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Helium resources accumulation regulations and their development prospects in China 中国氦资源积累法规及其发展前景
Pub Date : 2024-10-01 DOI: 10.1016/j.jnggs.2024.09.003
Jian Li , Xiaobo Wang , Zhusong Xu , Huiying Cui , Xiaomei Wang , Bin Zhang , Jianying Guo , Shizhen Tao , Jianfa Chen , Zengye Xie , Jixian Tian , Yifeng Wang
Helium is a globally scarce strategic resource that is relevant to national economies and the development of high-tech industries, and China primarily depends on imported helium for its industrial applications. Therefore, there is an urgent demand for clarifying helium formation and enrichment patterns, searching for helium-rich fields, and realizing China's helium resource inventory and development potential. This article analyzes the reservoir characteristics and accumulation conditions of typical helium-rich fields in China, and clarifying the origin and source of helium as well as the main controlling factors of helium enrichment. It was recognized that helium in natural gas in China mainly comes from crustal sources. Relatively shallow buried ancient U–Th-rich granite basement or intrusion, large and stable ancient uplift or submarine formed in the early period, good overburden of huge thick paste-salt rock or mudstone cover, and channels connecting the basement and reservoir, were the main controlling factors of helium enrichment. Four types of helium-rich gas reservoirs, namely helium-rich conventional gas, helium-rich shale gas, helium-rich non-hydrocarbon gas, and helium-rich water-soluble gas, have been modeled and predicted to be helium-rich favorable exploration areas. Based on this analysis, the prospect of helium resource development in China has been analyzed. It was proposed that the exploration of helium-rich fields and the comprehensive development and utilization of medium- and low-abundance helium resources are important ways to increase the domestic helium production in China in the future.
氦气是全球稀缺的战略资源,关系到国民经济和高新技术产业的发展,而中国的工业应用氦气主要依赖进口。因此,厘清氦的形成和富集规律,寻找富氦气田,实现中国氦资源的盘活和开发潜力,已成为当务之急。本文分析了中国典型富氦气田的储层特征和富集条件,阐明了氦气的成因、来源和富集的主要控制因素。研究认为,中国天然气中的氦主要来自地壳。埋藏相对较浅的古代富含铀-钍的花岗岩基底或侵入体、早期形成的大型稳定的古代隆起或海底、巨大厚浆盐岩或泥岩覆盖的良好覆盖层以及连接基底和储层的通道是氦富集的主要控制因素。富氦常规气、富氦页岩气、富氦非烃气、富氦水溶气四类富氦气藏经建模预测为富氦有利勘探区。在此基础上,分析了中国氦资源的开发前景。提出富氦气田勘探和中低丰度氦气资源综合开发利用是未来提高中国国内氦气产量的重要途径。
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引用次数: 0
Diagenetic features recorded in sedimentary rocks within a gas chimney: A case study from the Makassar Strait, offshore Indonesia 天然气烟囱内沉积岩中记录的成因特征:印度尼西亚近海望加锡海峡案例研究
Pub Date : 2024-10-01 DOI: 10.1016/j.jnggs.2024.07.003
Syahreza S. Angkasa , Harya D. Nugraha , Dian Yesy Fatimah , Ananda Bagus Krisna Pratama
Methane seeps, prevalent in ocean basins globally, indicate upward methane migration from the subsurface, often evident as gas chimneys in seismic reflection data. The footprint of this methane migration is often indicated by methane-derived authigenic carbonate (MDAC), a product of anaerobic oxidation of methane (AOM). Despite extensive research on MDAC from present-day seafloors and outcrops, understanding methane migration footprints from subsurface rock samples remains limited. Therefore, this study aims to investigate methane migration footprints from subsurface rock samples taken from a proven area of gas migration. This study utilized cutting samples from well XS-01 located in the Makassar Strait, offshore Indonesia. The well was drilled through a gas chimney into Oligocene carbonate reservoirs hosting a substantial methane column (102 m). Analysis of 44 cutting samples involved petrographic examination, Scanning Electron Microscope (SEM) imaging, and X-ray Diffraction (XRD) analysis to discern mineralogical content and diagenetic features signaling the presence of gas. A diagenetic texture called clotted peloidal micrite (CPM) was discovered within foraminifera fossils and around fractures based on petrographic analysis. CPM is a type of MDAC and predominantly occurs in fine-grained, siliciclastic rocks, indicating gas migration. This migration is interpreted to occur: (i) during the early burial stages originating from microbial activity since the Oligocene (biogenic gas); (ii) following matured source rock that reached its peak maturity from the Middle Eocene to the Pliocene (thermogenic gas); or (iii) interference of these two processes. The migration route persists until present day as evidenced by gas chimney and seabed pockmarks identified in seismic reflection data. This study emphasizes the importance of subsurface rock samples, such as cuttings, in uncovering gas migration footprints. Especially, where seismic data is unavailable or could not image fluid flow features. In addition, this study also provides a new perspective on diagenesis along methane migration route, complementing most of the research that is primarily focused on reservoir diagenesis.
