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Petrophysical Considerations for CO2 Capture and Storage 二氧化碳捕获与封存的岩石物理考虑因素
Munish Kumar, Gabriel Lauderdale-Smith
Carbon capture, utilization, and storage (CCUS) is a process that involves capturing carbon dioxide (CO2) emissions and storing them in geological formations. While the challenge of CCUS is one of multiple disciplines, this paper will discuss the key petrophysical considerations worth noting for CCUS projects. As the storage capacity and effectiveness of the storage reservoir depend on the physical and chemical properties of the geological formations that are used for storage, petrophysicists working on CCUS projects must have a good understanding of the subsurface and its limitations. Any CCUS project can be better managed by application and adherence to the CO2 Storage Resources Management System (SRMS), which aims to develop a consistent approach to estimating storable quantities of CO2 in the subsurface and evaluating development projects. In this paper, we will also discuss a risk matrix that we have designed as a tool for project petrophysicists to document uncertainties and rank them to enhance communication with team members. We finally share a petrophysical checklist to highlight considerations as the evaluation of prospective, contingent, and (commercial storage) capacity-scale CCUS projects are matured and use a well in the North West Shelf, Australia, as a case study to show how reservoirs can be analyzed for suitability for CO2 storage.
碳捕集、利用和封存(CCUS)是一个涉及捕集二氧化碳(CO2)排放物并将其封存在地质构造中的过程。CCUS 的挑战涉及多个学科,本文将讨论 CCUS 项目中值得注意的关键岩石物理因素。由于封存库的封存能力和效果取决于用于封存的地质构造的物理和化学性质,因此参与 CCUS 项目的岩石物理学家必须充分了解地下情况及其局限性。任何 CCUS 项目都可以通过应用和遵守二氧化碳封存资源管理系统 (SRMS) 得到更好的管理,该系统旨在开发一种一致的方法来估算地下二氧化碳的可存储量并评估开发项目。在本文中,我们还将讨论我们设计的风险矩阵,作为项目岩石物理学家记录不确定性并对其进行排序的工具,以加强与团队成员的沟通。最后,我们将分享一份岩石物理核对表,以强调在对远景、或有和(商业封存)产能规模的 CCUS 项目进行成熟评估时的注意事项,并以澳大利亚西北大陆架的一口井为案例,说明如何分析储层是否适合封存二氧化碳。
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引用次数: 0
Evaluating the Usefulness of Least Squares Regression in Petrophysics Interpretation 评估最小二乘回归法在岩石物理解释中的实用性
Lee Etnyre
This paper is to update the information provided in the author’s previous papers on evaluating the uncertainty in least squares results. It is prompted by new information that shows that the usefulness of any least squares result cannot be guaranteed by conventional statistics (such as R-squared, F-statistic, or standard error of the regression, sigma). A new method based on the singular value decomposition (SVD) of a matrix, when accompanied by a Relative Error Bound (REB) on the estimated parameters, provides the user with a tool that can better assess the usefulness of any least squares result. Another important aspect of the REB is that it provides the user of the SVD method with a powerful tool for judging which is the best among several candidate solutions. In addition, it provides the user with a numerically stable method of computing the data ordinarily provided by principal component regression by eliminating the need to perform an eigenvector-eigenvalue analysis of an ATA matrix. This is of particular interest because forming the ATA matrix is often accompanied by a loss of data. The new method also provides the user with an improved method for selection of which principal components should be retained for a given problem.
本文旨在更新作者以前关于评估最小二乘法结果不确定性的论文中提供的信息。新信息表明,任何最小二乘法结果的有用性都无法通过常规统计(如 R 方、F 统计或回归标准误差 sigma)来保证。一种基于矩阵奇异值分解(SVD)的新方法,配合估计参数的相对误差约束(REB),为用户提供了一种可以更好地评估任何最小二乘法结果有用性的工具。REB 的另一个重要方面是,它为 SVD 方法的用户提供了一个强大的工具,用于判断几个候选方案中哪个是最佳方案。此外,由于无需对 ATA 矩阵进行特征向量-特征值分析,它还为用户提供了一种数值稳定的方法,用于计算主成分回归通常提供的数据。这一点尤为重要,因为形成 ATA 矩阵往往会导致数据丢失。新方法还为用户提供了一种改进的方法,用于选择在特定问题中应保留哪些主成分。
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引用次数: 0
The Fundamental Flaws of the Waxman-Smits and Dual Water Formulations, Attempted Remedies, and New Revelations from Historical Laboratory Complex Conductivity Measurements 瓦克斯曼-斯密茨公式和双水公式的基本缺陷、尝试的补救措施以及实验室复合电导率历史测量的新启示
John Rasmus, David Kennedy, Dean Homan
