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A Novel Method of Incorporating CNT into Additive Manufacturing Electronics Dielectric Material 将 CNT 纳入增材制造电子电介质材料的新方法
Pub Date : 2024-07-16 DOI: 10.37665/5ng0w157
Daniel Slep, Fan Yang
Flexible Hybrid Electronics (FHE) Parts that are additively manufactured give engineers and designers greater flexibility in geometry, complexity, and variety or customizability. In this work, UV curable dielectric materials for additive electronics and incorporated Carbon Nano Tubes (CNTs) within a formulated UV/LED curable matrix was used. It will be shown that inkjet printing CNT mixture in specific manner with a commercial UV curable dielectric improves mechanical and thermal properties of the final dielectric compared to the dielectric without the CNT mixture, including a significant decrease in the coefficient of thermal expansion,  while keeping excellent electrical properties.
柔性混合电子(FHE)部件采用添加式制造,在几何形状、复杂性、多样性或可定制性方面为工程师和设计师提供了更大的灵活性。在这项工作中,使用了用于增材制造电子产品的紫外线固化电介质材料,并在配制的紫外线/LED 固化基质中加入了碳纳米管 (CNT)。研究表明,与不含碳纳米管混合物的电介质相比,以特定方式喷墨打印碳纳米管混合物与商用紫外线固化电介质可改善最终电介质的机械和热性能,包括显著降低热膨胀系数,同时保持优异的电气性能。
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引用次数: 0
Condition Monitoring System: A Flexible Hybrid Electronics Approach for Sealed Container Applications 状态监测系统:用于密封集装箱应用的灵活混合电子方法
Pub Date : 2024-07-16 DOI: 10.37665/631d5y77
M. Panahi, A. Hanson, D. Maddipatla, S. Masihi, B. Narakathu, B. Bazuin, Scott Miller, M. Atashbar
A comparative study is presented between two advanced flexible hybrid electronics (FHE) systems designed for monitoring temperature within storage containers across various industries, including food, pharmaceuticals, agriculture, automotive, and defense. The first system, a copper-flex system (CFS), employs an 88.9 µm polyimide substrate with 35 µm thick copper traces, coated with a 12.5 µm polyimide solder mask. The second system, a printed-flex system (PFS), utilizes a 127 µm polyimide substrate with high-temperature resistance and tensile strength. Conductive silver ink was screen-printed on the PFS substrate, and electronic components including a temperature sensor were attached. Functional and reliability tests were performed to check the accuracy and durability of the temperature sensor. Further, environmental and mechanical characterizations including moisture and insulation resistance, corrosion, elongation, bending, and terminal bond strength tests were performed based on ASTM and IPC-TM650 standards. Moisture and insulation resistance test on the PFS test coupons without a coating layer indicated stable resistance of approximately 18 MΩ, while permanent color change indicated oxidation of copper on uncoated CFS test coupons. After 72 hours of corrosion test, both the CFS and PFS “meander line” test coupons covered with polyimide showed negligible change in weight and resistance, approximately 0.35%. A Young’s modulus of 7.17 GPa and 2.6 GPa was calculated from the elongation test for the CFS and PFS, respectively. Bending tests on PFS revealed negligible average resistance change (0.1%) during 180° bending cycles, while no impact was recorded on the CFS. During the terminal bond strength test, soldered wires detached from the CFS test coupons at an average force of 43 N, while it was 3.8 N on the PFS test coupons. Both systems with polyimide coating layer demonstrate robustness and reliability for diverse applications in various industries.
