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Pub Date : 2024-12-28 DOI: 10.1002/metm.30

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引用次数: 0
Magnetic properties and I-V characteristics of DC magnetron sputtered [Co (0.2 nm)/Ni (0.4 nm)]10 thin films 直流磁控溅射 [Co (0.2 nm)/Ni (0.4 nm)]10 薄膜的磁特性和 I-V 特性
Pub Date : 2024-11-19 DOI: 10.1002/metm.29
Subrata Sarkar, Rafikul Hussain, Dhananjoy Rajbanshi, Sandeep Kumar Srivastava

A set of [Co(0.2 nm)/Ni(0.4 nm)]10 multilayers (MLs) thin films were fabricated on silicon and glass substrate under various distinct conditions (i) as-prepared films without an under-layer, (ii) films with a copper [Cu(2 nm)] underlayer (UL), (iii) films with an in situ annealed Ta/Cu UL during sputtering, and (iv) films with post-annealing treatment, by using a DC magnetron sputtering machine. The [Co/Ni] MLs thin films prepared under various conditions exhibit in-plane magnetic anisotropic behavior except as-prepared films which show isotropic behavior. The maximum saturation magnetization was observed in the as-prepared films prepared on both silicon and glass substrate. The Ta/Cu UL in situ annealing followed by post-annealing films exhibit highest coercivity, moderate saturation magnetization but lowest squareness in contrast to the films deposited under other conditions. The I-V curves of the films show diode like behavior with breakdown voltage of 42, 58, 14, and 21 V for [Co/Ni] MLs under four different conditions.

使用直流磁控溅射机在硅和玻璃基底上制作了一组[Co(0.2 nm)/Ni(0.4 nm)]10 多层 (MLs) 薄膜,这些薄膜在不同条件下分别为:(i) 不带底层的原样薄膜;(ii) 带有铜 [Cu(2 nm)] 底层 (UL) 的薄膜;(iii) 在溅射过程中原位退火的 Ta/Cu UL 薄膜;以及 (iv) 经过退火后处理的薄膜。在不同条件下制备的[Co/Ni] MLs 薄膜表现出平面内磁性各向异性,而未制备的薄膜则表现出各向同性。在硅基板和玻璃基板上制备的原位制备薄膜都能观察到最大饱和磁化。与在其他条件下沉积的薄膜相比,Ta/Cu UL 原位退火后再退火的薄膜具有最高的矫顽力和适度的饱和磁化,但方正度最低。薄膜的 I-V 曲线显示出类似二极管的行为,在四种不同条件下,[Co/Ni] ML 的击穿电压分别为 42、58、14 和 21 V。
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引用次数: 0
Advancements and challenges of industrial-level acidic CO2 electrolysis
Pub Date : 2024-09-01 DOI: 10.1002/metm.28
Shuchao Shen, Kang Yang, Guoliang Xu, Sheng Chen, César Ortiz-Ledón, Jingjing Duan

The use of green renewable energy to convert carbon dioxide (CO2) into valuable chemicals and fuels through CO2 electrolysis technology (also known as electrochemical CO2 reduction reaction, eCO2RR) is an advantageous technology, which could greatly aid the global carbon-neutral goal. Although progress has been made in alkaline/neutral media, low carbon conversion efficiency to target products, carbonate/bicarbonate salt precipitation, and blockage of electrode holes caused by CO2 are not conducive to industrial applications. Acidic media could address these issues; however, in these conditions, there are other challenges that need to be addressed, such as hydrogen evolution, poor tolerance of electrocatalysts, and electrolysers. This review discusses recent advances in industrial-level acidic CO2 electrolysis, including reaction mechanisms, electrocatalysts, and device design, aiming to promote its commercialization. In addition, a comprehensive evaluation strategy of an acidic eCO2RR system is proposed, and perspectives are provided based on related discussion.

