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Study of the Electronic Structure and Optical Properties of Rare Earth Luminescent Materials 稀土发光材料的电子结构与光学性质研究
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.1110002
Chengxi Zhang
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引用次数: 0
Overview of Precious Metal Content Analysis Methods in Automotive Catalytic Converter 汽车催化转化器中贵金属含量分析方法综述
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.1111002
Xianpeng Yang, Chengbao Xie, Ning Liu, Xin Du, Suqing Wang, Huasheng Jiang, Zhengang Zhang
With the increasing awareness of environmental protection, people’s concern of pollution issues arising. Vehicles, as the most important means of transportation, its exhaust emission has received considerable attention. The catalytic converter is able to purify harmful substances in exhaust gas. The absolute content of precious metals in the catalytic converter dominates the exhaust gas purification effect. Accurate detection of precious metal content is of great significance for controlling the cost of catalysts, ensuring catalytic performance and recovering precious metals from spent catalysts. We herein summarized several instruments for precious metals content exploration, such as X-ray fluorescence spectrometer (XRF), atomic absorption spectrometer (AAS), inductively coupled plasma emission spectrometer (ICP) and spectrophotometer. In this thesis, the feasibility of using various devices for characterizing precious metal content in catalytic converters is analyzed and their strengths or weaknesses are elaborated.
随着环保意识的增强,人们对污染问题的关注也随之产生。汽车作为最重要的交通工具,其尾气排放受到了人们的广泛关注。催化转化器能够净化废气中的有害物质。催化转化器中贵金属的绝对含量对废气净化效果起主导作用。贵金属含量的准确检测对于控制催化剂成本、保证催化性能以及从废催化剂中回收贵金属具有重要意义。本文综述了几种贵金属含量探测仪器,如x射线荧光光谱仪(XRF)、原子吸收光谱仪(AAS)、电感耦合等离子体发射光谱仪(ICP)和分光光度计。本文分析了各种催化转化器贵金属含量表征装置的可行性,阐述了各种装置的优缺点。
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引用次数: 0
Diagnosis of Wastewater Contamination by Metalic Trace Elements (MTE) in the Areas of Yopougon (South Abidjan) and Marcory, Koumassi (North Abidjan) from March to July 2021 2021年3月至7月在Yopougon(南阿比让)和marcoory, Koumassi(北阿比让)地区进行金属微量元素(MTE)废水污染诊断
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.1110003
Lydie Nina Amon, Aboubakar Sidik Diaby, Alfred Niamien Kouamé, Kouamé Eric Yao, Ali Sanou, Léon Koffi Konan, Kalpy Julien Coulibaly, Mireille Dosso
Contamination of the aquatic environment by Metallic Trace Elements (MTE) is a major problem encountered in our environment today. In Côte d’Ivoire, in some municipals, residential and industrial areas in the city of Abidjan, waste water of worrying quantity is discharged into the rainwater drainage channels which flow directly into the Ebrié lagoon. In order to identify the origin of the pollution by metallic trace elements (MTE) transported by this water, samples of wastewater were collected and then analyzed. ICP-MS was used for MTE (Cu, Fe, Zn, Al, Pb, Cd) analyses and results were statistically processed in multivariate form using PCA and Excel. The results showed high concentrations of metals, with the exception of Cd. The typological structure represents 85.74% of the total information for the MTE. Plan F1 represents 63.90% of the variance and describes water pollution by copper (0.95), zinc (0.90), iron (0.84) and aluminum (0.84). Plan F2 represents 21.84% and describes the enrichment of water with lead (0.84). It seems more than necessary to make manufacturers aware of the need to install wastewater treatment systems in order to avoid their discharge into the environment.