The Waxman-Smits formula was introduced in 1968 as a parallel conductance model to improve previous models. A careful inspection of the Waxman and Smits model reveals it is not a parallel conduction model by the conventional definition. First, Waxman-Smits assumed that “the electrical current transported by the counterions associated with the clay travels along the same tortuous path as the current attributed to the ions in the pore water” (Waxman and Smits, 1968), removing an essential feature of a parallel conduction model, that there be two separate conductors. Based on this assumption, they assign the same geometrical factor to both current paths. The geometrical factor is defined as the reciprocal of the formation resistivity factor (1/F or σm). Waxman-Smits found experimentally that a shaly sand appeared to have an F that was larger than a clean sand and introduced F* to account for this. Therefore, the tortuosity of the current paths through the clay and the pore water were deemed to be equivalent, with both tortuosities increasing equally as the clay content increased. Second, a parallel model requires the bulk conductivity of a volume to be weighted by the fractional volumes of the separate clay and interstitial water current paths. Clavier et al. (1977) discovered during the field testing of the new 1.1-GHz electromagnetic propagation tool that there existed a volume of clay water of near-constant salinity in shales. These two concepts are not accounted for in the Waxman-Smits model. A re-evaluation of the Waxman-Smits database by Clavier et al. (1977, 1984) revealed the F* increase was primarily due to the Waxman-Smits model not accounting for the physical presence of the volume of the clay water. The inclusion of the clay water volume in the dual water model produces a true parallel conductivity model. However, like Waxman-Smits, it assigns the same tortuosity to both the clay and pore water current paths. This assumption seems dubious based on observations of scanning electron microscope (SEM) photos showing actual clay morphologies. Laboratory measurements of pure clay and glass beads would allow one to quantify tortuosity changes due to the introduction of clay into an otherwise pure glass bead environment. Theoretically and experimentally, the value of the clay water conductivity (Ccw) at room temperature was found to be 6.8 S/m. Therefore, for a pore water conductivity (Cw) less than 6.8, the clay adds to the rock conductivity relative to an Archie rock, as written in the Waxman-Smits model. However, when Cw is greater than 6.8, the clay water subtracts from the rock conductivity relative to an Archie rock. This cannot be accommodated by the Waxman-Smits formulation. To correct for this model deficiency, B was made a function of salinity and temperature when, theoretically, it is a function of temperature only. Thirdly, neither model accurately predicts the rock conductivity at pore water salinities below approximately 0.5 to 1 S
瓦克斯曼-斯密茨公式是 1968 年推出的一种平行传导模型,用于改进以前的模型。对 Waxman 和 Smits 模型的仔细研究表明,按照传统定义,它并不是一个平行传导模型。首先,Waxman-Smits 假设 "与粘土相关的反离子传输的电流与孔隙水中离子传输的电流沿着相同的曲折路径行进"(Waxman 和 Smits,1968 年),从而取消了平行传导模型的一个基本特征,即存在两个独立的导体。基于这一假设,他们为两条电流路径分配了相同的几何因子。几何因子被定义为地层电阻率因子的倒数(1/F 或 σm)。Waxman-Smits 通过实验发现,有光泽的沙子的 F 值似乎大于干净的沙子,因此引入了 F* 来解释这一现象。因此,通过粘土和孔隙水的电流路径的迂回度被认为是相等的,随着粘土含量的增加,两者的迂回度同样增加。其次,平行模型要求体积电导率根据粘土和间隙水水流路径的体积分数加权。Clavier 等人(1977 年)在对新的 1.1 GHz 电磁传播工具进行现场测试时发现,页岩中存在盐度接近恒定的粘土水体积。Waxman-Smits 模型没有考虑这两个概念。Clavier 等人(1977 年,1984 年)对 Waxman-Smits 数据库的重新评估表明,F* 上升的主要原因是 Waxman-Smits 模型没有考虑到粘土水体积的物理存在。在双水模型中加入粘土水体积可产生真正的平行传导模型。然而,与 Waxman-Smits 模型一样,它也为粘土和孔隙水水流路径分配了相同的曲折度。根据对显示实际粘土形态的扫描电子显微镜(SEM)照片的观察,这一假设似乎并不可靠。对纯粘土和玻璃珠进行实验室测量,可以量化由于在纯玻璃珠环境中引入粘土而导致的迂回度变化。通过理论和实验发现,室温下粘土的导水率 (Ccw) 值为 6.8 S/m。因此,当孔隙水电导率(Cw)小于 6.8 时,粘土会增加岩石的电导率,这与阿奇岩的电导率相同,正如 Waxman-Smits 模型所描述的那样。然而,当 Cw 大于 6.8 时,相对于阿基岩,粘土水会减去岩石的传导性。Waxman-Smits 模型无法解决这一问题。为了纠正模型的这一缺陷,将 B 作为盐度和温度的函数,而理论上它只是温度的函数。第三,这两个模型都不能准确预测孔隙水盐度低于约 0.5 至 1 S/m 时的岩石电导率。对于地热评估、注水储层和天然淡水储层来说,在这些较低盐度条件下拥有一个合适的模型非常重要。我们根据对岩心正交电导率测量的研究和最近的实验室测量结果,提出了一种校正方法。
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引用次数: 0
Study on Rock Mechanics Parameter Prediction Method Based on DTW Similarity and Machine-Learning Algorithms 基于 DTW 相似性和机器学习算法的岩石力学参数预测方法研究
Wenjun Cai, Jianqi Ding, Zhong Li, Zhiming Yin, Yongcun Feng
