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Current Topics in Recycling [Working Title]最新文献

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Current Topics in Plastic Recycling 塑料回收的最新话题
Pub Date : 2021-12-29 DOI: 10.5772/intechopen.101575
Maria Anna Charitopoulou, E. Alexopoulou, P. Alexiou, Dimitris S. Achilias
This chapter presents an overview of current trends in plastic recycling and focuses on specific topics of interest. Firstly, there are presented all methods used for plastic recycling, along with the advantages and disadvantages of each method. Extra attention is paid to chemical recycling and especially, pyrolysis (thermal and catalytic), which is an environmentally friendly method that results in the formation of value-added products. Emphasis is given on three case studies where there are difficulties as regards the recycling of the plastic part: polymeric blends, since the existence of mixed plastic wastes may be challenging for their recycling; plastics originating in multilayer packaging, since the multilayer packaging consists of various materials, including plastics, paper, and metals that may be an obstacle for the recycling of the plastic part; and brominated flame-retarded plastics from waste electric and electronic equipment (WEEE), since in this case safe handling is required in order to avoid environmental contamination and a pretreatment step before recycling may be of paramount importance. These three case studies along with the mentioned difficulties and suggestions in order to overcome them are presented here, with the aim of offering insights for future studies on the management of plastic materials.
本章概述了当前塑料回收的趋势,并着重于感兴趣的具体主题。首先,介绍了塑料回收的所有方法,以及每种方法的优点和缺点。特别关注化学回收,特别是热解(热和催化),这是一种环境友好的方法,可形成增值产品。重点介绍了在回收塑料部分方面存在困难的三个案例研究:聚合物混合物,因为混合塑料废物的存在可能对其回收构成挑战;源自多层包装的塑料,因为多层包装由各种材料组成,包括塑料、纸张和金属,这些材料可能会阻碍塑料部分的回收;和来自废旧电气电子设备(WEEE)的溴化阻燃塑料,因为在这种情况下,需要安全处理以避免环境污染,并且在回收之前的预处理步骤可能是至关重要的。这三个案例研究以及所提到的困难和建议,以克服它们,在这里提出,目的是为未来的塑料材料管理研究提供见解。
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引用次数: 0
Compost, Social Sustainability, and Circular Economy in Guatemala 危地马拉的堆肥、社会可持续性和循环经济
Pub Date : 2021-11-09 DOI: 10.5772/intechopen.100280
Peter A. Kumble
The research presented in this chapter explores a variety of objectives: first, what are the dynamics and associated requirements for initiating a new start-up composting business that would embrace the principles of Circular Economy? Secondly, is there a market for compost both in an urban environment and for farmers regionally in a development world economy such as Guatemala? With this, how can employment opportunities for at-risk youth from the most impoverished neighborhood in Guatemala City be created while adhering to the tenants of social sustainability? And finally, what were the requirements involved in making compost in the challenging high altitude climatic conditions of Guatemala City?
本章提出的研究探讨了各种目标:首先,启动一个新的启动堆肥业务的动态和相关要求是什么,将拥抱循环经济的原则?其次,在城市环境和发展中国家如危地马拉的地区农民中,堆肥是否都有市场?在此基础上,如何为危地马拉城最贫困社区的高危青年创造就业机会,同时坚持社会可持续性的租户?最后,在危地马拉城具有挑战性的高海拔气候条件下制作堆肥有什么要求?
