Pub Date : 2024-01-29DOI: 10.1080/02603594.2024.2305884
Cheriyan Ebenezer, R. Vijay Solomon
The development of density functional theory (DFT) has significantly enhanced the use of computational chemistry as a tool in the design and development of ligands for the separation of actinides (...
密度泛函理论（DFT）的发展大大提高了计算化学在设计和开发用于分离锕系元素的配体方面的应用。
{"title":"Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review","authors":"Cheriyan Ebenezer, R. Vijay Solomon","doi":"10.1080/02603594.2024.2305884","DOIUrl":"https://doi.org/10.1080/02603594.2024.2305884","url":null,"abstract":"The development of density functional theory (DFT) has significantly enhanced the use of computational chemistry as a tool in the design and development of ligands for the separation of actinides (...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"3 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139752514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-03DOI: 10.1080/02603594.2023.2298366
Umesh I. Kaluarachchige Don, A. M. Buddhika Chandima, Dmitri Gelman, Richard L. Lord, Stanislav Groysman
This review focuses on the synthetic inorganic chemistry of structural and functional models of Mo-Cu CO dehydrogenase (CODH). Mo-Cu CODH is an aerobic enzyme that catalyzes CO oxidation. The activ...
这篇综述主要介绍了 Mo-Cu CO 脱氢酶（CODH）结构和功能模型的合成无机化学。Mo-Cu CODH 是一种催化 CO 氧化的有氧酶。其活化...
{"title":"Design and Reactivity of Early-Late Bimetallics as Structural and Functional Models of Mo Cu CODH","authors":"Umesh I. Kaluarachchige Don, A. M. Buddhika Chandima, Dmitri Gelman, Richard L. Lord, Stanislav Groysman","doi":"10.1080/02603594.2023.2298366","DOIUrl":"https://doi.org/10.1080/02603594.2023.2298366","url":null,"abstract":"This review focuses on the synthetic inorganic chemistry of structural and functional models of Mo-Cu CO dehydrogenase (CODH). Mo-Cu CODH is an aerobic enzyme that catalyzes CO oxidation. The activ...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"53 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139105170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-10DOI: 10.1080/02603594.2023.2291025
Jayaprakash Avinash, T. Chellapandi, G. Madhumitha, E. J. J. Samuel, S. P. V. Chamundeeswari, S. Roopan
{"title":"Current Trends on Ag\u0000 3\u0000 PO\u0000 4\u0000 -GO Based Heterojunction Photocatalyst for Photocatalytic Degradation of Organic Pollutants: A Review","authors":"Jayaprakash Avinash, T. Chellapandi, G. Madhumitha, E. J. J. Samuel, S. P. V. Chamundeeswari, S. Roopan","doi":"10.1080/02603594.2023.2291025","DOIUrl":"https://doi.org/10.1080/02603594.2023.2291025","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"2 6","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138584911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-29DOI: 10.1080/02603594.2023.2285064
Yahya Absalan, Faezeh Mokari, Behnaz Delaram, Mostafa Gholizadeh, Kambiz Suri
Metal-organic frameworks (MOFs) have been increasingly popular in photocatalytic water-splitting research areas due to their unique, tunable porosity, high stability, large surface activity, and ma...
{"title":"Optoelectronic Alteration of Metal-Organic Frameworks for Enhanced Photocatalytic Water Splitting Activity Under Solar Radiation","authors":"Yahya Absalan, Faezeh Mokari, Behnaz Delaram, Mostafa Gholizadeh, Kambiz Suri","doi":"10.1080/02603594.2023.2285064","DOIUrl":"https://doi.org/10.1080/02603594.2023.2285064","url":null,"abstract":"Metal-organic frameworks (MOFs) have been increasingly popular in photocatalytic water-splitting research areas due to their unique, tunable porosity, high stability, large surface activity, and ma...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"19 3","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138496457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-27DOI: 10.1080/02603594.2023.2261103
Na Sun, Hongyan Yu, Andrei S. Potapov, Yaguang Sun
ABSTRACTPropylene (C3H6) is a crucial olefin raw material used in the production of polypropylene, which is the world’s second-most produced synthetic plastic. Separating propylene from propane (C3H8) is an important and significant challenge for industry due to the similar molecular sizes and physical properties of these gases. At present, the usual method for this separation is energy-intensive cryogenic distillation, which has low efficiency and high energy consumption. Therefore, an energy-efficient alternative way is in an urgent demand. Metal-organic frameworks (MOFs) are promising candidates for propylene/propane separation, thanks to the well-defined, designable, modifiable, and flexible structures. This review provides a summary of a recent development of MOFs that are able to discriminate between propylene and propane. The key factors that determine the separation performance of MOFs, primarily from the perspectives of pore size, presence of open metal sites (OMS) and MOFs membranes are summarized. Besides, the challenges that must be addressed for the further development of separations utilizing MOFs are also discussed.KEYWORDS: Metal-organic frameworksseparationadsorptionpore sizeopen metal sites Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by “The Belt and Road” Innovative Talent Exchange Foreign Experts Project (DL2022006007L), the Scientific Research Project of the Educational Department of Liaoning Province (LJ2019011), the National Natural Science Foundation of China (22301191, 21671139), the China postdoctoral Science Foundation (2023M731798). A.S.P. acknowledges the Ministry of Science and Higher Education of the Russian Federation (121031700321-3).