Rock mechanics parameters are crucial factors for predicting rock behavior in oil and gas reservoirs, optimizing extraction strategies, and ensuring drilling safety. In this study, we propose a random forest (RF)-convolutional neural network (CNN)-long-term short-term memory network (LSTM) fusion model based on the dynamic time warping (DTW) algorithm to construct intelligent prediction models for elastic modulus, Poisson’s ratio, and compressive strength using real-time drilling engineering data. An autoencoder with a sliding window is employed to automatically identify abnormal points or segments in the calculated values of elastic modulus, Poisson’s ratio, and compressive strength obtained from drilled wells. These abnormal values are then corrected using a backpropagation (BP) neural network. Compared to single CNN-LSTM or single RF models, the RF-CNN-LSTM fusion model performs better. It achieves this by effectively combining the strengths of different algorithms in predicting outcomes. The accuracy of the RF-CNN-LSTM fusion model is over 94% when compared to the actual values. Furthermore, the analysis of the relative importance of input parameters reveals that weight on bit (WOB), temperature, displacement, equivalent circulation density (ECD), and mud density are the primary input features for predicting elastic modulus. For predicting Poisson’s ratio, the main input features include WOB, mud density, ECD, temperature, pumping pressure, displacement, and rate of penetration (ROP). Similarly, for predicting compressive strength, the main input features consist of WOB, temperature, displacement, ECD, and mud density. The research findings demonstrate that the rock mechanics parameter prediction models based on the RF-CNN-LSTM algorithm using DTW exhibit high computational accuracy in the B oil field of China. These results are significant for gaining a deeper understanding of the variations in rock mechanics parameters and optimizing drilling decisions.
岩石力学参数是预测油气藏岩石行为、优化开采策略和确保钻井安全的关键因素。在本研究中,我们提出了一种基于动态时间扭曲(DTW)算法的随机森林(RF)-卷积神经网络(CNN)-长期短期记忆网络(LSTM)融合模型,利用实时钻井工程数据构建弹性模量、泊松比和抗压强度的智能预测模型。采用滑动窗口自动编码器自动识别从钻井中获得的弹性模量、泊松比和抗压强度计算值中的异常点或段。然后使用反向传播 (BP) 神经网络修正这些异常值。与单一的 CNN-LSTM 模型或单一的 RF 模型相比,RF-CNN-LSTM 融合模型的性能更好。它通过有效结合不同算法在预测结果方面的优势来实现这一目标。与实际值相比,RF-CNN-LSTM 融合模型的准确率超过 94%。此外,对输入参数相对重要性的分析表明,钻头重量(WOB)、温度、位移、等效循环密度(ECD)和泥浆密度是预测弹性模量的主要输入特征。在预测泊松比时,主要输入参数包括钻头重量、泥浆密度、等效循环密度(ECD)、温度、泵压、位移和渗透率(ROP)。同样,预测抗压强度的主要输入特征包括 WOB、温度、位移、ECD 和泥浆密度。研究结果表明,基于使用 DTW 的 RF-CNN-LSTM 算法的岩石力学参数预测模型在中国 B 油田表现出较高的计算精度。这些结果对于深入了解岩石力学参数的变化和优化钻井决策具有重要意义。
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引用次数: 0
The Fundamental Flaws of the Waxman-Smits and Dual Water Formulations, Attempted Remedies, and New Revelations from Historical Laboratory Complex Conductivity Measurements 瓦克斯曼-斯密茨公式和双水公式的基本缺陷、尝试的补救措施以及实验室复合电导率历史测量的新启示
John Rasmus, David Kennedy, Dean Homan
The Waxman-Smits formula was introduced in 1968 as a parallel conductance model to improve previous models. A careful inspection of the Waxman and Smits model reveals it is not a parallel conduction model by the conventional definition. First, Waxman-Smits assumed that “the electrical current transported by the counterions associated with the clay travels along the same tortuous path as the current attributed to the ions in the pore water” (Waxman and Smits, 1968), removing an essential feature of a parallel conduction model, that there be two separate conductors. Based on this assumption, they assign the same geometrical factor to both current paths. The geometrical factor is defined as the reciprocal of the formation resistivity factor (1/F or σm). Waxman-Smits found experimentally that a shaly sand appeared to have an F that was larger than a clean sand and introduced F* to account for this. Therefore, the tortuosity of the current paths through the clay and the pore water were deemed to be equivalent, with both tortuosities increasing equally as the clay content increased. Second, a parallel model requires the bulk conductivity of a volume to be weighted by the fractional volumes of the separate clay and interstitial water current paths. Clavier et al. (1977) discovered during the field testing of the new 1.1-GHz electromagnetic propagation tool that there existed a volume of clay water of near-constant salinity in shales. These two concepts are not accounted for in the Waxman-Smits model. A re-evaluation of the Waxman-Smits database by Clavier et al. (1977, 1984) revealed the F* increase was primarily due to the Waxman-Smits model not accounting for the physical presence of the volume of the clay water. The inclusion of the clay water volume in the dual water model produces a true parallel conductivity model. However, like Waxman-Smits, it assigns the same tortuosity to both the clay and pore water current paths. This assumption seems dubious based on observations of scanning electron microscope (SEM) photos showing actual clay morphologies. Laboratory measurements of pure clay and glass beads would allow one to quantify tortuosity changes due to the introduction of clay into an otherwise pure glass bead environment. Theoretically