Pub Date : 2023-11-02DOI: 10.1007/s42247-023-00555-3
Shoaib Mallick, Jolly Bhadra, R. A. Shakoor, Muddasir Nawaz, Noora Hamad S. Al-Qahtani, Ahmed Bahgat Radwan, Muhsen El Haddadd, Ayesha Ahmed, Aya R. Hamad Al Mughrbi, Mohamed Abdelmoati, Hanan Alademi, Noora Al Thani
Abstract In this research work, we have studied the impact of Yttrium nanoparticles loaded with corrosion inhibitors dodecylamine (DOC) incorporated in polyolefin for the corrosion protection of steel. The surface analysis of pure polyolefin and polyolefin-Y 2 O 3 -DOC composite coatings by atomic force spectroscopy (AFM) shows that both of the coated samples’ roughness almost remain the same. Furthermore, the contact angle measurement shows an increase in the hydrophobicity of polyolefin-Y 2 O 3 with inhibitor. The release behavior of the corrosion inhibitors DOC was also studied at different pH. The x-ray diffraction for the loaded product shows that no physical and structural changes occur during the loading of the corrosion inhibitor. The electrochemical impedance spectroscopy (EIS) analysis demonstrates that smart polyolefin-Y 2 O 3 -DOC coating has better anticorrosion properties than pure polyolefin coating due to the effective release of DOC. An increase in charge transfer and pore resistance confirms the better barrier properties of the polyolefin-Y 2 O 3 -DOC composite coating. The inhibition efficiency of the polyolefin modified by Y 2 O 3 increased by 99% as compared to pure polyolefin coating. The carbon steel substrate became stable and the polymeric composite coating protectected the steel against corrosion in the oil and gas industry. In conclusion, the study shows that yttrium nanoparticles loaded with corrosion inhibitors incorporated in polyolefin have a significant impact on the corrosion protection of steel.
{"title":"Influence of polyolefin modified by Y2O3 as protective coatings against carbon steel corrosion into 3.5% NaCl media","authors":"Shoaib Mallick, Jolly Bhadra, R. A. Shakoor, Muddasir Nawaz, Noora Hamad S. Al-Qahtani, Ahmed Bahgat Radwan, Muhsen El Haddadd, Ayesha Ahmed, Aya R. Hamad Al Mughrbi, Mohamed Abdelmoati, Hanan Alademi, Noora Al Thani","doi":"10.1007/s42247-023-00555-3","DOIUrl":"https://doi.org/10.1007/s42247-023-00555-3","url":null,"abstract":"Abstract In this research work, we have studied the impact of Yttrium nanoparticles loaded with corrosion inhibitors dodecylamine (DOC) incorporated in polyolefin for the corrosion protection of steel. The surface analysis of pure polyolefin and polyolefin-Y 2 O 3 -DOC composite coatings by atomic force spectroscopy (AFM) shows that both of the coated samples’ roughness almost remain the same. Furthermore, the contact angle measurement shows an increase in the hydrophobicity of polyolefin-Y 2 O 3 with inhibitor. The release behavior of the corrosion inhibitors DOC was also studied at different pH. The x-ray diffraction for the loaded product shows that no physical and structural changes occur during the loading of the corrosion inhibitor. The electrochemical impedance spectroscopy (EIS) analysis demonstrates that smart polyolefin-Y 2 O 3 -DOC coating has better anticorrosion properties than pure polyolefin coating due to the effective release of DOC. An increase in charge transfer and pore resistance confirms the better barrier properties of the polyolefin-Y 2 O 3 -DOC composite coating. The inhibition efficiency of the polyolefin modified by Y 2 O 3 increased by 99% as compared to pure polyolefin coating. The carbon steel substrate became stable and the polymeric composite coating protectected the steel against corrosion in the oil and gas industry. In conclusion, the study shows that yttrium nanoparticles loaded with corrosion inhibitors incorporated in polyolefin have a significant impact on the corrosion protection of steel.","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"3 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135972900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-26DOI: 10.1007/s42247-023-00571-3
Waleed K. Al-Nowaiser, Sagheer A. Onaizi, Muhammad S. Vohra
{"title":"Synthesis and application of novel GO@ZIF-7 nanocomposite for the removal of lead from aqueous solutions","authors":"Waleed K. Al-Nowaiser, Sagheer A. Onaizi, Muhammad S. Vohra","doi":"10.1007/s42247-023-00571-3","DOIUrl":"https://doi.org/10.1007/s42247-023-00571-3","url":null,"abstract":"","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"25 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134908731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of various sodium hydroxide treatment parameters on the adsorption efficiency of rice husk for removal of methylene blue from water","authors":"Parminder Kaur, None Kalpana, Sandeep Kumar, Avneesh Kumar, Atul Kumar","doi":"10.1007/s42247-023-00574-0","DOIUrl":"https://doi.org/10.1007/s42247-023-00574-0","url":null,"abstract":"","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"11 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134908730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-20DOI: 10.1007/s42247-023-00570-4
