Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH1
R. Andersen, A. Bryan, Michelle Faust, P. Power
The intention of this chapter is to describe in detail reliable synthetic procedures for the uncomplexed metal bissilylamides M{N(SiMe3)2}2 (M =Mn, Fe, or Co) as well as those of their mono-tetrahydrofuran complexes M{N(SiMe3)2}2(THF). In addition, a synthesis for the bis(THF) complex Mn{N(SiMe3)2}2(THF)2 is given. The bis(trimethylsilyl)amido group {N(SiMe3)2} −1, 2 is one of the simplest, most versatile, and inexpensive bulky monodentate ligands. Its steric properties were first demonstrated by Bürger and Wannagat via the synthesis of several low(i.e. twoor three-) coordinate transition metal derivatives in the early 1960s. They were prepared by the simple reaction of an alkali metal salt of the amide {N(SiMe3)2} − with chromium, manganese, iron, cobalt, nickel, or copper halides. The list of new compounds 4 included the trivalent complexes M{N(SiMe3)2}3 (M = Cr and Fe), the divalent species M{N(SiMe3)2}2 (M =Mn, Co, and Ni (unstable)), and the monovalent Cu{N(SiMe3)2}. 4 The volatility of M(II) and M(III) derivatives supported the notion that the compounds had unassociated molecular structures and were therefore the first stable examples of open-shell (i.e. d–d) transition metal complexes with coordination numbers less than four. The closed-shell (d) Cu(I) derivative, although volatile, proved to be tetrameric {CuN(SiMe3)2}4 with four coppers arranged in a planar array and bridged by silylamido ligands. The trigonal planar coordination of the M(III) species was proven for Fe{N(SiMe3)2}3 via a determination of its crystal
{"title":"DIVALENT MANGANESE, IRON, AND COBALT BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND THEIR TETRAHYDROFURAN COMPLEXES","authors":"R. Andersen, A. Bryan, Michelle Faust, P. Power","doi":"10.1002/9781119477822.CH1","DOIUrl":"https://doi.org/10.1002/9781119477822.CH1","url":null,"abstract":"The intention of this chapter is to describe in detail reliable synthetic procedures for the uncomplexed metal bissilylamides M{N(SiMe3)2}2 (M =Mn, Fe, or Co) as well as those of their mono-tetrahydrofuran complexes M{N(SiMe3)2}2(THF). In addition, a synthesis for the bis(THF) complex Mn{N(SiMe3)2}2(THF)2 is given. The bis(trimethylsilyl)amido group {N(SiMe3)2} −1, 2 is one of the simplest, most versatile, and inexpensive bulky monodentate ligands. Its steric properties were first demonstrated by Bürger and Wannagat via the synthesis of several low(i.e. twoor three-) coordinate transition metal derivatives in the early 1960s. They were prepared by the simple reaction of an alkali metal salt of the amide {N(SiMe3)2} − with chromium, manganese, iron, cobalt, nickel, or copper halides. The list of new compounds 4 included the trivalent complexes M{N(SiMe3)2}3 (M = Cr and Fe), the divalent species M{N(SiMe3)2}2 (M =Mn, Co, and Ni (unstable)), and the monovalent Cu{N(SiMe3)2}. 4 The volatility of M(II) and M(III) derivatives supported the notion that the compounds had unassociated molecular structures and were therefore the first stable examples of open-shell (i.e. d–d) transition metal complexes with coordination numbers less than four. The closed-shell (d) Cu(I) derivative, although volatile, proved to be tetrameric {CuN(SiMe3)2}4 with four coppers arranged in a planar array and bridged by silylamido ligands. The trigonal planar coordination of the M(III) species was proven for Fe{N(SiMe3)2}3 via a determination of its crystal","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"os-49 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87246563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH8