and experimentally, the value of the clay water conductivity (Ccw) at room temperature was found to be 6.8 S/m. Therefore, for a pore water conductivity (Cw) less than 6.8, the clay adds to the rock conductivity relative to an Archie rock, as written in the Waxman-Smits model. However, when Cw is greater than 6.8, the clay water subtracts from the rock conductivity relative to an Archie rock. This cannot be accommodated by the Waxman-Smits formulation. To correct for this model deficiency, B was made a function of salinity and temperature when, theoretically, it is a function of temperature only. Thirdly, neither model accurately predicts the rock conductivity at pore water salinities below approximately 0.5 to 1 S
瓦克斯曼-斯密茨公式是 1968 年推出的一种平行传导模型,用于改进以前的模型。对 Waxman 和 Smits 模型的仔细研究表明,按照传统定义,它并不是一个平行传导模型。首先,Waxman-Smits 假设 "与粘土相关的反离子传输的电流与孔隙水中离子传输的电流沿着相同的曲折路径行进"(Waxman 和 Smits,1968 年),从而取消了平行传导模型的一个基本特征,即存在两个独立的导体。基于这一假设,他们为两条电流路径分配了相同的几何因子。几何因子被定义为地层电阻率因子的倒数(1/F 或 σm)。Waxman-Smits 通过实验发现,有光泽的沙子的 F 值似乎大于干净的沙子,因此引入了 F* 来解释这一现象。因此,通过粘土和孔隙水的电流路径的迂回度被认为是相等的,随着粘土含量的增加,两者的迂回度同样增加。其次,平行模型要求体积电导率根据粘土和间隙水水流路径的体积分数加权。Clavier 等人(1977 年)在对新的 1.1 GHz 电磁传播工具进行现场测试时发现,页岩中存在盐度接近恒定的粘土水体积。Waxman-Smits 模型没有考虑这两个概念。Clavier 等人(1977 年,1984 年)对 Waxman-Smits 数据库的重新评估表明,F* 上升的主要原因是 Waxman-Smits 模型没有考虑到粘土水体积的物理存在。在双水模型中加入粘土水体积可产生真正的平行传导模型。然而,与 Waxman-Smits 模型一样,它也为粘土和孔隙水水流路径分配了相同的曲折度。根据对显示实际粘土形态的扫描电子显微镜(SEM)照片的观察,这一假设似乎并不可靠。对纯粘土和玻璃珠进行实验室测量,可以量化由于在纯玻璃珠环境中引入粘土而导致的迂回度变化。通过理论和实验发现,室温下粘土的导水率 (Ccw) 值为 6.8 S/m。因此,当孔隙水电导率(Cw)小于 6.8 时,粘土会增加岩石的电导率,这与阿奇岩的电导率相同,正如 Waxman-Smits 模型所描述的那样。然而,当 Cw 大于 6.8 时,相对于阿基岩,粘土水会减去岩石的传导性。Waxman-Smits 模型无法解决这一问题。为了纠正模型的这一缺陷,将 B 作为盐度和温度的函数,而理论上它只是温度的函数。第三,这两个模型都不能准确预测孔隙水盐度低于约 0.5 至 1 S/m 时的岩石电导率。对于地热评估、注水储层和天然淡水储层来说,在这些较低盐度条件下拥有一个合适的模型非常重要。我们根据对岩心正交电导率测量的研究和最近的实验室测量结果,提出了一种校正方法。
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引用次数: 0
Changing the Game: Well Integrity Measurements Acquired on Drillpipe 改变游戏规则:通过钻杆获得油井完整性测量结果
Andy Hawthorn, Tonje Winther, Laurent Delabroy, Roger B. Steinsiek, Ian Leslie, Lynda Memiche, Abe Vereide
The industry is continuously challenged to improve the efficiency and safety of operations. This is evident over the last 30 years in the development and improvement of measurements acquired while drilling. However, this has, in general, until now not been applied to well integrity measurements such as casing integrity and cement evaluation, which have traditionally been acquired utilizing wireline deployment. This paper will show the results of a new drillpipe-deployed tool that can be run in parallel with existing well operations. The results from two differing North Sea wells will be compared to traditionally acquired wireline-deployed tools and will demonstrate that these measurements and the resultant interpretation can successfully be acquired on drillpipe. This allows for much improved efficiency of operations and, in fact, the ability to acquire this important data in well conditions and environments where it is difficult or, in some cases, impossible to log with conventional wireline techniques. Two wells were selected with different degrees of difficulty in terms of measurement acquisition and showing different well trajectories and mud types. Both wells were logged with both the new drillpipe-deployed technology and traditional wireline technology, allowing a direct comparison of the techniques and tools and paving the way for acceptance of the new drillpipe-conveyed technology. The new drillpipe-conveyed tool can be run anytime drillpipe is utilized in the well. A radial distribution of ultrasonic transducers arranged on the circumference of a drill collar allows for full azimuthal interpretation of the casing and cement while rotating the drillpipe. Analysis of the acquired data allows for the interpretation of caliper thickness and an evaluation of the material in the annular space behind the casing. In addition, the tool can provide casing collar location in real time and has the ability to orient downhole devices such as whipstocks, perforating guns, and oriented cutters. The two well examples conclusively demonstrate that the tool can be run in parallel with existing operations to minimize rig time and eliminate the need for a dedicated, standalone wireline operation. Also, the cement evaluation interpretation was comparable to the equivalent wireline technology. We will investigate which measurements and applications the new tool can be used for and where there may be further room for improvement.
