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A Theoretical Framework of Mechanical Properties of the Monolayer Graphene 单层石墨烯力学性能的理论框架
Pub Date : 2023-01-17 DOI: 10.11648/j.ajn.20220804.11
Mohammad Imran Aziz, Nafis Ahmad
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引用次数: 0
Flexible Solar Modules Using Polycarbonate for Templating and Encapsulation 使用聚碳酸酯模板和封装的柔性太阳能组件
Pub Date : 2021-09-06 DOI: 10.11648/J.AJN.20210703.12
M. Khayyat
Combining both approaches of fabricating photovoltaic cells and designing solar modules using polycarbonate in the form of nanospheres and panels is an innovate approach in solar cells technology. Polycarbonate nanospheres was employed to control the position of the growth of silicon nanowires using the technique of Nanoscale Chemical Templating. The grown silicon nanowires were catalyzed via Vapor-Liquid-Solid (VLS) technique at the Chemical Vapor Deposition (CVD) or UHVCVD reactor. The bottom-up grown nanowires were doped with aluminium (Al) throughout the growth process then the p-i-n junctions were formed material. The conventional silicon cells or the innovative ones can be incapsulated in a polycarbonate flexible-surfaces. The polycarbonate material will allow us to further increase the performance of the devices and decrease the overall costs. The study presents concepts along with their experimental proofs presented as Scanning Electron Microscopy (SEM) micrographs, and optical characterizations. The proposed method is also flexible, as it is amenable to both standard lithography techniques and self-assembled patterning techniques.
结合这两种制造光伏电池的方法和利用聚碳酸酯以纳米球和面板的形式设计太阳能组件是太阳能电池技术的一种创新方法。采用纳米化学模板技术,利用聚碳酸酯纳米球控制硅纳米线的生长位置。采用气相-液-固(VLS)技术在化学气相沉积(CVD)或UHVCVD反应器中催化制备硅纳米线。自下而上生长的纳米线在整个生长过程中掺杂铝,形成p-i-n结材料。传统的硅电池或创新的硅电池可以被封装在聚碳酸酯柔性表面中。聚碳酸酯材料将使我们能够进一步提高设备的性能并降低总体成本。该研究提出了概念,并通过扫描电子显微镜(SEM)显微照片和光学表征提出了实验证明。所提出的方法也是灵活的,因为它适用于标准光刻技术和自组装图案化技术。
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引用次数: 0
Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial 钕离子掺杂氧化锌纳米材料的光谱、结构和表征
Pub Date : 2021-09-04 DOI: 10.11648/J.AJN.20210703.11
S. Pal, Y. Sharma, J. Singh
Zinc oxide with neodymium ions nanomaterials were synthesized by using the chemical synthesis method. The materials were characterized by XRD, FTIR, TEM, SEM and spectral analysis. From XRD, TEM and SEM images, the estimated average particle size are 20, 100 and 200nm respectively. Nearly hexagonal shapes for the dark spots in the TEM images indicate that the ZnO nanoparticles are almost hexagonal. SEM demonstrates clearly the formation of cluster type of ZnO nanoparticles and change of the morphology of the nanoparticles with the Nd3+ different ions concentration. UV- Visible absorption spectrum of the ZnO:Nd3+ nanomaterial was analyzed on the basis of Judd-Ofelt (J-O) theory. Nine absorption and four fluorescence bands have been observed at room temperature. Energy interaction and intensity parameters have been computed Fluorescence band have been assigned to transitions 4F3/2 → 4I9/2, 4F3/2 →4I11/2, 4F3/2 →4I13/2, and 4F3/2 →4I15/2. The radiative properties were computed using the J-O intensity parameters and fluorescence data. The value of emission cross-section is an important parameter and signifies the rate of energy extraction from the optical material.