{"title":"Separation of Propylene and Propane Using Metal–Organic Frameworks","authors":"Na Sun, Hongyan Yu, Andrei S. Potapov, Yaguang Sun","doi":"10.1080/02603594.2023.2261103","DOIUrl":"https://doi.org/10.1080/02603594.2023.2261103","url":null,"abstract":"ABSTRACTPropylene (C3H6) is a crucial olefin raw material used in the production of polypropylene, which is the world’s second-most produced synthetic plastic. Separating propylene from propane (C3H8) is an important and significant challenge for industry due to the similar molecular sizes and physical properties of these gases. At present, the usual method for this separation is energy-intensive cryogenic distillation, which has low efficiency and high energy consumption. Therefore, an energy-efficient alternative way is in an urgent demand. Metal-organic frameworks (MOFs) are promising candidates for propylene/propane separation, thanks to the well-defined, designable, modifiable, and flexible structures. This review provides a summary of a recent development of MOFs that are able to discriminate between propylene and propane. The key factors that determine the separation performance of MOFs, primarily from the perspectives of pore size, presence of open metal sites (OMS) and MOFs membranes are summarized. Besides, the challenges that must be addressed for the further development of separations utilizing MOFs are also discussed.KEYWORDS: Metal-organic frameworksseparationadsorptionpore sizeopen metal sites Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by “The Belt and Road” Innovative Talent Exchange Foreign Experts Project (DL2022006007L), the Scientific Research Project of the Educational Department of Liaoning Province (LJ2019011), the National Natural Science Foundation of China (22301191, 21671139), the China postdoctoral Science Foundation (2023M731798). A.S.P. acknowledges the Ministry of Science and Higher Education of the Russian Federation (121031700321-3).","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"33 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135579373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-06DOI: 10.1080/02603594.2023.2255528
G. S. Ananthnag
{"title":"CrownPhos: A Review of Crown Ether Derivatives Decorated with Phosphorus Donors","authors":"G. S. Ananthnag","doi":"10.1080/02603594.2023.2255528","DOIUrl":"https://doi.org/10.1080/02603594.2023.2255528","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"16 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73512559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-14DOI: 10.1080/02603594.2023.2246902
M. El‐khateeb, Manar Ababneh, Phil Liebing, W. Weigand
{"title":"Mono- and Bi-Iron Chalcogenofumarato Complexes: Synthesis and Characterization","authors":"M. El‐khateeb, Manar Ababneh, Phil Liebing, W. Weigand","doi":"10.1080/02603594.2023.2246902","DOIUrl":"https://doi.org/10.1080/02603594.2023.2246902","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"78 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82848320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-06-10DOI: 10.1080/02603594.2023.2220295
M. Khrizanforov, A. Zagidullin, R. Shekurov, F. Akhmatkhanova, I. Bezkishko, V. Ermolaev, V. Miluykov
{"title":"Inorganic and Organometallic Polymers as Energy Storage Materials and Enhancing Their Efficiency","authors":"M. Khrizanforov, A. Zagidullin, R. Shekurov, F. Akhmatkhanova, I. Bezkishko, V. Ermolaev, V. Miluykov","doi":"10.1080/02603594.2023.2220295","DOIUrl":"https://doi.org/10.1080/02603594.2023.2220295","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"80 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80069585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-20DOI: 10.1080/02603594.2023.2200174
W. T. M. Seo, Emily Y. Tsui
{"title":"Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes","authors":"W. T. M. Seo, Emily Y. Tsui","doi":"10.1080/02603594.2023.2200174","DOIUrl":"https://doi.org/10.1080/02603594.2023.2200174","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"85 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83910301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-22DOI: 10.1080/02603594.2022.2157409
K. Monakhov
{"title":"Implication of counter-cations for polyoxometalate-based nano-electronics","authors":"K. Monakhov","doi":"10.1080/02603594.2022.2157409","DOIUrl":"https://doi.org/10.1080/02603594.2022.2157409","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"68 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80341849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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