首页 > 最新文献

MetalMat最新文献

英文 中文
Cover 封面
Pub Date : 2024-07-30 DOI: 10.1002/metm.26

{"title":"Cover","authors":"","doi":"10.1002/metm.26","DOIUrl":"https://doi.org/10.1002/metm.26","url":null,"abstract":"<p>\u0000 \u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.26","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141968333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Table of Content 目录
Pub Date : 2024-07-30 DOI: 10.1002/metm.27

No abstract is available for this article.

本文无摘要。
{"title":"Table of Content","authors":"","doi":"10.1002/metm.27","DOIUrl":"https://doi.org/10.1002/metm.27","url":null,"abstract":"<p>No abstract is available for this article.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.27","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141966493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MetalMat: Unveiling the transformative power of metals in science and technology 金属垫:揭示金属在科技领域的变革力量
Pub Date : 2024-07-21 DOI: 10.1002/metm.25
Elena Pereloma, Jun Sun

Since the dawn of civilization, metals have been integral to the fabric of modern society, shaping our technological landscape, and driving innovation across diverse industries. The intrinsic allure of metals lies in their versatility, strength, and adaptability, qualities that have propelled humanity towards new frontiers of scientific discovery and technological advancement. As we embark on this groundbreaking journey with MetalMat, the premier Wiley open access journal dedicated to metals in science and technology, we celebrate the enduring legacy and transformative potential of these remarkable materials.

At the core of MetalMat's mission lies a fundamental drive to deepen our understanding of the atomic and microstructural intricacies of metals, paving the way for the design of cutting-edge alloys with advanced properties tailored for specific applications. This prestigious publication is poised to explore the pivotal function of materials in advancing society, with a keen focus on addressing pressing global challenges such as climate change, sustainability, and other critical issues that define our present and shape our future.

MetalMat stands as a beacon of excellence, providing a platform for cutting-edge scientific and engineering research on both structural and functional metallic materials. The journal's scope encompasses a wide array of topics, ranging from the design, processing, and characterization of metals, alloys, intermetallics, and metal-matrix composites/compounds to the diverse applications of functional metallic materials in interdisciplinary research domains.

As the first Wiley open access journal dedicated to metal-related topics, MetalMat is poised to revolutionize the field by fostering a vibrant exchange of ideas and discoveries among researchers, scientists, and experts from around the world. With unwavering support from the international research community, MetalMat has assembled a stellar team of experts representing a diverse array of countries, including Australia, China, Belgium, Brazil, Chile, Germany, Japan, Singapore, UK, and the USA. This esteemed editorial board ensures that MetalMat not only pushes the boundaries of materials science but also serves as a guiding light, shaping the future of metallic materials research and fostering global collaboration.

One of the hallmarks of MetalMat is its commitment to an open-access publication model, which ensures that all published articles are freely accessible to a global audience. The journal's dedicated editorial team maintains an efficient review process, with an average turnaround time of approximately 1 month, to ensure the timely dissemination of cutting-edge research in the field. MetalMat welcomes a diverse range of contributions, including original research articles, comprehensive reviews, insightful perspectives, and short communications, all of which contribute to the vibrant tapestry of knowledge in this dynamic field.

