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Foreword to the special issue “From experimental mineralogy and crystallography to mineral deposit: a tribute to Milan Drábek” 特刊前言“从实验矿物学和晶体学到矿床:向Milan Drábek致敬”
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.330
F. Laufek, J. Kotková
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引用次数: 0
Milan Drábek: Bright, productive, witty, provocative Milan Drábek:聪明、高效、诙谐、挑衅
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.338
J. Kotková
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引用次数: 0
Amphibole and pyroxene as indicators of alkaline conditions in banded carbonatite-like marbles from Bližná, Český Krumlov Unit, Moldanubian Zone 在莫尔达努比安带ČeskýKrumlov单元的Bližná带状碳酸岩状大理石中,作为碱性条件指标的角闪石和辉石
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.336
Pavlína Radková, M. Novak, J. Cempírek, S. Houzar, R. Škoda
1 Department of Geological Sciences, Faculty of Science, Masaryk University, Kotlářská 2, CZ-611 37 Brno, Czech Republic; radkova4@uniba.sk 2 Department of Mineralogy, Petrography and Geology of Mineral Deposits, Faculty of Natural Sciences, Comenius University, Ilkovičova 6, 842 15 Bratislava, Slovakia 3 Department of Mineralogy and Petrography, Moravian Museum, Zelný trh 6, 659 37 Brno, Czech Republic * Corresponding author
1马萨里克大学理学院地质科学系Kotlářská 2捷克布尔诺CZ-611 37;radkova4@uniba.sk 2科美纽斯大学自然科学学院矿物学、岩石学和矿床地质学系,伊尔科维 ova 6,842 15布拉迪斯拉发,斯洛伐克3摩拉维亚博物馆矿物学和岩石学学系,Zelný trh 6,659 37布尔诺,捷克共和国*通讯作者
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引用次数: 0
Miscibility between synthetic FeS and TiS: An insight into the phase relations in natural Ti-bearing iron monosulfides 合成FeS与ti的混相:天然含ti单硫化铁物相关系的研究
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.334
N. Mészárosová, R. Skála, P. Mikysek, M. Drábek
Syntheses of (Fe,Ti)S analogs of natural Ti-bearing troilites were performed in evacuated and sealed silica glass tubes to investigate the extent of the knowledge on the solid solution between FeS and TiS. The synthesized (Fe,Ti)S phases were investigated using electron probe microanalysis and powder X-ray diffraction. The synthetic phases of the (Fe,Ti) S series adopt NiAs-type structure of P63/mmc space group in the compositional range from FeS to Fe0.5Ti0.5S. Members of the series rich in titanium crystallize in the R–3m space group. The stoichiometric TiS can adopt both structure types. Some additional diffraction peaks were observed in numerous samples. However, due to the insufficient quality of powder XRD data, crystal structure parameters of only samples with troilite 2C superstructure could be successfully refined. Systematic variation of deficit in metal (Me = Fe + Ti) site occupancy with titanium content was observed in the synthetic samples. This deficit increases with the increasing Ti content in a compositional range from pure FeS to Fe0.2Ti0.8S. In samples containing more titanium than this composition, the deficit of the metal site occupancy decreases, and the composition of end-member TiS is very close to the ideal stoichiometry.