金属微量元素(MTE)对水生环境的污染是当今环境中遇到的一个主要问题。在Côte科特迪瓦,在阿比让市的一些城市、住宅区和工业区,数量令人担忧的废水被排入雨水排水渠道,这些渠道直接流入ebri泻湖。为了确定该水携带的金属微量元素(MTE)污染的来源,收集了废水样品并进行了分析。采用ICP-MS进行MTE (Cu, Fe, Zn, Al, Pb, Cd)分析,并采用PCA和Excel对结果进行多元统计处理。结果表明,除Cd外,金属的浓度较高。类型结构占MTE总信息的85.74%。平面图F1代表63.90%的方差,描述了铜(0.95)、锌(0.90)、铁(0.84)和铝(0.84)对水污染的影响。平面图F2代表21.84%,描述了水中铅的富集(0.84)。似乎有必要让制造商意识到需要安装废水处理系统,以避免将其排放到环境中。
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引用次数: 0
Corn Starch Derived Capacitive Carbon Prepared by One-Step K<sub>2</sub>CO<sub>3</sub> Carbonization for Supercapacitors 一步法制备玉米淀粉衍生电容炭<sub>2</sub>CO<sub>3</sub>超级电容器的碳化
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.1110001
Ruiying Wu, Hongyan Pan
High-performance carbonaceous electrode materials for supercapacitors were synthesized by subjecting corn starch to a simple molten salt activation process with K2CO3 at a temperature of 850˚C. The resulting carbon material, obtained after activating for 1 hour, displayed excellent capacitive properties due to the synergistic effects of its porous structure. Utilizing these electrodes, the supercapacitor exhibited a high discharge capacitance (248 F g−1 at 1 A g−1), which is 2.4 times higher than that of activated carbon without K2CO3 activation. The enhancement in electrical performance was analyzed through SEM and XRD analysis, revealing that the porous and disordered structure provides a greater number of charge storage sites, resulting in improved capacitive performance.
以玉米淀粉为原料,在850℃的温度下,用K2CO3进行简单的熔盐活化,合成了高性能的超级电容器用碳质电极材料。活化1小时后得到的碳材料,由于其多孔结构的协同作用,表现出优异的电容性能。利用这些电极,超级电容器表现出很高的放电电容(在1 a g−1时为248 F g−1),比未活化K2CO3的活性炭高2.4倍。通过SEM和XRD分析分析电学性能的增强,发现多孔无序结构提供了更多的电荷存储位点,从而提高了电容性能。
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引用次数: 0
Kinetic and Thermodynamic Study of the Elimination of Remazol Black on Activated Carbon Based on <i>Ricinodendron heudelotii</i> Shells 基于</ amp;gt;蓖麻的活性炭去除雷马唑黑的动力学和热力学研究贝壳
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.119001
Kouakou Yao Urbain, Kambiré Ollo, Eroi N’goran Sévérin, Koné Yétchié Tchonrontcha, Trokourey Albert
Activated carbon made from the shells of Ricinodendron heudelotii was used to remove the remazol black dye in aqueous solution. The results of the characterization of this carbon revealed that it is microporous, with a basic global surface (0.337 mmol/L) and a specific surface of 612 m2/g. The prepared carbon therefore has excellent adsorbent properties. Kinetic and thermodynamic studies were carried out to describe the adsorption mechanism of remazol black on this carbon. It appears from this study that the pseudo-second-order kinetic model is the best suited to describe this adsorption phenomenon with an equilibrium time of 200 min. The adsorption equilibrium study revealed that Langmuir and Freundlich models can help to describe the adsorption process. We note that the optimum pH and optimum mass for the removal of 20 mg/L of remazol black are 3 and 0.25 g, respectively. This carbon made it possible to eliminate more than 98% of the remazol dye in aqueous solution. The thermodynamic study revealed that the adsorption is of the physisorption type, spontaneous and endothermic.