Ahmed I. Ibrahim, Sagheer A. Onaizi, Muhammad S. Vohra
{"title":"Novel CTAB functionalized graphene oxide for selenium removal: adsorption results and ANN & RSM modeling","authors":"Ahmed I. Ibrahim, Sagheer A. Onaizi, Muhammad S. Vohra","doi":"10.1007/s42247-023-00570-4","DOIUrl":"https://doi.org/10.1007/s42247-023-00570-4","url":null,"abstract":"","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"178 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135617017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-20DOI: 10.1007/s42247-023-00561-5
Pranay Rajendra Lanjekar, Narayan Lal Panwar
{"title":"Hydrogen gas separation through membrane technology and sustainability analysis of membrane: a review","authors":"Pranay Rajendra Lanjekar, Narayan Lal Panwar","doi":"10.1007/s42247-023-00561-5","DOIUrl":"https://doi.org/10.1007/s42247-023-00561-5","url":null,"abstract":"","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"242 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135617731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-18DOI: 10.1007/s42247-023-00567-z
Anil Dhanola
Abstract Plant fiber is one of the sorts of environmentally friendly resources that have been replenished over several years by nature and human invention. For the past few years, application of plant fibers as reinforcements into polymer matrixes has gained considerable interest due to their biodegradable nature. Introducing just one type of reinforcing element does not result in composites with remarkable physical and tribo-mechanical characteristics. Lately, significant research and innovation have been observed on hybrid plant fiber–based biocomposites (HPFBCs) in structural and automotive industries. One of the crucial topics that must be reviewed is the tribo-mechanical performances of these composites. Hence, the present review article aims to provide the friction and wear behaviors and mechanical properties of different HPFBCs under different operational conditions. Based on the understanding of tribo-mechanical aspects of HPFBCs, some prospects have also been suggested that need to be addressed and resolved in the future. This review article is anticipated to provide readers and researchers with valuable insights into the significance of tribo-mechanical performances in the assessment of HPFBCs for specific applications.
{"title":"A comprehensive overview on tribo-mechanical characteristics of hybrid plant fiber–based biocomposites","authors":"Anil Dhanola","doi":"10.1007/s42247-023-00567-z","DOIUrl":"https://doi.org/10.1007/s42247-023-00567-z","url":null,"abstract":"Abstract Plant fiber is one of the sorts of environmentally friendly resources that have been replenished over several years by nature and human invention. For the past few years, application of plant fibers as reinforcements into polymer matrixes has gained considerable interest due to their biodegradable nature. Introducing just one type of reinforcing element does not result in composites with remarkable physical and tribo-mechanical characteristics. Lately, significant research and innovation have been observed on hybrid plant fiber–based biocomposites (HPFBCs) in structural and automotive industries. One of the crucial topics that must be reviewed is the tribo-mechanical performances of these composites. Hence, the present review article aims to provide the friction and wear behaviors and mechanical properties of different HPFBCs under different operational conditions. Based on the understanding of tribo-mechanical aspects of HPFBCs, some prospects have also been suggested that need to be addressed and resolved in the future. This review article is anticipated to provide readers and researchers with valuable insights into the significance of tribo-mechanical performances in the assessment of HPFBCs for specific applications.","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"44 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135883804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-14DOI: 10.1007/s42247-023-00565-1
Jahirul Islam, Kamal Hossain
{"title":"First-principles simulations to investigate effect of hydrostatic pressure on structural, mechanical, electronic, and optical properties of the AgCdCl3 perovskite","authors":"Jahirul Islam, Kamal Hossain","doi":"10.1007/s42247-023-00565-1","DOIUrl":"https://doi.org/10.1007/s42247-023-00565-1","url":null,"abstract":"","PeriodicalId":11536,"journal":{"name":"Emergent Materials","volume":"31 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135804307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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