A

自人类文明诞生以来,金属一直是现代社会不可或缺的组成部分,它塑造了我们的技术面貌,并推动着各行各业的创新。金属的内在魅力在于其多功能性、强度和适应性,这些特质推动人类迈向科学发现和技术进步的新领域。金属导报》是威利出版的一本以金属为主题的开放式科技期刊,当我们与《金属导报》一起踏上这条开创性的征程时,我们为这些非凡材料的永恒遗产和变革潜力而欢呼。《金属导报》的核心使命在于从根本上加深我们对金属原子和微观结构复杂性的理解,为设计出具有先进性能、适合特定应用的尖端合金铺平道路。这本享有盛誉的刊物将致力于探索材料在推动社会进步方面的关键作用,重点关注应对气候变化、可持续发展等紧迫的全球性挑战,以及其他决定我们现在和未来的关键问题。MetalMat 是卓越的灯塔,为有关金属结构和功能材料的前沿科学和工程研究提供了一个平台。MetalMat 是一盏卓越的明灯,为结构和功能金属材料方面的前沿科学和工程研究提供了一个平台。该期刊的范围涵盖了从金属、合金、金属间化合物和金属基复合材料/化合物的设计、加工和表征到功能金属材料在跨学科研究领域的各种应用等一系列广泛的主题。在国际研究界的坚定支持下,《金属导报》组建了一支由来自澳大利亚、中国、比利时、巴西、智利、德国、日本、新加坡、英国和美国等不同国家的专家组成的明星团队。这个备受推崇的编辑委员会确保《金属材料学报》不仅能推动材料科学的发展,而且还能作为一盏指路明灯,塑造金属材料研究的未来并促进全球合作。《金属材料学报》的标志之一是其对开放获取出版模式的承诺,该模式确保全球读者都能免费获取所有发表的文章。该期刊的专业编辑团队保持着高效的审稿流程,平均审稿周期约为 1 个月,以确保及时传播该领域的前沿研究成果。MetalMat 欢迎多样化的投稿,包括原创研究文章、综合评论、独到见解和简短通讯,所有这些都有助于丰富这一充满活力的领域的知识。作为《金属导报》的主编,我们非常自豪和荣幸地欢迎您阅读我们的创刊号。这具有里程碑式的意义,标志着科技领域金属探索新篇章的开始。通过《金属导报》,我们旨在激励合作,激发创新,推动材料科学领域的进步,塑造一个金属在塑造我们的世界中继续发挥关键作用的未来。欢迎来到《金属导报》,在这里,金属的光辉与科学技术的前沿交汇在一起,在这里,可能性是无限的,就像这些非凡材料的无穷潜力一样。
{"title":"MetalMat: Unveiling the transformative power of metals in science and technology","authors":"Elena Pereloma,&nbsp;Jun Sun","doi":"10.1002/metm.25","DOIUrl":"10.1002/metm.25","url":null,"abstract":"<p>Since the dawn of civilization, metals have been integral to the fabric of modern society, shaping our technological landscape, and driving innovation across diverse industries. The intrinsic allure of metals lies in their versatility, strength, and adaptability, qualities that have propelled humanity towards new frontiers of scientific discovery and technological advancement. As we embark on this groundbreaking journey with MetalMat, the premier Wiley open access journal dedicated to metals in science and technology, we celebrate the enduring legacy and transformative potential of these remarkable materials.</p><p>At the core of MetalMat's mission lies a fundamental drive to deepen our understanding of the atomic and microstructural intricacies of metals, paving the way for the design of cutting-edge alloys with advanced properties tailored for specific applications. This prestigious publication is poised to explore the pivotal function of materials in advancing society, with a keen focus on addressing pressing global challenges such as climate change, sustainability, and other critical issues that define our present and shape our future.</p><p>MetalMat stands as a beacon of excellence, providing a platform for cutting-edge scientific and engineering research on both structural and functional metallic materials. The journal's scope encompasses a wide array of topics, ranging from the design, processing, and characterization of metals, alloys, intermetallics, and metal-matrix composites/compounds to the diverse applications of functional metallic materials in interdisciplinary research domains.</p><p>As the first Wiley open access journal dedicated to metal-related topics, MetalMat is poised to revolutionize the field by fostering a vibrant exchange of ideas and discoveries among researchers, scientists, and experts from around the world. With unwavering support from the international research community, MetalMat has assembled a stellar team of experts representing a diverse array of countries, including Australia, China, Belgium, Brazil, Chile, Germany, Japan, Singapore, UK, and the USA. This esteemed editorial board ensures that MetalMat not only pushes the boundaries of materials science but also serves as a guiding light, shaping the future of metallic materials research and fostering global collaboration.</p><p>One of the hallmarks of MetalMat is its commitment to an open-access publication model, which ensures that all published articles are freely accessible to a global audience. The journal's dedicated editorial team maintains an efficient review process, with an average turnaround time of approximately 1 month, to ensure the timely dissemination of cutting-edge research in the field. MetalMat welcomes a diverse range of contributions, including original research articles, comprehensive reviews, insightful perspectives, and short communications, all of which contribute to the vibrant tapestry of knowledge in this dynamic field.</p><p>A","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.25","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141819230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on realizing rechargeable batteries based on SOCl2/SO2 electrolyte systems 基于 SOCl2/SO2 电解质系统实现可充电电池的综述