本报告对两种先进的柔性混合电子(FHE)系统进行了比较研究,这两种系统设计用于监测食品、制药、农业、汽车和国防等各行各业存储容器内的温度。第一个系统是铜柔性系统 (CFS),采用 88.9 微米的聚酰亚胺基底,35 微米厚的铜线,表面涂有 12.5 微米的聚酰亚胺焊接掩膜。第二个系统是印刷柔性系统(PFS),采用 127 微米的聚酰亚胺基底,具有耐高温和抗拉强度。导电银墨被丝网印刷在 PFS 衬底上,并安装了包括温度传感器在内的电子元件。进行了功能和可靠性测试,以检查温度传感器的准确性和耐用性。此外,还根据 ASTM 和 IPC-TM650 标准进行了环境和机械特性测试,包括防潮和绝缘阻抗、腐蚀、伸长率、弯曲和终端结合强度测试。在没有涂层的 PFS 试样上进行的防潮和绝缘电阻测试表明,电阻值稳定在 18 MΩ 左右,而在没有涂层的 CFS 试样上进行的永久性颜色变化则表明铜发生了氧化。经过 72 小时的腐蚀测试后,覆盖聚酰亚胺的 CFS 和 PFS "蜿蜒线 "测试脆片的重量和电阻变化都微乎其微,约为 0.35%。根据伸长测试计算得出,CFS 和 PFS 的杨氏模量分别为 7.17 GPa 和 2.6 GPa。对 PFS 进行的弯曲测试表明,在 180° 的弯曲周期中,平均阻力变化(0.1%)可以忽略不计,而对 CFS 则没有任何影响。在终端粘接强度测试中,CFS 测试脆片上的焊线平均脱落力为 43 N,而 PFS 测试脆片上的脱落力为 3.8 N。这两种带有聚酰亚胺涂层的系统都表现出了坚固性和可靠性,可用于各行各业的各种应用。
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引用次数: 0
Intermetallic Compounds in Solder Alloys: Common Misconceptions 焊料合金中的金属间化合物:常见误解
Pub Date : 2024-07-16 DOI: 10.37665/pmtrnw39
David Hillman, T. Pearson, Richard Coyle
Intermetallic compounds (IMC) or intermediate phases are formed between two or more metallic elements in many metal alloy systems. During soldering, an IMC is formed at the soldered interface as the molten solder reacts with an element in the substrate. IMCs also can form within the bulk solder as the joint solidifies. IMCs have critical roles in the solder joint quality and reliability. Unlike most metal alloys, an intermetallic compound typically has a fixed stoichiometry and is in variance with the conventional phases or constituents in the metal system (e.g., alpha and beta). IMCs have a different crystal structure than any of its constituents and some but never all the characteristics and properties of its constituents. Ductility is an important solder joint property, and the low intrinsic ductility of IMCs is associated with brittle behavior and reliability risk in service. However, a review of published solder field failures shows little evidence that IMC properties or IMC evolution under service conditions reduce solder joint reliability. Most IMC-induced solder joint failures are found to result from incorrect material specification or uncontrolled soldering processes. This paper describes the IMCs that occur typically in eutectic, Sn63Pb37 solder and near-eutectic SAC305 or other tin-based Pb-free solder alloys, including how they impact solder joint reliability. The paper also describes the potential impact of IMCs on the solder joint reliability for the newest generation of Pb-free high-performance solder alloys.