在抽空和密封的二氧化硅玻璃管中合成了天然含钛三羟磷灰石的(Fe,Ti)S类似物,以研究对FeS和TiS之间固溶体的了解程度。用电子探针和粉末X射线衍射对合成的(Fe,Ti)S相进行了研究。(Fe,Ti)S系列的合成相采用P63/mmc空间群的NiAs型结构,组成范围从FeS到Fe0.5Ti0.5S。富含钛的系列成员在R–3m空间群中结晶。化学计量的TiS可以采用这两种结构类型。在许多样品中观察到一些额外的衍射峰。然而,由于粉末XRD数据的质量不足,只能成功地细化具有橄榄石2C上部结构的样品的晶体结构参数。在合成样品中观察到金属(Me=Fe+Ti)位点占有率随钛含量的系统变化。在从纯FeS到Fe0.2Ti0.8S的组成范围内,这种缺陷随着Ti含量的增加而增加。在含有比该组成更多的钛的样品中,金属位占有率的缺陷降低,并且末端成员TiS的组成非常接近理想化学计量。
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引用次数: 0
Cronstedtite from Litošice, Czech Republic 克朗斯泰德来自Litošice,捷克共和国
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.335
J. Hybler, Z. Dolníček, J. Sejkora
The layered iron silicate cronstedtite was encountered in ore veins in the exploration shaft mined in the Neoproterozoic black shale-hosted pyrite-manganese deposit near Litošice (Eastern Bohemia, Czech Republic) around 1955. It forms up to 2 mm thick black double or single bands in symmetrically zoned hydrothermal veins cutting shales. The specimens selected from available material were studied by single-crystal X-ray diffraction using the four-circle diffractometer with an area detector. The chemical composition of some of the specimens was determined by the electron probe microanalysis (EPMA) in the WDS mode. Furthermore, a polished section of the ore material with cronstedtite bands was prepared, and the mineral association was analyzed with the aid of back-scattered electron (BSE) images. The interpretation of reciprocal space (RS) sections produced by the diffractometer software allowed the determination of OD subfamilies (Bailey’s groups) A, B, C, D, and polytypes. The 1T polytype (subfamily C), a = 5.52, c = 7.12 Å, space group P31m, is the most abundant in the occurrence. In rare cases, it forms oriented crystal associations (allotwins) with the 1M polytype (subfamily A), a = 5.52 Å, b = 9.55, c = 7.136 Å, β = 104.4°, space group Cm. Fully disordered allotwinned crystals of the A + C subfamilies were found, too. In addition, few allotwins of the polytype 2H1 (subfamily D) with a small amount of 2H2, were identified. Unit cell parameters are a = 5.49, c = 14.21 Å, space groups are P63cm (2H1), and P63 (2H2). EPMA-WDS of selected crystals of prevailing 1T polytype revealed elevated contents of Mn (0.19–0.62 apfu) and low contents of Mg (up to 0.13 apfu) and Cl (up to 0.05 apfu), respectively. More rare 2H1 (+ 2H2) polytypes show elevated contents of Mg in the range of 0.19–0.62 apfu and distinctly lower Mn (up to 0.07 apfu) and Cl contents (up to 0.01 apfu). The BSE images reveal that cronstedtite bands are associated with multiple generations of carbonates (rhodochrosite, siderite, rarely magnesite and calcite), quartz, opal, pyrite and carbonate-fluorapatite. Intense metasomatic replacement of cronstedtite by opal and siderite appeared especially around the center of the studied vein.
1955年左右,在Litošice(捷克共和国东波希米亚)附近的新元古代黑色页岩黄铁矿锰矿床中开采的勘探竖井中的矿脉中发现了层状硅酸铁铬铁矿。它在对称分区的热液脉切割页岩中形成高达2毫米厚的黑色双带或单带。使用带面积检测器的四圆衍射仪,通过单晶X射线衍射对从可用材料中选择的样品进行了研究。通过WDS模式下的电子探针微量分析(EPMA)测定了一些样品的化学成分。此外,制备了具有铬铁矿带的矿石材料的抛光切片,并借助背散射电子(BSE)图像分析了矿物组合。衍射仪软件产生的倒易空间(RS)截面的解释允许确定OD亚家族(Bailey组)A、B、C、D和多型。1T多型(C亚家族),a=5.52,C=7.12Å,空间群P31m,在产状中最丰富。在极少数情况下,它与1M多型(亚家族A)形成定向晶体缔合(同素异形体),A=5.52Å,b=9.55,c=7.136Å,β=104.4°,空间群Cm。也发现了A+c亚家族的完全无序的同素异形晶体。此外,发现了少量2H2的多型2H1(D亚家族)的少数同素异形体。晶胞参数为a=5.49,c=14.21Å,空间群为P63cm(2H1)和P63(2H2)。主要1T多型的选定晶体的EPMA-WDS分别显示Mn含量升高(0.19–0.62 apfu)和Mg含量降低(高达0.13 apfu和Cl含量低(高达0.05 apfu)。更罕见的2H1(+2H2)多型显示Mg含量在0.19–0.62 apfu范围内升高,Mn(高达0.07 apfu)和Cl含量明显降低(高达0.01 apfu)。BSE图像显示,铬铁矿带与多代碳酸盐(菱锰矿、菱铁矿,很少有菱镁矿和方解石)、石英、蛋白石、黄铁矿和碳酸盐氟磷灰石有关。铬铁矿被蛋白石和菱铁矿强烈交代置换,尤其是在所研究矿脉的中心附近。
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引用次数: 0