Pub Date : 2024-05-08 DOI: 10.1002/metm.19
Xiangyu Gao, Guodong Chen, Jinran Sun, Shanmu Dong, Guanglei Cui
As representative high‐energy density primary batteries, Li‐SOCl2 and Li‐SO2 batteries possess superiorities including high working potential, long temperature range, low self‐discharge rate and high safety compared with other conventional primary batteries. In spite of the high energy features, these devices have only been applied for single discharge rather than achieved energy cyclic utilization via recharge. Various modifying strategies have been put out concerning the two electrolyte systems to liberate theoretical energy storage capability as much as possible over decades. Nevertheless, reversible chemistry is also urgently required nowadays for these sulfur‐based electrolyte primary batteries to achieve transformation and upgrading. In the review, we collect some of the modification works for Li‐SOCl2 and Li‐SO2 primary batteries since their invention and successively introduce some of the opening research studies of secondary batteries, designed technologies of which are demonstrated through aspects through anode interface, cathode materials, and electrolyte composition. Finally, it is aiming to look further into the future development of the reversibility of the unique electrolyte systems.
作为高能量密度原电池的代表,Li-SOCl2 和 Li-SO2 电池与其他传统原电池相比,具有工作电势高、温度范围长、自放电率低和安全性高等优点。尽管具有高能量的特点,但这些设备只能用于单次放电,而不能通过充电实现能量循环利用。几十年来,人们针对两种电解质系统提出了各种改进策略,以尽可能地提高理论储能能力。然而,如今这些硫基电解质原电池也迫切需要可逆化学来实现转型和升级。在这篇综述中,我们收集了锂-SOCl2 和锂-SO2 一次电池自发明以来的一些改造工作,并相继介绍了二次电池的一些开创性研究,从阳极界面、阴极材料和电解质组成等方面展示了二次电池的设计技术。最后,本研究旨在进一步探讨独特电解质系统可逆性的未来发展。
{"title":"A review on realizing rechargeable batteries based on SOCl2/SO2 electrolyte systems","authors":"Xiangyu Gao, Guodong Chen, Jinran Sun, Shanmu Dong, Guanglei Cui","doi":"10.1002/metm.19","DOIUrl":"https://doi.org/10.1002/metm.19","url":null,"abstract":"As representative high‐energy density primary batteries, Li‐SOCl2 and Li‐SO2 batteries possess superiorities including high working potential, long temperature range, low self‐discharge rate and high safety compared with other conventional primary batteries. In spite of the high energy features, these devices have only been applied for single discharge rather than achieved energy cyclic utilization via recharge. Various modifying strategies have been put out concerning the two electrolyte systems to liberate theoretical energy storage capability as much as possible over decades. Nevertheless, reversible chemistry is also urgently required nowadays for these sulfur‐based electrolyte primary batteries to achieve transformation and upgrading. In the review, we collect some of the modification works for Li‐SOCl2 and Li‐SO2 primary batteries since their invention and successively introduce some of the opening research studies of secondary batteries, designed technologies of which are demonstrated through aspects through anode interface, cathode materials, and electrolyte composition. Finally, it is aiming to look further into the future development of the reversibility of the unique electrolyte systems.","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140999938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced microstructural path modeling of primary recrystallization in aluminum alloys AA5182 and AA5657 铝合金 AA5182 和 AA5657 中原生再结晶的高级微观结构路径建模
Pub Date : 2024-03-12 DOI: 10.1002/metm.15
R. A. Vandermeer, X. C. Lei, E. F. F. Knipschildt-Okkels, F. Lin, R. E. Sanders, D. Juul Jensen