在许多金属合金体系中,两种或多种金属元素之间会形成金属间化合物(IMC)或中间相。在焊接过程中,当熔融焊料与基底中的元素发生反应时,就会在焊接界面上形成 IMC。当焊点凝固时,IMC 也会在散装焊料中形成。IMC 对焊点质量和可靠性起着至关重要的作用。与大多数金属合金不同,金属间化合物通常具有固定的化学计量,并与金属体系中的传统相或成分(如α和β)存在差异。IMC 的晶体结构不同于其任何成分,并具有其成分的某些特性和属性,但绝不是全部特性和属性。延展性是一种重要的焊点特性,IMC 的低内在延展性与脆性行为和使用中的可靠性风险有关。然而,对已公布的焊料现场故障的回顾表明,几乎没有证据表明 IMC 特性或 IMC 在使用条件下的演变会降低焊点可靠性。大多数 IMC 引起的焊点故障都是由不正确的材料规格或不可控的焊接工艺造成的。本文介绍了共晶锡 63Pb37 焊料和近共晶 SAC305 或其他锡基无铅焊料合金中通常会出现的 IMC,包括它们如何影响焊点可靠性。本文还介绍了 IMC 对最新一代无铅高性能焊料合金焊点可靠性的潜在影响。
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引用次数: 0
Modeling the Effects of Thermal Pad Voiding on Quad Flatpack No-lead (QFN) Components 热垫空化对四平面封装无铅(QFN)元件影响的建模
Pub Date : 2023-07-03 DOI: 10.37665/smt.v36i2.37
R. Wilcoxon, T. Pearson, D. Hillman
Finite element modeling was used to evaluate the effects of thermal pad solder voiding on the thermal resistance of Quad Flatpack No Lead components.  This included two different approaches for modeling solder voids: many small, distributed voids, the effects of which were averaged across the entire solder contact area or a single discrete void.  Two approaches were used for defining the thermal path established in the solder.  The effects of other design parameters - thermal boundary conditions, the presence of thermal vias under the package, and the size of the die power dissipation area – were also addressed. Modeling showed that thermal vias and external boundary conditions had the most significant impact on the package thermal resistance. Solder pad voids and concentrated die-level heat dissipation, for the range used in this study, had noticeable but less significant impacts on thermal resistance.  The study also compared different approaches for simulating solder voiding and identified ranges in which modeling simulations are most appropriate.
采用有限元模型分析了热垫焊空焊对Quad Flatpack无铅元件热阻的影响。这包括两种不同的焊锡空洞建模方法:许多小的、分布的空洞,其影响在整个焊锡接触区域或单个离散空洞中平均。两种方法用于确定焊料中的热路径。其他设计参数的影响——热边界条件,封装下热过孔的存在,以及模具功耗面积的大小——也得到了解决。模拟结果表明,热通孔和外边界条件对封装热阻的影响最为显著。对于本研究中使用的范围,焊盘空隙和集中的模级散热对热阻有明显但不太显著的影响。该研究还比较了模拟焊漏的不同方法,并确定了建模模拟最合适的范围。
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引用次数: 0
Pb-Free Solders and Aerospace/Defense (A&D) High Performance Considerations 无铅焊料和航空航天/国防(A&D)高性能考虑因素
Pub Date : 2023-07-03 DOI: 10.37665/smt.v36i2.30
A. Rafanelli, D. Hillman, C. Johnson, R. Coyle, T. Pearson
The Aerospace & Defense (A & D) industries maintain a high level of interest in the expansive amount of work performed in developing and qualifying Pb-free solder alloys.  The three main areas of interest continue to be thermal cycle, mechanical shock, and vibration.  The past twenty years have seen an unprecedented increase in alloy development such that the concepts of “generations of solders and “families of solders” have been coined to help manage the numerous individual alloys on the market today.  This paper will discuss work done with Pb-free solder alloys, many with the addition of constituents focusing on varying property enhancements.  The purpose is to provide a “snap shot” summary of progress to date and relate perspectives both as advantages and concerns solely in a constructive manner to aid researchers in planning their next steps in development and qualification of these alloys.
航空航天和国防(a&d)行业对开发和鉴定无铅焊料合金的大量工作保持着高度的兴趣。热循环、机械冲击和振动仍然是人们感兴趣的三个主要领域。在过去的二十年里,合金的发展出现了前所未有的增长,因此“几代焊工”和“焊工家庭”的概念已经被创造出来,以帮助管理当今市场上众多的单个合金。本文将讨论使用无铅焊料合金所做的工作,其中许多添加了侧重于不同性能增强的成分。目的是提供迄今为止进展的“快照”总结,并以建设性的方式将优势和关注的观点联系起来,以帮助研究人员规划这些合金的下一步发展和鉴定。
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引用次数: 0
Lower Temperature Soldering Using Supercooled Liquid Metal 使用过冷液态金属进行低温焊接
Pub Date : 2023-07-03 DOI: 10.37665/smt.v36i2.36
Ian D. Tevis, D. Paramanik
Lead-free solder metal alloys can be formed into supercooled liquid metal microcapsules and used to create solid full metal interconnects at dramatically lower processing temperatures. These alloys can be made with or without bismuth. The technology encapsulates known and established RoHS compliant solder alloys inside a thin oxide/organic shell nanofilm that keeps the metal in a metastable supercooled liquid state at ambient temperatures. The thin oxide/organic shell can be mechanically broken or chemically dissolved to release the liquid metal that then rapidly solidifies all without requiring heat.  The novel solder interconnect technology avoids thermal damage to components and materials, or quality issues caused by coefficient of thermal expansion mismatch.
