Pub Date : 2020-01-01DOI: 10.1055/sos-sd-231-00086
J. Tellis
The combination of transition-metal catalysis and visible-light photocatalysis offers opportunities for the development of unique new forms of reactivity. Presented in this chapter is an overview of the various strategies that can be used to design these dual catalytic transformations. Emphasis is placed on understanding the specific role that a photocatalyst can play in augmenting the reactivity of a substrate or cocatalyst to achieve otherwise challenging transformations.
{"title":"1.2.1 General Principles of Transition-Metal/Photocatalyst Dual Catalysis","authors":"J. Tellis","doi":"10.1055/sos-sd-231-00086","DOIUrl":"https://doi.org/10.1055/sos-sd-231-00086","url":null,"abstract":"The combination of transition-metal catalysis and visible-light photocatalysis offers opportunities for the development of unique new forms of reactivity. Presented in this chapter is an overview of the various strategies that can be used to design these dual catalytic transformations. Emphasis is placed on understanding the specific role that a photocatalyst can play in augmenting the reactivity of a substrate or cocatalyst to achieve otherwise challenging transformations.","PeriodicalId":11383,"journal":{"name":"Dual Catalysis in Organic Synthesis 1","volume":"66 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87506076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.1055/sos-sd-231-00004
O. Riant, S. Rout
Recent years have witnessed significant advances in molecular synthesis through rationally designed dual catalysis. Major achievements in dual catalysis have been accomplished with the aid of highly chemoselective palladium/copper and palladium/nickel catalyst systems. These examples have showcased the full compatibility of transition-metal catalysts with one another. To date, numerous examples of palladium/copper or palladium/nickel catalysis have been successfully performed, demonstrating the achievement of chemical syntheses via greener processes with alternative energy sources.
{"title":"1.1.2 Palladium/Copper and Palladium/Nickel Dual Catalysis","authors":"O. Riant, S. Rout","doi":"10.1055/sos-sd-231-00004","DOIUrl":"https://doi.org/10.1055/sos-sd-231-00004","url":null,"abstract":"Recent years have witnessed significant advances in molecular synthesis through rationally designed dual catalysis. Major achievements in dual catalysis have been accomplished with the aid of highly chemoselective palladium/copper and palladium/nickel catalyst systems. These examples have showcased the full compatibility of transition-metal catalysts with one another. To date, numerous examples of palladium/copper or palladium/nickel catalysis have been successfully performed, demonstrating the achievement of chemical syntheses via greener processes with alternative energy sources.","PeriodicalId":11383,"journal":{"name":"Dual Catalysis in Organic Synthesis 1","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84974872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}