When analyzing recrystallization kinetics data, it is extremely important to use a model, which has appropriate assumptions for nucleation and growth, including spatial distribution of nuclei, nucleation rate, growth rate, and directionality. In the present work, we reveal how advanced microstructural path modeling (MPM) can successfully fit kinetics data for the complex recrystallization of two different industrial aluminum alloys. Simpler models have failed to fit the data over the entire recrystallization period. The new model allows for spatially clustered nucleation and for different growth rates in different sample directions, whereby the grains evolve with an aspect ratio different from 1. Based on the MPM analysis, the specific nucleation and growth parameters as well as the recrystallized grain sizes are deduced, and the recrystallization characteristics of the two alloys are compared. The work demonstrates the power of quantitative metallography and the wealth of recrystallization information that may be obtained from MPM modeling of such stereological data.

在分析再结晶动力学数据时,使用具有适当成核和生长假设(包括核的空间分布、成核率、生长率和方向性)的模型极为重要。在本研究中,我们揭示了先进的微结构路径建模(MPM)如何成功拟合两种不同工业铝合金复杂再结晶的动力学数据。较简单的模型无法拟合整个再结晶期的数据。基于 MPM 分析,推导出了特定的成核和生长参数以及再结晶晶粒尺寸,并对两种合金的再结晶特性进行了比较。这项工作展示了定量金相学的威力,以及通过对此类立体数据进行 MPM 建模可以获得的丰富的再结晶信息。
{"title":"Advanced microstructural path modeling of primary recrystallization in aluminum alloys AA5182 and AA5657","authors":"R. A. Vandermeer,&nbsp;X. C. Lei,&nbsp;E. F. F. Knipschildt-Okkels,&nbsp;F. Lin,&nbsp;R. E. Sanders,&nbsp;D. Juul Jensen","doi":"10.1002/metm.15","DOIUrl":"10.1002/metm.15","url":null,"abstract":"<p>When analyzing recrystallization kinetics data, it is extremely important to use a model, which has appropriate assumptions for nucleation and growth, including spatial distribution of nuclei, nucleation rate, growth rate, and directionality. In the present work, we reveal how advanced microstructural path modeling (MPM) can successfully fit kinetics data for the complex recrystallization of two different industrial aluminum alloys. Simpler models have failed to fit the data over the entire recrystallization period. The new model allows for spatially clustered nucleation and for different growth rates in different sample directions, whereby the grains evolve with an aspect ratio different from 1. Based on the MPM analysis, the specific nucleation and growth parameters as well as the recrystallized grain sizes are deduced, and the recrystallization characteristics of the two alloys are compared. The work demonstrates the power of quantitative metallography and the wealth of recrystallization information that may be obtained from MPM modeling of such stereological data.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.15","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140250501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly efficient electrocatalysts for seawater electrolysis under high current density: A critical review 高电流密度下用于海水电解的高效电催化剂:重要综述
Pub Date : 2024-01-08 DOI: 10.1002/metm.11
Nutthaphak Kitiphatpiboon, Meng Chen, Changrui Feng, Shasha Li, Abuliti Abudula, Guoqing Guan

According to the International Energy Agency (IEA) strategy, water electrolysis will be a second priority for hydrogen production by 2030, which can support sustainable development goals (SDGs). However, for the large-scale application, especially seawater electrolysis at a high current density, cost and durability of the electrocatalytic system need to be taken into account. Herein, fundamental mechanisms of seawater electrolysis in a wide range of pH values, potential electrocatalysts for overall water splitting, recent progress on synthesis electrocatalysts and basic principles for the evaluation of electrocatalysts are reviewed. Subsequently, critical parameters and issues for scaling-up of seawater electrolyzers are critically discussed. Finally, future prospects for completing sustainable hydrogen production from seawater for sustainable development are outlooked. It is anticipated to offer guidelines for the design and production of innovative electrocatalysts with high electrocatalytic activity and durability for the industrial scale application.