无铅焊料金属合金可以形成过冷液态金属微胶囊,并用于在极低的加工温度下创建固体全金属互连。这些合金可含或不含铋制成。该技术将已知和已建立的符合RoHS标准的焊料合金封装在薄的氧化物/有机壳纳米膜中,使金属在环境温度下保持亚稳过冷液态。薄的氧化物/有机外壳可以机械破碎或化学溶解,以释放液态金属,然后在不需要加热的情况下迅速固化。新型焊料互连技术避免了元器件和材料的热损伤,避免了热膨胀系数不匹配引起的质量问题。
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引用次数: 0
Influence of Element Lead (Pb) Content in Tin Plating on Tin Whisker Initiation/Growth 镀锡中元素铅(Pb)含量对锡晶须萌生/生长的影响
Pub Date : 2023-03-20 DOI: 10.37665/smt.v36i1.28
D. Hillman, T. Pearson, R. Wilcoxon, Grace Cooke, Sue Margheim, Elena Gladen, T. Munson, D. Fritz
The implementation of the Restriction of Hazardous Substances (RoHS) European Union (EU) Directive in 2005 resulted in the introduction of pure tin as an acceptable surface finish for printed circuit boards and component terminations. A drawback of pure tin surface finishes is the potential to form tin whiskers.  Tin whiskers are a metallurgical phenomenon that is associated with tin rich/pure tin materials and has been a topic of intense industry interest. The acceptance and usage of pure tin by the electronics industry component fabricators is understandable as the pure tin surface finishes are inexpensive, are simple plating systems to operate and have reasonable solderability characteristics. However, high performance/harsh environment electronics typically have product life cycles that are measured in decades and therefore are much more susceptible to the potential long term threat of tin whiskers. The GEIA-STD-0005-2 “Standard for Mitigating the Effects of Tin Whiskers in Aerospace and High Performance Electronic Systems” established the definition of the term “Pb-free tin” as :  “Pb-free Tin is defined to be pure tin or any tin alloy with <3% lead (Pb) content by weight. A functional definition of “pure tin” was necessary so that the electronics industry could establish tin whisker risk protocols against a known acceptable target value in terms of soldering materials and processes. An investigation was conducted to determine the influence of 1% - 5% elemental lead (Pb) content in tin plating on tin whisker initiation and growth. The investigation results were used in the revision of the GEIA-STD-0005-2 “Standard for Mitigating the Effects of Tin Whiskers in Aerospace and High Performance Electronic Systems” specification technical discussions.
