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Effect of Amine Type on Lignin Modification to Evaluate Its Reactivity in Polyol Construction for Non-Isocyanate Polyurethanes (NIPU) 胺型对木质素改性的影响及其在非异氰酸酯聚氨酯(NIPU)多元醇结构中的反应性
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2023.027835
S. Kazemi Najafi, F. Najafi, A. Pizzi, Fatemeh Farhood Hassani Khorshidi, R. Behrooz
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引用次数: 2
Optical and Mechanical Properties of Ramie Fiber/Epoxy Resin Transparent Composites 苎麻纤维/环氧树脂透明复合材料的光学和力学性能
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2023.028111
Chunhua Liu, Dongfang Zou, Qinqin Huang, Shang Li, Xia Zheng, Xingong Li
The residual resources of ramie fi ber-based textile products were used as raw materials. Ramie fi ber felt (RF) was modi fi ed by NaClO 2 aqueous solution and then impregnated with water-based epoxy resin (WER). RF/WER transparent composite materials were prepared by lamination hot pressing process. The composite materials ’ color difference, transmittance, haze, density, water absorption, and mechanical properties were determined to assess the effects of NaClO 2 treatment and the number of ramie fi ber layers on the properties of the prepared composites. The results showed signi fi cantly improved optical and mechanical properties of the RF/WER transparent composites after NaClO 2 treatment. With the increase of ramie fi ber layers, the composites ’ whiteness, transmittance, and water absorption decreased while the haze increased. For material with three layers, the optical trans-mittance in the visible light region was 82%, and the haze was 96%, indicating the material has both high transmittance and high haze characteristics. The tensile strength increases with the increase of the number of layers, and the tensile strength of the composite with six layers is 243 MPa. This study broadens the scope of application of ramie fi ber as a new option for home decoration materials.
以苎麻纤维基纺织品的剩余资源为原料。采用氯化钠水溶液改性苎麻纤维毡(RF),再用水性环氧树脂(WER)浸渍。采用层压热压法制备了RF/WER透明复合材料。通过测定复合材料的色差、透光率、雾度、密度、吸水率和力学性能,评价naclo2处理和苎麻纤维层数对复合材料性能的影响。结果表明,经过naclo2处理后,RF/WER透明复合材料的光学性能和力学性能得到了显著改善。随着苎麻纤维层数的增加,复合材料的白度、透光率和吸水率降低,而雾度增加。对于三层材料,可见光区的透光率为82%,雾度为96%,表明该材料具有高透光率和高雾度的特性。抗拉强度随层数的增加而增加,6层复合材料的抗拉强度为243 MPa。本研究拓宽了苎麻纤维作为一种新的家居装饰材料的应用范围。
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引用次数: 0
Optimization of Mortar Compressive Strength Prepared with Waste Glass Aggregate and Coir Fiber Addition Using Response Surface Methodology 用响应面法优化掺加废玻璃骨料和椰壳纤维的砂浆抗压强度
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2023.028987
C. Rahmawati, L. Handayani, Muhtadin, Muhammad Faisal, Muhammad Zardi, S. M. Sapuan, Agung Efriyo Hadi, J. Ahmad, Haytham F. Isleem
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引用次数: 0
Flexible Biofoams Based on Furanics and Fatty Acids Esterified Tannin 基于呋喃和脂肪酸酯化单宁的柔性生物泡沫
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2023.030373
Elham Azadeh, Ummi Hani Abdullah, C. Gérardin, A. Pizzi, P. Gérardin, C. Ségovia
Water repellant, flexible biofoams using tannin esterified with various fatty acid chains, namely lauric, palmitic and oleic acids, by reaction with lauryl chloride, palmitoyl chloride, and oleyl chloride were developed and their characteristics compared with the equivalently esterified rigid biofoams. Glycerol, while initially added to control the reaction temperature, was used as a plasticizer yielding flexible biofoams presenting the same water repellant character that the equivalent rigid foams. Acetaldehyde was used as the cross-linking agent instead of formaldehyde, as it showed a better performance with the esterified tannin. The compression results showed a significant decrease of the Modulus of Elasticity (MOE) of the flexible foams in relation to that of the rigid foams, confirming their flexible character. The lauryland palmitoyl-esterified biofoams presented similar mechanical properties, while the oleyl-esterified biofoam presented different mechanical and morphological result not really showing the expected flexibility. Both the esterified rigid and flexible tannin-based biofoams showed good water resistance and their sessile drop contact angle analysis as a function of time confirmed this characteristic. Scanning Electron Microscope (SEM) analysis showed the flexible foams to present a higher proportion of closed cells than the rigid foams. Conversely, the cells depth of the flexible foams was lower than that of the rigid foam. As regards their thermal resistance, the flexible foams showed a slight loss of mass compared to the rigid ones without glycerol. Both types of foams presented much lower surface friability of non-esterified rigid foams.
