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Estimation of Exhalation Rates of Radon and Thoron in the Soil Samples Collected from Gurugram, Haryana, India 印度哈里亚纳邦Gurugram土壤样品中氡和钍的呼出率估计
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i11.2657
Natural radioactivity is the term used to describe radioactivity that persists in the soil, rocks, and water due to fundamental radionuclides such as uranium, thorium, potassium, etc. As a result, radiation affects everyone on the planet. Researchers worldwide find this topic particularly interesting due to the hazardous effects of radionuclides on human health. A systematic survey employing trustworthy methodological approaches is necessary to objectively assess these radionuclides in the environment. In the present paper, ZnS:Ag scintillator-based SMART RnDuo (AQTEK System, India) is used to measure exhalation rates of isotopes 222Rn and 220Rn (radon and thoron) of soil samples. Forty soil samples were studied. For the study of 222Rn, monitoring of the mass exhalation (Rm) was conducted. In the case of 220Rn, monitoring of surface exhalation (Rs) was studied. The radon mass exhalation rate is found in the range of 14±1 to 55±5 mBqkg−1h−1 with an average of 34±10 mBqkg−1h−1 and thoron surface exhalation rate in the range of 2200±215 to 7560±420 Bqm−2h−1 with an average of 4280±960 Bqm−2h−1. Thus, elevated thoron level is observed in most of the samples. Results are compared with the world’s average values.
自然放射性是指由于铀、钍、钾等基本放射性核素在土壤、岩石和水中持续存在的放射性。因此,辐射影响着地球上的每个人。由于放射性核素对人类健康的有害影响,全世界的研究人员都觉得这个问题特别有趣。为了客观地评价环境中的这些放射性核素,有必要采用可靠的方法进行系统的调查。本文利用基于ZnS:Ag闪烁体的SMART RnDuo(印度AQTEK系统)测量了土壤样品中222Rn和220Rn同位素(氡和钍)的呼出率。对40个土壤样品进行了研究。对于222Rn的研究,进行了大量呼出(Rm)的监测。在220Rn的情况下,研究了表面呼出(Rs)的监测。氡质量呼出率范围为14±1 ~ 55±5 mBqkg−1h−1,平均值为34±10 mBqkg−1h−1;氡表面呼出率范围为2200±215 ~ 7560±420 Bqm−2h−1,平均值为4280±960 Bqm−2h−1。因此,在大多数样品中观察到钍水平升高。结果与世界平均值进行了比较。
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引用次数: 0
Synthesis of Iron Oxide Nanoparticles from Scrapped Waste Materials for Efficient Dye Removal to Purify Industrial Waste Water 废料合成氧化铁纳米颗粒高效除染净化工业废水
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i11.3113
In this investigation, we used a circular economy approach by recycling metal scrap from industry as a component in creating nanoparticles. For producing iron oxide NPs we used electrochemical method with scrapped rusted iron nails as electrodes. In this technique, we used 50mM ferrous sulphate solution as an electrolyte and a direct current power supply. Different methods were used to characterise the synthesised iron oxide NPs, including ultraviolet-visible (UV-visible) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM). The results demonstrated that the synthesised iron oxide NPs have an average crystallite size of 7.54 nm. Iron oxide NPs has potential to adsorb Congo red dye hence prepared NPs have been utilised for the adsorption of Congo red dye.
在本次调查中,我们采用了循环经济的方法,回收来自工业的金属废料作为制造纳米粒子的组成部分。采用电化学方法,以生锈的废铁钉为电极制备氧化铁纳米粒子。在这项技术中,我们使用50mM硫酸亚铁溶液作为电解液和直流电源。采用紫外可见光谱(UV-visible)、傅里叶变换红外光谱(FTIR)、x射线衍射(XRD)和透射电子显微镜(TEM)等方法对合成的氧化铁NPs进行表征。结果表明,合成的氧化铁纳米粒子的平均晶粒尺寸为7.54 nm。氧化铁NPs具有吸附刚果红染料的潜力,因此制备的NPs已被用于吸附刚果红染料。
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引用次数: 0
Unravelling the Ultralow Thermal Conductivity of Ternary Antimonide Zintl Phase RbGaSb2: A First-principles Study 揭开三元锑锌RbGaSb2的超低导热性:第一性原理研究
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i9.3152
The recent discovery of antimonide based Zintl phase compounds has sparked the research in finding high-performance thermoelectric materials. In present study, a ternary antimonide Zintl phase RbGaSb 2 is investigated using First-principles calculations. A good agreement observed between our computed results, such as lattice parameter and thermal conductivity, with the experimental report validating our theoretical framework. A direct band gap of 1.17 eV is obtained using Tran Blaha modified Becke Johnson approach. The negative value of Seebeck coefficient indicates its n-type character. We purpose a strategy for enhancing power factor via carrier concentration optimization. The calculated results reveal the anisotropic transport properties. The intrinsic ultralow lattice thermal conductivity about 0.094 Wm -1 K -1 along the x-direction, and 0.019 Wm -1 K -1 along z-direction at room temperature is obtained. The ZT value can reach 0.90 (in x-direction) and 0.85 (in z-direction) for n-type doping at 900 K, indicating RbGaSb 2 as promising thermoelectric material.