甲烷渗漏普遍存在于全球海洋盆地,表明甲烷从地下向上迁移,在地震反射数据中通常表现为气体烟囱。甲烷迁移的足迹通常由甲烷衍生的自生碳酸盐(MDAC)表明,MDAC 是甲烷厌氧氧化(AOM)的产物。尽管对现今海床和露头的 MDAC 进行了广泛研究,但对地下岩石样本中甲烷迁移足迹的了解仍然有限。因此,本研究旨在调查从已证实的天然气迁移区域采集的地下岩石样本中的甲烷迁移足迹。本研究利用了位于印度尼西亚近海望加锡海峡的 XS-01 井的切割样本。这口井是通过一个天然气烟囱钻进的,钻进的是新近纪碳酸盐岩储层,其中有大量甲烷柱(102 米)。对 44 个切割样本的分析包括岩相学检查、扫描电子显微镜 (SEM) 成像和 X 射线衍射 (XRD) 分析,以辨别矿物含量和成岩特征,这预示着天然气的存在。根据岩相学分析,在有孔虫化石内部和裂缝周围发现了一种成岩质地,称为凝块球状微晶岩(CPM)。CPM 是 MDAC 的一种,主要出现在细粒硅质岩中,表明气体迁移。据解释,这种迁移发生在(i) 自渐新世以来的早期埋藏阶段,源于微生物活动(生物成因气体);(ii) 在中始新世至上新世达到顶峰的成熟源岩之后(热成因气体);或 (iii) 这两个过程的干扰。从地震反射数据中发现的天然气烟囱和海底麻点可以证明,迁移路线一直持续到今天。这项研究强调了地下岩石样本(如岩屑)在揭示天然气迁移足迹方面的重要性。尤其是在地震数据不可用或无法对流体流动特征进行成像的情况下。此外,这项研究还为甲烷迁移路线上的成岩作用提供了一个新的视角,补充了大部分主要关注储层成岩作用的研究。
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引用次数: 0
Genetic mechanism and main controlling factors of deep marine condensate reservoirs: A case study of the Shunbei No.4 fault zone in Tarim Basin, NW China 深部海洋凝析气藏的成因机理及主要控制因素:中国西北部塔里木盆地顺北 4 号断裂带案例研究
Pub Date : 2024-10-01 DOI: 10.1016/j.jnggs.2024.09.002
Weilong Peng , Shang Deng , Jibiao Zhang , Cheng Huang , Huabiao Qiu , Yingtao Li , Yuqing Liu , Dawei Liu
Typical condensate reservoirs have been developed in the No.4 fault zone of the Shunbei area in the Tarim Basin. However, exploration expansion is restricted due to the unclear genetic mechanisms and main controlling factors of condensate accumulation. Through a comprehensive analysis of organic geochemical characteristics and the regional geological background, the genetic mechanisms and main controlling factors of condensate accumulation in the No.4 fault zone of the Shunbei area have been identified, and the following understandings are mainly obtained: (1) the condensate oil and gas reservoirs in the No.4 fault zone of the Shunbei area are mainly primary condensate reservoirs, and their formation is mainly affected by differential maturation of organic matter, multi-phase accumulation, and secondary alteration; (2) the overall secondary effects on the condensate oil and gas reservoirs in the Shunbei No.4 fault zone are relatively weak, however, the secondary effect experienced by the middle and southern sections is relatively stronger compared to the northern section; these secondary processes include oil cracking, gas invasion, and thermochemical sulfate reduction (TSR); and (3) the enrichment degree of condensate oil and gas reservoirs in the northern section of the Shunbei No.4 fault zone is significantly higher than in the middle and southern sections; the enrichment and high production of condensate oil and gas are mainly controlled by transport conditions and reservoir scale. Stronger fault activity, better transport conditions, larger reservoir size, and thinner gypsum-salt rock layers facilitate the upward migration of oil and gas along strike-slip faults, leading to higher production and enrichment of condensate.