Origin of V-Cr-Ti-mineralization in thermally overprinted metal-rich black shales from the Teplá-Barrandian Unit (Bohemian Massif) and implications for metal remobilization during metamorphism Teplá-Barrandian单元(波西米亚地块)热叠加富金属黑色页岩中V-Cr-Ti矿化的起源以及变质作用期间金属再活化的意义
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.337
F. Veselovský, J. Pašava, O. Pour, L. Ackerman
We present a detailed study of geochemical composition and ore mineralogy of black shales from Chynín, Czech Republic, representing Ediacaran organic matter-rich sediments, which were subject to regional and contact metamorphism. They are part of the Blovice Accretionaly Complex (BAC) in the Teplá–Barrandian Unit (TBU) and are located close to the contact with the Central Bohemian Pluton (CBP). The black shales were encountered with metasilicites, metabasalts, and basic tuffitic rocks in the CHY-2 drill hole (250 m deep) and are regionally associated with hornfels bodies. The geochemistry of these shales indicates that they correspond to metal-rich black shales deposited under strongly reducing conditions (TOC/Pmolar > 100, high Mo and U values). On the other hand, the lack of a positive link between TOC and redox-sensitive metals (e.g., V, U, Cr, Ni, Mo) and their generally negative correlation with sulfur indicate important late-stage metal and sulfur remobilization. This is reflected in the mineralogical composition of the shales, which documents a thermal event in their history. Abundant framboidal pyrite (pyrite I) was recrystallized into coarse aggregates (pyrite II), locally accompanied by chalcopyrite, sphalerite, and rare molybdenite, pentlandite and breithauptite. Abundant pyrrhotite formed there due to selective desulfurization of pyrite I and II during the contact metamorphism. Locally, this process was also accompanied by the replacement of pyrrhotite by V–Cr–O (karelianite – V2O3 and eskolaite – Cr2O3, mostly with dominant karelianite end-member) and Ti–V–O (vanadium rutile, schreyerite – V2Ti3O9 and a phase with the theoretical composition V4Ti3O12, yet unknown to the mineralogical system). Vanadium–Cr–Ti elemental associations reported from different localities of Neoproterozoic metal-rich black shales, metal-rich black shales, and (meta)silicites in TBU indicate similar sources of these elements but different conditions of their accumulation.
本文详细研究了捷克Chynín地区黑色页岩的地球化学组成和矿物学特征,该地区为埃迪卡拉纪富有机质沉积,受区域变质作用和接触变质作用影响。它们是Teplá-Barrandian单元(TBU)中的Blovice吸积复合体(BAC)的一部分,位于与中波西米亚岩体(CBP)接触的附近。在250 m深的CHY-2钻孔中,黑色页岩与变质硅质、变质玄武岩和基性凝灰岩相遇,并与角砾体有区域性联系。这些页岩的地球化学特征表明,它们对应于在强还原条件下(TOC/Pmolar bbb100,高Mo和U值)沉积的富金属黑色页岩。另一方面,TOC与氧化还原敏感金属(如V、U、Cr、Ni、Mo)之间缺乏正相关,而它们与硫之间普遍呈负相关,表明后期金属和硫的再活化具有重要意义。这反映在页岩的矿物学组成上,它记录了它们历史上的一个热事件。丰富的草莓状黄铁矿(黄铁矿I)重结晶为粗粒集合体(黄铁矿II),局部伴有黄铜矿、闪锌矿和稀有的辉钼矿、镍黄铁矿和辉钼矿。接触变质作用中,黄铁矿I、II选择性脱硫,形成丰富的磁黄铁矿。局部还伴有磁黄铁矿被V-Cr-O(钾长石- V2O3和矽长石- Cr2O3,主要以钾长石端元为主)和Ti-V-O(钒金红石、石长石- V2Ti3O9和一种理论组成为V4Ti3O12,但矿物学系统未知的相)取代。新元古代富金属黑色页岩、富金属黑色页岩和TBU(元)硅岩不同部位的钒-铬-钛元素组合表明,这些元素的来源相似,但富集条件不同。
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引用次数: 1
Perryite, (Ni,Fe)16PSi5, from the Mount Egerton aubrite: the first natural P-Si-ordered phosphide-silicide (Ni,Fe)16PSi5橄榄石:第一个天然的p -si有序磷化硅化物
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-12-29 DOI: 10.3190/jgeosci.331
S. Britvin, S. Krivovichev, O. Vereshchagin, N. S. Vlasenko, V. Shilovskikh, M. Krzhizhanovskaya, M. S. Lozhkin, E. Obolonskaya, Yulia O. Kopylova
