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Journal of the Japan Society of Colour Material最新文献

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Drying Process of Ink Dot Analyzed by Using Digital Holographic Microscope 用数字全息显微镜分析墨点干燥过程
Pub Date : 2022-10-20 DOI: 10.4011/shikizai.95.297
M. Yokota
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引用次数: 0
Spontaneous Formation of Monodisperse Structural Colored Particles Obtained by Rotational Stirring 通过旋转搅拌获得的单分散结构有色颗粒的自发形成
Pub Date : 2022-10-20 DOI: 10.4011/shikizai.95.302
Y. Takeoka
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引用次数: 0
Selective Inactivation of Microorganisms with Photocatalyst 光催化剂对微生物选择性失活的影响
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.262
Sho Usuki, K. Yamatoya, K. Nakata
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引用次数: 0
Development of the Photocatalytic Bioaerosol Elimination System Specialized in the Control of Aerosol Infection such as COVID-19 新型冠状病毒等气溶胶感染专用光催化生物气溶胶消除系统的研制
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.256
N. Negishi, Ryou Yamano, Taro Sato
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引用次数: 1
Nanohybrid Photocatalysts with Heteroepitaxial Junction for Solar Chemical Transformations 具有异质外延结的纳米杂化光催化剂用于太阳化学转化
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.275
S. Naya, H. Tada
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引用次数: 0
Energy Conversion Using Photocatalysts Learning from Photosynthesis 从光合作用中学习利用光催化剂进行能量转换
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.269
Haruki Nagakawa, Morio Nagata
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引用次数: 0
The Latest Technology for Large Format Inkjet Printers 大幅面喷墨打印机的最新技术
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.287
Y. Nakazawa
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引用次数: 0
Development of New Standard LED for Total Luminous Flux Evaluation LED总光通量评价新标准的研制
Pub Date : 2022-09-20 DOI: 10.4011/shikizai.95.282
Yuri Nakazawa, K. Godo, Y. Yamaji, Takayuki Masazumi, Shinya Kume
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引用次数: 0
Appearance and Rheology of Automotive Topcoats 汽车面漆的外观和流变性
Pub Date : 2022-08-20 DOI: 10.4011/shikizai.95.235
K. Tachi
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引用次数: 0
Synthesis of Blue Fluorescent Benzotriazoles Incorporating 2-(2-Hydroxyphenyl)-2H-Benzotriazole Derivatives and their Optical Properties and Photostability 含2-(2-羟基苯基)- 2h -苯并三唑衍生物的蓝色荧光苯并三唑的合成及其光学性质和光稳定性
Pub Date : 2022-08-20 DOI: 10.4011/shikizai.95.220
Toshiyuki Uesaka, Fumihisa Komeya, Shoujirou Yoshida, T. Shimeno, S. Yagi, Takeshi Maeda
To gain insight into the improvement of photostability for blue fluorescent benzotriazole derivatives, we synthesized dyad molecules consisting of various derivatives and UV absorbers 2-(2-hydroxyphenyl)-2 H -benzotriazole components (2HPBTA) linked by an ester bond. The dyad molecules showed blue fluorescence, but their fluorescence quantum yields were lower than those of blue fluorescent benzotriazole derivatives without 2HPBTA. The quantum chemical calculations predicted that the excited state intramolecular proton transfer (ESIPT) is thermodynamically allowed for the dyad molecules and is a factor that inhibits radiative deactivation. The polymer films containing dyad molecules showed blue fluorescence, but their fluorescence intensities were decreased after continuous UV irradiation. This result suggested that the 2HPBTA components linked by an ester bond do not affect the photostability of the dyad molecules. On the other hand, the substituents on the benzene ring of blue fluorescent benzotriazole components significantly affected the fluorescence intensities of the dyad molecules.
为了深入了解蓝色荧光苯并三唑衍生物的光稳定性,我们合成了由各种衍生物和紫外线吸收剂组成的双分子2-(2-羟基苯基)-2 H -苯并三唑成分(2HPBTA)通过酯键连接。双偶分子呈现蓝色荧光,但其荧光量子产率低于不含2HPBTA的苯并三唑衍生物的蓝色荧光。量子化学计算预测,激发态分子内质子转移(ESIPT)是热力学允许的二元分子,是一个抑制辐射失活的因素。含有双分子的聚合物薄膜呈现蓝色荧光,但连续紫外照射后其荧光强度降低。这一结果表明,由酯键连接的2HPBTA组分不影响二元分子的光稳定性。另一方面,蓝色荧光苯并三唑组分苯环上的取代基显著影响双分子的荧光强度。
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引用次数: 0
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Journal of the Japan Society of Colour Material
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