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引用次数: 0
Urban Mining of e-Waste and the Role of Consumers 电子垃圾的城市挖掘和消费者的作用
Pub Date : 2021-10-19 DOI: 10.5772/intechopen.100363
Dimitris Georgantzis Garcia, Sven Kevin van Langen
This chapter adds to the body of literature on the Circular Economy (CE), urban mining, and their intersection with consumer behaviour, by first providing a review of existing and emergent EU regulations aimed towards enhancing the collection rate of household WEEE. The fast growth of the EEE waste stream and its potential for Urban Mining as well as the inability of WEEE collection to keep up with the growth of the EEE industry is showcased with statistical data. The final section critically analyses the literature the intersection between consumer behaviour and closed-loop supply chains for EEE, identified through a systematic keyword search to ensure replicability. The findings point at a lack of theoretical, methodological and product-case heterogeneity among the identified sources, with most of them employing the Theory of Planned Behaviour and survey methods and focusing on mobile phones or general WEEE. While the literature suggests important behavioural differences across EEE categories, this was not representatively explored. The final section contributes to filling this gap by developing a taxonomy of EEE categories based on characteristics that may predispose consumer behaviour. The identified dimensions are: size, involvement, long-term reliability expectations, value type, internet access, multifunctionality, the quality of being outdated and social meaning.
本章增加了关于循环经济(CE),城市采矿及其与消费者行为的交叉点的文献,首先提供了旨在提高家庭报废电子电气设备收集率的现有和新兴欧盟法规的审查。统计数据显示了电子电气设备废物流的快速增长及其对城市采矿的潜力,以及电子电气设备收集无法跟上电子电气设备行业的增长。最后一部分批判性地分析了文献中消费者行为和EEE闭环供应链之间的交集,通过系统的关键字搜索来确定,以确保可复制性。研究结果指出,在已确定的来源中,缺乏理论、方法和产品案例的异质性,其中大多数采用计划行为理论和调查方法,并专注于手机或一般WEEE。虽然文献表明不同电子电气设备类别之间存在重要的行为差异,但这并没有代表性的探讨。最后一节通过开发基于可能倾向于消费者行为的特征的电子电气设备类别分类法来填补这一空白。确定的维度是:规模,参与,长期可靠性期望,价值类型,互联网接入,多功能性,过时的质量和社会意义。
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引用次数: 1
Retreatment of Polymer Wastes by Disintegrator Milling 聚合物废弃物的粉碎再处理
Pub Date : 2021-09-21 DOI: 10.5772/intechopen.99715
P. Kulu, D. Goljandin
Global introduction of waste utilization techniques to the polymer market is currently not fully developed but has enormous potential. Before reintegration of used material into a new product, it normally requires grinding, that is shredding, crushing, or milling. In traditional grinders, the generated stresses in the material to be ground are equal to or less than the strength of the material. If by traditional methods, the stresses generated are compressive + shift, so by milling based on collision are tension + shift. Due to the high stress-material strength ratio at collision, it is possible to crush not only brittle materials but also ductile materials. This process allows easily combining the grinding of composite materials with their separation into individual constituents. In the current study, the mechanical recycling of the following groups of polymer materials was studied: pure brittle and soft polymers (PMMA, HDPE and IER), blends of plastics (ABS+PMMA, PC + ABS), reinforced plastics (PMMA+GFP); elastomers (rubber and tyres), and printed circuit boards (PCB).
