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Cryogenic Tensile Behavior of Ferrous Medium-entropy Alloy Additively Manufactured by Laser Powder Bed Fusion 利用激光粉末床熔融技术添加制造的中熵铁合金的低温拉伸行为
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.8
Seungyeon Lee, K. Kim, Ji-Hun Yu, Hyoung-Seop Kim, J. Bae, Jeong-Min Park
The emergence of ferrous-medium entropy alloys (FeMEAs) with excellent tensile properties represents a potential direction for designing alloys based on metastable engineering. In this study, an FeMEA is successfully fabricated using laser powder bed fusion (LPBF), a metal additive manufacturing technology. Tensile tests are conducted on the LPBF-processed FeMEA at room temperature and cryogenic temperatures (77 K). At 77 K, the LPBF-processed FeMEA exhibits high yield strength and excellent ultimate tensile strength through active deformation-induced martensitic transformation. Furthermore, due to the low stability of the face-centered cubic (FCC) phase of the LPBF-processed FeMEA based on nano-scale solute heterogeneity, stress-induced martensitic transformation occurs, accompanied by the appearance of a yield point phenomenon during cryogenic tensile deformation. This study elucidates the origin of the yield point phenomenon and deformation behavior of the FeMEA at 77 K.
具有优异拉伸性能的铁-中熵合金(FeMEA)的出现为基于易变工程的合金设计提供了一个潜在的方向。在本研究中,利用金属增材制造技术激光粉末床熔融(LPBF)成功制造出了铁-中熵合金(FeMEA)。在室温和低温(77 K)下对 LPBF 加工的 FeMEA 进行了拉伸试验。在 77 K 温度下,LPBF 加工的 FeMEA 通过主动变形诱导的马氏体转变表现出较高的屈服强度和优异的极限拉伸强度。此外,由于基于纳米尺度溶质异质性的 LPBF 加工铁甲醇的面心立方(FCC)相稳定性较低,因此会发生应力诱导的马氏体转变,并伴随着低温拉伸变形过程中屈服点现象的出现。本研究阐明了屈服点现象的起源和铁金属氧化物在 77 K 时的变形行为。
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引用次数: 0
Fabrication of Ti-Mo Core-shell Powder and Sintering Properties for Application as a Sputtering Target 用作溅射靶材的钛钼核壳粉末的制备和烧结性能
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.43
Won Hee Lee, C. Park, Heeyeon Kim, Yuncheol Ha, Jongmin Byun, Young Do Kim
In this study, a core-shell powder and sintered specimens using a mechanically alloyed (MAed) Ti-Mo powder fabricated through high-energy ball-milling are prepared. Analysis of sintering, microstructure, and mechanical properties confirms the applicability of the powder as a sputtering target material. To optimize the MAed Ti-Mo powder milling process, phase and elemental analyses of the powders are performed according to milling time. The results reveal that 20 h of milling time is the most suitable for the manufacturing process. Subsequently, the MAed Ti-Mo powder and MoO 3 powder are milled using a 3-D mixer and heat-treated for hydrogen reduction to manufacture the core-shell powder. The reduced core-shell powder is transformed to sintered specimens through molding and sintering at 1300 and 1400 o C. The sintering properties are analyzed through X-ray diffraction and scanning electron microscopy for phase and porosity analyses. Moreover, the microstructure of the powder is investigated through optical microscopy and electron probe microstructure analysis. The Ti-Mo core-shell sintered specimen is found to possess high density, uniform microstructure, and excellent hardness properties. These results indicate that the Ti-Mo core-shell sintered specimen has excellent sintering properties and is suitable as a sputtering target material.
本研究使用通过高能球磨制造的机械合金(MAed)钛钼粉末制备了芯壳粉末和烧结试样。对烧结、微观结构和机械性能的分析证实了该粉末可用作溅射靶材。为了优化 MAed Ti-Mo 粉末研磨工艺,根据研磨时间对粉末进行了相和元素分析。结果表明,20 小时的研磨时间最适合制造工艺。随后,使用三维混合器碾磨 MAed Ti-Mo 粉末和 MoO 3 粉末,并进行氢还原热处理,以制造核壳粉末。通过 X 射线衍射和扫描电子显微镜进行相和孔隙率分析,分析烧结特性。此外,还通过光学显微镜和电子探针微观结构分析研究了粉末的微观结构。结果发现,钛钼核壳烧结试样具有高密度、均匀的微观结构和优异的硬度特性。这些结果表明,钛钼核壳烧结试样具有优异的烧结性能,适合用作溅射靶材。
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引用次数: 0
Development of High-strength, High-temperature Nb-Si-Ti Alloys through Mechanical Alloying 通过机械合金化开发高强度高温铌硅钛合金
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.30
Jung-Joon Kim, Sang-Min Yoon, Deok-Hyun Han, Jongmin Byun, Young-Kyun Kim
The aerospace and power generation industries have an increasing demand for high-temperature, high-strength materials. However, conventional materials typically lack sufficient fracture toughness and oxidation resistance at high temperatures. This study aims to enhance the high-temperature properties of Nb-Si-Ti alloys through ball milling. To analyze the effects of milling time, the progression of alloying is evaluated on the basis of XRD patterns and the microstructure of alloy powders. Spark plasma sintering (SPS) is employed to produce compacts, with thermodynamic modeling assisting in predicting phase fractions and sintering temperature ranges. The changes in the microstructure and variation in the mechanical properties due to the adjustment of the sintering temperature provide insights into the influence of Nb solid solution, Nb5Si3, and crystallite size within the compacts. By investigating the changes in the mechanical properties through strengthening mechanisms, such as precipitation strengthening, solid solution strengthening, and crystallite refinement, this study aims to verify the applicability of Nb-Si-Ti alloys in advanced material systems.