以蓖麻壳为原料制备活性炭,用于去除水中的雷马唑黑色染料。表征结果表明,该碳具有微孔结构,基本总表面积为0.337 mmol/L,比表面积为612 m2/g。因此制备的碳具有优异的吸附剂性能。对雷马唑黑在该碳上的吸附机理进行了动力学和热力学研究。研究表明,拟二级动力学模型最适合描述这种平衡时间为200 min的吸附现象。吸附平衡研究表明,Langmuir和Freundlich模型有助于描述吸附过程。我们注意到去除20 mg/L雷马唑黑的最佳pH和最佳质量分别为3和0.25 g。这种碳可以消除水溶液中98%以上的雷马唑染料。热力学研究表明,该吸附为自然吸附型吸热吸附。
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引用次数: 0
Synthesis, Characterization and Properties of Polymeric <i>p</i>-Benzoyl-4,4'-Diaminobenzoylaniline 聚合物<i> > /i>-苯甲酰-4,4'-二氨基苯甲酰苯胺的合成、表征和性能
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.118003
Chundong Mi, Menglan Yuan, Yuchen Zhang, He Li, Qianfeng Zhang
An aromatic polyamide was synthesized by low-temperature poly-condensation reaction from terephthaloyl chloride and 4,4'-diaminobenzanilide (4,4'-DABA). The synthesized polyamide had a characteristic peak of carbon atoms in the amide group at 166 ppm, which was demonstrated by the solid nuclear magnetic resonance carbon spectrum. It was shown to be the stretching vibration absorption peak of the amide N-H bond at 3342 cm−1 by Fourier infrared (FT-IR) spectroscopy. It was obtained that the energy band near 1100 - 1276 cm−1 belongs to the absorption peak of the para-substituted benzene ring and the band near 2977 cm−1 was the C-H stretching vibration peak of the benzene ring by Raman spectroscopy. The molecular structure of the synthesized polyamide compound was confirmed by FT-IR, Raman, and solid 13C-NMR spectroscopies. It was proved that the polymer is stable up to 300˚C and has a relatively high stability by the thermogravimetric analysis. It was also confirmed by the fluorescence spectrum that it has a strong blue fluorescence near 420 nm. The morphological characteristics of the polymer were further demonstrated by electron scanning electron microscopy (SEM). The properties of polymeric p-benzoyl-4,4'-diaminobenzoyl-aniline were found to emit strong blue fluorescence and have good thermal stability, making it a promising functional material for fluorescence in the blue region with potential for large-scale applications.
以对苯二甲酰氯和4,4′-二氨基苯并苯胺(4,4′-DABA)为原料,通过低温缩聚反应合成了芳香族聚酰胺。合成的聚酰胺在166 ppm处有酰胺基碳原子的特征峰,通过固体核磁共振碳谱图证实了这一点。傅里叶红外光谱(FT-IR)表明,它是酰胺N-H键在3342 cm−1处的拉伸振动吸收峰。拉曼光谱分析表明,1100 ~ 1276 cm−1附近的能带属于对取代苯环的吸收峰,2977 cm−1附近的能带是苯环的C-H伸缩振动峰。合成的聚酰胺化合物的分子结构经FT-IR、拉曼光谱和固体13C-NMR确证。热重分析结果表明,该聚合物在300℃下稳定,具有较高的稳定性。荧光光谱也证实了它在420 nm附近具有较强的蓝色荧光。通过电子扫描电镜(SEM)进一步表征了聚合物的形态特征。聚合物对苯甲酰-4,4′-二氨基苯甲酰苯胺具有较强的蓝色荧光和良好的热稳定性,是一种很有前途的蓝色荧光功能材料,具有大规模应用的潜力。
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引用次数: 0
Synthesis, Structural Characterization and Antimicrobial Activity of a Novel Cobalt(II) Complex Based on 3-Methyl-1-Phenyl-4-(2-Thienoyl)-Pyrazol-5-One 基于3-甲基-1-苯基-4-(2-硫烯基)-吡唑-5- one的新型钴(II)配合物的合成、结构表征及抗菌活性
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.118007
Emeline Sorelle Mefouegang, Claudelle Sybilline Anensong Djadock, Golngar Djimassingar, Gabriel Tchuente Kamsu, Donald Raoul Tchuifon Tchuifon, Alain Charly Tagne Kuate, Dirk Bockfeld, Jean Ngoune
New cobalt(II) complex, [Co(O2C15H11N2S)2(OH2)2]∙2H2O (1∙2H2O), has been synthesized upon reaction of cobalt chloride hexahydrate (Co(Cl)2∙6H2O) with 3-methyl-1-Phenyl-4-(2-thienoyl)-pyrazol-5-one (referred as HL) in ethanol at room temperature. Single crystal X-ray diffraction (XRD), spectroscopic methods, and microelemental analyses were used to characterize 1∙2H2O. Compound 1∙2H2O crystallizes in the orthorhombic crystal system with a Pbca space group and with the cobalt atom being pseudo-octahedral coordinated. The broth microdilution technique was used to screen the free ligand (HL) and the complex (1∙2H2O) for antimicrobial activities. HL has a low activity (MIC > 100 μg/mL) on all microorganisms, whereas compound 1∙2H2O displayed moderate activity (10 ∙2H2O exhibited bactericidal and fungicidal activity respectively on all the bacteria and yeasts tested. These findings reveal that the antimicrobial activity of HL was enhanced upon coordination to Co(II) ion against all microorganisms (bacteria and fungus).
