龄,以及相应的锆石日期,被认为反映了变质事件,在此期间发生了渐熔熔融,产生了花岗闪长岩岩浆。在同一事件中,在更古老的锆石岩心上形成了过度生长。约3.02 Ga是目前已知的Kasaï克拉通南部最古老的年代,并与该地区的D2变质事件有关。此外,黑云母片麻岩中的其他锆石日期表明其史前史至少可追溯到3.09 Ga。
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引用次数: 25
An overview of carbonate-hosted mineral deposits in the Otavi Mountain Land, Namibia: implications for ore genesis 纳米比亚奥塔维山地碳酸盐岩矿床概述:对矿石成因的影响
Pub Date : 1993-04-01 DOI: 10.1016/0899-5362(93)90048-U
F. Pirajno , B.D. Joubert

A model of metallogenesis for the carbonate-hosted base metal deposits of the Otavi Mountain Land (Namibia) is proposed based on stratigraphic, mineralogical, metal association, Pb and S isotope systematics and fluid inclusion data. Three mineralising episodes are recognised. The first involved low-temperature and high-salinity basinal fluids, which formed the Berg Aukas-type deposits of Mississippi Valley-Type (MVT) affinity. These are characterised by a Zn-Pb metal association. The second episode appears to have involved Cu-rich fluids having higher temperatures and lower salinities of possible metamorphic origin. These formed Tsumeb-type deposi ts, characterised by a metal association of Cu-Pb-Zn-Ag, locally accompanied by Fe-Mn oxides and silicates. The third and last episode is related to recent weathering, which resulted in the precipitation of V-rich minerals.

根据地层、矿物学、金属组合、Pb、S同位素系统学和流体包裹体资料,提出了纳米比亚奥塔维山地碳酸盐岩型贱金属矿床成矿模式。确认了三个矿化期。第一个涉及低温、高盐度的盆地流体,形成了密西西比河谷型(MVT)亲和的Berg aukas型矿床。它们的特征是锌-铅金属缔合。第二阶段似乎涉及温度较高、盐度较低的富铜流体,可能起源于变质岩。这些形成了summeb型矿床,其特征是铜-铅-锌-银的金属结合,局部伴有Fe-Mn氧化物和硅酸盐。第三期也是最后一期与近代风化作用有关,风化作用导致富v矿物沉淀。
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引用次数: 34
Dating the cessation of Kibaran magmatism in Natal, South Africa 确定南非纳塔尔基巴兰岩浆活动停止的年代
Pub Date : 1993-04-01 DOI: 10.1016/0899-5362(93)90046-S
R.J. Thomas , B.M. Eglington , S.A. Bowring

Published U-Pb and Pb-Pb zircon dates from pre- to late-tectonic granitoids of the Kibaran (Grenvillian) Natal Metamorphic Province fall within the range ≈1200 to ≈1040 Ma. A major problem regarding the duration and timing of magmatism in the Natal belt has been the age of the youngest intrusive events. This is important within a Gondwana context, especially with respect to the nature and distribution of the Pan-African event in this area. It is known that the youngest magmatic rocks in Natal are certain undeformed, cross-cutting microgranite dykes (Mbizana Microgranite) from the Margate Terrane. These dykes have previously given a Rb-Sr whole-rock date of ≈950 Ma, showing them to be broadly late Kibaran in age. This paper presents new U-Pb data from four zircon fractions from the Mbizana Microgranite, which give a date of emplacement of 1026 ± 3 Ma. Consequently, this date is considered to define the latest magmatic event in the Natal Metamorphic Province and points to the timing of the cessation of Kibaran magmatism in this area. The data supports recent suggestions that there was no Pan-African magmatic activity in Natal. The ≈950 Ma Rb-Sr dates previously obtained for these rocks are re-interpreted as representing the time at which the dykes cooled through the Rb-Sr biotite and K-feldspar blocking temperatures.

已公布的Kibaran (Grenvillian) Natal变质省构造前至构造晚期花岗岩类U-Pb和Pb-Pb锆石年龄在≈1200 ~≈1040 Ma之间。关于纳塔尔带岩浆活动的持续时间和时间的一个主要问题是最年轻侵入事件的年龄。这在冈瓦纳的背景下是重要的,特别是在该地区泛非事件的性质和分布方面。已知纳塔尔最年轻的岩浆岩是来自马盖特地体的一些未变形的、交叉切割的微花岗岩岩脉(Mbizana微花岗岩)。这些岩脉之前给出的Rb-Sr全岩年代约为950 Ma,表明它们的年龄大致为基巴兰晚期。本文报道了来自Mbizana微花岗岩的4个锆石组分的新的U-Pb数据,给出了侵位时间为1026±3 Ma。因此,这个日期被认为定义了纳塔尔变质省最新的岩浆事件,并指出了该地区基巴兰岩浆活动停止的时间。这些数据支持了最近关于纳塔尔没有泛非岩浆活动的建议。以前获得的这些岩石的≈950 Ma Rb-Sr日期被重新解释为代表岩脉通过Rb-Sr黑云母和k -长石阻塞温度冷却的时间。
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引用次数: 34
期刊
Journal of African Earth Sciences (and the Middle East)
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