航空航天和发电行业对高温、高强度材料的需求与日俱增。然而,传统材料通常缺乏足够的高温断裂韧性和抗氧化性。本研究旨在通过球磨提高 Nb-Si-Ti 合金的高温性能。为了分析研磨时间的影响,根据 XRD 图谱和合金粉末的微观结构评估了合金化的进展。采用火花等离子烧结(SPS)技术生产紧凑型材料,热力学模型有助于预测相分数和烧结温度范围。调整烧结温度会引起微观结构的变化和机械性能的变化,这有助于深入了解铌固溶体、Nb5Si3 和致密材料中晶粒尺寸的影响。通过研究沉淀强化、固溶强化和晶粒细化等强化机制对力学性能的影响,本研究旨在验证 Nb-Si-Ti 合金在先进材料体系中的适用性。
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引用次数: 0
Fabrication of Bi2Te2.5Se0.5 by Combining Oxide-reduction and Compressive-forming Process and Its Thermoelectric Properties 结合氧化还原和压缩成形工艺制备 Bi2Te2.5Se0.5 及其热电特性
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.50
Young Soo Lim, Gil-Geun Lee
We report the effect of plastic deformation on the thermoelectric properties of n-type Bi 2 Te 2.5 Se 0.5 compounds. N-type Bi 2 Te 2.5 Se 0.5 powders are synthesized by an oxide-reduction process and consolidated via spark-plasma sintering. To explore the effect of plastic deformation on the thermoelectric properties, the sintered bodies are subjected to uniaxial pressure to induce a controlled amount of compressive strains (-0.2, -0.3, and -0.4). The shaping temperature is set using a thermochemical analyzer, and the plastic deformation effect is assessed without altering the material composition through differential scanning calorimetry. This strategy is crucial because the conventional hot-forging process can often lead to alterations in material composition due to the high volatility of chalcogen elements. With increasing compressive strain, the (00l) planes become aligned in the direction perpendicular to the pressure axis. Furthermore, an increase in the carrier concentration is observed upon compressive plastic deformation, i.e ., the donor-like effect of the plastic deformation in n-type Bi 2 Te 2.5 Se 0.5 compounds. Owing to the increased electrical conductivity through the preferred orientation and the donor-like effect, an improved ZT is achieved in n-type Bi 2 Te 2.5 Se 0.5 through the compressive-forming process.
我们报告了塑性变形对 n 型 Bi 2 Te 2.5 Se 0.5 化合物热电性能的影响。N 型 Bi 2 Te 2.5 Se 0.5 粉末是通过氧化还原工艺合成的,并通过火花等离子烧结固化。为了探索塑性变形对热电特性的影响,对烧结体施加单轴压力,以诱导可控的压缩应变(-0.2、-0.3 和 -0.4)。使用热化学分析仪设定成型温度,并通过差示扫描量热法在不改变材料成分的情况下评估塑性变形效果。这一策略至关重要,因为传统的热锻工艺往往会因为钙元素的高挥发性而导致材料成分的改变。随着压缩应变的增加,(00l) 平面会在垂直于压力轴的方向上排列。此外,在压缩塑性变形时,还观察到载流子浓度的增加,即在 n 型 Bi 2 Te 2.5 Se 0.5 化合物中塑性变形的捐献者效应。由于优选取向和类施主效应提高了导电性,n 型 Bi 2 Te 2.5 Se 0.5 在压塑成型过程中实现了更高的 ZT 值。
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引用次数: 0
Development of Composite-film-based Flexible Energy Harvester using Lead-free BCTZ Piezoelectric Nanomaterials 利用无铅 BCTZ 压电纳米材料开发基于复合薄膜的柔性能量收集器
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.16
Gwang Hyeon Kim, Hyeon Jun Park, Bitna Bae, Haksu Jang, Cheol Min Kim, Donghun Lee, Kwi-Il Park
Composite-based piezoelectric devices are extensively studied to develop sustainable power supply and selfpowered devices owing to their excellent mechanical durability and output performance. In this study, we design a leadfree piezoelectric nanocomposite utilizing (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ) nanomaterials for realizing highly flexible energy harvesters. To improve the output performance of the devices, we incorporate porous BCTZ nanowires (NWs) into the nanoparticle (NP)-based piezoelectric nanocomposite. BCTZ NPs and NWs are synthesized through the solidstate reaction and sol-gel-based electrospinning, respectively; subsequently, they are dispersed inside a polyimide matrix. The output performance of the energy harvesters is measured using an optimized measurement system during repetitive mechanical deformation by varying the composition of the NPs and NWs. A nanocomposite-based energy harvester with 4:1 weight ratio generates the maximum open-circuit voltage and short-circuit current of 0.83 V and 0.28 A, respectively. In this study, self-powered devices are constructed with enhanced output performance by using piezoelectric energy harvesting for application in flexible and wearable devices.