根据国际能源机构(IEA)的战略,到 2030 年,水电解将成为制氢的第二优先领域,这将有助于实现可持续发展目标(SDGs)。然而,要实现大规模应用,尤其是在高电流密度下进行海水电解,需要考虑电催化系统的成本和耐用性。本文综述了在广泛的 pH 值范围内进行海水电解的基本机制、整体水分离的潜在电催化剂、合成电催化剂的最新进展以及评估电催化剂的基本原则。随后,批判性地讨论了扩大海水电解槽规模的关键参数和问题。最后,展望了利用海水完成可持续制氢以促进可持续发展的未来前景。预计该研究将为设计和生产具有高电催化活性和耐用性的创新型电催化剂提供指导,以实现工业规模的应用。
{"title":"Highly efficient electrocatalysts for seawater electrolysis under high current density: A critical review","authors":"Nutthaphak Kitiphatpiboon,&nbsp;Meng Chen,&nbsp;Changrui Feng,&nbsp;Shasha Li,&nbsp;Abuliti Abudula,&nbsp;Guoqing Guan","doi":"10.1002/metm.11","DOIUrl":"10.1002/metm.11","url":null,"abstract":"<p>According to the <i>International Energy Agency</i> <i>(IEA)</i> strategy, water electrolysis will be a second priority for hydrogen production by 2030, which can support sustainable development goals (SDGs). However, for the large-scale application, especially seawater electrolysis at a high current density, cost and durability of the electrocatalytic system need to be taken into account. Herein, fundamental mechanisms of seawater electrolysis in a wide range of pH values, potential electrocatalysts for overall water splitting, recent progress on synthesis electrocatalysts and basic principles for the evaluation of electrocatalysts are reviewed. Subsequently, critical parameters and issues for scaling-up of seawater electrolyzers are critically discussed. Finally, future prospects for completing sustainable hydrogen production from seawater for sustainable development are outlooked. It is anticipated to offer guidelines for the design and production of innovative electrocatalysts with high electrocatalytic activity and durability for the industrial scale application.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.11","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139446417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface challenges and research progress toward solid polymer electrolytes-based lithium metal batteries 基于固体聚合物电解质的锂金属电池的界面挑战和研究进展
Pub Date : 2024-01-05 DOI: 10.1002/metm.13
Dechao Zhang, Shimei Li, Qi Xiong, Zhaodong Huang, Hu Hong, Shuo Yang, Jiaxiong Zhu, Chunyi Zhi

Solid-state lithium metal batteries (SLMBs) based on solid polymer electrolytes (SPEs) are a promising option for next-generation energy storage systems owing to their enhanced safety and energy density. However, the unstable interfaces resulting from continuous side reactions between electrodes and SPEs during cycling have hindered the practical application of SLMBs. In this review, we first provide an overview of the development and fundamentals of SPEs. Subsequently, the interface issues, factors influencing interface stability, and strategies to stabilize and enhance the compatibilities of the SPEs/electrodes interface are summarized. Finally, we propose perspectives on improving interface contact and stability through effective strategies for practical high-energy SLMBs. This review aims to deepen the understanding of interfacial issues between SPEs and electrodes and provide specific solutions to improve the electrochemical performances of SLMBs.