Hanan E. Abdou, A. A. Mohamed, J. Fackler, Mukunda M. Ghimire, M. Omary, D. Schilter, T. Rauchfuss, J. A. Denny, M. Darensbourg, M. Morshedi, P. Simpson, Bandar A. Babgi, Katy A. Green, G. J. Moxey, Mark S. Jennaway, M. Cifuentes, M. Humphrey, Samantha G. Eaves, P. Low, K. J. Nelson, Joel S A Miller, T. Woods, K. Dunbar, T. Johnstone, P. Štarha, A. Habtemariam, Sergey S. Zalesskiy, V. Ananikov, Alan J. Reay, I. Fairlamb, W. Geiger, J. Zink, M. J. Shaw, Jared S. Silvia, C. Cummins, D. Mindiola, P. L. Damon, T. Hayton, Matthias Reiners, Nico Ehrlich, M. Walter, Alexandre Hervé, C. D. Sofield, R. Andersen
{"title":"SYNTHESIS OF SELECTED TRANSITION METAL AND MAIN GROUP COMPOUNDS WITH SYNTHETIC APPLICATIONS","authors":"Hanan E. Abdou, A. A. Mohamed, J. Fackler, Mukunda M. Ghimire, M. Omary, D. Schilter, T. Rauchfuss, J. A. Denny, M. Darensbourg, M. Morshedi, P. Simpson, Bandar A. Babgi, Katy A. Green, G. J. Moxey, Mark S. Jennaway, M. Cifuentes, M. Humphrey, Samantha G. Eaves, P. Low, K. J. Nelson, Joel S A Miller, T. Woods, K. Dunbar, T. Johnstone, P. Štarha, A. Habtemariam, Sergey S. Zalesskiy, V. Ananikov, Alan J. Reay, I. Fairlamb, W. Geiger, J. Zink, M. J. Shaw, Jared S. Silvia, C. Cummins, D. Mindiola, P. L. Damon, T. Hayton, Matthias Reiners, Nico Ehrlich, M. Walter, Alexandre Hervé, C. D. Sofield, R. Andersen","doi":"10.1002/9781119477822.CH8","DOIUrl":"https://doi.org/10.1002/9781119477822.CH8","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84110206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH6
Chia-Wei Hsu, Y. Tsai, B. Cossairt, C. Camp, J. Arnold, C. Cummins
{"title":"SYNTHETIC ROUTE TO WHITE PHOSPHORUS (P4\u0000) AND ARSENIC TRIPHOSPHIDE (AsP3\u0000)","authors":"Chia-Wei Hsu, Y. Tsai, B. Cossairt, C. Camp, J. Arnold, C. Cummins","doi":"10.1002/9781119477822.CH6","DOIUrl":"https://doi.org/10.1002/9781119477822.CH6","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81514387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH7
A. Arif, B. Benac, A. Cowley, Richard A. Jones, Kenneth B. Kidd, C. M. Nunn, Andreas Kuckowski, S. Schulz, P. R. Harris, D. Atwood, C. Knapp, C. Carmalt, Jana Weßing, K. Freitag, Ganesamoorthy Chelladurai, Roland A. Fischer, J. Arnold, H. Roesky, Gregory S. Hair, D. Barisic, R. Anwander
{"title":"SYNTHETIC ROUTES TO PHOSPHIDO AND ARSENIDO DERIVATIVES OF THE GROUP 13 METALS ALUMINUM, GALLIUM, AND INDIUM, TRIS(TERT-BUTYL)GALLIUM AND ITS REACTIONS WITH AMMONIA, AND THE ALUMINUM(I) SPECIES PENTAMETHYLCYCLOPENTADIENYL ALUMINUM TETRAMER","authors":"A. Arif, B. Benac, A. Cowley, Richard A. Jones, Kenneth B. Kidd, C. M. Nunn, Andreas Kuckowski, S. Schulz, P. R. Harris, D. Atwood, C. Knapp, C. Carmalt, Jana Weßing, K. Freitag, Ganesamoorthy Chelladurai, Roland A. Fischer, J. Arnold, H. Roesky, Gregory S. Hair, D. Barisic, R. Anwander","doi":"10.1002/9781119477822.CH7","DOIUrl":"https://doi.org/10.1002/9781119477822.CH7","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"23 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89371548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH3
Riccardo Peloso, I. Resa, Amor Rodríguez, E. Carmona, K. Freitag, Cameron Jones, A. Stasch, Aaron J. Boutland, Felicitas Lips
{"title":"COMPOUNDS WITH Zn-Zn AND Mg-Mg BONDS","authors":"Riccardo Peloso, I. Resa, Amor Rodríguez, E. Carmona, K. Freitag, Cameron Jones, A. Stasch, Aaron J. Boutland, Felicitas Lips","doi":"10.1002/9781119477822.CH3","DOIUrl":"https://doi.org/10.1002/9781119477822.CH3","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"34 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86370993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH2
C. Glock, Sven Krieck, M. Westerhausen, Catherine M. Lavin, Miriam M. Gillett-Kunnath, Karin Ruhlandt, M. Hill, M. Anker, Andrew S. S. Wilson, Catherine Weetman, P. Arnold, Alex J. Veinot, Darcie L. Stack, J. Clyburne, Jason D. Masuda, D. Dickie, Ujwal Chadha, R. Kemp