全球将废物利用技术引入聚合物市场目前尚未充分发展,但具有巨大的潜力。在将使用过的材料重新整合成新产品之前,通常需要研磨,即切碎、粉碎或碾磨。在传统的研磨机中,被研磨材料中产生的应力等于或小于材料的强度。如果说传统方法产生的应力是压缩+位移,那么基于碰撞的铣削方法产生的应力是张力+位移。由于在碰撞时具有较高的应力-材料强度比,不仅可以粉碎脆性材料,而且可以粉碎延性材料。这个过程可以很容易地将复合材料的研磨与分离成单独的成分结合起来。在目前的研究中,研究了以下几类高分子材料的机械回收:纯脆性和软性聚合物(PMMA、HDPE和IER)、塑料共混物(ABS+PMMA、PC + ABS)、增强塑料(PMMA+GFP);弹性体(橡胶和轮胎)和印刷电路板(PCB)。
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引用次数: 1
Effect of Environmental Aging on Tensile Properties of Post-Consumer Recycled (PCR) Polycarbonates 环境老化对消费后再生聚碳酸酯拉伸性能的影响
Pub Date : 2021-09-08 DOI: 10.5772/intechopen.99528
R. Islam, Syed Zameer, Jacki Laiz, David Z. Chen, Anthony Yu, A. Chakravartula
In this chapter, tensile properties of different grades of post-consumer recycled (PCR) polycarbonate (PC) plastics have been compared with conventional or virgin PC before and after different aging conditions. 50 and 75% recycled PCs showed comparable yield strength (∼57 MPa), maximum tensile strength (∼70 MPa) and maximum strain (∼190–200%) before aging, when compared to virgin PC of same melt flow rate (MFR of ∼10 g/10 min). From the fractography analysis (optical and scanning electron microscopy) of the both virgin and 50% recycled PC, it is evident that the fracture morphologies are very similar and they are indicative of ductile failure. It is observed that with the presence of temperature and humidity (60°C 90% RH) aging, tensile strength starts to drop over time but most importantly both 50% and 75% PCR grades showed similar aging behavior compared to virgin PC (10–13% strength degradation after 500 hours of aging). Reliability modelling showed comparable B10, Weibull Alpha and Weibull Beta values between Virgin PC and PCR grades after different aging conditions. Fractography analysis of fresh and aged 75% PCR also showed ductile features.
在本章中,不同等级的消费后再生聚碳酸酯(PCR) (PC)塑料的拉伸性能进行了比较,在不同的老化条件之前和之后的常规或原始PC。与相同熔体流动速率(MFR为~ 10 g/10 min)的原始PC相比,50%和75%的再生PC在老化前表现出相当的屈服强度(~ 57 MPa)、最大抗拉强度(~ 70 MPa)和最大应变(~ 190-200%)。从原始PC和50%再生PC的断口分析(光学和扫描电镜)来看,很明显,断裂形态非常相似,它们表明韧性破坏。观察到,在温度和湿度(60°C 90% RH)老化的情况下,拉伸强度开始随着时间的推移而下降,但最重要的是,50%和75% PCR等级与原始PC相比表现出相似的老化行为(500小时后强度下降10-13%)。可靠性模型显示,不同老化条件下,Virgin PC和PCR等级的B10、Weibull Alpha和Weibull Beta值具有可比性。新鲜和老化75% PCR的断口分析也显示出韧性特征。
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引用次数: 0
Recent Advances in Pre-Treatment of Plastic Packaging Waste 塑料包装废弃物预处理研究进展
Pub Date : 2021-08-13 DOI: 10.5772/intechopen.99385
Rita Carvalho, Martijn Roosen, Sibel Ügdüler, K. V. Geem, K. Ragaert, D. Achilias, S. Meester
There is an urgent need to close the loop of plastic waste. One of the main challenges towards plastic packaging waste recycling is the presence of a variety of contaminants. These contaminants include organic residues, additives, labels, inks and also other plastic types that can be present in the waste stream due to missorting or in multimaterial structures (e.g. multilayer films in packaging). In this context, pre-treatment processes are a promising route to tackle the difficulties that are encountered in mechanical and chemical recycling due to these contaminants. This chapter gives better insight on the already existing pre-treatment techniques and on the advances that are being developed and/or optimized in order to achieve closed-loop recycling. Some of these advanced pre-treatments include chemical washing to remove inks (deinking), extraction methods to remove undesired plastic additives and dissolution-based pre-treatments, such as delamination and dissolution-precipitation techniques.