基于固体聚合物电解质(SPE)的固态锂金属电池(SLMB)具有更高的安全性和能量密度,是下一代能源存储系统的理想选择。然而,在循环过程中,电极和 SPE 之间的持续副反应会导致界面不稳定,这阻碍了 SLMB 的实际应用。在本综述中,我们首先概述了 SPE 的发展和基本原理。随后,我们总结了界面问题、影响界面稳定性的因素以及稳定和增强 SPE/电极界面兼容性的策略。最后,我们提出了通过有效策略改善界面接触和稳定性的观点,以用于实用的高能 SLMB。本综述旨在加深对固相萃取剂和电极之间界面问题的理解,并为改善 SLMB 的电化学性能提供具体的解决方案。
{"title":"Interface challenges and research progress toward solid polymer electrolytes-based lithium metal batteries","authors":"Dechao Zhang,&nbsp;Shimei Li,&nbsp;Qi Xiong,&nbsp;Zhaodong Huang,&nbsp;Hu Hong,&nbsp;Shuo Yang,&nbsp;Jiaxiong Zhu,&nbsp;Chunyi Zhi","doi":"10.1002/metm.13","DOIUrl":"10.1002/metm.13","url":null,"abstract":"<p>Solid-state lithium metal batteries (SLMBs) based on solid polymer electrolytes (SPEs) are a promising option for next-generation energy storage systems owing to their enhanced safety and energy density. However, the unstable interfaces resulting from continuous side reactions between electrodes and SPEs during cycling have hindered the practical application of SLMBs. In this review, we first provide an overview of the development and fundamentals of SPEs. Subsequently, the interface issues, factors influencing interface stability, and strategies to stabilize and enhance the compatibilities of the SPEs/electrodes interface are summarized. Finally, we propose perspectives on improving interface contact and stability through effective strategies for practical high-energy SLMBs. This review aims to deepen the understanding of interfacial issues between SPEs and electrodes and provide specific solutions to improve the electrochemical performances of SLMBs.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.13","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139382975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances and key challenges of the emerging MBenes from synthesis to applications 从合成到应用的新兴 MBenes 的最新进展和主要挑战
Pub Date : 2023-12-26 DOI: 10.1002/metm.12
Zhuobin Guo, Liangzhu Zhang, Tasmia Azam, Zhong-Shuai Wu

Two-dimensional (2D) transition metal borides (MBenes) as an analog to 2D transition metal carbides/nitrides (MXenes) have been considered promising platform materials for exploring their physical and chemical properties, due to their tunable composition, excellent stability, and good conductivity. Lots of theoretical studies have predicted possible mechanical, magnetic, and catalytic properties of MBenes, which inspired their research in energy storage and conversion applications. However, a detailed review focusing on the synthesis of high-quality MBene nanosheets and their energy-related applications is not available. In this review, MBene with different structures and the latest developments in synthesizing high-quality MBene nanosheets from top-down exfoliation and down-top chemical vapor deposition are first summarized. Then, the basic properties of MBene are investigated, including mechanical properties, metallicity, and magnetism. Next, their key applications such as hydrogen production, ammonia production, and energy storage are elaborately discussed. Finally, the future perspectives and key challenges of MBenes's synthesis and applications are briefly provided.