采用化学合成方法合成了含钕离子氧化锌纳米材料。采用XRD、FTIR、TEM、SEM和光谱分析对材料进行了表征。从XRD、TEM和SEM图像中,估计的平均粒径分别为20、100和200nm。TEM图像中黑点的近六边形形状表明ZnO纳米粒子几乎是六边形的。扫描电镜清楚地显示了ZnO纳米颗粒簇型的形成以及不同浓度的Nd3+对纳米颗粒形貌的影响。基于Judd-Ofelt (J-O)理论分析了ZnO:Nd3+纳米材料的紫外-可见吸收光谱。在室温下观察到9条吸收带和4条荧光带。计算了能量相互作用和强度参数,确定了4F3/2→4I9/2、4F3/2→4I11/2、4F3/2→4I13/2和4F3/2→4I15/2跃迁的荧光带。利用J-O强度参数和荧光数据计算了其辐射特性。发射截面的大小是光学材料能量提取速率的重要参数。
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引用次数: 1
Upconverter Nanoparticles as Plasmon-induced Broadband Light Converters 等离子体诱导宽带光转换器的上变换器纳米粒子
Pub Date : 2021-05-08 DOI: 10.11648/J.AJN.20210702.11
V. León
We show numerically how lanthanide-doped upconverter nanocrystals inserted at optimal positions in adjustable and smooth 2D plasmonic arrays may change and potentially control the whole UV-visible-NIR reflectance spectra displayed by these structures. The analysis and interplay between a custom-built simple 5-levels 2-electrons quantum model and the bare structure have been studied in depth and revealed very fundamental and interesting physics. Essentially, the largely and selectively enhanced white-light excitation field and optimized local density of states at the location of the emitters favor some energy transfer paths and a redistribution of light energy in a broad spectral range. Interestingly, the extent to which the spectra can be modulated owing to the emission properties of such very robust multilevel emitters may find interesting applications and notably allow increased efficiency of emission in Light Emitting Devices or solar light redistribution and collection in Solar cells, where conversions from one color to any other one play a major role.
我们在数值上展示了在可调和光滑的二维等离子体阵列中插入在最佳位置的掺杂镧系上转换器纳米晶体如何改变并潜在地控制这些结构显示的整个紫外-可见-近红外反射光谱。对自定义的简单5能级2电子量子模型与裸结构之间的分析和相互作用进行了深入的研究,揭示了非常基础和有趣的物理学。从本质上讲,大量和选择性增强的白光激发场和优化的局域态密度在发射器的位置有利于一些能量转移路径和光能在宽光谱范围内的重新分配。有趣的是,由于这种非常强大的多能级发射器的发射特性,光谱可以调制的程度可能会发现有趣的应用,特别是可以提高发光装置的发射效率或太阳能电池中的太阳能光再分配和收集,其中从一种颜色到任何其他颜色的转换起着重要作用。
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引用次数: 0
Obtained Carbon Nano-onions from Underwater Arc Discharge Without the Complex Purification Procedures 采用水下电弧放电法制备碳纳米洋葱,无需复杂的提纯程序
Pub Date : 2021-02-23 DOI: 10.11648/J.AJN.20210701.14
Salih Mohamed Osman, Asma Mohamed Elhussein, Fatma Osman Mahmoud, Mohammed Bilal Sabahelkher, L. Caputi, Andrea Scarcello, F. Alessandro
Carbon nano-onions (CNOs), which consist of concentric graphitic shells, currently attract much attention because of their unique structural and physical properties, which are different from the properties of the other carbon nanomaterials such as fullerenes, graphene, and carbon nanotubes (CNTs). Due to their small size, the large external surface area and high conductivity, CNOs are used for supercapacitor applications. The arc discharge underwater is an effective and simple method for the synthesis of larger CNOs in reasonable quantities. In this research, we have been obtained carbon nanomaterials using arc discharge in water between two high purity graphite electrodes. The main experimental techniques used to characterize carbon nanostructures have been Transmission Electron Microscopy (TEM) and Raman Spectroscopy. Among them, Raman spectroscopy is the most useful non-destructive technique capable of differentiating between these various structures. Our TEM images showed that the samples collected from the material floating on the water surface consist CNOs with other carbon nanomaterials such as CNTs. We observed for the first time the formation of solid agglomerate on the cathode surface. Raman and TEM results revealed that the agglomerate is made exclusively of CNOs. The defragmentation of such agglomerate allows to obtain CNOs free of other carbon nanomaterials without the complex purification procedures needed for floating nanomaterials.