{"title":"CALCIUM, STRONTIUM, GERMANIUM, TIN, AND LEAD BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND 2,2,6,6-TETRAMETHYLPIPERIDIDO ANDN-ISOPROPYLPHENYLAMIDO DERVATIVES OF POTASSIUM AND CALCIUM","authors":"C. Glock, Sven Krieck, M. Westerhausen, Catherine M. Lavin, Miriam M. Gillett-Kunnath, Karin Ruhlandt, M. Hill, M. Anker, Andrew S. S. Wilson, Catherine Weetman, P. Arnold, Alex J. Veinot, Darcie L. Stack, J. Clyburne, Jason D. Masuda, D. Dickie, Ujwal Chadha, R. Kemp","doi":"10.1002/9781119477822.CH2","DOIUrl":"https://doi.org/10.1002/9781119477822.CH2","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88266857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH4
G. Martinez, J. Killion, Bailey J. Jackson, Alison R. Fout, Brittney E. Petel, E. Matson, Benjamin M. Gridley, G. J. Moxey, D. Kays, A. Bryan, P. Power, J. Erickson, Ryan D. Riparetti, Toby J. Blundell, Ana M. Geer Ramos, Helen R. Sharpe, Mariham Y. Abraham, Jared C. Smith, Yuzhong Wang, G. Robinson, M. Saleh, Khalid. Osman, R. Wehmschulte, W. Brennessel, J. Ellis, R. Wolf, Uttam Chakraborty, Philipp Büschelberger, Christian Rödl, Anne-Kathrin Wiegel
{"title":"STERICALLY CROWDED σ- AND π-BONDED METAL ARYL COMPLEXES","authors":"G. Martinez, J. Killion, Bailey J. Jackson, Alison R. Fout, Brittney E. Petel, E. Matson, Benjamin M. Gridley, G. J. Moxey, D. Kays, A. Bryan, P. Power, J. Erickson, Ryan D. Riparetti, Toby J. Blundell, Ana M. Geer Ramos, Helen R. Sharpe, Mariham Y. Abraham, Jared C. Smith, Yuzhong Wang, G. Robinson, M. Saleh, Khalid. Osman, R. Wehmschulte, W. Brennessel, J. Ellis, R. Wolf, Uttam Chakraborty, Philipp Büschelberger, Christian Rödl, Anne-Kathrin Wiegel","doi":"10.1002/9781119477822.CH4","DOIUrl":"https://doi.org/10.1002/9781119477822.CH4","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75106263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-07DOI: 10.1002/9781119477822.CH5
Brandon R. Barnett, Charles C Mokhtarzadeh, Joshua S. Figueroa, P. Lummis, Shuai Wang, Joshua D. Queen, John Gavenonis, Nicolas Schüwer, T. Tilley, J. Boynton, P. Power, Treffly B. Ditri, N. Weidemann, Douglas W. Agnew, Patrick W. Smith, Alex E. Carpenter, Jade Pratt, Noah Mendelson
{"title":"TERPHENYL LIGANDS AND COMPLEXES","authors":"Brandon R. Barnett, Charles C Mokhtarzadeh, Joshua S. Figueroa, P. Lummis, Shuai Wang, Joshua D. Queen, John Gavenonis, Nicolas Schüwer, T. Tilley, J. Boynton, P. Power, Treffly B. Ditri, N. Weidemann, Douglas W. Agnew, Patrick W. Smith, Alex E. Carpenter, Jade Pratt, Noah Mendelson","doi":"10.1002/9781119477822.CH5","DOIUrl":"https://doi.org/10.1002/9781119477822.CH5","url":null,"abstract":"","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90909628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2010-09-08DOI: 10.1002/9780470651568.CH8
C. Fellay, G. Laurenczy
Keywords: ruthenium ; chloride free ; water soluble ; tosylate Reference EPFL-CHAPTER-161810doi:10.1002/9780470651568.ch8 Record created on 2010-12-16, modified on 2017-05-12
{"title":"Synthesis of chloride free ruthenium(II) hexaaqua tosylate, [Ru(H2O)6]tos2","authors":"C. Fellay, G. Laurenczy","doi":"10.1002/9780470651568.CH8","DOIUrl":"https://doi.org/10.1002/9780470651568.CH8","url":null,"abstract":"Keywords: ruthenium ; chloride free ; water soluble ; tosylate Reference EPFL-CHAPTER-161810doi:10.1002/9780470651568.ch8 Record created on 2010-12-16, modified on 2017-05-12","PeriodicalId":13689,"journal":{"name":"Inorganic Syntheses","volume":"27 1","pages":"152-155"},"PeriodicalIF":0.0,"publicationDate":"2010-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73179036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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