2005年欧盟(EU)有害物质限制(RoHS)指令的实施导致纯锡作为印刷电路板和元件端子的可接受表面处理引入。纯锡表面处理的一个缺点是有可能形成锡须。锡晶须是一种与富锡/纯锡材料相关的冶金现象,一直是业界关注的热点。电子工业元件制造商对纯锡的接受和使用是可以理解的,因为纯锡表面处理价格低廉,电镀系统操作简单,具有合理的可焊性特征。然而,高性能/恶劣环境电子产品通常具有数十年的产品生命周期,因此更容易受到锡晶须潜在的长期威胁。GEIA-STD-0005-2“减轻航空航天和高性能电子系统中锡晶须影响的标准”将术语“无铅锡”定义为:“无铅锡定义为纯锡或按重量计铅(Pb)含量<3%的任何锡合金。”“纯锡”的功能定义是必要的,这样电子工业就可以根据焊接材料和工艺的已知可接受目标值建立锡晶须风险协议。研究了镀锡中1% ~ 5%元素铅含量对锡晶须萌生和生长的影响。调查结果用于修订GEIA-STD-0005-2“减轻航空航天和高性能电子系统中锡晶须影响的标准”规范技术讨论。
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引用次数: 0
Aerosol Jet Printed Interconnects for Millimeter-Wave Components 用于毫米波组件的气溶胶喷射打印互连
Pub Date : 2023-03-20 DOI: 10.37665/smt.v36i1.35
James Feng, B. Germann, A. Ramm, F. Herrault, John R. Hamre
As millimeter wave RF device applications expand above traditional microwave frequency bands in the global communications, automotive and Mil-Aero markets, the need to limit interconnect signal losses related to parasitic elements has never been more important. As the frequency increases, device designers are facing numerous challenges, complications, and costs when fabricating interconnects with techniques such as copper pillar bumps, wire, ribbon or wedge bonding in 3DIC packaging. Printing conformal interconnects with Aerosol Jet® direct-write technology can offer package designers and RF engineers a new approach for optimizing interconnect transitions to active die, tailoring the loss characteristics to specific application requirements and eliminating the need to compensate for high signal transmission losses. Printed interconnects can be digitally designed into the package with a variety of metallic and dielectric materials. As these interconnects are conformally printed on the 3D surface of the package, the trace length can be minimized with zero loop height, reducing parasitic inductance to active die circuitry specifically for die on board, die in trench, or die on die with pads-up packaging configurations. In this work, Aerosol Jet® printed interconnects with silver nanoparticle inks are compared with the gold microstrip transmission lines as well as traditional gold bond wires, for performance up to 110 GHz.  We will share examples showcasing that the printed interconnects can have similar RF transmission performance to microstrip, with significantly lower loss than bondwires especially at high frequencies.  We will also discuss design effects for Aerosol Jet® printed RF interconnects up to 110 GHz based on a set of results for different line heights with a given line width printed with a silver ink.
随着毫米波射频器件在全球通信、汽车和航空航天市场的应用扩展到传统微波频段以上,限制与寄生元件相关的互连信号损耗的需求变得前所未有的重要。随着频率的增加,器件设计人员在使用3DIC封装中的铜柱凸点、导线、带状或楔形键合等技术制造互连时,面临着许多挑战、复杂性和成本。使用Aerosol Jet®直写技术打印保形互连可以为封装设计人员和射频工程师提供一种优化互连过渡到有源芯片的新方法,根据特定的应用要求定制损耗特性,并消除补偿高信号传输损耗的需要。印刷的互连可以用各种金属和介电材料数字化设计到封装中。由于这些互连是在封装的3D表面上共形打印的,因此走线长度可以最小化,环路高度为零,从而减少了寄生电感,特别是对于板上模、槽内模或具有衬垫封装配置的模上模的有源电路。在这项工作中,使用银纳米颗粒油墨的Aerosol Jet®印刷互连与金微带传输线以及传统的金键合线进行了比较,其性能高达110 GHz。我们将分享一些例子,展示印刷互连可以具有与微带相似的射频传输性能,特别是在高频下,其损耗明显低于键合线。我们还将根据一组使用银墨水印刷的给定线宽的不同线高的结果,讨论高达110 GHz的气溶胶喷射®印刷RF互连的设计效果。
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引用次数: 2
Mechanical Characterization of SAC305 and SnPb36Ag2 BGA Assemblies Under Static Flexural Loading 静态弯曲载荷下SAC305和SnPb36Ag2 BGA组件的力学特性
Pub Date : 2023-03-20 DOI: 10.37665/smt.v36i1.34
J. Libot, O. Dalverny, J. Alexis, Jeremy Bosq
Static bending-induced solder joints damage is a main reliability concern for aerospace and military industries whose Printed Circuit Board Assemblies (PCBAs) are required to remain functional under flexural loading. In order to dissipate heat in an equipment, it is common to install thermal gap pads on electronic packages. When compressing thermal gap pads during the fixture process, the PCBA can bend and solder joints can therefore crack if the deflection is too important. This paper reports the durability of 96.5Sn-3.0Ag-0.5Cu (SAC305) and 62Sn-36Pb-2Ag (SnPb36Ag2) Ball Grid Array (BGA) assemblies under static flexural loading at -55°C, 20°C and 125°C. As electronic equipment can be stored at high temperature for prolonged durations, some SAC305 test vehicles were also aged at 125°C for 192 hours. For each test configuration, the bending tests were conducted at a ramp-rate of 2 mm/min and the central displacement-to-failure was measured. Finite Element Modeling (FEM) analysis was conducted considering a global-local approach and the transfer function between the central displacement-to-failure and the local PCB strain near the critical solder joints was determined for each test configuration. The results give the necessary data for designers to assess whether a specific PCBA design subjected to static bending is at risk or not.
