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Efficient phenol removal from aqueous solution using iron-coated pumice and leca as an available adsorbents: evalution of kinetics and isotherm studies 用铁包覆浮石和leca作为有效的吸附剂从水溶液中有效去除苯酚:动力学和等温线研究的评价
Pub Date : 2018-10-31 DOI: 10.30955/gnj.002783
R. Shokoohi, Zahra Torkshavand, S. Bajalan, H. Zolghadnasab, Z. Khodayari
Searching for low cost, accessible, simple implementation, and environmentally friendly adsorbents has been one of the concern of researchers in recent years. Therefore, the aim of this study was to investigate the efficient phenol removal from a synthetic aqueous solution using iron-coated pumice and LECA as an available adsorbents. Bath adsorption experiments were carried out to evaluate the effects of the independent variables such as pH (3-5-7-9-11), initial concentration of phenol (10-50mg/L), contact time (10-60 min) and different concentrations of pumice and LECA (0.2-1 g/100 cc) on the phenol adsorption. The results of the experiments showed that there was a direct relationship between the phenol removal efficiency and increasing the contact time and the adsorbent dosage but it has reverse relationship with the increasing of pH and phenol initial concentration. The optimal condition of parameters for phenol removal were 200 rpm agitation speed, 0.6 g adsorbent dosage, 30 min contact time, and 20 mg/L initial phenol concentration. The study of isotherm and kinetic models showed that the experimental data of the phenol adsorption process were correlated with Freundlich (R2pumice=0.9749, R2LECA=0.9487) and Pseudo-second order (R2pumice=0.9745, R2LECA=0.9486) models. Based on this study’s results, the modified pumice and LECA have a high ability to remove the phenol compounds from aqueous solution.
寻找成本低、易于获取、实施简单、环境友好的吸附剂是近年来研究人员关注的问题之一。因此,本研究的目的是研究用铁包覆浮石和LECA作为有效吸附剂对合成水溶液中苯酚的有效去除。通过液浴吸附实验,考察了pH(3-5-7-9-11)、苯酚初始浓度(10-50mg/L)、接触时间(10- 60min)以及不同浓度浮石和LECA (0.2-1 g/ 100cc)对苯酚吸附的影响。实验结果表明,苯酚去除率与增加接触时间和吸附剂投加量成正比关系,与pH和苯酚初始浓度的增加成反比关系。最佳脱酚条件为:搅拌转速200 rpm,吸附剂用量0.6 g,接触时间30 min,苯酚初始浓度20 mg/L。等温模型和动力学模型的研究表明,苯酚吸附过程的实验数据符合Freundlich模型(R2pumice=0.9749, R2LECA=0.9487)和伪二级模型(R2pumice=0.9745, R2LECA=0.9486)。研究结果表明,改性浮石和LECA对水溶液中酚类化合物具有较高的去除能力。
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