基于复合材料的压电器件具有优异的机械耐久性和输出性能,因此被广泛用于开发可持续电源和自供电器件。在本研究中,我们利用 (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ) 纳米材料设计了一种无铅压电纳米复合材料,用于实现高柔性能量收集器。为了提高器件的输出性能,我们在基于纳米粒子(NP)的压电纳米复合材料中加入了多孔 BCTZ 纳米线(NW)。BCTZ NPs 和 NWs 分别通过固态反应和溶胶-凝胶电纺丝法合成,然后分散在聚酰亚胺基质中。在重复机械变形过程中,通过改变 NPs 和 NWs 的成分,使用优化的测量系统测量了能量收集器的输出性能。重量比为 4:1 的纳米复合材料能量收集器产生的最大开路电压和短路电流分别为 0.83 V 和 0.28 A。本研究利用压电能量收集技术构建了输出性能更强的自供电设备,可应用于柔性和可穿戴设备。
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引用次数: 0
Effect of Abnormal Grain Growth on Ionic Conductivity in LATP 异常晶粒生长对 LATP 离子传导性的影响
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.23
Hyungik Choi, Yoonsoo Han
This study investigates the effect of the microstructure of Li 1.3 Al 0.3 Ti 1.7 ( PO 4 ) 3 (LATP), a solid electrolyte, on its ionic conductivity. Solid electrolytes, a key component in electrochemical energy storage devices such as batteries, differ from traditional liquid electrolytes by utilizing solid-state ionic conductors. LATP, characterized by its NASICON structure, facilitates rapid lithium-ion movement and exhibits relatively high ionic conductivity, chemical stability, and good electrochemical compatibility. In this study, the microstructure and ionic conductivity of LATP specimens sintered at 850, 900, and 950 o C for various sintering times are analyzed. The results indicate that the changes in the microstructure due to sintering temperature and time significantly affect ionic conductivity. Notably, the specimens sintered at 900 o C for 30 min exhibit high ionic conductivity. This study presents a method to optimize the ionic conductivity of LATP. Additionally, it underscores the need for a deeper understanding of the Li-ion diffusion mechanism and quantitative microstructure analysis.
本研究探讨了固体电解质 Li 1.3 Al 0.3 Ti 1.7 ( PO 4 ) 3 (LATP) 的微观结构对其离子导电性的影响。固态电解质是电池等电化学储能设备中的关键成分,与传统的液态电解质不同,它利用的是固态离子导体。以 NASICON 结构为特征的 LATP 可促进锂离子的快速移动,并具有相对较高的离子电导率、化学稳定性和良好的电化学兼容性。本研究分析了在 850、900 和 950 o C 温度下烧结的 LATP 试样在不同烧结时间下的微观结构和离子电导率。结果表明,烧结温度和时间导致的微观结构变化会显著影响离子导电率。值得注意的是,在 900 o C 下烧结 30 分钟的试样具有较高的离子导电率。本研究提出了一种优化 LATP 离子导电率的方法。此外,它还强调了深入了解锂离子扩散机制和定量微观结构分析的必要性。
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引用次数: 0
Effect of Tool Shape and Insertion Depth on Joining Properties in Friction Stir Spot Welding of Aluminum Alloy/high-strength Steel Sheets 工具形状和插入深度对铝合金/高强度钢板摩擦搅拌点焊接合性能的影响
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.37
Su-Ho An, Young-Keun Jeong
Friction stir spot welding (FSSW) is a solid-state joining process and a rapidly growing dissimilar material welding technology for joining metallic alloys in the automotive industry. Welding tool shape and process conditions must be appropriately controlled to obtain high bonding characteristics. In this study, FSSW is performed on dissimilar materials AA5052-H32 aluminum alloy sheet and SPRC440 steel sheet, and the influence of the shape of joining tool and tool insertion depth during joining is investigated. A new intermetallic compound is produced at the aluminum and steel sheets joint. When the insertion depth of the tool is insufficient, the intermetallic compound between the two sheets did not form uniformly. As the insertion depth increased, the intermetallic compound layer become uniform and continuous. The joint specimen shows higher values of tensile shear load as the diameter and insertion depth of the tool increase. This shows that the uniform formation of the intermetallic compound strengthens the bonding force between the joining specimens and increases the tensile shear load.