最近发现的基于锑化物的Zintl相化合物引发了寻找高性能热电材料的研究。本文用第一性原理计算方法研究了一种三元锑化物Zintl相RbGaSb2。我们的计算结果,如晶格参数和热导率,与实验报告验证了我们的理论框架之间有很好的一致性。采用Tran Blaha修正的Becke Johnson方法获得了1.17 eV的直接带隙。塞贝克系数为负值表明其具有n型特征。我们提出了一种通过优化载流子浓度来提高功率因数的策略。计算结果揭示了各向异性输运性质。在室温下,沿x方向的本征超低晶格导热系数约为0.094 Wm-1K-1,沿z方向的本征超低晶格导热系数约为0.019 Wm-1K-1。在900 K时,n型掺杂的ZT值可达x方向0.90和z方向0.85,表明RbGaSb2是一种很有前途的热电材料。
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引用次数: 0
Adsorption of RB dye by Ce and Er Doped SnO2 Photocatalysts for Water Remediation Ce和Er掺杂SnO2光催化剂对RB染料的吸附及水处理
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i9.3407
This study focuses on synthesis of pure SnO2 nanoparticles and SnO2 nanoparticles doped with Erbium (Er) at 7% and Cerium (Ce) at 7% using sol-gel method. The aim was to evaluate their photocatalytic performance in degrading the harmful Rose bengal dye. XRD analysis confirmed that both undoped and rare earth-doped SnO2 nanoparticles exhibited a tetragonal rutile structure. Photoluminescence (PL) analysis revealed an increase in oxygen vacancy concentration with higher dopant incorporation. Furthermore, band gap of doped SnO2 nanoparticles was reduced compared to pure SnO2. The reduction in the band gap was primarily attributed to creation of vacancy defects caused by dopants. Photocatalytic experiments demonstrated that within 60 minutes of UV light exposure, Er 7% doped SnO2 nanoparticles achieved the degradation of 95.32% of Rose bengal dye. These findings highlight the potential of Er 7% doped SnO2 as a highly effective catalyst for large-scale degradation of industrial waste, specifically organic dyes.
本文主要研究了溶胶-凝胶法制备了纯SnO2纳米粒子和掺铒(Er)和铈(Ce)分别为7%和7%的SnO2纳米粒子。目的是评价其光催化降解有害的孟加拉玫瑰染料的性能。XRD分析证实,未掺杂和掺稀土的SnO2纳米颗粒均表现为四方金红石结构。光致发光(PL)分析表明,随着掺杂剂的增加,氧空位浓度增加。此外,与纯SnO2相比,掺杂SnO2纳米颗粒的带隙减小。带隙的减小主要是由于掺杂剂引起的空位缺陷的产生。光催化实验表明,在紫外光照射60分钟内,掺铒7%的SnO2纳米粒子对粉红染料的降解率达到95.32%。这些发现突出了Er 7%掺杂SnO2作为大规模降解工业废物,特别是有机染料的高效催化剂的潜力。
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引用次数: 0
Influence of Various Parameters on the Triboelectric Generation of Bulk Materials 不同参数对块状材料摩擦发电的影响
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i9.4741
In this paper we report the study of mechanical energy harvesting of ambient energy based on triboelectric effect. We choose the bulk form of poly-tetrafluoroethylene (PTFE) as electronegative (E-) material and human hand and plywood as the electropositive (E+) materials, respectively making a single electrode based triboelectric generator (TEG). The E+ and E- material were rubbed together to produce a voltage output, which was measured by using a sensitive electrometer. This investigation was carried out for different surface morphology, surface areas of contact, thickness and types of electrode contacts and rubbing frequency. It was observed that sufficient voltage and charge generation was achieved to power low energy devices like LED bulbs, with the highest voltage generation of ~6.2 V for rectangular PTFE sheet, having one surface coated with a thin film of copper for making electrode and other one is made rough using sandpaper, as the E- material and plywood as the E+ material. We observed that the voltage output is influenced by the surface morphology, type of E+ material for the same E- material, frequency of rubbing strokes and frictional area of contact.