采用单宁与十二烷基氯、棕榈酰氯和油酰氯反应,与月桂酸、棕榈酸和油酸等多种脂肪酸链酯化,制备了具有防水性的柔性生物泡沫,并与同等酯化的刚性生物泡沫进行了性能比较。甘油最初是用来控制反应温度的,后来被用作增塑剂,生产出与同等刚性泡沫具有相同拒水性的柔性生物泡沫。用乙醛代替甲醛作为交联剂,其与酯化单宁的交联性能更好。压缩结果表明,柔性泡沫的弹性模量(MOE)明显低于刚性泡沫,证实了其柔性特性。月桂棕榈酰酯化生物泡沫具有相似的力学性能,而油酰酯化生物泡沫具有不同的力学和形态结果,并没有真正表现出预期的柔韧性。酯化后的刚性和柔性单宁基生物泡沫均表现出良好的耐水性,其固滴接触角随时间的变化分析证实了这一特性。扫描电镜(SEM)分析表明,柔性泡沫比刚性泡沫具有更高的闭孔比例。相反,柔性泡沫的细胞深度低于刚性泡沫。在耐热性方面,与不含甘油的刚性泡沫相比,柔性泡沫的质量损失较小。两种类型的泡沫均表现出比非酯化硬质泡沫低得多的表面脆性。
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引用次数: 0
Antibacterial Chitosan-Gelatin Microcapsules Modified with Green-Synthesized Silver Nanoparticles for Food Packaging 绿色合成纳米银修饰抗菌壳聚糖-明胶微胶囊用于食品包装
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2022.021456
Long Li, Yanan Lu, Yu Chen, Jiayi Bian, Li Wang, Li Li
Silver nanoparticles (Ag NPs) are an effective antibacterial agent, but their application in food packaging is limited due to their easy agglomeration and oxidation. In this study, antibacterial microcapsules were fabricated using Ginkgo biloba essential oil (GBEO) as core material and chitosan and type B gelatin biopolymer as capsule materials. These antibacterial microcapsules were then modified with green-synthesized Ag NPs, blended into the biopolymer polylactic acid (PLA), and finally formed as films. Physicochemical properties and antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were evaluated. Results showed that the prepared antibacterial PLA films exhibited excellent antibacterial activity against foodborne pathogens. Its TVC exceeded the limit value of 7 log CFU/g at 7 days compared with the 5 days of pure PLA films. Therefore, these films can extend the shelf life of grass carp fillets by 2–3 days under refrigeration.
