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Influence of Plastic Deformation and Aging Process on Microstructure and Tensile Properties of Cast Ti-6Al-2Sn-2Zr-2Mo-1.5Cr-2Nb-0.1Si Alloy 塑性变形和时效工艺对铸造Ti-6Al-2Sn-2Zr-2Mo-1.5Cr-2Nb-0.1Si合金组织和拉伸性能的影响
Pub Date : 2021-06-17 DOI: 10.4236/OJMETAL.2021.112002
M. S. El-Deeb, K. Ibrahim, S. S. Mohamed, R. Elshaer
In the present work, titanium alloy with a composition of Ti-6.5Al-3Mo-1.9Nb-2.2Sn-2.2Zr-1.5Cr (TC21) was subjected to plastic deformation and aging processes. A Plastic deformation at room temperature with 2%, 3% and 4% stroke strain was applied on the studied samples. Then, the samples aged at 575°C for 4 hr. By applying different plastic deformation ratios, the structure revealed an elongated and thin β-phase embedded in an α-phase. Secondary α-platelets were precipitated in the residual β-phase. Maximum hardness (HV440) was obtained for 4% deformed + aged samples. Minimum hardness (HV320) was recorded for the as-cast samples without deformation. The highest ultimate tensile strength of 1311 MPa was obtained for 4% deformed + aged samples due to presence of high amount of dislocation density as well as precipitation of secondary α-platelets in the residual β-phase. The lowest ultimate tensile strength of 1020 MPa was reported for as-cast samples. Maximum elongation of 14% was registered for 4% deformed + aged samples and minimum one of 3% was obtained for as-cast samples. Hence, strain hardening + aging can enhance considerably the elongation of TC21 Ti-alloy up to 366% and 133% in case of applying 4% deformation + aged compared to as-cast and aged samples without applying plastic deformation, respectively.
本研究对Ti-6.5Al-3Mo-1.9Nb-2.2Sn-2.2Zr-1.5Cr (TC21)钛合金进行了塑性变形和时效处理。对所研究的样品进行了2%、3%和4%行程应变的室温塑性变形。然后,将样品在575℃下时效4小时。采用不同的塑性变形比,结构呈现出嵌入α相的细长β相。次级α-血小板在残余β相析出。变形+时效4%的试样硬度最高,为HV440。无变形铸态试样的最低硬度记录为HV320。4%变形+时效试样的极限抗拉强度最高,达到1311 MPa,这主要是由于位错密度较大以及残余β相中次生α-血小板的析出。铸态试样的最低极限抗拉强度为1020 MPa。对于4%变形+时效的试样,最大伸长率为14%,而对于铸态试样,最小伸长率为3%。因此,与未施加塑性变形的铸态和时效样品相比,应变硬化+时效在施加4%变形+时效的情况下,TC21钛合金的伸长率分别可提高366%和133%。
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引用次数: 0
A New Type of Strong Metal-Support Interaction Caused by Antimony Species 锑类引起的新型强金属-载体相互作用
Pub Date : 2020-06-30 DOI: 10.4236/ojmetal.2020.102002
A. Benhmid, K. E. Ttaib, K. Edbey, V. N. Kalevaru, B. Lücke
Interactions between metals and supports are of fundamental interest in heterogeneous catalysis, Noble metal particles supported on transition metal oxides (TMO) may undergo a so-called strong metal-support interaction via encapsulation. This perspective addresses catalytic properties of the metal catalysts in the SMSI state which can be explained on the basis of complementary studies. The electronic geometric and bifunctional effects originating from strong metal-support interactions (SMSI) that are responsible for the catalyst’s activity, selectivity, and stability are key factors that determine performance. A series of Pd-Sb supported on different metal oxide (i.e. SiO2, γ-Al2O3, TiO2, and ZrO2) were prepared by the impregnation method. The catalysts were characterized by N2 adsorption (BET-SA and pore size distribution), TEM (transmission electron microscope), TPR (temperature-programmed reduction), CO-chemisorption, the structural characterization of Pd (dispersity, surface area), interaction between Pd and Sb2O3 and also the influence of the nature of the support were investigated. SiO2 supported Pd catalyst exhibited the highest surface area (192.6 m2/g) and pore volume (0.542 cm3/g) compared to the other supported oxides catalysts. The electron micrographs of these catalysts showed a narrow size particle distribution of Pd, but with varying sizes which in the range from 1 to 10 nm, depending on the type of support used. The results show almost completely suppressed of CO chemisorption when the catalysts were subjected to high temperature reduction (HTR), this suppression was overcome by oxidation of a reduced Pd/MeOx catalysts followed by re-reduction in hydrogen at 453 K low temperature reduction (LTR), almost completely restored the normal chemisorptive properties of the catalysts, this suppression was attributed by SbOx species by a typical SMSI effect as known for other reducible supports such as TiO2, ZrO2, CeO2, and Nb2O5.