碳纳米洋葱(Carbon nano-onions, CNOs)是一种由同心石墨壳构成的纳米材料,由于其独特的结构和物理性质而备受关注,这与富勒烯、石墨烯和碳纳米管等其他碳纳米材料的性质不同。由于其体积小,外表面积大,电导率高,CNOs被用于超级电容器应用。水下电弧放电是一种有效而简单的方法,可以合成大量的CNOs。在本研究中,我们利用两个高纯度石墨电极之间的水中电弧放电获得了碳纳米材料。用于表征碳纳米结构的主要实验技术是透射电子显微镜(TEM)和拉曼光谱。其中,拉曼光谱是最有用的非破坏性技术,能够区分这些不同的结构。我们的TEM图像显示,从漂浮在水面上的材料中收集的样品由CNOs和其他碳纳米材料(如CNTs)组成。首次在阴极表面观察到固体结块的形成。拉曼光谱和透射电镜结果显示,该团块完全由CNOs组成。这种团聚体的整理允许获得不含其他碳纳米材料的CNOs,而无需浮动纳米材料所需的复杂纯化程序。
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引用次数: 1
Nanoindentation Induced Elastic-plastic Deformation of GaN Nanomembrane on a Sapphire Substrate 蓝宝石衬底上纳米压痕诱导GaN纳米膜的弹塑性变形
Pub Date : 2021-01-28 DOI: 10.11648/J.AJN.20210701.13
M. Khayyat, E. Bourhis, Rami T. Elafandy, T. Ng, B. Ooi
One of the main challenges of the production of a blue laser is the preparation of defect-free GaN layers. It is of high tehnological interest to characterize GaN nanomembrane mechanically for further advanced applications. The current study addresses the impact of applied stresses on GaN nanomembranes, which are placed on sapphire the substrates, using nanoindentation as a nondestructive test. The mechanical response of the 20, and 100 nm thin GaN nanomembrane were studied at different normal applied loads ranging from 1 mN down to 0.1 mN using the Berkovich nanoindentation technique. There were plastic deformation regions at the nanoindented GaN nanomembranes monitored by the load-displacement (p-h) curves. The depth of the deformed regions increased with increasing the applied loads on the diamond indenter. Beside the in-situ depth estimation of the residual nanoindentation using the instrumented nanoindentation machine, Atomic Force Microscopy (AFM) has been deployed as an ex-situ measurements of indentations depth. Scanning Electron Microscopy (SEM) provided us with surface images of the indented membranes. Indentation of the 100 nm thick GaN nanomembrane, where the effect of the substrate is reduced, showed discontinuity in the p-h curves. These discontinuity or pop-in events were attributed to a possible sudden initiation and propagation of threading dislocations in the GaN nanomembrane which was free of threading dislocation upon fabrication. It was suggested to employ μ-Raman spectroscopy methods to investigate the possible structural phase transformation of thicker GaN nanomembranes and to measure the compressive or tensile stresses within the center of the indented zones. Where the observed sudden load-displacements discontinuity or depth excursions during indentation of GaN nanomembranes can be attributed.