塔里木盆地顺北 4 号断裂带已开发出典型的凝析油藏。然而,由于凝析油积聚的成因机制和主要控制因素尚不明确,勘探拓展受到限制。通过对有机地球化学特征和区域地质背景的综合分析,查明了顺北 4 号断裂带凝析油积聚的成因机理和主要控制因素,主要认识如下1)顺北 4 号断裂带凝析油气藏以原生凝析油气藏为主,其形成主要受有机质差异熟 化、多相堆积和次生蚀变的影响;(2)顺北 4 号断裂带凝析油气藏总体次生影响相对较弱, 但其形成主要受有机质差异熟化、多相堆积和次生蚀变的影响。(3) 顺北 4 号断裂带北段凝析油气藏的富集程度明显高于中段和南段,凝析油气的富集和高产主要受运移条件和储层规模的控制。断层活动较强,运移条件较好,储层规模较大,石膏盐岩层较薄,有利于油气沿走向滑动断层上移,导致凝析油产量和富集度较高。
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引用次数: 0
Differences in gas sources of the Changxing–Feixianguan formations around the Kaijiang-Liangping Trough and favorable exploration directions for coal-formed gas generated by the Upper Permian Longtan Formation, Sichuan Basin, China 中国四川盆地开江-梁平海槽周边长兴-飞仙关地层的气源差异及上二叠统龙潭地层煤成气的有利勘探方向
Pub Date : 2024-10-01 DOI: 10.1016/j.jnggs.2024.09.001
Shipeng Huang , Zhenyu Zhao , Ai Yue , Hua Jiang , Xingwang Tian , Qingchun Jiang , Debo Ma , Wei Song , Haijing Song
Through the analysis of natural gas composition, carbon and hydrogen isotopes of alkane gases, reservoir bitumen, source rock conditions, and source–reservoir combinations, this study clarifies the differences in gas sources and the origins of natural gas in the Permian Changxing Formation–Triassic Feixianguan Formation on both sides of the Kaijiang–Liangping Trough. Additionally, it identifies favorable exploration directions for coal-formed gas generated by the Longtan Formation in the Sichuan Basin. The following understanding was obtained: (1) The natural gas in the Changxing–Feixianguan formations mainly composed of alkane gas, typical of dry gas. (2) The carbon isotope values of methane and ethane in the Changxing–Feixianguan formations on the east side of the trough are lower than those on the west side. Specifically, the ethane carbon isotope value in the Longgang Gas Field on the west side is higher than that in the Yuanba Gas Field, while the methane hydrogen isotope value is lower in the Longgang Gas Field compared to the Yuanba Gas Field. (3) The natural gas in the Dongyuezhai, Puguang, and Yuanba gas fields predominantly originates from sapropelic organic matter of the Wujiaping Formation, with kerogen types II1–I; in contrast, the Longgang Gas Field contains a mixture of coal-formed gas and oil-type gas, with a slightly higher content of coal-formed gas, originating from mixed organic matter of the Wujiaping Formation, with kerogen type II1–II2. (4) Multiple types of gas, such as coal rock gas, tight sandstone gas, and shale gas, can be formed within the Longtan Formation. The Suining–Luzhou and Langzhong–Guang'an–Fuling areas are identified as favorable zones for the exploration of coal rock gas and marine–continental transitional shale gas, respectively. Additionally, the reef and shoal development areas of the Changxing Formation in the Suining–Hechuan and Guang'an–Nanchong regions are also favorable exploration areas for coal-formed gas.
该研究通过对天然气成分、烷烃气体碳氢同位素、储层沥青、源岩条件、源-储层组合等方面的分析,明确了开江-梁平海槽两侧二叠系长兴层-三叠系飞仙关层的气源差异和天然气成因。此外,还确定了四川盆地龙滩地层煤成气的有利勘探方向。取得了以下认识:(1)长兴-飞仙关地层中的天然气主要由烷烃气组成,是典型的干气。(2)槽东侧长兴-飞仙关地层中甲烷和乙烷的碳同位素值低于槽西侧地层。具体来说,西侧龙岗气田的乙烷碳同位素值高于元坝气田,而龙岗气田的甲烷氢同位素值低于元坝气田。(3)东岳寨气田、普光气田和元坝气田的天然气主要来源于吴家坪地层的溶岩型有机质,角质类型为Ⅱ1-Ⅰ型;而龙岗气田含有煤成气和油气混合气,煤成气含量略高,来源于吴家坪地层的混合有机质,角质类型为Ⅱ1-Ⅱ2型。(4)龙潭地层内可形成煤岩气、致密砂岩气、页岩气等多种类型的天然气。遂宁-泸州和阆中-广安-涪陵地区分别被确定为煤岩气和海相大陆过渡页岩气的有利勘探区。此外,遂宁-合川和广安-南充地区长兴地层的礁石和滩涂发育区也是煤成气的有利勘探区。
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引用次数: 0
Natural gas accumulation conditions and exploration directions of Carboniferous clastic rocks in the northeastern margin of Junggar Basin, China 中国准噶尔盆地东北缘石炭系碎屑岩天然气赋存条件及勘探方向
Pub Date : 2024-10-01 DOI: 10.1016/j.jnggs.2024.09.004
Yanzhao Wei , Abulimiti Yiming , Weian Wu , Aicheng Wu , Fan Yang , Chaowei Liu , Zesheng Wang , Boyu Zhou
The Carboniferous strata in the northeastern Junggar Basin are an important exploration field for natural gas in the basin. However, volcanic rocks have long been the primary exploration target. In contrast, the exploration and research of clastic rocks associated with source formations have been largely overlooked, resulting in an insufficient understanding of the reservoir forming conditions and exploration potential of Carboniferous clastic rocks. Through the evaluation of Carboniferous source rocks, effective source stove characterization, clastic reservoir evaluation, oil and gas source correlation, and reservoir formation model construction in this region, three key findings have been made. First, the Carboniferous in the northeastern Junggar Basin has developed three sets of high-quality gas source rocks: the Dishuiquan Formation, the Songkalsu B Member, and the Shiqiantan Formation. These formations correspond to three hydrocarbon source centers: the Sannan–Dishuiquan Sag, the Wucaiwan Sag–Dajing area, and the Dongdao Haizi Sag–Baijiahai High. Second, the Carboniferous system in the northeast has developed multiple types of large-scale reservoirs, including sand conglomerates, sandstones, turbidites, dolomitic rocks, and shale. These reservoirs are generally characterized by low porosity to ultra-low porosity and low permeability to ultra-low permeability reservoirs. There is a dissolution pore development zone at depths of 2900–4500 m. Third, a comparison of oil and gas sources reveals that all three sets of gas source rocks contribute to the natural gas found in the northeast, with obvious characteristics of near-source reservoir formation. The Carboniferous clastic rocks host two types of natural gas reservoirs: unconventional and conventional near-source reservoirs. It is predicted that there is an orderly accumulation pattern of shale gas, tight sandstone gas, and conventional natural gas reservoirs. This study reveals that the Carboniferous clastic rock source and reservoir configuration in the northeastern Junggar Basin is highly favorable, and the natural gas reservoirs in source and near-source clastic rocks represent important exploration directions.
