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Response of radiochromic film dosimeters to gamma rays in different atmospheres 放射性致色膜剂量计对不同大气中伽马射线的响应
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90160-8
W.L. McLaughlin, J.C. Humphreys, Chen Wenxiu

The high-dose gamma ray response (103 - 5×105 Gy) of radiochromic film dosimeters, with ten kinds of plastic matrices (polychlorostyrene containing 1 or 25% C

, polybromostyrene containing 2 or 43% Br, nylon, polyvinyl chloride, cellulose triacetate, and an aromatic polymide) were investigated when irradiated under certain conditions in vacuum and in different atmospheres (air, oxygen, nitrogen, and nitrous oxide). In addition, the stability of the films was studied for storage periods up to one month after irradiation under these conditions.

The responses and stabilities of the polyhalostyrene and nylon films were only slightly affected by the different atmospheres of irradiation, but there were marked differences of response for the other film types. The dyed cellulose triacetate films and polyvinylchloride films are generally more sensitive in N2O and O2-deprived atmospheres than in air or in O2, but the opposite is true for the dyed polyvinyl butyral and aromatic nylon films. The dyed cellulose triacetate and dyed polychlorostryrene with 1% C

are the most stable films for all conditions or irradiation. For accurate routine radiation processing dosimetry, it is important to know the conditions of irradiation so that appropriate dosimetry systems and procedures may be used and so that suitable correction factors can be applied. Emphasis must be given to differences in atmospheric conditions encountered by dosimeters in practical industrial situations, which may cause marked differences in ultimate response factors.

研究了十种塑料基体(含1或25% C的聚氯乙烯、含2或43% Br的聚苯乙烯、尼龙、聚氯乙烯、三醋酸纤维素和芳香族聚酰胺)在真空和不同气氛(空气、氧气、氮气和氧化亚氮)下辐照时的高剂量伽马射线响应(103 - 5×105 Gy)。此外,在这些条件下辐照后,研究了膜的稳定性长达一个月。聚苯乙烯和尼龙薄膜的响应和稳定性受辐照气氛的影响较小,而其他类型薄膜的响应差异较大。染色的三醋酸纤维素薄膜和聚氯乙烯薄膜通常在N2O和O2缺乏的气氛中比在空气或O2中更敏感,但染色的聚乙烯醇丁醛和芳香族尼龙薄膜的情况正好相反。用1% C染色的三醋酸纤维素和聚氯苯乙烯在所有条件或辐照下都是最稳定的膜。为了进行准确的常规辐射处理剂量测定,了解辐照条件是很重要的,这样可以使用适当的剂量测定系统和程序,并可以应用适当的校正因子。必须强调剂量计在实际工业环境中所遇到的大气条件的差异,这可能导致最终反应因子的显著差异。
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引用次数: 21
Electron irradiation effect on minority carrier lifetime and other electrical characteristics in silicon power devices 电子辐照对硅功率器件中少数载流子寿命及其它电学特性的影响
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90164-5
P.G. Fuochi , P.G. Di Marco, A. Monti, G.M. Bisio , E. Di Zitti, B. Passerini , S. Tenconi

Irradiation of silicon power rectifiers with electrons of 12 MeV energy has been carried out. Minority carrier lifetime τ, forward voltage VF, reverse recovered charge QRR, reverse recovery time tRR for the diodes, circuit commutated turn-off time tq, and on-state voltage VT for the thyristors are measured as a function of dose. Power diodes and thyristors obtained from 〈111〉 neutron transutation or phosphorus doped float-zone silicon slices having 120Ωcm and 65Ωcm starting resistivity respectively and Ga-diffused are irradiated at room temperature. A linear relationship between carrier lifetime of irradiated diodes and electron dose is found and the calculated damage coefficients are kτ = 1.1x10-8 cm2/s and 7.2x10-9 cm2/s for the low-level and high-level lifetimes respectively at 25°C. For irradiated thyristors the linear relationship between turn-off time and dose yields ktq = 3x10-9 cm2/s at 125°C. Electron irradiation also affects the resistivity of the starting n-type silicon, increasing it of ≈ 15Ωcm for radiation doses > 1×104 Gy. A dose rate effect on the electrical characteristics of the devices using pulses of different duration is analyzed. Annealing studies are carried out at 150 °C, 200°C and 360°C to assess the stability of the defects produced by the electron bombardment by monitoring the variation of the electrical characteristics of the irradiated devices in the temperature range of interest. DLTS measurements performed on electron irradiated power rectifiers have revealed a complex defect pattern. The E1 defect level (Ec-0.17 ev) is the principal recombination center that controls lifetime following room temperature irradiation. The energy levels and capture cross sections of these irradiation induced-defects are reported. This study confirms that lifetime control in silicon power devices is feasible by high energy electrons. The major advantages of this technique over metallic diffusion or 60Co γ-irradiation methods are: better quality, lower processing cost and higher device yields. Annealing after irradiation is important to ensure long-term device stability.