油气行业不断面临着提高作业效率和安全性的挑战。在过去的30年里,这一点在钻井过程中测量数据的发展和改进中得到了明显的体现。然而,到目前为止,这种方法还没有应用于套管完整性和固井评价等井的完整性测量,这些数据通常是通过电缆下入获得的。本文将展示一种新的钻杆下入工具的结果,该工具可以与现有的井作业并行运行。来自北海两口不同井的结果将与传统的电缆部署工具进行比较,并将证明这些测量结果和由此产生的解释可以成功地在钻杆上获得。这大大提高了作业效率,实际上,在常规电缆技术难以测井的井况和环境中,也能够获得这些重要的数据。在测量采集、井眼轨迹和泥浆类型方面,选择了难度不同的两口井。这两口井都使用了新的钻杆下入技术和传统的电缆技术进行了测井,从而可以直接比较技术和工具,为接受新的钻杆下入技术铺平道路。这种新型钻杆输送工具可以在任何使用钻杆的情况下下入。安装在钻铤圆周上的径向分布的超声波换能器,可以在旋转钻杆的同时对套管和水泥进行全方位的解释。对获取的数据进行分析,可以解释井径器的厚度,并对套管后面环空空间的材料进行评估。此外,该工具还可以提供套管接箍的实时定位,并能够定位井下设备,如斜向器、射孔枪和定向切削齿。这两口井的实例最终证明,该工具可以与现有作业并行运行,以最大限度地减少钻机时间,并消除对专用电缆作业的需求。此外,固井评价解释与等效电缆技术相当。我们将调查新工具可以用于哪些测量和应用,以及哪里可能有进一步改进的空间。
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引用次数: 0
Development and Baseline Comparison of a New Pulsed-Neutron Spectroscopy Tool for Carbon- Oxygen Analysis and Three-Phase Saturation Monitoring 用于碳氧分析和三相饱和度监测的新型脉冲中子能谱学工具的开发与基线比较
Ian McGlynn, T. Anniyev, F. Inanc, D. Chace, Alexandr Kotov, Emmannuel Soans, Ardi Batubara
A new slim multidetector pulsed-neutron wireline-logging tool has been developed for openhole or casedhole formation evaluation saturation analysis and time-lapse monitoring. With a greater neutron source output and high-spectral resolution gamma ray detectors, the tool can be operated with reduced uncertainty or faster logging speeds. New, fully programable digital electronics provide a range of acquisition modes optimized for specific formation evaluation objectives. Neutrons are generated from a high-output pulsed-neutron generator, which propagates radially outward, passing through the borehole, completion material, and into the formation. Energy is lost through scattering, and neutrons are absorbed by the surrounding material. Gamma rays are emitted from scattering and absorption interactions at discrete energies, which can be measured by one of three spectral gamma scintillation detectors. The energy distribution of these incident gamma rays by inelastic and capture interactions is affected by the elemental composition of the material. A salinity-independent oil-water saturation assessment begins with the deconvolution of neutron-induced gamma ray inelastic spectra into constituent elemental components. Carbon-oxygen ratios (C/O) of elemental yields are then compared to a reference model to determine the relative saturation and porosity-filled volume of oil and water. In PNC (pulsed-neutron capture) acquisition mode, a salinity-dependent oil-water saturation assessment is determined from neutron capture cross section (sigma) measurements, which are compared to formation and porosity fluids using a mass balance approach. Gas saturation assessment is determined from gas-sensitive inelastic (RIN13) and capture (RATO13) ratios. Gas ratios are compared to a reference model to assess the relative saturation of fluids, typically distinguishing gas from water or gas from oil. Gas saturation is not limited to hydrocarbon components and can also be used for saturation analysis of H2, He, CO2, N2, and other non-hydrocarbon-bearing components. A new Omni-mode acquisition combining simultaneous PNC and C/O measurements was also developed. This acquisition mode provides advantages in reducing multipass logging typically required from separate PNC and C/O acquisitions. By including PNC neutron capture sigma, gas-sensitive neutron capture and inelastic measurements, and C/O inelastic measurements, the simultaneous Omni-mode (PNC+C/O) acquisition is specifically optimized for three-phase saturation analysis applications, including baseline CO2 sequestration evaluation for carbon capture, utilization, and storage (CCUS) CO2 and steamflood time-lapse monitoring. Results from a field example are presented to demonstrate the new technology with spectral C/O saturation analysis compared to traditional windows C/O analysis and to compare the performance of the next-generation tool to the legacy tool. Multiphase saturations from C/O and RIN13 measurements and comp