以六水氯化钴(Co(Cl)2∙6H2O)与3-甲基-1-苯基-4-(2-噻吩基)-吡唑-5- 1(简称HL)在室温下于乙醇中反应,合成了新的钴(II)配合物[Co(O2C15H11N2S)2(OH2)2]∙2H2O(1∙2H2O)。采用单晶x射线衍射(XRD)、光谱方法和微量元素分析对1∙2H2O进行了表征。化合物1∙2H2O在具有Pbca空间基团和钴原子为拟八面体配位的正交晶系中结晶。采用微量肉汤稀释法筛选游离配体(HL)和配合物(1∙2H2O)的抑菌活性。HL对所有微生物的活性均较低(MIC > 100 μg/mL),而化合物1∙2H2O表现出中等活性(10∙2H2O对所有细菌和酵母菌分别表现出杀菌和杀真菌活性)。这些结果表明,HL与Co(II)离子配合后,对所有微生物(细菌和真菌)的抑菌活性均增强。
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引用次数: 0
Molecular Dynamics (MD) Applications in Materials Science and Engineering and Nanotechnology 分子动力学(MD)在材料科学与工程和纳米技术中的应用
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.1111001
Rishaad Khan
Molecular dynamics (MD) is a computer simulation technique that helps to explore the behavior and properties of molecules and atoms. MD has been used in research and development in many spaces, including materials science and engineering and nanotechnology. MD has been proven useful in topics like the nano-engineering of construction materials, correcting graphene planar defects, studying self-assembling bio-materials, and the densification, consolidation, and sintering of nanocrystalline materials.
分子动力学(MD)是一种有助于探索分子和原子的行为和性质的计算机模拟技术。MD已被应用于许多领域的研究与开发,包括材料科学与工程以及纳米技术。MD在建筑材料的纳米工程、修正石墨烯平面缺陷、研究自组装生物材料以及纳米晶体材料的致密化、固结和烧结等领域已被证明是有用的。
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引用次数: 0
Investigation of the Potential of Using Liquid Rubbers in Rubber Industry 液体橡胶在橡胶工业中的应用潜力探讨
Pub Date : 2023-01-01 DOI: 10.4236/msce.2023.119002
Emine Demir, Gasim Altundal, Husnu Gerengi, Canan Yüksel
Along with the developing technology in the rubber industry, the use of natural and synthetic rubbers as well as liquid rubbers has increased significantly in recent years. The formulation of the tread compound, which directly affects the performance of a tire, is generally produced from natural and synthetic rubbers. Intensive scientific studies have been carried out on liquid rubbers because they reduce the consumption of process oils used in the tire production phase and increase dispersion. In this study, the rheological and physico-mechanical properties of rubbers developed using only liquid rubber (liquid isoprene and liquid SBR) with four different viscosities and without using process oil (Styrene Butadiene Rubber—SBR) were investigated. It has been observed that the rubber blends produced by adding four different liquid rubbers to the same recipe caused changes in rheological and physico-mechanical properties compared to the reference sample. It was observed that the minimum torque/viscosity (ML), maximum torque/viscosity (MH) and curing time (t90) in some of the formulas tested decreased significantly due to the use of liquid rubber.
近年来,随着橡胶工业技术的发展,天然橡胶和合成橡胶以及液体橡胶的使用量显著增加。胎面胶的配方直接影响轮胎的性能,一般由天然橡胶和合成橡胶制成。对液体橡胶进行了深入的科学研究,因为它们减少了轮胎生产阶段使用的工艺油的消耗,并增加了分散性。研究了仅使用四种不同粘度的液体橡胶(液体异戊二烯和液体丁二烯橡胶)而不使用工艺油(苯乙烯丁二烯橡胶- SBR)制备的橡胶的流变学和物理力学性能。我们观察到,将四种不同的液体橡胶加入到相同的配方中产生的橡胶共混物与参考样品相比,流变学和物理机械性能发生了变化。结果表明,部分配方的最小扭矩/粘度(ML)、最大扭矩/粘度(MH)和固化时间(t90)因使用液体橡胶而显著降低。
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引用次数: 0
期刊
Journal of Materials Science and Chemical Engineering
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