生产蓝色激光器的主要挑战之一是制备无缺陷的氮化镓层。机械表征氮化镓纳米膜具有很高的技术价值,可用于进一步的高级应用。目前的研究解决了施加应力对放置在蓝宝石衬底上的GaN纳米膜的影响,使用纳米压痕作为无损检测。利用Berkovich纳米压痕技术研究了20 nm和100 nm GaN纳米薄膜在1 mN到0.1 mN的不同载荷下的力学响应。载荷-位移(p-h)曲线监测到纳米缩进GaN纳米膜存在塑性变形区。随着金刚石压头所受载荷的增加,变形区域的深度增加。除了利用仪器纳米压痕机对残余纳米压痕进行原位深度估计外,原子力显微镜(AFM)也被用作压痕深度的原位测量。扫描电子显微镜(SEM)为我们提供了缩进膜的表面图像。在100 nm厚的GaN纳米膜的压痕处,衬底的影响减小,p-h曲线呈现不连续。这些不连续性或弹出事件归因于GaN纳米膜中螺纹位错的突然启动和传播,而GaN纳米膜在制造时没有螺纹位错。建议采用μ-拉曼光谱方法研究较厚的GaN纳米膜可能发生的结构相变,并测量压痕区中心的压应力或拉应力。在GaN纳米膜压痕过程中观察到的突然负载-位移不连续或深度偏移可以归因于此。
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引用次数: 2
Electrical and Optical Characteristics of Copper Antimony Sulphide Thin Films Fabricated in Chemical Baths of Different Growth Media 在不同生长介质的化学浴中制造的硫化锑铜薄膜的电气和光学特性
Pub Date : 2020-05-29 DOI: 10.11648/j.ajn.20200601.11
A. I. Onyia, M. N. Nnabuchi, A. Chima
Chemical Bath Deposition Technique has been used to fabricate thin films of copper antimony sulphide in two different growth media: water and polyvinyl alcohol and the effects of these media on the electrical and optical properties of the CuSbS2 thin films studied. The technique required a liquid precursor; usually a solution of organic metallic powder dissolved in an organic solvent and kept in a reaction bath where reaction takes place. The precursor reaction chemicals used were copper chloride, antimony chloride and sodium thiosulphate and precipitations were on pre-cleaned borosilicate glass substrate at room temperature and pH of 9.1. Both deposits were subsequently similarly annealed for an hour each at a temperature of 250°C before testing the optical characteristics of both films using a UV-VIS-NIR 200 – 1100 nm range spectrophotometer and electrical characteristics, using a Quadpro four point probe. A proton induced Rutherford backscattering done on films detected thicknesses of films to be 545 nm and 514 nm for water and PVA bath deposits respectively. The thin film resistivities recorded were also 770 Ωm and 699 Ωm respectively. Absorbance, refractive indices, and other major optical parameters of the thin films varied differently with growth media in the infra red but remained fairly same in the visible and other higher frequency ranges.
化学浴沉积技术用于在两种不同的生长介质(水和聚乙烯醇)中制造硫化锑铜薄膜,并研究了这些介质对 CuSbS2 薄膜的电气和光学特性的影响。该技术需要液态前驱体,通常是溶解在有机溶剂中的有机金属粉末溶液,并将其置于反应槽中进行反应。使用的前驱体反应化学品为氯化铜、氯化锑和硫代硫酸钠,沉淀在室温和 pH 值为 9.1 的预清洁硼硅玻璃基板上。随后,两种沉淀物同样在 250°C 的温度下各退火一小时,然后使用 UV-VIS-NIR 200 - 1100 nm 范围的分光光度计测试两种薄膜的光学特性,并使用 Quadpro 四点探针测试其电气特性。对薄膜进行质子诱导卢瑟福反向散射检测发现,水浴和 PVA 浴沉积的薄膜厚度分别为 545 nm 和 514 nm。记录到的薄膜电阻率也分别为 770 Ωm 和 699 Ωm。薄膜的吸收率、折射率和其他主要光学参数随生长介质的不同而变化,在红外线范围内不同,但在可见光和其他较高频率范围内基本保持不变。
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引用次数: 2
Preparation of Stable Microemulsions with Different Droplet Size 不同液滴大小稳定微乳的制备
Pub Date : 2019-12-11 DOI: 10.11648/J.AJN.20190504.18
Huang Shiyu, Chen Jiaxuan, Zhu Yeting, Wei Yelu, Di Tongtong, Shen Hangyan
Microemulsion is a widely used technique for preparing nanoparticles. The droplet size in stable microemulsions is a key parameter for limiting the size and shape of the formed nanoparticles. In this paper, the stable microemulsions were synthesized by two titration methods, the water titration method and the co-surfactant titration. Six reagents with different HLB were used as surfactants, including Span-80, E-1302, EL-10, MOA-9, Triton X-114 and OP-10. Quasi ternary phase diagrams of O/W and W/O microemusions with different surfactants were established according to the composition of surfactant, co-surfactant, oil and water. The size of the microemulsions droplets was characterized by using Zetasizer Nano S90. Within the stable micromulsions region, the droplet size was systemically controlled from 1 nm to 120 nm by changing different surfactants and controlling the quality ratio of components. A complex dependence of the droplet size on the water to surfactant ratio and the co-surfactant to surfactant ratio was established. In the stable microemulsions region, the droplets size increases dramatically with increased the water to surfactant ratio and the larger droplet size is obtained with increasing the co-surfactant amount.