利用绿色可再生能源,通过二氧化碳电解技术(又称电化学二氧化碳还原反应,eCO2RR)将二氧化碳(CO2)转化为有价值的化学品和燃料,是一项具有优势的技术,可大大有助于实现全球碳中和目标。虽然在碱性/中性介质方面取得了进展,但目标产品的碳转化效率低、碳酸盐/碳酸氢盐沉淀以及二氧化碳导致的电极孔堵塞等问题不利于工业应用。酸性介质可以解决这些问题;但是,在这些条件下,还需要应对其他挑战,如氢进化、电催化剂耐受性差以及电解槽等。本综述讨论了工业级酸性二氧化碳电解的最新进展,包括反应机理、电催化剂和装置设计,旨在促进其商业化。此外,还提出了酸性 eCO2RR 系统的综合评估策略,并在相关讨论的基础上提出了展望。
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引用次数: 0
Cover 封面
Pub Date : 2024-07-30 DOI: 10.1002/metm.26

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引用次数: 0
Table of Content 目录
Pub Date : 2024-07-30 DOI: 10.1002/metm.27

No abstract is available for this article.

本文无摘要。
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引用次数: 0
MetalMat: Unveiling the transformative power of metals in science and technology 金属垫:揭示金属在科技领域的变革力量
Pub Date : 2024-07-21 DOI: 10.1002/metm.25
Elena Pereloma, Jun Sun

Since the dawn of civilization, metals have been integral to the fabric of modern society, shaping our technological landscape, and driving innovation across diverse industries. The intrinsic allure of metals lies in their versatility, strength, and adaptability, qualities that have propelled humanity towards new frontiers of scientific discovery and technological advancement. As we embark on this groundbreaking journey with MetalMat, the premier Wiley open access journal dedicated to metals in science and technology, we celebrate the enduring legacy and transformative potential of these remarkable materials.

At the core of MetalMat's mission lies a fundamental drive to deepen our understanding of the atomic and microstructural intricacies of metals, paving the way for the design of cutting-edge alloys with advanced properties tailored for specific applications. This prestigious publication is poised to explore the pivotal function of materials in advancing society, with a keen focus on addressing pressing global challenges such as climate change, sustainability, and other critical issues that define our present and shape our future.

MetalMat stands as a beacon of excellence, providing a platform for cutting-edge scientific and engineering research on both structural and functional metallic materials. The journal's scope encompasses a wide array of topics, ranging from the design, processing, and characterization of metals, alloys, intermetallics, and metal-matrix composites/compounds to the diverse applications of functional metallic materials in interdisciplinary research domains.

As the first Wiley open access journal dedicated to metal-related topics, MetalMat is poised to revolutionize the field by fostering a vibrant exchange of ideas and discoveries among researchers, scientists, and experts from around the world. With unwavering support from the international research community, MetalMat has assembled a stellar team of experts representing a diverse array of countries, including Australia, China, Belgium, Brazil, Chile, Germany, Japan, Singapore, UK, and the USA. This esteemed editorial board ensures that MetalMat not only pushes the boundaries of materials science but also serves as a guiding light, shaping the future of metallic materials research and fostering global collaboration.

One of the hallmarks of MetalMat is its commitment to an open-access publication model, which ensures that all published articles are freely accessible to a global audience. The journal's dedicated editorial team maintains an efficient review process, with an average turnaround time of approximately 1 month, to ensure the timely dissemination of cutting-edge research in the field. MetalMat welcomes a diverse range of contributions, including original research articles, comprehensive reviews, insightful perspectives, and short communications, all of which contribute to the vibrant tapestry of knowledge in this dynamic field.