迫切需要关闭塑料废物的循环。塑料包装废弃物回收的主要挑战之一是各种污染物的存在。这些污染物包括有机残留物、添加剂、标签、油墨以及由于分类不当或多材料结构(例如包装中的多层薄膜)而可能存在于废物流中的其他塑料类型。在这种情况下,预处理工艺是解决由于这些污染物而在机械和化学回收中遇到的困难的有希望的途径。本章对现有的预处理技术以及为实现闭环回收而正在开发和/或优化的进展提供了更好的见解。其中一些先进的预处理包括化学洗涤去除油墨(脱墨),提取方法去除不需要的塑料添加剂和溶解为基础的预处理,如分层和溶解沉淀技术。
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引用次数: 5
Phytomass-Derived Multifunctional Activated Carbon as a “Wonder-Material”: A Paradigm Shift of Filth-to-Wealth 植物质衍生的多功能活性炭作为一种“神奇材料”:从污秽到财富的范式转变
Pub Date : 2021-08-13 DOI: 10.5772/intechopen.99448
P. Kalyani, T. R. Banuprabha, Chinnamayan Sudharsana, N. Anvarsha
Activated carbon (AC) is a wonder-material that finds multifarious applications such as catalytic supports, removal of pollutants, electrodes in energy gadgets, gas storage etc. Surface area, chemical constituents and pore structures are a few traits required in the ACs which largely depend on the source of the precursors and processing methodologies adopted. In this context, the idea of recycling phytomass for producing ACs has attracted researchers seeing that the inexpensive and renewable nature of the phytomass can reduce the overall cost of producing ACs with diversified features and that it does not add CO2 to the atmosphere leading to global warming (plants release only the same amount of CO2 as they consumed while growing). Further, phytomass after their life possess no value but their conversion into ACs would be an economically profitable option leading to inexpensive ACs. As a consequent of these advantages this chapter has been planned and designed to provide certain interesting multifunctional aspects of low-cost phytomass derived ACs. The chapter is expected to provide research insights oriented towards identification of unexplored phytomass or wastes which could lead to carbon with novel properties tunable to the applications. Filth-to-wealth or in other words, recycling of wastes provides a strategy categorized under circular-bioeconomy, which is the want of the hour.
活性炭(AC)是一种神奇的材料,有多种用途,如催化载体,去除污染物,能源装置的电极,气体储存等。活性炭的表面面积、化学成分和孔隙结构等特征在很大程度上取决于前驱体的来源和所采用的加工方法。在这种背景下,回收植物质的想法产生ac吸引了研究人员,因为植物质的廉价和可再生特性可以降低生产具有多种特性的ac的总成本,并且它不会向大气中增加二氧化碳导致全球变暖(植物在生长过程中只释放与消耗相同数量的二氧化碳)。此外,植物质量在其生命后没有价值,但将其转化为ac将是一种经济上有利可图的选择,导致廉价的ac。由于这些优点,本章已被计划和设计,以提供一些有趣的多功能方面的低成本植物质衍生的ACs。本章预计将提供面向识别未开发的植物质或废物的研究见解,这些植物质或废物可能导致具有可调应用的新特性的碳。从污秽到财富,或者换句话说,废物回收提供了一种被归类为循环生物经济的策略,这是当前的需要。
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引用次数: 0
Performance Analysis and Modeling of Microplastic Separation through Hydro Cyclones 水力旋流器分离微塑料的性能分析与建模
Pub Date : 2021-08-11 DOI: 10.5772/intechopen.99447
Fabio Borgia
The filtering hydro cyclone is a solid–liquid separation device, generally conical in shape. The hydro cyclone allows the separation of microplastics from water, to facilitate micro-recycling. To test the capabilities of a hydro cyclone at separating microplastics from water, Rietema’s standard sizes, mathematical and computational fluid dynamics (CFD) modeling were used. The results show that, even dough the mathematical model in unreliable when considering parameters out-side standard operation conditions, hydro cyclone microplastic separation can be achieved at 98% efficiency. Particles reach the outlet on average in 1.5 s for a flow velocity of 2 m/s, and denser microplastics end up in the underflow.