微乳液是制备纳米颗粒的一种广泛应用的技术。稳定微乳中的液滴尺寸是限制纳米颗粒尺寸和形状的关键参数。本文采用水滴定法和助表面活性剂滴定法两种滴定法合成了稳定的微乳。采用6种不同HLB的试剂作为表面活性剂,分别为Span-80、E-1302、EL-10、MOA-9、Triton X-114和OP-10。根据表面活性剂、助表面活性剂、油和水的组成,建立了不同表面活性剂的油/水和油/水微乳液的准三元相图。用Zetasizer Nano S90表征了微乳液滴的大小。在稳定微乳液范围内,通过改变不同的表面活性剂和控制组分的质量比,系统地将液滴尺寸控制在1 ~ 120 nm之间。建立了液滴尺寸与水表面活性剂比和助表面活性剂比的复杂关系。在稳定微乳区,随着水与表面活性剂比的增加,微乳滴粒径显著增大,随着助表面活性剂用量的增加,微乳滴粒径增大。
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引用次数: 0
Identifying an Improved Jute Variety Preferring Physico-chemical Properties 黄麻改良品种的物化特性鉴定
Pub Date : 2019-12-05 DOI: 10.11648/J.AJN.20190504.15
M. Hossen, A. Khatton, Fa Dilruba
There are so many fibres, but not all of them are textile. Textile materials are generally soft, flexible, and capable of being transformed into desired shapes without resistance and durable over a reasonable period of wear. Jute –the Golden fibre of Bangladesh is used widely for various purposes. For the assessment of fibre quality of three types of jute fibre e.g. newly released jute variety-72, bleached fibre and variety O-9897 were considered for the analysis of physical properties (Reed jute fibre length, Brightness index, Whiteness index, Bundle strength and Fineness index) and chemical analysis (Cellulose, Hemicellulose, Lignin, Ash content, Fat/Oil content, Oil content in jute seed, Pectin content and safonification value) under the present study.Some field level morphological information was taken as quality contributing characteristics. The study was conducted at the Chemistry Division, Textile Physics Division and Pilot Plant and Processing Division of Bangladesh Jute Research Institute, Dhaka, Bangladesh during 2017-2019. The assessment of physico-chemical properties of the variety O-72 was blue seeded with lower percentage of oil content than naturally brown seeded but saponification value was higher, Brightness (22.04%), fineness (36.26%) and bundle strength (06.20 lb/mg) index were very much comparable to bleached jute samples using 6% hydrogen peroxide. Cellulose content was 65.68% as well as lignin and hemicelluloses content were 13.95% and 17.94% respectively which were more prominent than O-9897 varieties of jute fibres.