为裸眼或套管井地层评价、饱和度分析和延时监测,开发了一种新型单径多探测器脉冲中子电缆测井工具。凭借更大的中子源输出和高光谱分辨率的伽马射线探测器,该工具可以降低不确定性,提高测井速度。全新的、完全可编程的数字电子设备提供了一系列针对特定地层评价目标进行优化的采集模式。中子由高输出脉冲中子发生器产生,径向向外传播,穿过井眼、完井材料,进入地层。能量因散射而损失,中子被周围的物质吸收。伽玛射线是由散射和吸收相互作用发出的离散能量,可以用三个光谱伽玛闪烁探测器中的一个来测量。这些入射伽马射线的非弹性和俘获相互作用的能量分布受材料元素组成的影响。不依赖于含盐量的油水饱和度评估首先要将中子诱发的伽马射线非弹性谱反褶积为组成元素分量。然后将元素产率的碳氧比(C/O)与参考模型进行比较,以确定油和水的相对饱和度和孔隙度填充体积。在PNC(脉冲中子捕获)采集模式中,通过中子捕获横截面(sigma)测量来确定含盐量相关的油水饱和度评估,并使用质量平衡方法将其与地层和孔隙流体进行比较。气饱和度评估由气敏非弹性比(RIN13)和俘获比(RATO13)确定。气比与参考模型进行比较,以评估流体的相对饱和度,通常区分气与水或气与油。气饱和度不仅限于烃类成分,还可以用于H2、He、CO2、N2和其他非含烃成分的饱和度分析。同时开发了一种结合PNC和C/O测量的新型omni模式采集。这种采集模式的优势在于减少了PNC和C/O采集通常需要的多通道日志记录。通过包括PNC中子捕获sigma,气敏中子捕获和非弹性测量,以及C/O非弹性测量,同时omni模式(PNC+C/O)采集专门针对三相饱和度分析应用进行了优化,包括碳捕获,利用和储存(CCUS)二氧化碳的基线CO2封存评估和蒸汽驱延时监测。现场实例的结果表明,与传统的窗口C/O分析相比,新技术具有光谱C/O饱和度分析,并将下一代工具的性能与传统工具进行了比较。还介绍了C/O和RIN13测量的多相饱和度以及与延时饱和度监测的传统解释的兼容性。
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引用次数: 0
Time-Scaling Creep in Salt Rocks for Underground Storage 用于地下储藏的盐岩的时间刻度蠕变
Talha H. Khan, Michael T. Myers, L. Hathon, Gabriel C. Unomah
Salt is an elastoviscoplastic material that exhibits time-dependent deformation (creep). Experimental measurements of salt creep behavior help predict underground gas repositories’ long-term geomechanical behavior. Previous time-scaling creep experiments have focused on the axial strain of unconsolidated sands. i.e., time-scaling creep effects under zero lateral strain conditions without describing the creep behavior of the radial strain. In addition, the time-scaling creep of the radial and axial strain has not been investigated in salts. A comparative testing procedure and analysis method was conducted on Spindletop salt plugs using triaxial tests for multistage triaxial tests (MST) and different holding time durations and stress regimes, resulting in time-dependent strain responses (creep tests). The MST showed evolving deformational mechanisms under the mapped yield surface based on the irrecoverable to recoverable strain ratio beginning with crack closure or conformance, plasticity, and ending at early crystal surface failure. Unlike unconsolidated sands, salts showed both time and strain amplitude scaling. The axial and radial strain data show scaling behavior under low and high levels of deviatoric stress separated by a transitional period. The salt showed only an axial creep response at low deviatoric stress distally from the yield surface (one-dimesional (1D) response or zero lateral strain), which indicates negative dilatant deformation or uniaxial compaction. In contrast, the salts showed equal strain amplitude scaling factors both axially and radially at high deviatoric stress proximal to the yield surface (two-dimensional (2D) response or unconstrained boundary condition), which suggests positive dilatant deformation. Microstructural images showed accumulated creep damage under high deviatoric stress associated with parallel planes of dislocation-intergranular slip, microcracking, and compaction-induced dilational strains. The period of scaling is interpreted as regions where a single mechanism is dominating. Strain amplitude scaling for both low and high deviatoric creep stress tests provides inputs for a constitutive model of creep response in understanding the magnitude of mechanical damage associated with time-independent stress-strain curves in salts for the structural integrity of salt caverns during cyclic fluid injection and depletion.