Perryite, natural Ni-silicide, is a minor but regular constituent of the metal phase in enstatite chondrite (aubrite) and enstatite chondrite meteorites. Its synthetic analog was shown to have promising catalytic properties. The first-time solution of the crystal structure of natural perryite was completed on the material from the Mount Egerton aubrite. The mineral is trigonal, R3̄c, a = 6.6525(5), c = 37.998(5) Å, V = 1456.3(3) and Z = 6. The structure was refined to R1 = 0.0137 based on 457 independent observed reflections. The chemical formula obtained from the structure refinement, (Ni14.14Fe1.88)Σ16.02PSi5, agrees with that derived from the electron microprobe data, (Ni13.39Fe2.65Co0.01)Σ16.05P1.22Si4.74. This research showed that P and Si in perryite are ordered, resulting in the simplified formula (Ni,Fe)16PSi8, in contrast to the currently accepted variant (Ni,Fe)8(Si,P)3. The detailed results of EBSD study reveal previously unknown relationships between perryite, associated α-(Fe,Ni) metal (also known as kamacite) and schreibersite, (Fe,Ni)3P. Since enstatitic meteorites represent the early stages of nebular accretion, our results demonstrate that the crystal-chemical factor could affect the differentiation of chemical elements upon the onset of the Solar System formation.
Perryite是一种天然的硅化镍,是顽火辉石球粒陨石(aubrite)和顽火辉石陨石中金属相的一种次要但规则的成分。其合成类似物被证明具有良好的催化性能。在埃格顿火山灰岩的材料上首次解决了天然绿柱石的晶体结构。该矿物是三角的,R3̄c,a=6.6525(5),c=37.998(5)Å,V=1456.3(3)和Z=6。基于457个独立观察到的反射,该结构被细化为R1=0.0137。通过结构细化得到的化学式(Ni14.14Fe1.88)∑16.02PSi5与电子探针数据得到的化学公式(Ni13.39Fe2.65Co0.01)∑16.05P1.22Si4.74一致。这项研究表明,与目前接受的变体(Ni,Fe)8(Si,P)3相比,钙钛矿中的P和Si是有序的,从而得到简化的公式(Ni,Fe)16PSi8。EBSD研究的详细结果揭示了以前未知的苝矿、伴生的α-(Fe,Ni)金属(也称为钾铝矿)和schreibersite(Fe,镍)3P之间的关系。由于顽火陨石代表了星云吸积的早期阶段,我们的研究结果表明,晶体化学因素可能会影响太阳系形成时化学元素的分化。
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引用次数: 1
A word of the Editor-in-Chief 总编辑的话
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-11-08 DOI: 10.3190/jgeosci.325
J. Plašil
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引用次数: 0
Bismuth, lead-bismuth and lead-antimony sulfosalts from the granite-hosted hydrothermal quartz veins at the Elisabeth mine, Gemerská Poloma, Spišsko-gemerské rudohorie Mts., Slovakia 斯洛伐克gemersk<s:1> Poloma, Spišsko-gemerské rudohorie Mts. Elisabeth矿花岗岩热液石英脉中的铋、铅铋和铅锑磺化盐
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-11-08 DOI: 10.3190/jgeosci.328
M. Števko, J. Sejkora
An interesting assemblage of bismuth and complex lead–bismuth and lead–antimony sulfosalts have been identified in samples from hydrothermal quartz veins hosted in S-type granitic rocks at the Elisabeth mine near Gemerská Poloma, Slovakia. We provide the first detailed study of the chemical composition of sulfosalts from the hydrothermal veins directly related to the specialized (Sn–W–F enriched) Gemeric granites. Bismuthinite derivates (bismuthinite and phases with naik ranging from 21.3 to 23.7 and 30.3), minerals of the kobellite–tintinaite series (with Sb/(Sb + Bi) atomic ratio ranging considerably between 0.13 and 0.71), giessenite–izoklakeite series (with Sb/(Sb + Bi) from 0.26 to 0.33) as well as Pb–Sb sulfosalts (mainly jamesonite, boulangerite, robinsonite and their Bi-rich varieties) are common. Rare Bi-enriched rouxelite, bournonite and minerals of the tetrahedrite group were also observed. The two distinct types of sulfosalts associations were distinguished, each related to the different type of host rock and with variable Bi/Sb ratio. The first is represented predominantly by Bi-rich sulfosalts (bismuthinite derivates, kobellite, giessenite–izoklakeite) and occurs in the quartz veins hosted in P-enriched leucogranite. The second association is developed only in hydrothermal quartz veins hosted in porphyric granites and except of Bi (bismuthinite derivates) also significant amounts of Sb-rich sulfosalts (tintinaite, boulangerite, robinsonite, jamesonite, rouxelite, bournonite and tetrahedrite-(Zn) to tetrahedrite(Fe)) are present.