用12mev能量的电子辐照硅功率整流器。测量了少数载流子寿命τ、正向电压VF、反向恢复电荷QRR、二极管反向恢复时间tRR、电路换流关断时间tq和晶闸管导通电压VT作为剂量的函数。在室温下辐照< 111 >中子置换或掺磷浮区硅片得到的功率二极管和晶闸管,分别具有120Ωcm和65Ωcm启动电阻率和ga扩散。发现辐照二极管的载流子寿命与电子剂量呈线性关系,在25°C时,低能级和高能级寿命的损伤系数分别为kτ = 1.1x10-8 cm2/s和7.2x10-9 cm2/s。对于辐照晶闸管,在125℃时,关断时间与剂量之间的线性关系为ktq = 3 × 10-9 cm2/s。电子辐照对起始n型硅的电阻率也有影响,随着辐照剂量的增大,其电阻率≈15Ωcm;1×104 Gy。分析了不同持续时间脉冲对器件电特性的剂量率效应。退火研究在150°C, 200°C和360°C下进行,通过监测辐照器件在感兴趣的温度范围内的电特性变化来评估电子轰击产生的缺陷的稳定性。在电子辐照功率整流器上进行的DLTS测量揭示了一个复杂的缺陷模式。E1缺陷能级(Ec-0.17 ev)是控制室温辐照后寿命的主要复合中心。报道了这些辐照缺陷的能级和俘获截面。本研究证实了利用高能电子控制硅功率器件的寿命是可行的。与金属扩散或60Co γ辐照方法相比,该技术的主要优点是:质量更好,加工成本更低,器件收率更高。辐照后的退火对于保证器件的长期稳定性至关重要。
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引用次数: 4
The effects of various monomers on crosslinking efficiency 不同单体对交联效率的影响
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90165-7
R.W. Waldron, H.F. McRae, J.D. Madison

The addition of polyfunctional monomers when compounding radiation cured polymers increases the crosslinking efficiency of the radiation. Various monomers were added to a flame retarded base formulation to investigate their crosslinking efficiency. These samples were then crosslinked by electron beam irradiation and their physical properties were measured. Variations were noted in tensile strength, elongation, and gel/swell tests. The monomers studied were di-, tri-, and tetra-functional, and represented a wide range of effects on the physical properties.

复合辐射固化聚合物时加入多官能团单体,提高了辐射的交联效率。将不同的单体加入到阻燃碱配方中,考察其交联效率。然后用电子束辐照交联这些样品并测量它们的物理性质。在拉伸强度、伸长率和凝胶/膨胀测试中发现了变化。所研究的单体有二官能团、三官能团和四官能团,它们对材料的物理性质有广泛的影响。
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引用次数: 18
Dose response characteristics of special opti-chromic waveguides 特殊光色波导的剂量响应特性
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90156-6
K.C. Humprerys, A.D. Kantz

In 1981 Kronenberg, McLaughlin, and Siebentritt proposed measurement of radiation dosage using optical waveguides with leuco dye solutions. Based on this work, an opti-chromic system was proposed at the Fourth International Meeting on Radiation Processing. This opti-chromic system has been evaluated by McLaughlin and Radak. The opti-chromic waveguide system may be even more valuable for other applications which involve measurements with special requirements and configurations.

The linearity of the radiation response can be enhanced by proper selection of leuco dye concentration, waveguide materials, organic activator solvents, and trace chemical additives. This paper presents experimental data resulting from an examination of the organic solvents TEP, DMSO, and n-propyl alcohol in relationship to stability, temperature characteristics, and radiation chemistry.

The experimental data indicates that by varying the types and combinations of organic solvents, special opti-chromic waveguides can be fabricated to measure various radiation ranges under a variety of temperature ranges which have stability over time.

1981年,Kronenberg、McLaughlin和Siebentritt提出了用光波导测量辐射剂量的方法,其中光波导含有无色染料溶液。在此基础上,在第四届国际辐射处理会议上提出了一种光致变色系统。McLaughlin和Radak对该光致变色系统进行了评价。对于其他涉及特殊要求和配置的测量的应用,光-色波导系统可能更有价值。通过适当选择染料浓度、波导材料、有机激发剂溶剂和微量化学添加剂,可以提高辐射响应的线性度。本文介绍了从有机溶剂TEP, DMSO和正丙醇的稳定性,温度特性和辐射化学关系的检查的实验数据。实验数据表明,通过改变有机溶剂的种类和组合,可以制备出在不同温度范围内测量不同辐射范围的特殊光色波导,且随时间的推移具有稳定性。
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引用次数: 5
The present state of industrial application of electron processing system in Japan and Asian countries 电子处理系统在日本及亚洲各国的工业应用现状
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90172-4
I. Sakamoto, K. Mizusawa, M. Kashiwagi, Y. Hoshi

This report describes the latest informations of the utilization of electron processing systems in Japan and electron processing systems for cross-linking of wire insulations and curing of plywood coating in Asian countries and the latest features of electron processing systems.