准噶尔盆地东北部的石炭纪地层是该盆地重要的天然气勘探区。但长期以来,火山岩一直是主要的勘探目标。相比之下,与源地层相关的碎屑岩的勘探和研究却在很大程度上被忽视,导致人们对石炭纪碎屑岩的储层形成条件和勘探潜力认识不足。通过对该地区石炭纪源岩的评价、有效的源炉特征描述、碎屑岩储层评价、油气源相关性研究和储层形成模型构建,取得了三项重要发现。首先,准噶尔盆地东北部石炭系发育了三套优质气源岩:滴水泉地层、松卡尔苏B层和石阡滩地层。这些地层分别对应着三个油气源中心:三南-滴水泉地层、五彩湾地层-大井地区、东道海子地层-白家海高地。其次,东北石炭系发育了多种类型的大型储层,包括砂砾岩、砂岩、浊积岩、白云质岩和页岩。这些储层一般具有低孔隙度到超低孔隙度、低渗透率到超低渗透率储层的特征。第三,通过油气源对比发现,三组气源岩都对东北部发现的天然气有贡献,具有明显的近源成藏特征。石炭纪碎屑岩蕴藏着两种类型的天然气储层:非常规储层和常规近源储层。据预测,页岩气、致密砂岩气和常规天然气储层存在有序的聚集模式。该研究揭示了准噶尔盆地东北部石炭系碎屑岩岩源和储层构造的有利条件,岩源和近源碎屑岩天然气储层是重要的勘探方向。
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引用次数: 0
Helium resource and play classification systems, effective reservoir control elements, and enrichment patterns in China 中国的氦资源和氦游戏分类系统、有效的储层控制要素和富集模式
Pub Date : 2024-08-01 DOI: 10.1016/j.jnggs.2024.08.002
Shizhen Tao, Yue Chen, Yiqing Yang

The classification system, effective reservoir control elements, and major enrichment and exploration modes of helium resources in China are analyzed based on the source of helium, carrier, geological background, and anatomy of typical helium-rich fields. Firstly, based on the special characteristics of helium and the correlation analysis of natural gas accumulation and reservoir formation, we analyzed and sorted out the helium resource and play type classification scheme and classification system in China from nine aspects, namely, the source of helium parental sources, helium type diversities, the storage and carrier types, the technically and economically recoverable characteristics of carrier gases, the carrier gas genesis, the main components of carrier gases, the matching combination of helium sources and reservoirs, background of prototype basin structure, and helium content, to lay the foundation for the subsequent targeted and detailed studies and evaluation programs in different categories. Secondly, the analysis points out the characteristics of helium resource types in the east, middle, and west of China in terms of longitudinal and transverse distribution, tectonic dynamics, geological and geochemical characteristics, and key conditions for the formation of helium deposits. Thirdly, from the perspective of the helium “generation-migration-accumulation” system and the controlling elements and effectiveness of helium-rich reservoir formation, we analyze the effective controlling elements of helium accumulation and the related problems that deserve attention in geological evaluation and point out the misunderstandings in helium reservoir formation and exploration evaluation. Last but not least, from the perspective of basin tectonic background, helium enrichment controlling mechanism and exploration direction, the exploration and evaluation direction and classification scheme for the four element combination zones of “original basin–structure–lithology–carrier gas” helium accumulation in China have been proposed, based on which, four types of basins and eight types of helium-rich zones in China have been sorted out. In these eight types of helium-rich zones, eight typical helium-rich field enrichment and exploration patterns, including the ancient uplift type of China's craton, fracture-fold variant of the craton margin, fracture-rise type of depression basin, slope bulge and uplift type of foreland basin, fracture-convex type of fracture basin, and U/Th-rich basement type of basin were analyzed, and the main controlling factors of the formation of different types of helium-rich deposits were analyzed, which will provide a reference for the subsequent exploration and discovery of similar helium-rich areas and exploration target evaluation.