在斯洛伐克gemersk Poloma附近Elisabeth矿的s型花岗质岩石中的热液石英脉样品中,发现了铋和复杂的铅铋和铅锑硫酸盐的有趣组合。我们首次详细研究了与特化(富Sn-W-F)泛绿花岗岩直接相关的热液脉中亚硫酸盐的化学成分。铋矿衍生物(铋矿和含铁相范围分别为21.3 ~ 23.7和30.3)、小辉石—tintinaite系列矿物(Sb /(Sb + Bi)原子比在0.13 ~ 0.71之间)、辉石—izoklakeite系列矿物(Sb /(Sb + Bi)原子比在0.26 ~ 0.33之间)以及Pb-Sb硫酸盐盐(主要是詹姆斯辉石、绢云石、罗滨石及其富Bi品种)较为常见。此外,还发现了稀有的富铋辉石、bournonite和四面体矿类矿物。发现了两种不同类型的硫代盐组合,它们与不同类型的寄主岩石有关,并具有不同的Bi/Sb比值。第一类主要以富铋硫酸盐(铋矿衍生物、小球石、辉石-异沸石)为代表,产于富磷浅花岗岩体中的石英脉中。第二种组合仅在含斑花岗岩的热液石英脉中发育,除铋(铋矿衍生物)外,还存在大量富硒的硫酸盐(tintinaite, boulangerite, robinsonite, jamesonite, rouxite, bournonite和四面体-(Zn)到四面体(Fe))。
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引用次数: 1
Rapidcreekite of anthropogenic origin - ’korkinoite’ from burnt mine dump in the Chelyabinsk coal basin, South Urals, Russia: crystal structure refinement, thermal behavior and spectroscopic characterization 来自俄罗斯南乌拉尔州车里雅宾斯克煤盆地燃烧矿山排土场的“科尔基岩”:晶体结构细化、热行为和光谱表征
IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-11-08 DOI: 10.3190/jgeosci.327
M. Avdontceva, A. Zolotarev, S. Krivovichev, M. G. Krzhizhanovskaya, V. Bocharov, V. Shilovskikh, M. Rassomakhin
1 Institute of Earth sciences, Saint-Petersburg State University, Universitetskaya emb. 7/9, 199034, St. Petersburg, Russia; m.avdontceva@spbu.ru 2 Nanomaterials Research Center, Federal Research Center, Kola Centre, Russian Academy of Sciences, 14, Fersman st., Apatity, 184209, Murmansk Region, Russia 3 Centre for Geo-Environmental Research and Modelling, Saint-Petersburg State University, Ulyanovskaya st., 1, St. Petersburg, Russia 4 South Urals Federal Research Center of Mineralogy and Geoecology of UB RAS, 456317 Miass, Russia * Corresponding author
1俄罗斯圣彼得堡国立大学地球科学研究所,俄罗斯圣彼得堡圣彼得堡国立大学199034年7月9日,俄罗斯圣彼得堡;m.avdontceva@spbu.ru 2俄罗斯科学院联邦研究中心科拉中心纳米材料研究中心,14,俄罗斯摩尔曼斯克地区费斯曼街,184209,俄罗斯3圣彼得堡国立大学地球环境研究与建模中心,乌里扬诺夫斯卡亚街,1,俄罗斯圣彼得堡4俄罗斯南乌拉尔联邦矿物与地质生态学研究中心,456317,俄罗斯misass,俄罗斯*通讯作者
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引用次数: 1
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Journal of Geosciences
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