本文报道了基于摩擦电效应的环境能机械能收集的研究。我们选择块状聚四氟乙烯(PTFE)作为电负性(E-)材料,人的手和胶合板作为电正性(E+)材料,分别制作了单电极摩擦发电机(TEG)。E+和E-材料摩擦在一起产生电压输出,用灵敏静电计测量。研究了不同的表面形貌、接触表面积、电极接触的厚度和类型以及摩擦频率。观察到产生足够的电压和电荷来为LED灯泡等低能耗器件供电,其中矩形聚四氟乙烯板产生的最高电压为~6.2 V,其中一个表面涂有铜薄膜用于制作电极,另一个表面用砂纸进行粗糙处理,作为E-材料,胶合板作为E+材料。我们观察到,电压输出受表面形貌、相同E-材料的E+材料类型、摩擦行程频率和接触摩擦面积的影响。
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引用次数: 0
Effect of Ag Layer Thickness and Interference of Cu-SnO2/Ag/Cu-SnO2 (CTO/Ag/CTO) Multilayer Thin Film on the Electrical and Optical Properties Cu-SnO2/Ag/Cu-SnO2 (CTO/Ag/CTO)多层薄膜Ag层厚度和干涉对电学和光学性能的影响
4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.56042/ijpap.v61i9.3498
The present study reports the successful fabrication of CTO/Ag/CTO multilayer thin films with different sandwiched layer (Ag) thickness on a glass substrate by the E-beam evaporation Method. The influence of sandwiched layer thickness and stacking of layers on electrical and optical properties was investigated. Several analytical tools such as X-ray diffraction, Atomic Force microscopy, Hall Effect measurement, and UV-visible spectroscopy were used to investigate the morphological, electrical, and optical properties of the multilayer thin film structure. Multilayer thin film with 14nm Ag thickness exhibited a good combination of conductivity and transmittance (i.e. 4.64 × 104 Ω-1cm-1, 69.3%). The conduction mechanism can be explained on the basis of the islands growth mechanism of Volmer-weber model as Ag film was grown on an amorphous CTO surface. The Haacke’s figure of merit was calculated for valuing the overall performance of the transparent conducting film. The maximum figure of merit is reported as 8.7 × 10-3 Ω-1 for multilayer thin film having Ag thickness of 14nm.
本文报道了用电子束蒸发法在玻璃基板上成功制备了不同夹层厚度的CTO/Ag/CTO多层薄膜。研究了夹心层厚度和层间堆叠对材料电学和光学性能的影响。利用x射线衍射、原子力显微镜、霍尔效应测量和紫外可见光谱等分析工具研究了多层薄膜结构的形态学、电学和光学性质。Ag厚度为14nm的多层薄膜具有良好的电导率和透光率组合(4.64 × 104 Ω-1cm-1, 69.3%)。银膜在非晶CTO表面生长时的传导机理可以用Volmer-weber模型的岛生长机理来解释。哈克的价值指数是用来评估透明导电膜的整体性能的。Ag厚度为14nm的多层薄膜的最大优值为8.7 × 10-3 Ω-1。
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引用次数: 0
Quantum Transport in Mesoscopic Systems 介观系统中的量子输运
IF 0.7 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-01-06 DOI: 10.3390/books978-3-03943-367-4
A. Jayannavar
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引用次数: 37
Temperature dependence of dielectric constant and loss tangent in methyl ammonium aluminium alum 甲基铵铝明矾介电常数和损耗正切的温度依赖性
IF 0.7 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2016-03-22 DOI: 10.7598/cst2016.1206
A. Rawat
A model of pseudospin-lattice coupled mode for methyl ammonium aluminium alum (MASD) has been modified to include cubic and quartic phonon anharmonic interactions. With the help of double-time temperature dependent Green’s function method and modified Hamiltonian, expressions for soft mode frequency, dielectric constant and loss tangent have been evaluated. By fitting model values of physical quantities in the theoretical expressions, temperature dependence of soft mode frequency, dielectric constant and loss tangent have been obtained and compared with experimental results of Pepinsky et al. 15 , which show a good agreement.