二维(2D)过渡金属硼化物(MBenes)与二维过渡金属碳化物/氮化物(MXenes)类似,由于其可调整的成分、出色的稳定性和良好的导电性,一直被认为是探索其物理和化学特性的有前途的平台材料。许多理论研究预测了 MBenes 可能具有的机械、磁性和催化特性,这激发了人们对其在能量存储和转换应用方面的研究。然而,关于高质量 MBene 纳米片的合成及其能源相关应用的详细综述还没有。本综述首先概述了不同结构的 MBene 以及通过自上而下剥离和自下而上化学气相沉积合成高质量 MBene 纳米片的最新进展。然后,研究了 MBene 的基本特性,包括机械特性、金属性和磁性。接着,详细讨论了它们的主要应用,如制氢、制氨和储能。最后,简要介绍了美贝烯合成和应用的未来前景和主要挑战。
{"title":"Recent advances and key challenges of the emerging MBenes from synthesis to applications","authors":"Zhuobin Guo,&nbsp;Liangzhu Zhang,&nbsp;Tasmia Azam,&nbsp;Zhong-Shuai Wu","doi":"10.1002/metm.12","DOIUrl":"https://doi.org/10.1002/metm.12","url":null,"abstract":"<p>Two-dimensional (2D) transition metal borides (MBenes) as an analog to 2D transition metal carbides/nitrides (MXenes) have been considered promising platform materials for exploring their physical and chemical properties, due to their tunable composition, excellent stability, and good conductivity. Lots of theoretical studies have predicted possible mechanical, magnetic, and catalytic properties of MBenes, which inspired their research in energy storage and conversion applications. However, a detailed review focusing on the synthesis of high-quality MBene nanosheets and their energy-related applications is not available. In this review, MBene with different structures and the latest developments in synthesizing high-quality MBene nanosheets from top-down exfoliation and down-top chemical vapor deposition are first summarized. Then, the basic properties of MBene are investigated, including mechanical properties, metallicity, and magnetism. Next, their key applications such as hydrogen production, ammonia production, and energy storage are elaborately discussed. Finally, the future perspectives and key challenges of MBenes's synthesis and applications are briefly provided.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.12","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lithium metal anode: Past, present, and future 金属锂阳极:过去、现在和未来
Pub Date : 2023-10-31 DOI: 10.1002/metm.6
Wen-Ze Huang, Pan Xu, Xue-Yan Huang, Chen-Zi Zhao, Xiaofei Bie, Hao Zhang, Aibing Chen, Elena Kuzmina, Elena Karaseva, Vladimir Kolosnitsyn, Ximin Zhai, Tao Jiang, Li-Zhen Fan, Deping Wang, Qiang Zhang

Over the past three decades, lithium-based batteries have greatly influenced our daily lives. However, their limited energy density poses challenges in meeting growing demand. To increase energy density, lithium metal anode is considered critical. This review systematically examines the history of lithium metal anode development, highlights notable advances in fundamental understandings, materials design, and characterization techniques. Forthcoming opportunities are discussed to promote the practical applications of lithium metal anodes.

在过去的三十年里,锂电池极大地影响了我们的日常生活。然而,它们有限的能量密度给满足日益增长的需求带来了挑战。为了提高能量密度,锂金属负极被认为是关键所在。本综述系统地回顾了锂金属负极的发展历史,重点介绍了在基本认识、材料设计和表征技术方面取得的显著进展。此外,还讨论了促进锂金属负极实际应用的未来机遇。
{"title":"Lithium metal anode: Past, present, and future","authors":"Wen-Ze Huang,&nbsp;Pan Xu,&nbsp;Xue-Yan Huang,&nbsp;Chen-Zi Zhao,&nbsp;Xiaofei Bie,&nbsp;Hao Zhang,&nbsp;Aibing Chen,&nbsp;Elena Kuzmina,&nbsp;Elena Karaseva,&nbsp;Vladimir Kolosnitsyn,&nbsp;Ximin Zhai,&nbsp;Tao Jiang,&nbsp;Li-Zhen Fan,&nbsp;Deping Wang,&nbsp;Qiang Zhang","doi":"10.1002/metm.6","DOIUrl":"10.1002/metm.6","url":null,"abstract":"<p>Over the past three decades, lithium-based batteries have greatly influenced our daily lives. However, their limited energy density poses challenges in meeting growing demand. To increase energy density, lithium metal anode is considered critical. This review systematically examines the history of lithium metal anode development, highlights notable advances in fundamental understandings, materials design, and characterization techniques. Forthcoming opportunities are discussed to promote the practical applications of lithium metal anodes.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135871715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Trends of sustainable recycling technology for lithium-ion batteries: Metal recovery from conventional metallurgical processes to innovative direct recycling 锂离子电池可持续回收技术的发展趋势:从传统冶金工艺到创新型直接循环利用的金属回收
Pub Date : 2023-10-11 DOI: 10.1002/metm.5
Yongteng Dong, Haocheng Ji, Xiaoxue Wu, Nengzhan Zheng, Junxiong Wang, Guanjun Ji, Yuanmao Chen, Guangmin Zhou, Zheng Liang