A

自人类文明诞生以来,金属一直是现代社会不可或缺的组成部分,它塑造了我们的技术面貌,并推动着各行各业的创新。金属的内在魅力在于其多功能性、强度和适应性,这些特质推动人类迈向科学发现和技术进步的新领域。金属导报》是威利出版的一本以金属为主题的开放式科技期刊,当我们与《金属导报》一起踏上这条开创性的征程时,我们为这些非凡材料的永恒遗产和变革潜力而欢呼。《金属导报》的核心使命在于从根本上加深我们对金属原子和微观结构复杂性的理解,为设计出具有先进性能、适合特定应用的尖端合金铺平道路。这本享有盛誉的刊物将致力于探索材料在推动社会进步方面的关键作用,重点关注应对气候变化、可持续发展等紧迫的全球性挑战,以及其他决定我们现在和未来的关键问题。MetalMat 是卓越的灯塔,为有关金属结构和功能材料的前沿科学和工程研究提供了一个平台。MetalMat 是一盏卓越的明灯,为结构和功能金属材料方面的前沿科学和工程研究提供了一个平台。该期刊的范围涵盖了从金属、合金、金属间化合物和金属基复合材料/化合物的设计、加工和表征到功能金属材料在跨学科研究领域的各种应用等一系列广泛的主题。在国际研究界的坚定支持下,《金属导报》组建了一支由来自澳大利亚、中国、比利时、巴西、智利、德国、日本、新加坡、英国和美国等不同国家的专家组成的明星团队。这个备受推崇的编辑委员会确保《金属材料学报》不仅能推动材料科学的发展,而且还能作为一盏指路明灯,塑造金属材料研究的未来并促进全球合作。《金属材料学报》的标志之一是其对开放获取出版模式的承诺,该模式确保全球读者都能免费获取所有发表的文章。该期刊的专业编辑团队保持着高效的审稿流程,平均审稿周期约为 1 个月,以确保及时传播该领域的前沿研究成果。MetalMat 欢迎多样化的投稿,包括原创研究文章、综合评论、独到见解和简短通讯,所有这些都有助于丰富这一充满活力的领域的知识。作为《金属导报》的主编,我们非常自豪和荣幸地欢迎您阅读我们的创刊号。这具有里程碑式的意义,标志着科技领域金属探索新篇章的开始。通过《金属导报》,我们旨在激励合作,激发创新,推动材料科学领域的进步,塑造一个金属在塑造我们的世界中继续发挥关键作用的未来。欢迎来到《金属导报》,在这里,金属的光辉与科学技术的前沿交汇在一起,在这里,可能性是无限的,就像这些非凡材料的无穷潜力一样。
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引用次数: 0
Topological quantum materials for spintronics 用于自旋电子学的拓扑量子材料
Pub Date : 2024-06-08 DOI: 10.1002/metm.24
Jinyu Duan, Shuai Hu, Ping Wang, Delin Zhang, Yong Jiang

Spintronics is an innovative field that exploits the intrinsic spin property of electrons instead of their charge, holding the promise of revolutionizing conventional electronic devices. Over the past decade, researchers have been actively exploring new materials as potential replacements for traditional spintronic materials. This endeavor is driven by the aspiration to create spintronic devices with ultralow power consumption, ultrahigh storage density, and remarkable stability. In recent years, topological quantum materials (TQMs) have attracted considerable interest due to their unique band structure and exceptional properties. These materials carry the potential to pave the way for breakthroughs in the design of spintronic devices, offering promising solutions to solve challenges currently faced in the field of spintronics. In this review, we first introduce the properties of various TQMs, including band structure and crucial transport properties. Subsequently, we focus on the diverse applications of TQMs in spintronics. Delving further, we discuss the current challenges and the potential directions for advancing and exploring TQMs.

自旋电子学是一个利用电子固有自旋特性而非电荷的创新领域,有望彻底改变传统的电子设备。在过去十年中,研究人员一直在积极探索新材料作为传统自旋电子材料的潜在替代品。这一努力的动力来自于创造具有超低功耗、超高存储密度和超强稳定性的自旋电子器件的愿望。近年来,拓扑量子材料(TQMs)因其独特的带状结构和优异的性能引起了人们的极大兴趣。这些材料有望为自旋电子器件的突破性设计铺平道路,为解决当前自旋电子学领域所面临的挑战提供前景广阔的解决方案。在这篇综述中,我们首先介绍了各种 TQM 的特性,包括带状结构和关键传输特性。随后,我们重点介绍了 TQM 在自旋电子学中的各种应用。深入探讨之后,我们将讨论当前的挑战以及推进和探索 TQMs 的潜在方向。
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引用次数: 0
A review on realizing rechargeable batteries based on SOCl2/SO2 electrolyte systems 基于 SOCl2/SO2 电解质系统实现可充电电池的综述
Pub Date : 2024-05-08 DOI: 10.1002/metm.19
Xiangyu Gao, Guodong Chen, Jinran Sun, Shanmu Dong, Guanglei Cui

As representative high-energy density primary batteries, Li-SOCl2 and Li-SO2 batteries possess superiorities including high working potential, long temperature range, low self-discharge rate and high safety compared with other conventional primary batteries. In spite of the high energy features, these devices have only been applied for single discharge rather than achieved energy cyclic utilization via recharge. Various modifying strategies have been put out concerning the two electrolyte systems to liberate theoretical energy storage capability as much as possible over decades. Nevertheless, reversible chemistry is also urgently required nowadays for these sulfur-based electrolyte primary batteries to achieve transformation and upgrading. In the review, we collect some of the modification works for Li-SOCl2 and Li-SO2 primary batteries since their invention and successively introduce some of the opening research studies of secondary batteries, designed technologies of which are demonstrated through aspects through anode interface, cathode materials, and electrolyte composition. Finally, it is aiming to look further into the future development of the reversibility of the unique electrolyte systems.