金属和载体之间的相互作用是多相催化研究的重要内容,过渡金属氧化物(TMO)上的贵金属颗粒可能通过封装发生所谓的强金属-载体相互作用。这种观点解决了金属催化剂在SMSI状态下的催化性能,这可以在互补研究的基础上解释。由强金属支撑相互作用(SMSI)产生的电子几何效应和双功能效应决定了催化剂的活性、选择性和稳定性,是决定催化剂性能的关键因素。采用浸渍法制备了不同金属氧化物(SiO2、γ-Al2O3、TiO2和ZrO2)上的Pd-Sb。通过N2吸附(BET-SA和孔径分布)、TEM(透射电镜)、TPR(程序升温还原)、co -化学吸附、Pd的结构表征(分散性、表面积)、Pd与Sb2O3的相互作用以及载体性质的影响对催化剂进行了表征。SiO2负载Pd催化剂的比表面积(192.6 m2/g)和孔体积(0.542 cm3/g)均高于其他负载的氧化物催化剂。这些催化剂的电子显微图显示钯的粒径分布较窄,但根据所使用的载体类型的不同,钯的粒径在1 ~ 10 nm之间变化。结果表明,高温还原(HTR)几乎完全抑制了CO的化学吸附,这种抑制作用通过还原Pd/MeOx催化剂的氧化和453 K低温还原(LTR)下的氢再还原(LTR)来克服,几乎完全恢复了催化剂的正常化学吸附性能,这种抑制作用由SbOx物种归因于典型的SMSI效应,这是其他还原性载体(如TiO2)所知道的。ZrO2, CeO2和Nb2O5。
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引用次数: 0
Separation of Molybdenum Isotopes at Supercritical Fluid Extraction with Carbon Dioxide in a Vertical Gradient Field of Temperatures 垂直梯度温度场下二氧化碳超临界萃取钼同位素的分离
Pub Date : 2020-03-18 DOI: 10.4236/ojmetal.2020.101001
B. Borts, S. Skoromnaya, Viktor Ivanovich Tkachenко
Separation of molybdenum isotope complexes by supercritical fluid extraction (SFE) with carbon dioxide was studied experimentally. The extraction of molybdenum isotope complexes was carried out in the updated extraction chamber (reactor) of the SFE-U installation, which provided an initial pressure of P ≤ 20 MPa at constant temperatures of the upper T1 = 35°C and bottom T2 = 45°C flanges. The device, through which the eluent was discharged, involved a set of four thin tubes of different lengths located inside the reactor. The axes of the tubes and the reactor are parallel and the tubes are equally spaced circumferentially inside the reactor. The extract was removed from each tube through channels isolated from each other and located in the bottom flange with cylindrical expansion, in which several layers of filter paper were placed. After passing through the filters the extract entered a restrictor designed to remove the eluent from the reactor. The initial pressure of carbon dioxide and the holding time of the extract were specified in the experiments. The level of the eluent sampling was set by the lengths of the tubes depending on the reactor height. A method of producing molybdenum complexes was described. It was experimentally shown that at an initial pressure of 20 MPa and a given holding time a difference from the natural content of Mo isotopes for given heights of extract sampling depending on the reactor height was observed in extracts removed through filters. The ranges of deviation of the content of molybdenum isotopes in extracts from natural one were determined.