银纳米粒子是一种有效的抗菌剂,但由于其易团聚和氧化,限制了其在食品包装中的应用。本研究以银杏精油(GBEO)为核心材料,壳聚糖和B型明胶生物聚合物为胶囊材料制备抗菌微胶囊。然后用绿色合成的Ag NPs修饰这些抗菌微胶囊,混合到生物聚合物聚乳酸(PLA)中,最终形成薄膜。对其理化性质及对大肠杆菌和金黄色葡萄球菌的抑菌活性进行了评价。结果表明,制备的聚乳酸抗菌膜对食源性致病菌具有良好的抗菌活性。与纯PLA膜相比,其TVC在第7天超过了7 log CFU/g的极限值。因此,这些薄膜可以使草鱼鱼片在冷藏条件下的保质期延长2-3天。
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引用次数: 7
Mechanical Properties of Self-Compacting Rubberized Concrete with Different Rubber Types under Triaxial Compression 不同橡胶类型自密实橡胶混凝土三轴压缩力学性能研究
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2022.022074
Chunlin Meng, W. Fu, J. Shen, Y. Su, C. Ye
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引用次数: 0
Properties and Hydration Mechanism of Cementitious Materials Prepared from Calcined Coal Gangue 煅烧煤矸石制备胶凝材料的性能及水化机理
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2022.022893
Zhaopeng Wang, Shaowu Jiu, Hui Li, Kaifeng Zhang, Simeng Cheng
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引用次数: 1
Nano-CaO Promotes the Release of Carbon Sources from Municipal Sludge and the Preparation of Double-Network Hydrogels with High Swelling Ratios 纳米氧化钙促进城市污泥中碳源的释放和制备高溶胀比双网水凝胶
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2022.022972
Yalin Li, Yu Huang, Lei Liu, Haozhao Liu, Haiyang He, Dongxue Lu, Tingting Dong
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引用次数: 1
Phosphorus Containing Rubber Seed oil as a Flame Retardant Plasticizer for Polyvinyl Chloride 含磷橡胶籽油作为聚氯乙烯阻燃增塑剂的研究
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2022.024160
Hongying Chu, Huabei Li, Xiao‐yan Sun, Yao Zhang
The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body. Hence, producing functional bio-based plasticizers via exploiting clean and reusable resources meets the satisfaction of current demands. In this study, flame-retardant rubber seed oil-based plasticize (FRP) was prepared via epoxidation reaction and ring opening addition reactions, which was used as a flame-resistant plasticizer for polyvinyl chloride to replace petroleum-based phthalate plasticizer. When DOP was replaced with FRP, the torque of PVC blends increased from 11.4 to 18.4 N⋅m, the LOI value increased from 24.3% for PVC-FRP-0% to 33.1% for PVC-FRP-20. The THR value diminished from 39 MJ/m (pertaining to PVC-FRC-0) to 22 MJ/m Tg increased from 23°C to 47°C, the weight loss of plasticized PVC blends significantly reduced from 22.6% to 2.8% in leaching tests. The study provided a new way to prepare flame retardant plasticizer using rubber seed oil as raw material.
邻苯二甲酸酯类增塑剂由于迁移性差和对人体的潜在危害,在世界范围内的应用受到限制。因此,利用清洁、可重复利用的资源生产功能性生物基增塑剂是满足当前需求的。本研究通过环氧化反应和开环加成反应制备了阻燃橡胶籽油基增塑剂(FRP),作为聚氯乙烯阻燃增塑剂替代石油基邻苯二甲酸酯增塑剂。当用FRP代替DOP时,PVC共混物的扭矩从11.4 N·m增加到18.4 N·m, LOI值从PVC-FRP-0%的24.3%增加到PVC-FRP-20的33.1%。THR值从39 MJ/m(属于PVC- frc -0)下降到22 MJ/m, Tg从23°C增加到47°C,浸出试验中塑化PVC共混物的失重率从22.6%显著降低到2.8%。为以橡胶籽油为原料制备阻燃增塑剂提供了一条新途径。
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引用次数: 1
A Review of the Advances Made in Improving the Durability of Welded Wood against Water in Light of the Results of African Tropical Woods Welding 从非洲热带木材焊接试验结果看提高焊接木材抗水耐久性的研究进展
4区 材料科学 Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.32604/jrm.2023.024079
Jean Jalin Eyinga Biwole, Achille Bernard Biwole, A. Pizzi, Joseph Zobo Mfomo, C閟ar Segovia, A. Ateba, Evariste Fedoung Fongnzossie, S. Ouertani, Xinyi Chen, B閚o顃 Ndiwe, Dieudonn�Abessolo, P. Méausoone
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引用次数: 3
期刊
Journal of Renewable Materials
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