作为高能量密度原电池的代表,Li-SOCl2 和 Li-SO2 电池与其他传统原电池相比,具有工作电势高、温度范围长、自放电率低和安全性高等优点。尽管具有高能量的特点,但这些设备只能用于单次放电,而不能通过充电实现能量循环利用。几十年来,人们针对两种电解质系统提出了各种改进策略,以尽可能地提高理论储能能力。然而,如今这些硫基电解质原电池也迫切需要可逆化学来实现转型和升级。在这篇综述中,我们收集了锂-SOCl2 和锂-SO2 一次电池自发明以来的一些改造工作,并相继介绍了二次电池的一些开创性研究,从阳极界面、阴极材料和电解质组成等方面展示了二次电池的设计技术。最后,本研究旨在进一步探讨独特电解质系统可逆性的未来发展。
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引用次数: 0
A review of the microstructure and tensile behavior of additively manufactured metastable β Ti alloys 添加剂制造的可代谢β钛合金的微观结构和拉伸行为综述
Pub Date : 2024-04-11 DOI: 10.1002/metm.17
Elena Pereloma

This review summarizes and critically discusses the current knowledge on the microstructures and tensile properties of metastable β Ti alloys fabricated by selective laser melting and laser metal deposition techniques. The effects of post-heat treatments are also addressed. The spatial variations in the microstructure and properties are linked with the processing parameters. The review also compares the additively manufactured and post heat-treated metastable β Ti alloys with their wrought counterparts. It highlights the research questions for further investigations.

这篇综述总结并批判性地讨论了目前有关通过选择性激光熔化和激光金属沉积技术制造的可转移 β Ti 合金的微观结构和拉伸性能的知识。此外,还讨论了后热处理的影响。微观结构和性能的空间变化与加工参数有关。综述还比较了添加式制造和后热处理的可转移 β Ti 合金与锻造的同类合金。它强调了进一步研究的问题。
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引用次数: 0
Overview of application of automated SEM/EDS measurements for inclusion characterization in steelmaking 自动化 SEM/EDS 测量在炼钢过程中的夹杂物表征应用概述
Pub Date : 2024-04-10 DOI: 10.1002/metm.18
Shashank Ramesh Babu, Susanne K. Michelic

The scanning electron microscope equipped with an energy dispersive spectroscopy (SEM/EDS) is considered as a state-of-the-art characterization tool to determine the morphological features and the chemical composition of non-metallic inclusions in steel. Such a characterization is pivotal to assessing the steel quality, which influences the properties of end products. This paper offers a comprehensive review of the SEM/EDS system, tracing its historical developments and methodological advancements by various research groups which have contributed to non-metallic inclusion analysis. Then the discussions transition to developments that have matured the SEM/EDS platform. The paper highlights selected examples utilizing the SEM/EDS to examine inclusions across various steel grades and at different stages of the metallurgical process. Finally, latest advancements in integrating machine learning techniques to expedite the analysis process were discussed.

配备能量色散光谱仪(SEM/EDS)的扫描电子显微镜被认为是最先进的表征工具,可用于确定钢中非金属夹杂物的形态特征和化学成分。这种表征对于评估钢材质量至关重要,因为钢材质量会影响最终产品的性能。本文全面回顾了 SEM/EDS 系统,追溯了该系统的历史发展和各研究小组在方法上的进步,这些研究小组对非金属夹杂物分析做出了贡献。然后,讨论转向使 SEM/EDS 平台更加成熟的发展。论文重点介绍了利用 SEM/EDS 在冶金过程的不同阶段对不同钢种的夹杂物进行检查的部分实例。最后,还讨论了整合机器学习技术以加快分析过程的最新进展。
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引用次数: 0
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