搅拌摩擦点焊(FSSW)是一种固态连接工艺,也是汽车工业中一种快速发展的异种材料焊接技术,用于连接金属合金。必须适当控制焊接工具的形状和工艺条件,才能获得较高的焊接特性。在本研究中,对异种材料 AA5052-H32 铝合金板和 SPRC440 钢板进行了全固态无缝焊接,并研究了焊接过程中焊接工具形状和工具插入深度的影响。铝板和钢板连接处产生了一种新的金属间化合物。当工具插入深度不够时,两片板材之间的金属间化合物形成不均匀。随着插入深度的增加,金属间化合物层变得均匀且连续。随着工具直径和插入深度的增加,接头试样显示出更高的拉伸剪切载荷值。这表明金属间化合物的均匀形成增强了连接试样之间的结合力,并提高了拉伸剪切载荷。
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引用次数: 0
Research Trends in Electromagnetic Shielding using MXene-based Composite Materials 使用 MXene 基复合材料的电磁屏蔽研究趋势
Pub Date : 2024-02-28 DOI: 10.4150/kpmi.2024.31.1.57
Siyeon Kim, Jongmin Byun
Recent advancements in electronic devices and wireless communication technologies, particularly the rise of 5G, have raised concerns about the escalating electromagnetic pollution and its potential adverse impacts on human health and electronics. As a result, the demand for effective electromagnetic interference (EMI) shielding materials has grown significantly. Traditional materials face limitations in providing optimal solutions owing to inadequacy and low performance due to small thickness. MXene-based composite materials have emerged as promising candidates in this context owing to their exceptional electrical properties, high conductivity, and superior EMI shielding efficiency across a broad frequency range. This review examines the recent developments and advantages of MXene-based composite materials in EMI shielding applications, emphasizing their potential to address the challenges posed by electromagnetic pollution and to foster advancements in modern electronics systems and vital technologies.
电子设备和无线通信技术的最新进展,尤其是 5G 的兴起,引发了人们对不断升级的电磁污染及其对人类健康和电子产品潜在不利影响的担忧。因此,对有效电磁干扰(EMI)屏蔽材料的需求大幅增长。传统材料由于厚度小、性能低,在提供最佳解决方案方面受到限制。基于 MXene 的复合材料因其优异的电气性能、高导电性和在宽频率范围内卓越的 EMI 屏蔽效率,已成为这方面的理想候选材料。本综述探讨了 MXene 基复合材料在 EMI 屏蔽应用中的最新发展和优势,强调了它们在应对电磁污染带来的挑战以及促进现代电子系统和重要技术进步方面的潜力。
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引用次数: 0
Fabrication and Sintering Behavior Analysis of Molybdenum-tungsten Nanopowders by Pechini Process 用 Pechini 工艺制作钼钨纳米粉体及其烧结特性分析
Pub Date : 2023-10-30 DOI: 10.4150/kpmi.2023.30.5.436
Suyeon Kim, Taehyun Kwon, Seulgi Kim, Dongju Lee
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引用次数: 0
Formation of Phases and Mechanical Properties of YSZ-Based Thermal Barrier Coating Materials Doped with Rare Earth Oxides 掺杂稀土氧化物的 YSZ 基隔热涂层材料的成相和力学性能
Pub Date : 2023-10-30 DOI: 10.4150/kpmi.2023.30.5.402
Yong Seok Choi, Gye-Won Lee, Sahn Nahm, Yoon-Suk Oh
{"title":"Formation of Phases and Mechanical Properties of YSZ-Based Thermal Barrier Coating Materials Doped with Rare Earth Oxides","authors":"Yong Seok Choi, Gye-Won Lee, Sahn Nahm, Yoon-Suk Oh","doi":"10.4150/kpmi.2023.30.5.402","DOIUrl":"https://doi.org/10.4150/kpmi.2023.30.5.402","url":null,"abstract":"","PeriodicalId":16122,"journal":{"name":"Journal of Korean Powder Metallurgy Institute","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139311426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Korean Powder Metallurgy Institute
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