有这么多的纤维,但并不是所有的都是纺织纤维。纺织材料通常是柔软的,有弹性的,并且能够在没有阻力的情况下转变成所需的形状,并且在合理的磨损时间内耐用。黄麻——孟加拉国的金色纤维,被广泛用于各种用途。以新上市的黄麻品种—72、漂白后的黄麻品种—O-9897为研究对象,对其物理性能(黄麻纤维长度、亮度指数、白度指数、束强和细度指数)和化学性能(纤维素、半纤维素、木质素、灰分含量、脂/油含量、黄麻籽含油量、果胶含量和皂化值)进行了评价。一些田间水平的形态信息作为质量贡献特征。该研究是在2017-2019年期间在孟加拉国达卡的孟加拉国黄麻研究所的化学部门、纺织物理部门和中试工厂和加工部门进行的。对O-72品种的理化性质进行了评价,结果表明:用6%过氧化氢漂白后的黄麻样品的光亮度(22.04%)、细度(36.26%)和束强(06.20 lb/mg)指标与天然棕色黄麻相比,蓝籽油含量较低,但皂化值较高。纤维素含量为65.68%,木质素和半纤维素含量分别为13.95%和17.94%,比O-9897品种更为显著。
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引用次数: 0
Contamination of Heavy Metals, Source, Effects on Leaving Things and Different Remediation Techniques in Soil: A Review 土壤中重金属污染、来源、对残留物的影响及不同修复技术综述
Pub Date : 2019-12-05 DOI: 10.11648/J.AJN.20190504.17
A. Sisay
Different researches showed that contamination of heavy metals in soil has become more and more serious, which affects Both soil fertility degradation and detrimental to human health through food chain causing adverse effects on human health. The concentration of metals beyond Maximum Permissible Level (MCL) leads to number of nervous, cardiovascular, renal, neurological impairment as well as bone diseases and several other health disorders and also computed the macronutrient in the human body. Due to these it needs more attention towards the contamination area using either prevention or minimizing methods of the source of contamination. Different researches mentioned different remediation techniques which involve phytoremediation, lime, phosphates, and different biochar materials. Remediation mechanisms basically consist of two fundamental principles. The first is to completely remove contaminations from polluted area and the second is to transform these pollutants to harmless forms. The application of Biochar in soil makes dual purpose which ameliorating soil fertility and remediated heavy metal due to the content of different physicochemical properties. So in this paper, including source of heavy metal, effect of heavy metal in human, plant growth and soil microorganism and remediation technique of contaminated soil, reaction of biochar in soil and application of biochar in soil quality were discussed. Therefore this is particular importance as it indicates the value of biochar as alternative remediation and amendments to ameliorate soil nutrient and acid soils for small-scale farmers who cannot afford to regularly purchase lime and mineral fertilizers as compared to phytoremediation techniques. But phytoremediation wide scope of area use of plants to partially or substantially remediate selected contaminants in contaminated soil, sludge, sediment, groundwater, surface water, and wastewater.
不同的研究表明,土壤中重金属的污染越来越严重,不仅影响土壤肥力退化,而且通过食物链危害人体健康,对人体健康造成不良影响。金属浓度超过最大允许水平(MCL)导致许多神经、心血管、肾脏、神经损伤以及骨骼疾病和其他几种健康疾病,并计算了人体内的大量营养素。因此,需要更多地关注污染区域,使用预防或最小化污染源的方法。不同的研究提到了不同的修复技术,包括植物修复、石灰、磷酸盐和不同的生物炭材料。补救机制基本上包括两个基本原则。一是彻底清除污染区域的污染物,二是将这些污染物转化为无害的形式。生物炭在土壤中的应用由于其理化性质的不同,达到了改良土壤肥力和修复重金属的双重目的。本文从重金属的来源、重金属对人体、植物生长和土壤微生物的影响、污染土壤的修复技术、生物炭在土壤中的反应以及生物炭在土壤质量中的应用等方面进行了探讨。因此,这是特别重要的,因为它表明了与植物修复技术相比,生物炭作为改善土壤养分和酸性土壤的替代修复和修正的价值,对于那些无法负担定期购买石灰和矿物肥料的小农来说。植物修复是指利用植物对污染土壤、污泥、沉积物、地下水、地表水和废水中选定的污染物进行部分或实质性修复。
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引用次数: 2
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American Journal of Nanosciences
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