实验研究了二氧化碳超临界流体萃取法分离钼同位素配合物。钼同位素络合物的提取在SFE-U装置更新后的提取室(反应器)中进行,初始压力为P≤20 MPa,上T1 = 35℃,下T2 = 45℃法兰恒温。该装置是用来排出洗脱液的,它包括一组四根不同长度的细管,这些细管位于反应堆内部。管和反应器的轴是平行的,管在反应器内圆周上是等距的。提取液通过相互隔离的通道从每个管中取出,这些通道位于圆柱形膨胀的底部法兰中,其中放置了几层滤纸。在通过过滤器后,萃取物进入一个用来从反应器中除去洗脱液的限制器。实验中规定了二氧化碳的初始压力和提取液的保存时间。淋洗液取样的水平由取决于反应器高度的管的长度来设定。介绍了一种生产钼配合物的方法。实验表明,在20 MPa的初始压力和给定的保持时间下,通过过滤器去除的萃取物中Mo同位素的天然含量与给定萃取物取样高度的差异取决于反应器高度。测定了天然钼提取物中钼同位素含量的偏差范围。
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引用次数: 1
Synthesis of Polymer Blend Ferrite Composite for Microwave Absorption at X-Band Frequency x波段微波吸收聚合物共混铁氧体复合材料的合成
Pub Date : 2019-12-30 DOI: 10.4236/ojmetal.2019.94004
P. Dipak, D. C. Tiwari, S. Dwivedi
The microwave absorption properties of polymer composite PANI/PVA/NiFe2O3 are investigated. The polymer composites of PANI/PVA and NiFe2O3 are prepared in two steps. NiFe2O3 is synthesized by modified sol gel method and PANI by chemical polymerization method. Microwave absorption parameters of polymer composite are measured at X-band. The microwave absorption is found to be -28 dB (99%) at 10.2 GHz. Different characterization techniques such as SEM-EDX, FTIR and XRD are done. The SEM result shows flakes like structure for PANI/PVA and crystalline structure for NiFe2O3. FTIR of the composite reveals the interaction between the PANI/PVA and NiFe2O3.
研究了PANI/PVA/NiFe2O3聚合物复合材料的微波吸收性能。采用两步法制备了PANI/PVA和NiFe2O3聚合物复合材料。采用改性溶胶凝胶法和聚苯胺化学聚合法合成了NiFe2O3。在x波段测量了聚合物复合材料的微波吸收参数。在10.2 GHz处的微波吸收为-28 dB(99%)。采用SEM-EDX、FTIR和XRD等不同的表征技术。SEM结果显示PANI/PVA为片状结构,NiFe2O3为结晶结构。FTIR揭示了PANI/PVA与NiFe2O3之间的相互作用。
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引用次数: 3
Isolation of Iron Bacteria from Washing Sludge Filters Kolda (Senegal) Water Treatment Station and Study of the Kinetics of Biological Degradation of the Iron (II) Kolda(塞内加尔)水处理站洗涤污泥过滤器中铁细菌的分离及铁的生物降解动力学研究(II)
Pub Date : 2019-09-30 DOI: 10.4236/ojmetal.2019.93003
M. Faye, F. Sambe, M. Dieng, A. Toure, Matar Faye, C. Diop
In the present work, the treatment of synthetic waters doped with iron (II) has been studied. The treatment mechanism used in this study is the biological oxidation which consists, in test tubes, of bringing bacteria isolated on Petri dishes into contact with water containing divalent iron (II). These de-ironing bacteria (non-specific bacteria) are used to carry out laboratory biological oxidation experiments on iron (II) under different pH conditions (pH = 3.4 - 3.6, pH = 7.3 - 7.5 and pH = 9.8 - 10) and variable concentration of iron (II). Biological treatment trials included different concentrations of iron during time intervals of a day. Examination of the elimination kinetics of Iron (II) indicates a removal rate of 59.453% for an initial iron concentration in the synthetic solution of 1 mg·L−1 at basic pH (pH = 9.8 - 10). Therefore, the degradation of divalent iron by this method seems to be quite effective, but it should be noted that biological nitrification is impaired by the presence of high iron concentrations above 5 mg·L−1.
本文对掺杂铁(II)的合成水的处理进行了研究。本研究中使用的处理机制是生物氧化,在试管中,将培养皿中分离的细菌与含有二价铁(II)的水接触。这些除铁细菌(非特异性细菌)用于在不同pH条件下(pH = 3.4 - 3.6,pH = 7.3 - 7.5和pH = 9.8 - 10)和可变浓度的铁(II)。生物处理试验包括在一天的时间间隔内不同浓度的铁。对铁(II)去除动力学的研究表明,当初始铁浓度为1 mg·L−1时,在碱性pH (pH = 9.8 ~ 10)下,铁(II)的去除率为59.453%。因此,用这种方法降解二价铁似乎是相当有效的,但应该注意的是,当铁浓度超过5 mg·L−1时,生物硝化作用会受到损害。
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引用次数: 1
Fatigue Performance of Heat Treated TC21 Ti-Alloy 热处理TC21钛合金的疲劳性能
Pub Date : 2019-06-30 DOI: 10.4236/OJMETAL.2019.92002
R. Elshaer, K. Ibrahim, A. Barakat, R. Abbas
TC21 is considered a new titanium alloy that is used in aircraft applications as a replacement for the famous Ti-6Al-4V alloy due to its high strength. The effect of single and duplex stage heat treatments on fatigue behavior of TC21 Ti-alloy (Ti-6Al-2Sn-2Zr-3Mo-1Cr-2Nb-0.09Si, wt.%) was investigated. Two heat treatment cycles were applied on as-received TC21 Ti-alloy. The first cycle was called single stage heat treatment (SSHT). The other cycle was named duplex stage heat treatment (DSHT). Typical microstructures of SSHT & DSHT composed of primary equiaxed α phase, residual β phase and secondary α phase (αs). Secondary α phase was precipitated in the residual β phase due to low cooling rate using air cooling and aging treatment. Morphology of α phase does not change after solution treatments, while their volume fraction and grain size were changed. SSHT showed the highest fatigue strength of 868 MPa due to high tensile strength, hardness and existing of high percentages of residual β phase in the microstructure. However, DSHT reported lower fatigue strength of 743 MPa due to increasing grain size of α phase. The fracture surface of fatigue samples showed cleavage ductile fracture mode for both heat treatment cycles.