从氦气的来源、载体、地质背景、典型富氦气田解剖等方面,分析了中国氦气资源的分类体系、储层有效控制要素、主要富集勘探模式。首先,基于氦气的特殊性和天然气积聚与成藏的相关性分析,从氦气母源、氦气类型多样性、储藏类型和载体类型等九个方面,分析梳理了我国氦气资源及赋存类型划分方案和分类体系、载气的技术经济可采特征、载气成因、载气的主要成分、氦源与储层的匹配组合、盆地结构原型背景、氦含量等九个方面,为后续有针对性地开展不同类别的详细研究和评价方案奠定基础。其次,分析指出了我国东、中、西部氦资源类型的纵横向分布特征、构造动力学特征、地质地球化学特征以及氦矿床形成的关键条件。再次,从氦气 "生成-迁移-富集 "系统和富氦储层形成的控制要素及有效性角度,分析了氦气富集的有效控制要素和地质评价中值得关注的相关问题,指出了氦储层形成和勘探评价中存在的误区。最后,从盆地构造背景、富氦控制机理和勘探方向等方面,提出了中国 "原始盆地-构造-岩性-载气 "氦气聚集四要素组合带的勘探评价方向和分类方案,并据此梳理出中国四类盆地和八类富氦带。在这八种类型的富氦带中,有八种典型的富氦田富集和勘探模式,包括中国古代克拉通隆起型、克拉通边缘断裂-褶皱变型、断裂-隆起型凹陷盆地、斜坡隆起-隆起型前陆盆地、断裂-凸起型断裂盆地、U/Th-富集基底型、U/Th-富集基底型、U/Th-富集基底型、U/Th-富集基底型、U/Th-富集基底型、U/Th-富集基底型、分析了不同类型富氦矿床形成的主要控制因素,为后续类似富氦地区的勘探发现和勘探目标评价提供了参考。
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引用次数: 0
Geochemical evaluation of Sarvak oil reservoir using biomarkers, carbon isotope and trace element: A case study from Southwest Iran 利用生物标记、碳同位素和微量元素对 Sarvak 油藏进行地球化学评估:伊朗西南部案例研究
Pub Date : 2024-08-01 DOI: 10.1016/j.jnggs.2024.06.001
Soheila Bagheri, Maryam Pourbagher, Mohsen Shourab

The crude oils of the Sarvak reservoir were studied by integrated geochemical, inorganic and isotopic analyses to evaluate the origin, depositional conditions, geological age, thermal maturity of the source rocks and possible facies from which these oils were sourced. This study provides new insights into the Middle-Jurassic age source rock in the Azar Oilfield. This is the first geochemical study in Azar Oilfield where non-biomarker parameters and biomarker parameters were utilized to achieve the objectives. The n-alkane distribution pattern along with their standard ratios, including CPI (0.83–1.03), TAR (0.18–0.29) and isoprenoids (Pr/Ph, 0.52–0.65) as well as pristane/n-C17 versus phytane/n-C18 cross-plot indicate a marine source of the organic matter deposited in an anoxic condition. The sterane parameters such as C27 and C29 are characterized by the predominance of C27ααα-20R steranes (41%–49%) and also depict the algal source of organic matter. The organic input and facies of the source units were also determined by terpanes C29/C30H, Ts/Tm, C35/C34-HH, and DBT/Phen. The relatively high ratio of C29/C30H along with the ratios of Ts/Tm (<0.5) and C35/C34 (>0.8) reflect the carbonate marine facies of the source rocks. Furthermore, the higher values of the homohopane index (>0.1) along with the low ratio of the gammacerane/C30-H (0.06–0.22) as well as the high ratio of V/Ni (>1) further indicate anoxic environments. The dibenzothiophene/phenanthrene ratios of the oil samples (from 2.43 to 3.25) indicate the marine carbonates/marl zone. This genetic classification is also supported by stable carbon isotopic compositions (δ1³C). Most of the maturity-related biomarkers and non-biomarker parameters such as CPI, steranes-C29S/(S + R), ββ/(αα+ββ), moretane to hopane (M29/C30H), pentacyclic terpanes C27Ts/(Ts + Tm), C32-S/(S + R) hopanes, and methyl phenanthrene index agree that the analyzed oils have originated from mature source rocks. Ultimately, this study has demonstrated that analyses of biomarkers and their stable isotope compositions (δ13C and δ34S) complemented with trace element data provide an excellent novel tool for better understanding the basic concepts in petroleum basins and for solving a wide range of problems during petroleum exploration.