过滤式水力旋流器是一种固液分离装置,一般呈锥形。水力旋流器允许从水中分离微塑料,以促进微回收。为了测试水力旋流器从水中分离微塑料的能力,研究人员使用了Rietema的标准尺寸、数学和计算流体动力学(CFD)模型。结果表明,即使在数学模型不可靠的情况下,考虑非标准操作条件下的参数,水力旋流器的微塑性分离效率仍可达到98%。当流速为2m /s时,颗粒平均在1.5 s内到达出口,密度较大的微塑料最终进入底流。
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引用次数: 1
An Evaluation of Recycled Polymeric Materials Usage in Denim with Lifecycle Assesment Methodology 用生命周期评价方法评价再生高分子材料在牛仔布中的应用
Pub Date : 2021-08-11 DOI: 10.5772/intechopen.99446
Sedef Uncu Akı, C. Candan, B. Nergis, Neslihan Sebla Önder
Today, World economy is only 8.6% circular, which creates a huge potential in materials reuse. To close the Emission Gap by 2032, this percentage needs to be doubled. The circular economy ensures that with less virgin material input and fewer emissions. With the help of effective recycling technologies, virgin material use can be decreased and especially petroleum based materials impact can fall within planetary boundaries. This book chapter analyzes different chemical and biological recycling technologies, their advantages and challenges in denim production. Moreover, Life Cycle Assessment (LCA) analysis will be used to evaluate the environmental impact of recycled polymeric materials usage in denim fabrics. Finally, it concludes by challenges and the future of chemically recycled materials in denim production and opportunities to evaluate waste as a raw material to design circular systems.
今天,世界经济中循环经济仅占8.6%,这为材料再利用创造了巨大的潜力。为了在2032年之前消除排放差距,这一比例需要增加一倍。循环经济以更少的原始材料投入和更少的排放确保了这一点。在有效回收技术的帮助下,可以减少原始材料的使用,特别是石油基材料的影响可以在地球范围内。本章分析了不同的化学和生物回收技术,它们在牛仔生产中的优势和挑战。此外,生命周期评估(LCA)分析将用于评估再生聚合物材料在牛仔布面料中的使用对环境的影响。最后,它总结了牛仔布生产中化学回收材料的挑战和未来,以及评估废物作为设计循环系统的原材料的机会。
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引用次数: 0
Industrial Re-Use of Composites 复合材料的工业再利用
Pub Date : 2021-08-09 DOI: 10.5772/intechopen.99452
Albert ten Busschen
The amount of obsolete composites is increasing on a global scale, for example yacht hulls from a growing leisure industry and large rotor blades from wind energy production. Until now it has not been possible to recycle or disassemble thermoset composites into their original constituent parts of fibre reinforcement and resins. Subsequently a new method of re-use has been developed. This method involves machining the obsolete composite product into strips or flakes for re-use as reinforcing elements which, when combined with fresh resin and fibre, enable the production of a brand new component. This, in effect, preserves and re-uses the mechanical properties of the original obsolete composite. This method has been proven in manufacturing retaining walls, also guide beams for canals, crane mats and bridge decking, all using the strips or flakes from end of life composite products. For use on an industrial scale, a positive business case is imperative. In order to prove the industrial technology, new products have to contain a sufficiently high percentage of re-used composites in combination with automated processing. This has been achieved with “push-pultrusion” which is in essence a further development of the long established pultrusion process.
在全球范围内,废弃复合材料的数量正在增加,例如来自日益增长的休闲产业的游艇船体和来自风能生产的大型转子叶片。到目前为止,还不可能回收或分解热固性复合材料,使其成为纤维增强和树脂的原始组成部分。随后,开发了一种新的重用方法。这种方法包括将过时的复合材料产品加工成条状或片状,作为增强元件重新使用,当与新树脂和纤维结合时,可以生产全新的部件。这实际上保留并重新利用了原始过时复合材料的机械性能。这种方法已经在制造挡土墙、运河导梁、起重机垫和桥梁桥面上得到了证明,所有这些都使用了报废复合材料产品的条或片。为了在工业规模上使用,积极的商业案例是必不可少的。为了证明工业技术,新产品必须包含足够高的重复使用复合材料的百分比,并结合自动化加工。这是通过“推拉挤”实现的,本质上是长期建立的拉挤工艺的进一步发展。
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引用次数: 0
期刊
Current Topics in Recycling [Working Title]
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