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Dual Catalysis in Organic Synthesis 1最新文献

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1.2.1 General Principles of Transition-Metal/Photocatalyst Dual Catalysis 1.2.1过渡金属/光催化剂双催化的一般原理
Pub Date : 2020-01-01 DOI: 10.1055/sos-sd-231-00086
J. Tellis
The combination of transition-metal catalysis and visible-light photocatalysis offers opportunities for the development of unique new forms of reactivity. Presented in this chapter is an overview of the various strategies that can be used to design these dual catalytic transformations. Emphasis is placed on understanding the specific role that a photocatalyst can play in augmenting the reactivity of a substrate or cocatalyst to achieve otherwise challenging transformations.
过渡金属催化和可见光催化的结合为发展独特的新形式的反应性提供了机会。在本章中提出的是各种策略的概述,可用于设计这些双催化转化。重点放在理解光催化剂在增强底物或助催化剂的反应性以实现其他具有挑战性的转化方面所起的具体作用。
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引用次数: 0
1.1.2 Palladium/Copper and Palladium/Nickel Dual Catalysis 1.1.2钯/铜和钯/镍双催化
Pub Date : 2020-01-01 DOI: 10.1055/sos-sd-231-00004
O. Riant, S. Rout
Recent years have witnessed significant advances in molecular synthesis through rationally designed dual catalysis. Major achievements in dual catalysis have been accomplished with the aid of highly chemoselective palladium/copper and palladium/nickel catalyst systems. These examples have showcased the full compatibility of transition-metal catalysts with one another. To date, numerous examples of palladium/copper or palladium/nickel catalysis have been successfully performed, demonstrating the achievement of chemical syntheses via greener processes with alternative energy sources.
近年来,通过合理设计双催化在分子合成方面取得了重大进展。高化学选择性钯/铜和钯/镍催化剂体系在双催化方面取得了重大成就。这些例子显示了过渡金属催化剂之间的完全相容性。迄今为止,已经成功地进行了许多钯/铜或钯/镍催化的例子,证明了通过替代能源的更环保过程实现化学合成的成就。
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引用次数: 0
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Dual Catalysis in Organic Synthesis 1
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