通过综合地球化学、无机和同位素分析,对 Sarvak 储层的原油进行了研究,以评估这些原油的来源、沉积条件、地质年龄、源岩的热成熟度以及可能的油层。这项研究为了解阿扎尔油田的中侏罗纪源岩提供了新的视角。这是阿扎尔油田首次利用非生物标志物参数和生物标志物参数来实现目标的地球化学研究。正构烷烃的分布模式及其标准比率,包括 CPI(0.83-1.03)、TAR(0.18-0.29)和异戊烷(Pr/Ph,0.52-0.65),以及pristane/n-C17 与 phytane/n-C18 的交叉图,表明有机质沉积于缺氧条件下的海洋来源。C27 和 C29 等甾烷参数的特点是以 C27ααα-20R 甾烷为主(41%-49%),这也说明了有机物的藻类来源。源单元的有机输入和面貌也是通过萜类 C29/C30H、Ts/Tm、C35/C34-HH 和 DBT/Phen 确定的。相对较高的 C29/C30H 比值以及 Ts/Tm 比值(0.5)和 C35/C34 比值(0.8)反映了源岩的碳酸盐海洋面貌。此外,较高的均相指数值(0.1)、较低的伽马塞烷/C30-H 比率(0.06-0.22)以及较高的 V/Ni 比率(1)进一步表明了缺氧环境。油类样本的二苯并噻吩/菲比率(从 2.43 到 3.25)表明属于海洋碳酸盐/泥浆区。稳定的碳同位素组成(δ1³C)也支持这种基因分类。大多数与成熟度相关的生物标志物和非生物标志物参数,如 CPI、甾烷-C29S/(S + R)、β/(αα+ββ)、戊烷到庚烷(M29/C30H)、五环萜烷 C27Ts/(Ts + Tm)、C32-S/(S + R)庚烷和甲基菲指数,都表明所分析的油类源自成熟的源岩。这项研究最终证明,生物标志物及其稳定同位素组成(δ13C 和 δ34S)分析与痕量元素数据互补,为更好地理解石油盆地的基本概念和解决石油勘探过程中的各种问题提供了一个极好的新工具。
{"title":"Geochemical evaluation of Sarvak oil reservoir using biomarkers, carbon isotope and trace element: A case study from Southwest Iran","authors":"Soheila Bagheri,&nbsp;Maryam Pourbagher,&nbsp;Mohsen Shourab","doi":"10.1016/j.jnggs.2024.06.001","DOIUrl":"10.1016/j.jnggs.2024.06.001","url":null,"abstract":"<div><p>The crude oils of the Sarvak reservoir were studied by integrated geochemical, inorganic and isotopic analyses to evaluate the origin, depositional conditions, geological age, thermal maturity of the source rocks and possible facies from which these oils were sourced. This study provides new insights into the Middle-Jurassic age source rock in the Azar Oilfield. This is the first geochemical study in Azar Oilfield where non-biomarker parameters and biomarker parameters were utilized to achieve the objectives. The <em>n</em>-alkane distribution pattern along with their standard ratios, including CPI (0.83–1.03), TAR (0.18–0.29) and isoprenoids (Pr/Ph, 0.52–0.65) as well as pristane/<em>n</em>-C<sub>17</sub> versus phytane/<em>n</em>-C<sub>18</sub> cross-plot indicate a marine source of the organic matter deposited in an anoxic condition. The sterane parameters such as C<sub>27</sub> and C<sub>29</sub> are characterized by the predominance of C<sub>27</sub>ααα-20R steranes (41%–49%) and also depict the algal source of organic matter. The organic input and facies of the source units were also determined by terpanes C<sub>29</sub>/C<sub>30</sub>H, Ts/Tm, C<sub>35</sub>/C<sub>34</sub>-HH, and DBT/Phen. The relatively high ratio of C<sub>29</sub>/C<sub>30</sub>H along with the ratios of Ts/Tm (&lt;0.5) and C<sub>35</sub>/C<sub>34</sub> (&gt;0.8) reflect the carbonate marine facies of the source rocks. Furthermore, the higher values of the homohopane index (&gt;0.1) along with the low ratio of the gammacerane/C<sub>30</sub>-H (0.06–0.22) as well as the high ratio of V/Ni (&gt;1) further indicate anoxic environments. The dibenzothiophene/phenanthrene ratios of the oil samples (from 2.43 to 3.25) indicate the marine carbonates/marl zone. This genetic classification is also supported by stable carbon isotopic compositions (<em>δ</em><sup>1</sup>³C). Most of the maturity-related biomarkers and non-biomarker parameters such as CPI, steranes-C<sub>29</sub>S/(S + R), ββ/(αα+ββ), moretane to hopane (M<sub>29</sub>/C<sub>30</sub>H), pentacyclic terpanes C<sub>27</sub>Ts/(Ts + Tm), C<sub>32</sub>-S/(S + R) hopanes, and methyl phenanthrene index agree that the analyzed oils have originated from mature source rocks. Ultimately, this study has demonstrated that analyses of biomarkers and their stable isotope compositions (<em>δ</em><sup>13</sup>C and <em>δ</em><sup>34</sup>S) complemented with trace element data provide an excellent novel tool for better understanding the basic concepts in petroleum basins and for solving a wide range of problems during petroleum exploration.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":"9 4","pages":"Pages 281-302"},"PeriodicalIF":0.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000373/pdfft?md5=ffe12e8fa53b19e9d993b8fb2eecb97e&pid=1-s2.0-S2468256X24000373-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Helium content and helium enrichment conditions of coalbed methane and shale gas 煤层气和页岩气的氦含量和氦富集条件
Pub Date : 2024-08-01 DOI: 10.1016/j.jnggs.2024.07.001
Shengfei Qin , Zizhuo Zhao , Wei Wu , Guoxiao Zhou , Gang Tao , Jiyuan Li

Aiming to address whether coal-bed methane and shale gas can form helium-rich gas reservoirs, this paper employs geochemical research methods to analyze the content of uranium (U) and thorium (Th) in coal and shale, as well as the helium content in coal-bed and shale gas reservoirs. An objective evaluation of the helium-generating potential and helium-bearing properties of coal and shale is provided. It is observed that although the content of U and Th in coal and shale is significantly higher than in other rocks, resulting in relatively more helium production from radioactive decay, the large amount of natural gas generated by coal and shale exerts a serious dilution effect on helium, making it difficult for coal beds and shale to enrich helium. The organic carbon content of coal is much higher than that of shale, leading to a greater generation of natural gas from coal beds compared to shale. Consequently, the helium content of coal-bed gas is much lower than that of shale gas. The helium rich shale gas and coal bed gas found in a few areas are attributed to the helium supply from other rocks in the gas reservoir, which is mostly distributed on or near the old granite masses, or in the tectonic active zones. In addition to capturing some of the helium produced by the coal beds and shales themselves, helium from other rocks, particularly from ancient basement rocks, is also captured, though this is not common.