TC21被认为是一种新型钛合金,由于其高强度,被用于飞机应用,作为著名的Ti-6Al-4V合金的替代品。研究了单段和双段热处理对TC21钛合金(Ti-6Al-2Sn-2Zr-3Mo-1Cr-2Nb-0.09Si, wt.%)疲劳性能的影响。对TC21钛合金进行了两个热处理循环。第一个循环称为单阶段热处理(SSHT)。另一个循环称为双相阶段热处理(DSHT)。SSHT和DSHT的典型显微组织由初生等轴α相、残余β相和次生α相(αs)组成。由于空气冷却和时效处理的冷却速率较低,在残余的β相中析出了次生α相。固溶处理后α相的形貌没有发生变化,但其体积分数和晶粒尺寸发生了变化。SSHT合金具有较高的抗拉强度、硬度和组织中残余β相的高比例,其最高疲劳强度为868 MPa。然而,由于α相晶粒尺寸的增大,DSHT的疲劳强度降低至743 MPa。在两个热处理循环中,疲劳试样断口均呈现解理韧性断裂模式。
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引用次数: 1
Determination of Phase Transformation for TC21 Ti-Alloy by Dilatometry Method 膨胀法测定TC21钛合金的相变
Pub Date : 2019-03-31 DOI: 10.4236/OJMETAL.2019.91001
R. Elshaer, K. Ibrahim, A. Barakat, A. Farahat, R. Abbas
The α + β ↔ β phase transformation kinetics of TC21 Ti-alloy during continuous heating and cooling were studied using a dilatometric technique. Dilatometric heating curve exhibited that two characteristic reflection points can be observed with increasing the heating temperature. Ts referred to the initial transformation temperature of α + β → β and Tf referred to the final transformation temperature of α + β → β. Ts was reported at 720°C, whereas the corresponding Tf was obtained at 950°C. The initial and final transforming temperatures by the first derivative curve were reported at 730°C and 955°C, respectively, which are close to the values obtained in the dilatometric heating curve. Dilatometric cooling curve showed that the starting temperature of β → β + α phase transformation was 880°C; however, the corresponding finishing temperature was 670°C. The starting and finishing temperatures using the first derivative curve were obtained at 665°C and 885°C, respectively. The first derivative for the studied dilatometric heating and cooling curves showed that the starting and finishing temperatures of α + β ↔ β phase transformation were more accurate and objective. Results show the α + β → β transformation heating curve exhibits a typical S-shaped pattern.
用膨胀法研究了TC21钛合金在连续加热和冷却过程中的α + β↔β相变动力学。膨胀加热曲线显示,随着加热温度的升高,可以观察到两个特征反射点。其中,Ts为α + β→β的初始转变温度,Tf为α + β→β的最终转变温度。在720°C时得到Ts,而在950°C时得到相应的Tf。一阶导数曲线的初始和最终转变温度分别为730℃和955℃,与膨胀加热曲线的值接近。膨胀冷却曲线表明,β→β + α相变的起始温度为880℃;而相应的加工温度为670℃。利用一阶导数曲线得到的起始温度和结束温度分别为665℃和885℃。所研究的膨胀加热和冷却曲线的一阶导数表明,α + β↔β相变的开始和结束温度更为准确和客观。结果表明:α + β→β相变加热曲线呈典型的s型。
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引用次数: 3
Design Intervention: An Artistic Strategy (A Strategy) to Minimize Text Fading and Metal Commemorative Plaque Theft in Ghana 设计干预:加纳减少文字褪色和金属纪念匾盗窃的艺术策略
Pub Date : 1900-01-01 DOI: 10.4236/ojmetal.2023.131001
Ansah-Asiedu Junior, Mensah Fiifi Ebenezer, Vicku Charles, Samuel Nii Adamah Sampah, H. Barfi-Mensah, Anita Akwaa Toffah
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引用次数: 0
Rigorous Electromagnetic Modeling of a Micro Strip Line Incorporating a Flat and Thick Metallic Conductor Based on the Skin Effect Phenomenon 基于趋肤效应的含扁厚金属导体微带线严格电磁建模
Pub Date : 1900-01-01 DOI: 10.4236/ojmetal.2022.121001
R. Mejri, T. Aguili
In most studies of microstrip circuits, the majority of researchers assume that the microstrip structures studied have flat metallic conductors of finite widths but without thickness. But in reality these types of structures integrate metallic copper conductors of different thicknesses. If we neglect this thickness we introduce error in the electrical parameters of the microstrip structure, which affects the effective permittivity, the characteristic impedance, the adaptation of the circuit, the resonance frequency, etc. Given the importance of this parameter (thickness of the metal of micro rubon structures), rigorous electro-magnetic modeling of the thick micro rubon line based on the skin effect phenomenon (In fact at high frequency the skin effect phenomenon occurs and the current only flows on the periphery of the conductor) has been proposed to improve the studied electric model and ensure the increase in the precision of the analysis method used: Wave concept iterative process. The good agreement between the simulated and published data justifies the improvement of the model.