The remarkable market growth of lithium-ion batteries (LIBs) for various applications has been witnessed in the past two decades. However, as a retirement wave of more and more LIBs approaches, the disposed end-of-life batteries represent a growing hazard to ecosystem and human health. Recycling valuable metals from those spent LIBs still remain challenging because the current conventional metallurgical recycling processes involve the emission of toxic gas and waste chemicals as well as intensive energy consumption. These processes are not considered as green recycling approaches that contradict with the principles of carbon neutrality and circular economy embraced by the world. Hence, implementing green and sustainable recycling technologies of spent LIBs, especially for cathode materials, is an urgent need. This review provides a comprehensive understanding and critical evaluation of traditional pyrometallurgy, hydrometallurgy, and state-of-the-art direct recycling for recovering valuable metal materials from the spent LIB cathode. The fundamentals, methods, efficiencies, and feasibility of the three recycling approaches are also assessed. In addition, the recent progress for green innovation of hydrometallurgical and direct recycling processes as well as the potential research tendency for spent LIBs are discussed.

在过去的二十年里,用于各种应用的锂离子电池(LIBs)在市场上取得了长足的发展。然而,随着越来越多的锂离子电池退役潮的来临,报废电池对生态系统和人类健康的危害日益严重。从这些废锂电池中回收有价值的金属仍然具有挑战性,因为目前传统的冶金回收工艺会排放有毒气体和废弃化学品,并消耗大量能源。这些工艺并不被视为绿色回收方法,与碳中和和循环经济的原则相悖。因此,迫切需要对废锂电池(尤其是阴极材料)实施绿色和可持续的回收技术。本综述对传统火法冶金学、湿法冶金学以及从废 LIB 阴极回收有价值金属材料的最先进直接回收技术进行了全面的了解和严格的评估。同时还对这三种回收方法的基本原理、方法、效率和可行性进行了评估。此外,还讨论了湿法冶金和直接回收工艺绿色创新的最新进展,以及废锂电池的潜在研究趋势。
{"title":"Trends of sustainable recycling technology for lithium-ion batteries: Metal recovery from conventional metallurgical processes to innovative direct recycling","authors":"Yongteng Dong,&nbsp;Haocheng Ji,&nbsp;Xiaoxue Wu,&nbsp;Nengzhan Zheng,&nbsp;Junxiong Wang,&nbsp;Guanjun Ji,&nbsp;Yuanmao Chen,&nbsp;Guangmin Zhou,&nbsp;Zheng Liang","doi":"10.1002/metm.5","DOIUrl":"10.1002/metm.5","url":null,"abstract":"<p>The remarkable market growth of lithium-ion batteries (LIBs) for various applications has been witnessed in the past two decades. However, as a retirement wave of more and more LIBs approaches, the disposed end-of-life batteries represent a growing hazard to ecosystem and human health. Recycling valuable metals from those spent LIBs still remain challenging because the current conventional metallurgical recycling processes involve the emission of toxic gas and waste chemicals as well as intensive energy consumption. These processes are not considered as green recycling approaches that contradict with the principles of carbon neutrality and circular economy embraced by the world. Hence, implementing green and sustainable recycling technologies of spent LIBs, especially for cathode materials, is an urgent need. This review provides a comprehensive understanding and critical evaluation of traditional pyrometallurgy, hydrometallurgy, and state-of-the-art direct recycling for recovering valuable metal materials from the spent LIB cathode. The fundamentals, methods, efficiencies, and feasibility of the three recycling approaches are also assessed. In addition, the recent progress for green innovation of hydrometallurgical and direct recycling processes as well as the potential research tendency for spent LIBs are discussed.</p>","PeriodicalId":100919,"journal":{"name":"MetalMat","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/metm.5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136211838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
MetalMat
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1