修正了甲基铵铝明矾(MASD)的赝自旋-晶格耦合模式模型,使其包含立方和四次声子非调和相互作用。利用双时间温度相关格林函数法和修正哈密顿量,求出了软模频率、介电常数和损耗正切的表达式。通过拟合理论表达式中物理量的模型值,得到了软模频率、介电常数和损耗正切与温度的依赖关系,并与Pepinsky et al. 15的实验结果进行了比较,结果吻合较好。
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引用次数: 0
Plasmon characteristics in stage-1 graphene intercalation compounds 一级石墨烯插层化合物中的等离子体特性
IF 0.7 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2015-05-18 DOI: 10.1063/1.4915393
S. Acharya, Raman Sharma
The plasmon characteristics in stage-1 graphene intercalation compounds (GIC’s) using the massless Dirac fermion (MDF) gas approximation have been reported. The superlattice model of GIC’s with negligible c-axis conductivity has been considered. With the discussion of the weak and the strong c-axis coupling at graphene-intercalant hetrojunction plasmon characteristics of GIC’s are predicted. A reasonable agreement has been found between our results and the experimental results of Ritsko and Rice.
利用无质量狄拉克费米子(MDF)气体近似,报道了一级石墨烯插层化合物(GIC)中的等离子体特征。考虑了c轴电导率可忽略的超晶格模型。通过对石墨烯-插层异质结弱和强c轴耦合的讨论,预测了石墨烯-插层异质结等离子体的特性。我们的结果与Ritsko和Rice的实验结果有相当的一致性。
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引用次数: 1
Ecological, exergetic efficiency and heating load optimizations for irreversible variable-temperature heat reservoir simple air heat pump cycles 不可逆变温蓄热器简单空气热泵循环的生态、有效效率和热负荷优化
IF 0.7 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2009-12-01 DOI: 10.1093/IJLCT/CTP037
Y. Bi, Lingen Chen, F. Sun
Thermodynamic optimization of an irreversible air heat pump with variable-temperature heat reservoirs and hot- and cold-side counter-flow heat exchangers has been studied. The expressions of the heating load, the exergetic efficiency and the ecological function of the heat pump cycle are derived. Performance comparisons among exergetic efficiency optimization, ecological optimization and traditional heating load optimization objectives are done. The effect of the pressure ratio of the compressor, the allocation of heat exchanger inventory and the heat capacity rate matching between the working fluid and the heat reservoirs on the optimal performance of the cycle has been investigated by detailed numerical examples. When the performance optimization of the cycle is carried out by selecting the pressure ratio, three optimization objectives give simultaneously attention to the coefficient of performance (COP). The pressure ratio should be the one that is little bigger than the optimum pressure ratio corresponding to maximum COP, however, the results of three optimization objectives are consistent by optimizing the allocation of heat exchanger inventory and optimizing the heat capacity rate matching between the working fluid and the heat reservoirs. The optimum allocations of heat conductance are close to each other, and they are all less than 0.5. The results may provide guidelines for the design and optimization of practical air heat pump plants.
研究了具有变温蓄热器和冷热侧逆流换热器的不可逆空气热泵的热力优化问题。推导了热泵循环的热负荷、用能效率和生态功能的表达式。比较了用能优化、生态优化和传统热负荷优化目标的性能。通过详细的数值算例,研究了压缩机压力比、换热器库存配置、工质与蓄热器热容率匹配等因素对循环优化性能的影响。在选择压力比进行循环性能优化时,三个优化目标同时关注性能系数(COP)。压力比应略大于最大COP对应的最佳压力比,但通过优化换热器库存配置和优化工质与储热器的热容比匹配,三个优化目标的结果是一致的。导热系数的最优分配较为接近,均小于0.5。研究结果可为实际空气热泵装置的设计和优化提供指导。
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引用次数: 6
期刊
Indian Journal of Pure & Applied Physics
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