针对煤层气和页岩气能否形成富氦气藏的问题,本文采用地球化学研究方法,分析了煤和页岩中铀(U)和钍(Th)的含量,以及煤层气和页岩气藏中氦的含量。对煤和页岩的氦生成潜力和含氦特性进行了客观评价。研究发现,虽然煤和页岩中铀和钍的含量明显高于其他岩石,放射性衰变产生的氦相对较多,但煤和页岩产生的大量天然气对氦产生了严重的稀释作用,使煤层和页岩难以富集氦。煤的有机碳含量远高于页岩,导致煤层产生的天然气比页岩多。因此,煤层气的氦含量远低于页岩气。在少数地区发现的富氦页岩气和煤层气是由于气藏中其他岩石的氦气供应造成的,这些岩石大多分布在古老的花岗岩体上或附近,或在构造活跃地带。除了捕获煤层和页岩本身产生的部分氦气外,还捕获来自其他岩石,特别是来自古老基底岩石的氦气,不过这种情况并不常见。
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引用次数: 0
Hydrocarbon-generating potential of the Middle Permian Lucaogou source rock in the eastern Junggar Basin, China 中国准噶尔盆地东部中二叠统卢卡沟源岩的碳氢化合物生成潜力
Pub Date : 2024-08-01 DOI: 10.1016/j.jnggs.2024.07.002
Deyu Gong , Yihao Miao , Xuan Chen , Hongguang Gou , Tong Lin , Di Li , Runze Yang , Yan Han

The Middle Permian Lucaogou Formation is the most significant source rock in the eastern Junggar Basin. Previous studies have confirmed its excellent hydrocarbon-generating potential in the Jimsar Sag. However, its potential in other areas of the eastern Junggar Basin remains uncertain. Based on total organic carbon and pyrolysis, organic petrology, hydrocarbon simulation experiments, basin simulation, and combined well-seismic coupling interpretation, this study systematically compares the hydrocarbon-generating potential of the Lucaogou source rock in the Jimsar Sag with other areas of the eastern Junggar Basin. It discusses the sedimentary environment of high-quality source rocks and depicts the distribution of practical source kitchens. The Lucaogou source rocks in the eastern Junggar Basin are oil-prone, dominated by type I–II kerogen, and generally classified as good to excellent source rocks. Nowadays, the area of the Lucaogou source rocks that have entered the main oil-generating window is approximately 11 × 103 km2. Except for the bulge area, the Lucaogou source rocks in the eastern Junggar Basin successively entered the hydrocarbon-generating threshold during the Jurassic and the main oil-generating window in the Cretaceous. The Lucaogou source rocks in the Jimsar Sag and other parts of the eastern Junggar Basin share similar biomarker fingerprints, characterized by relatively low ratios of Pr/Ph, Pr/n-C17, Tm/C30 hopane, C19/C20 tricyclic terpene, and C24 tetracyclic terpene/C26 tricyclic terpene, and high β-carotene content, gammacerane index, and Ts/Tm ratios. These characteristics reflect deposition in a strongly reducing brackish lacustrine environment with parental sources dominated by lower organisms such as algae and bacteria. Generally, the Lucaogou source rocks in the eastern Junggar Basin have an oil-generating intensity of more than 3 × 106 t/km2. Several oil-generating centers with an intensity of more than 5 × 106 t/km2 have developed in the front of the Bogda Mountain, Jimsar Sag, Dongdaohaizi Sag, Wucaiwan Sag, and Shazhang Fault Zone, covering a total area of approximately 12,500 km2. These characteristics of the Lucaogou source rocks promise favorable potential for forming large and medium oil fields. The results further consolidated the oil and gas resources in the eastern Junggar Basin and provided valuable references for exploring future oil and gas fields.