本文介绍了日本电子处理系统的最新应用情况,亚洲国家在电线绝缘交联和胶合板涂层固化方面的电子处理系统的最新情况,以及电子处理系统的最新特点。
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引用次数: 24
Protonation of the reduced species in irradiated acetonitrile 辐照乙腈中还原物的质子化
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90187-6
W.A Mulac, A Bromberg, D Meisel

The rate of the reaction of the radiolytically produced reduced species in acetonitrile with various protic solutes (alcohols and water) was measured by the competition method and by directly following the rate of disappearance of the reduced species in pulse radiolytic experiments. The rate constants thus obtained were correlated with the pKa of the protic additives. This correlation leads to the conclusion that the reaction occurs via a proton transfer. Temperature effect studies on the rate of this reaction lead to the conclusion that the reactive species is the dimer anion radical (CH3CN)-2.

通过竞争法和直接跟踪脉冲辐射分解实验中还原物的消失速率,测定了在乙腈中辐射分解产生的还原物与各种质子溶质(醇和水)的反应速率。所得的速率常数与质子添加剂的pKa有关。这种相互关系得出的结论是,反应是通过质子转移发生的。温度对反应速率的影响研究表明,反应物质为二聚阴离子自由基(CH3CN)-2。
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引用次数: 5
Energy transfer in irradiated cyclohexane solutions 辐照环己烷溶液中的能量转移
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90201-8
L.H. Luthjens, H.C. de Leng, L. Wojna´rovits, A. Hummel

From the decrease of yield of solvent fluorescent excited states in cyclohexane by the electron scavenger CO2 the efficiency of formation of this excited state from ion recombination is found to be 0.4 ± 0.1. Energy transfer studies using cis-decalin as a solute seem to provide evidence for the formation of higher excited states in irradiated cyclohexane with a yield of 0.8 (100 eV)-1. These states are capable of fast energy transfer to the solute.

从电子清除剂CO2对环己烷溶剂荧光激发态产率的降低来看,离子复合生成该激发态的效率为0.4±0.1。使用顺式十氢化萘作为溶质的能量转移研究似乎为在产率为0.8 (100 eV)-1的辐照环己烷中形成更高激发态提供了证据。这些态能够快速地向溶质转移能量。
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引用次数: 12
Proton-transfer reactions in ionized gases 电离气体中的质子转移反应
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90212-2
W. Stiller, R. Schmidt, R. Schuster
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引用次数: 2
Design principles of high-activity gamma-irradiation facilities 高活性伽马辐照设施的设计原则
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90217-1
V. Stenger, P. Hargittai, B. Ka´lma´n, M. Sztyevko
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引用次数: 1
Process engineering aspects and the further development of the onion irradiator GBZ 81 gbz81洋葱辐照器的工艺工程方面及进一步发展
Pub Date : 1985-01-01 DOI: 10.1016/0146-5724(85)90221-3
G. Huebner, E. Winkler, P. Schuemichen, Th. Luther

The gamma irradiator GBZ 81 is a specific onion irradiator and easy to use for all types of bulk-cargo irradiation. It largely works automatically. The irradiator may be integrated into the storing line of onions from the field to the warehouse. Its output is about 7.5–8.0 ton/h, corresponding to 2000–3000 ton per harvest period. The efficiency of the gamma irradiator is about 13%. Considering the low building cost, the simple design and the automatic operation of the irradiation plant this comparatively low efficiency is acceptable, especially if the cobalt-60 sources are used during the remaining times of the year in another facility, e.g. a multipurpose irradiator of a higher efficiency. This programme is realized at present by the combination of a new multipurpose gamma-irradiation facility and some onion irradiators of the type GBZ 81.

伽马辐照器gbz81是一种特殊的洋葱辐照器,易于用于所有类型的散货辐照。它基本上是自动工作的。该辐照器可集成到从田间到仓库的洋葱存储线中。其产量约为7.5-8.0吨/小时,相当于每个采收期2000-3000吨。辐照器的效率约为13%。考虑到低建筑成本,简单的设计和自动操作的辐照厂,这种相对较低的效率是可以接受的,特别是如果钴-60源在一年的其余时间在另一个设施中使用,例如效率较高的多用途辐照器。这一计划目前是由一个新的多用途伽玛辐照设备和gbz81型的一些洋葱辐照器相结合实现的。
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引用次数: 2
期刊
Radiation Physics and Chemistry (1977)
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