静电弯曲引起的焊点损坏是航空航天和军事工业的主要可靠性问题,其印刷电路板组件(pcba)需要在弯曲载荷下保持功能。为了在设备中散热,通常在电子封装上安装热隙垫。当在夹具过程中压缩热间隙垫时,PCBA可能弯曲,如果偏转太重要,焊点可能因此破裂。本文报道了96.5Sn-3.0Ag-0.5Cu (SAC305)和62Sn-36Pb-2Ag (SnPb36Ag2)球栅阵列(BGA)组件在-55°C、20°C和125°C静态弯曲载荷下的耐久性。由于电子设备可以在高温下长时间储存,一些SAC305测试车辆也在125°C下老化192小时。对于每种测试配置,弯曲测试以2 mm/min的斜坡速率进行,并测量中心位移到破坏。采用全局-局部方法进行有限元建模(FEM)分析,确定了每种测试配置下关键焊点附近的中心位移-失效与局部PCB应变之间的传递函数。结果为设计师提供了必要的数据,以评估特定的PCBA设计是否受到静态弯曲的风险。
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引用次数: 0
A Gauge Study of an Intercomparison Evaluation to Implement the use of Fine-Pitch Test Patterns for Surface Insulation Resistance (SIR) Testing of Solder Fluxes 在焊锡助焊剂表面绝缘电阻(SIR)测试中使用细间距测试模式的相互比较评估的测量研究
Pub Date : 2022-04-01 DOI: 10.37665/smt.v35i1.24
C. Hunt
SIR is a recognised tool for establishing electrochemical reliability of electronic assemblies. Currently the test patterns in the standards reflect coarse pitch components. An intercomparison has been completed with the aim of establishing the introduction of a fine pitch SIR pattern with a 200µm gap. This exercise included the contribution from seven international participants. This new pattern moves the test method forward into the realm of current technologies where components of this pitch are common place. The study reported here validates the basis for the introduction of the new pattern, and confirms acceptable Gauge R&R for the SIR technique. The analysis also highlights the challenges in controlling humidity to achieve comparable results between different users. The results also point to the challenges in achieving acceptable Gauge R&R when measuring resistances >1011Ω.
SIR是建立电子组件电化学可靠性的公认工具。目前标准中的测试模式反映的是粗节距部件。为了建立具有200 μ m间隙的细间距SIR模式的引入,已经完成了相互比较。这项工作包括七个国际参与者的贡献。这种新模式将测试方法推进到当前技术的领域,在这个领域中,这种pitch的组件是常见的。这里报告的研究验证了引入新模式的基础,并确认了SIR技术的可接受的测量R&R。该分析还强调了控制湿度以在不同用户之间实现可比结果的挑战。结果还指出了在测量电阻>1011Ω时实现可接受的Gauge R&R的挑战。
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引用次数: 0
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Journal of Surface Mount Technology
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