在大多数对微带电路的研究中,大多数研究者假设所研究的微带结构具有有限宽度但没有厚度的扁平金属导体。但实际上,这些类型的结构集成了不同厚度的金属铜导体。如果忽略这个厚度,微带结构的电学参数就会产生误差,从而影响有效介电常数、特性阻抗、电路的自适应、谐振频率等。考虑到该参数(微橡胶结构的金属厚度)的重要性,提出了基于集肤效应现象(实际上在高频下会出现集肤现象,电流仅在导体外围流动)的厚微橡胶线的严格电磁建模,以改进所研究的电模型,并确保所使用的分析方法的精度提高:波概念迭代过程。模拟数据与公布数据吻合较好,证明了模型的改进。
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引用次数: 0
Effect of Cast Thickness and Austenitizing Temperature on Microstructure and Mechanical Properties of ADI and IADI Castings 铸件厚度和奥氏体化温度对ADI和IADI铸件组织和力学性能的影响
Pub Date : 1900-01-01 DOI: 10.4236/ojmetal.2021.113003
Ahmed Negm, S. Mohamed, M. Ibrahim, I. Moussa, K. Ibrahim
This investigation studies the impact strength, tensile strength, hardness, and wear behavior of thin wall austempered and intercritically austempered ductile iron samples with a chemical composition of 3.37% C, 2.7% Si, 0.30% Mn, 0.01% S, and 0.01% P. The austempered samples were austenitized at 900˚C for 1 h and rapidly quenched in a salt bath furnace at 375˚C for 1 h. The intercritically austempered samples were sub-austenitized at 810˚C for 1 h and rapidly quenched in a salt bath furnace at 375˚C for 1 h. The properties of the austempered and intercritically austempered thin wall plates of 5, 10, and 15 mm thickness were evaluated and compared to the as-cast samples. Austempering process affects greatly the tensile properties of all cast thicknesses where ultimate strength reached 1004 MPa for 5-mm thickness. Optimum impact toughness of 40 J was obtained for the austempered samples of 10-and 15-mm thicknesses. The intercritically austempered samples showed properties between the austempered and as-cast samples. Maximum wear resistance was also reported for the austempered samples due to containing retained austenite in the structure which in turn transformed into martensite that increases well the wear resistance. Maximum ultimate strength (1056)
本文研究了化学成分为3.37% C、2.7% Si、0.30% Mn、0.01% S的薄壁等温和临界间等温球墨铸铁试样的冲击强度、拉伸强度、硬度和磨损性能。和0.01% p .奥氏体回火样本austenitized 900˚C 1 h和快速淬火盐浴炉的375˚C 1 h。临界区等温淬火样本sub-austenitized 810˚C 1 h和快速淬火在盐浴炉375˚C 1 h。等温淬火的属性和临界区等温淬火薄壁板5、10和15毫米厚度进行了评估和比较的铸的样本。等温回火工艺对各铸件厚度的拉伸性能影响较大,5mm厚度的极限强度可达1004 MPa。10mm和15mm等温试样的最佳冲击韧性为40j。临界间等温试样的性能介于等温试样和铸态试样之间。由于在组织中含有残留的奥氏体,而奥氏体又转化为马氏体,从而提高了耐磨性,因此,等温试样具有最大的耐磨性。最大极限强度(1056)
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引用次数: 0
期刊
Open Journal of Metal
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