盐是一种弹粘塑性材料,表现出随时间的变形(蠕变)。盐蠕变行为的实验测量有助于预测地下储气库的长期地质力学行为。以往的时间尺度蠕变试验主要集中在松散砂的轴向应变上。即,在没有描述径向应变蠕变行为的情况下,零侧向应变条件下的时间尺度蠕变效应。此外,还没有对盐的径向和轴向应变的时间尺度蠕变进行研究。对Spindletop盐塞进行了三轴试验和多级三轴试验(MST),并采用不同的保温时间和应力状态进行了对比试验,得到了随时间变化的应变响应(蠕变试验)。基于不可恢复应变比和可恢复应变比,MST在屈服面下呈现出演化的变形机制,从裂纹闭合或一致性开始,到塑性,结束于早期晶面破坏。与松散砂不同,盐表现出时间和应变振幅的标度。轴向和径向应变数据显示,在低和高偏应力水平下,有一个过渡时期。在离屈服面较远的低偏应力下,盐只表现出轴向蠕变响应(一维(1D)响应或零侧向应变),这表明盐存在负膨胀变形或单轴压实。相反,在接近屈服面(二维响应或无约束边界条件)的高偏应力下,盐在轴向和径向上表现出相同的应变幅值缩放因子,这表明盐具有正的膨胀变形。显微结构图像显示,在高偏应力下,累积蠕变损伤与位错平行面——晶间滑移、微裂纹和压实引起的膨胀应变有关。缩放期被解释为单一机制占主导地位的区域。低偏差和高偏差蠕变应力测试的应变幅标度为蠕变响应的本构模型提供了输入,以了解盐中与时间无关的应力-应变曲线相关的机械损伤程度,以确保盐洞在循环流体注入和衰竭过程中的结构完整性。
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引用次数: 0
Applications of Two-Dimensional Laboratory Higher-Frequency NMR in Unconventional Shale Characterization 二维实验室高频 NMR 在非常规页岩表征中的应用
Z. H. Xie, Omar Reffell
The complexity of the microstructure and fluids in unconventional reservoirs presents challenges to the traditional approaches to the evaluation of geological formations and petrophysical properties due to the low porosity, ultralow permeability, complex lithology, and fluid composition. Nuclear magnetic resonance (NMR) techniques have been playing major roles in unconventional shale characterization in the last decades as NMR can provide critical information about the reservoirs for quantifying their petrophysical parameters and fluid properties and estimating productivity. Laboratory NMR techniques at higher frequency (HF), e.g., 23 MHz, especially two-dimensional (2D) T1-T2 mapping, and their applications have been essential for the noninvasive characterization of tight rock samples for identifying kerogen, bitumen, heavy or light hydrocarbons, and bound or capillary water. Traditional T2 cutoffs, established with low frequency (LF) NMR, no longer apply and need new definitions to reflect the inferences from water and hydrocarbons separately. The crushed rock analysis method, as applied to unconventional formations, has been successful in evaluating total porosity and water saturation but also suffers from inconsistency in results due to desiccation and solvent effects. In the past decade, the oil and gas industry has witnessed significant development of HF NMR techniques that couple advances in petrophysics, petroleum engineering, and geochemistry with a broad range of applications. It is necessary to review such technological advances and draw conclusions to benefit unconventional core analysis programs. This article will summarize key advances in laboratory NMR applications in unconventional shale characterization, including monitoring processes of liquids equilibrium, desiccation, and imbibition in fresh shale samples, determination of activation energy of hydrocarbons in shales, monitoring changes in a shale sample during liquid flooding experiments, and direct measurements on kerogen.
