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The relation between temperature and silica benthic exchange rates and implications for near-seabed formation of diagenetic opal 温度与底栖二氧化硅交换速率的关系及其对近海底成岩蛋白石形成的影响
Pub Date : 2020-12-01 DOI: 10.1016/j.ringps.2020.100002
Shahab Varkouhi, Jonathan Wells

This study calculated the dissolution rates of biogenic silica deposited on the seafloor and the silicic acid benthic flux for 22 Ocean Drilling Program sites. Simple models developed for two host sediment types—siliciclastic and carbonate—were used to explain the variability of biogenic silica dissolution and recycling under present-day low (−0.3 to 2.14 °C) bottom-water temperatures. The kinetic constants describing silicic acid release and silica saturation concentration increased systematically with increasing bottom-water temperatures. When these temperature effects were incorporated into the diagenetic models, the prediction of dissolution rates and diffusive fluxes was more robust. This demonstrates that temperature acts as a primary control that decreases the relative degree of pore-water saturation with biogenic opal while increasing the silica concentration. The correlation between the dissolution rate and benthic flux with temperature was pronounced at sites where biogenic silica is hosted in surficial sediments mostly composed of biogenic carbonates. This association is because the dissolution of carbonates provides the alkalinity necessary for both silica dissolution (also its reprecipitation as opal-CT) and clay formation; thus strongly reducing the retarding influence of clays on biogenic opal dissolution. Conversely, the silica exchange rates were modified by presence of aluminosilicates, which led to a higher burial efficiency for biogenic opal in detrital- than in carbonate-dominated benthic layers. Though model prediction of first-order silica early transformation suggests likely effects from surface temperatures (0–4 °C) on opal-CT precipitation over short geological times (< 4 Ma) near seabed in the Antarctic Site 751, the relationship between silica solubility and surface-area variability in time is a more critical control. Since silica solubility and surface area decrease with time, the < 4 Ma elapsed time aged opal-A to the point that changes in specific surface area caused minor effects on solubility, allowing for formation of opal-CT at low temperature settings near the seabed.

本研究计算了22个海洋钻探项目地点沉积在海底的生物源二氧化硅的溶解速率和硅酸底栖生物通量。为两种宿主沉积物类型(硅酸和碳酸盐)开发的简单模型用于解释在当今低(- 0.3至2.14°C)底水温度下生物成因二氧化硅溶解和再循环的变异性。随着底水温度的升高,描述硅酸释放的动力学常数和二氧化硅饱和浓度有系统地增加。当这些温度效应被纳入成岩模型时,对溶解速率和扩散通量的预测更加可靠。这表明温度是主要的控制因素,降低了生物蛋白石孔隙水饱和度的相对程度,同时增加了二氧化硅浓度。在主要由生物成因碳酸盐组成的表层沉积物中含有生物成因二氧化硅的地点,溶解速率和底栖生物通量与温度的相关性显著。这种联系是因为碳酸盐的溶解为二氧化硅溶解(也为蛋白石ct的再沉淀)和粘土的形成提供了必需的碱度;从而大大降低了粘土对生物成因蛋白石溶解的延缓作用。相反,硅酸铝的存在改变了二氧化硅交换速率,这导致碎屑中生物蛋白石的埋藏效率高于碳酸盐为主的底栖地层。虽然一阶硅早期转变的模型预测表明,表面温度(0-4°C)可能对短地质时间内蛋白石ct降水产生影响(<4ma)时,二氧化硅溶解度与表面积随时间变化的关系是更为关键的控制因素。由于二氧化硅的溶解度和比表面积随时间的推移而减小,4 Ma的时间使蛋白石- a老化到比表面积变化对溶解度影响很小的程度,从而允许在海底附近的低温环境下形成蛋白石ct。
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引用次数: 9
Delineation of discontinuity using multi-channel seismic attributes: An implication for identifying fractures in gas hydrate sediments in offshore Mahanadi basin 利用多道地震属性圈定不连续面:对Mahanadi盆地近海天然气水合物沉积物裂缝识别的启示
Pub Date : 2020-12-01 DOI: 10.1016/j.ringps.2020.100007
Neha Rai , Dip Kumar Singha , Pradeep Kumar Shukla , Kalachand Sain

Seismic attributes derived from post stack seismic data are important tools to delineate and characterize the subsurface geological features and discontinuities such as fracture, fault and many more. In this paper we have used two seismic profiles (MH-38A and MH-38B) of 2D multi-channel data along north-south direction with seafloor depth ranging from 1450 m to 2175 m in the deep offshore Mahanadi basin. The gas hydrate indicator, bottom simulating reflector (BSR) is easily identified but the discontinuities such as fractures are not observed directly from the seismic data. Therefore, we have computed the total four most suitable attributes which are reflection strength, instantaneous frequency, instantaneous bandwidth and instantaneous quality factor. We have compared the relative changes of the attribute values along the layers in the four derived attributes and hence, have recognized total three and seven discontinuities for MH-38A and MH-38B respectively, at near and away from the well location. Most faults are passing in NNW-SSE and N-S direction either in the gas hydrate layer or below BSR. These discontinuities are called as natural fractures which are validated by the fractures observed from resistivity image log at well site NGHP-01–19 and NGHP-01–09 for CDP ranges 1561 to 1681 in line MH-38A and 1357 to 1458 in line MH-38B respectively. The discontinuities in the gas hydrate sediments are useful for anisotropy study and to map the chimney system through which the free gas can flow from below BSR to up direction.

叠后地震数据的地震属性是圈定和表征地下地质特征和不连续面(如裂缝、断层等)的重要工具。本文利用了Mahanadi盆地海底深度1450 ~ 2175 m的2条二维多通道地震剖面(MH-38A和MH-38B),沿南北方向进行了研究。海底模拟反射面(BSR)很容易识别,但裂缝等不连续面不能直接从地震资料中观测到。因此,我们计算出了四个最合适的属性,即反射强度、瞬时频率、瞬时带宽和瞬时品质因子。我们比较了四个衍生属性中属性值沿层的相对变化,从而识别出MH-38A和MH-38B分别在井位附近和远离井位的3个和7个不连续面。在天然气水合物层内或BSR以下,大部分断层沿NNW-SSE和N-S方向通过。这些不连续结构被称为天然裂缝,通过NGHP-01-19和NGHP-01-09井场电阻率成像测井在MH-38A和MH-38B线的CDP范围分别为1561 ~ 1681和1357 ~ 1458观测到的裂缝进行了验证。天然气水合物沉积物中的不连续面有助于研究各向异性和绘制自由气体从BSR下向上流动的烟囱系统。
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引用次数: 8
期刊
Results in Geophysical Sciences
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