中二叠统卢卡沟地层是准噶尔盆地东部最重要的源岩。先前的研究已经证实,它在吉木萨尔沙格具有极佳的碳氢化合物生成潜力。然而,其在准噶尔盆地东部其他地区的潜力仍不确定。本研究基于总有机碳和热解、有机岩石学、碳氢化合物模拟实验、盆地模拟以及井震耦合解释,系统地比较了吉木萨尔沙格的卢卡沟源岩与准噶尔盆地东部其他地区的碳氢化合物生成潜力。研究讨论了优质源岩的沉积环境,并描绘了实用源岩套件的分布。准噶尔盆地东部的卢草沟源岩属于易生油岩,以I-II型角质岩为主,一般被划分为良好至极佳的源岩。目前,卢草沟源岩进入主生油窗口的面积约为 11×103 平方公里。除隆起区外,准噶尔盆地东部的卢草沟源岩先后于侏罗纪进入油气生成临界期和白垩纪进入主生油窗口期。吉木萨尔沙格和准噶尔盆地东部其他地区的卢卡沟源岩具有相似的生物标志物指纹,其特征是Pr/Ph、Pr/n-C17、Tm/C30 hopane、C19/C20三环萜烯和C24四环萜烯/C26三环萜烯的比率相对较低,而β-胡萝卜素含量、伽马塞烷指数和Ts/Tm比率较高。这些特征反映了在强还原性咸水湖环境中的沉积情况,亲本来源以藻类和细菌等低等生物为主。一般来说,准噶尔盆地东部卢卡沟源岩的产油强度超过 3 × 106 吨/平方公里。在博格达山前带、吉木萨尔下陷、东道海子下陷、五彩湾下陷和沙张断裂带上发育了多个生油强度大于 5×106 t/km2 的生油中心,总面积约 12500 平方公里。卢草沟源岩的这些特征为形成大、中型油田提供了有利条件。该成果进一步巩固了准噶尔盆地东部的油气资源,为今后勘探油气田提供了宝贵的参考依据。
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引用次数: 0
Solid bitumen Rhenium-Osmium (Re–Os) isotope geochronology and existing problems: Sampled of Sinian-Cambrian gas reservoir in Sichuan Basin, China 固体沥青铼锇(Re-Os)同位素地质年代学及存在的问题:中国四川盆地新元古代-寒武纪气藏取样
Pub Date : 2024-08-01 DOI: 10.1016/j.jnggs.2024.08.001
Xiang Ge , Shisheng Xu , Guangyou Zhu , Xinyu Chen , Yaxian Gao , Chuanbo Shen

Understanding the key timings related to petroleum evolution is crucial for optimizing exploration targets and assessing oil/gas resources, attract petroleum geologists’ attention worldwide. Recently, hydrocarbon (oil and bitumen) Re–Os isotope dating has been innovatively applied to constrain the timing related to oil/gas generation, however, the resulting Re–Os isochron ages can be complex and challenging to interpret. This study utilizes various geochemical and geochronological data from Sinian to Cambrian natural gas reservoirs in the Sichuan Basin to reconstruct the hydrocarbon evolution process and discuss the significance of different bitumen Re–Os dating results. The gas accumulation in the Sinian-Cambrian reservoirs experienced four stages of evolution: (1) initial oil generation during the Ordovician to Silurian periods, (2) secondary oil generation during the Triassic period, (3) gas generation through thermal cracking of liquid oil from the Jurassic to Cretaceous periods, and (4) gas reservoir redistribution since the late Cretaceous. The Re–Os dates (ca. 485 Ma) of low maturity and biodegraded bitumen from the western Sichuan Basin record the oil generation during the Ordovician before the Caledonian tectonic event. The Re–Os dates (ca.184–128 Ma) of highly mature bitumen associated with MVT Pb–Zn deposits in northern Sichuan Basin provide insights into both liquid oil-cracking and thermochemical sulfate reduction (TSR) processes. The complex Re–Os dates (ca.414 Ma, ca.154 Ma) of highly mature bitumen from the central Sichuan Basin may represent different periods related to either oil or gas generation. Future studies should explore the genetic type, maturity, thermal cracking, or TSR degrees of bitumen to better understand the significance of Re–Os dates.

了解与石油演化相关的关键时间对于优化勘探目标和评估石油/天然气资源至关重要,这引起了全球石油地质学家的关注。最近,碳氢化合物(石油和沥青)Re-Os 同位素年代测定被创新性地应用于制约与石油/天然气生成有关的时间,然而,由此产生的 Re-Os 等时线年龄可能很复杂,解释起来具有挑战性。本研究利用四川盆地新元古代至寒武纪天然气储层的各种地球化学和地质年代数据,重建了油气演化过程,并讨论了不同沥青Re-Os测年结果的意义。新元古代-寒武纪储层中的天然气聚集经历了四个演化阶段:(1)奥陶纪至志留纪的初始生油阶段;(2)三叠纪的二次生油阶段;(3)侏罗纪至白垩纪的液态油热裂解生气阶段;(4)白垩纪晚期以来的气藏再分布阶段。四川盆地西部低成熟生物降解沥青的 Re-Os 年代(约 485Ma)记录了加里东构造事件之前奥陶纪的石油生成过程。四川盆地北部与MVT铅锌矿床有关的高度成熟沥青的Re-Os年代(约184-128 Ma),为液态石油裂解和热化学硫酸盐还原(TSR)过程提供了启示。四川盆地中部高度成熟沥青的复杂Re-Os年代(约414Ma,约154Ma)可能代表了与石油或天然气生成有关的不同时期。未来的研究应探索沥青的基因类型、成熟度、热裂解或 TSR 程度,以更好地理解 Re-Os 日期的意义。
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引用次数: 0
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Journal of Natural Gas Geoscience
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