非常规储层微观结构和流体的复杂性,由于其低孔隙度、超低渗透率、复杂岩性和流体成分,给传统的地质地层和岩石物性评价方法带来了挑战。核磁共振(NMR)技术在过去几十年中一直在非常规页岩表征中发挥着重要作用,因为核磁共振可以提供有关储层的关键信息,用于量化储层的岩石物理参数和流体性质,并估计产能。高频(如23mhz)的实验室核磁共振技术,特别是二维(2D) T1-T2测绘技术,及其应用对于致密岩石样品的非侵入性表征至关重要,可用于识别干酪根、沥青、重碳氢化合物或轻烃,以及束缚水或毛细水。由低频核磁共振(LF)建立的传统T2截止点不再适用,需要新的定义来分别反映水和碳氢化合物的推断。应用于非常规地层的碎石分析方法在评估总孔隙度和含水饱和度方面取得了成功,但由于干燥和溶剂的影响,结果不一致。在过去的十年中,油气行业见证了HF NMR技术的重大发展,该技术将岩石物理学、石油工程和地球化学的进步与广泛的应用相结合。有必要回顾这些技术进步,并得出有利于非常规岩心分析项目的结论。本文将总结实验室核磁共振在非常规页岩表征中的关键应用进展,包括监测新鲜页岩样品中的液体平衡、干燥和渗吸过程,测定页岩中碳氢化合物的活化能,监测页岩样品在液体驱实验中的变化,以及直接测量干酪根。
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引用次数: 0
A New Workflow for Assessment of Fluid Components and Pore Volumes From 2D NMR Measurements in Formations With Complex Mineralogy and Pore Structure 根据二维核磁共振测量结果评估具有复杂矿物学和孔隙结构的地层中的流体成分和孔隙体积的新工作流程
Artur Posenato Garcia, R. Mallan, Boquin Sun
It is challenging to reliably identify fluid components and estimate their saturations in formations with complex lithology, complex pore structure, or varying wettability conditions. Common practices for assessing fluid saturations rely on the interpretation of resistivity measurements. These techniques require model calibration, which is time consuming/expensive and can only differentiate conductive and nonconductive fluids. Interpretation of 2D NMR maps provides a viable alternative for identifying fluid components and fluid volumes. However, conventional techniques for the interpretation of 2D NMR rely on cutoffs in the T1-T2 or D-T2 maps. The application of cutoffs is prone to inaccuracies when fluid-component relaxation responses overlap. To address these shortcomings, we introduce a new workflow for identifying/tracking fluid components and estimating their volumes from the interpretation of 2D NMR measurements. We developed a workflow that approximates 2D NMR maps with a superposition of 2D Gaussian distributions. The algorithm automatically determines the optimum number of Gaussian distributions and their corresponding properties (i.e., amplitudes, variances, and means). Next, a clustering technique is implemented to the dataspace containing the Gaussian distribution parameters obtained for the entire logged interval. Each Gaussian is assigned to a cluster corresponding to different pore/fluid components. We then calculate the volumes under the Gaussian distributions corresponding to each cluster at each depth. The volumes associated with each cluster translate directly into the pore volumes corresponding to the different fluid components (e.g., heavy/light hydrocarbon, bound/free water) at each depth. A highlighted contribution of this work is that, in contrast to the alternative petrophysical interpretation techniques for fluid characterization, the introduced workflow does not require calibration efforts, user-defined cutoffs, or proprietary data sets. Furthermore, approximating 2D NMR data with a superposition of Gaussian distributions improves the accuracy of estimated pore volumes of fluid components with overlapping NMR responses. The clustering using the Gaussian distribution parameters as inputs enables depth tracking of different fluid components without making use of user-defined 2D cutoffs. Finally, the multidimensional nature of the introduced clustering provides the unique capability of identifying different fluid components with 2D NMR response located in the same range of coordinates in a T1-T2 map. We successfully verified the reliability and robustness of the new workflow for enhancing petrophysical interpretation in two organic-rich mudrock formations with complex mineralogy and pore structure.
在具有复杂岩性、复杂孔隙结构或不同润湿性条件的地层中,可靠地识别流体组分并估计其饱和度是一项挑战。评估流体饱和度的常用方法依赖于电阻率测量的解释。这些技术需要模型校准,这既耗时又昂贵,而且只能区分导电和非导电流体。二维核磁共振图的解释为确定流体成分和流体体积提供了一种可行的替代方法。然而,传统的二维核磁共振解释技术依赖于T1-T2或D-T2图的截止点。当流体分量松弛响应重叠时,截止点的应用容易产生不准确性。为了解决这些缺点,我们引入了一种新的工作流程,用于识别/跟踪流体成分,并从二维核磁共振测量的解释中估计其体积。我们开发了一个近似二维核磁共振图与二维高斯分布叠加的工作流程。该算法自动确定高斯分布的最佳数量及其相应的属性(即振幅、方差和均值)。其次,对包含整个日志间隔的高斯分布参数的数据空间实现聚类技术。每个高斯分布被分配到对应于不同孔隙/流体成分的簇。然后,我们在高斯分布下计算每个深度对应的每个簇的体积。与每个簇相关的体积直接转化为每个深度不同流体成分(例如,重烃/轻烃,束缚水/自由水)对应的孔隙体积。这项工作的一个突出贡献是,与流体表征的其他岩石物理解释技术相比,引入的工作流程不需要校准工作、用户定义的截止值或专有数据集。此外,用高斯分布的叠加来近似二维核磁共振数据,可以提高具有重叠核磁共振响应的流体组分孔隙体积估计的准确性。使用高斯分布参数作为输入的聚类可以在不使用用户定义的2D截止点的情况下对不同流体成分进行深度跟踪。最后,引入的聚类的多维性提供了识别不同流体成分的独特能力,这些流体成分具有位于T1-T2图中相同坐标范围内的二维NMR响应。在两个具有复杂矿物学和孔隙结构的富有机质泥岩地层中,成功验证了新工作流程的可靠性和鲁棒性。
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引用次数: 0
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Petrophysics – The SPWLA Journal of Formation Evaluation and Reservoir Description
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