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Self-Lubricating Glass Composite Nanocoatings 自润滑玻璃复合纳米涂层
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-22 DOI: 10.1007/s11003-023-00740-z
V. Babak, N. M. Fialko, V. Shchepetov, S. Kharchenko, Ya. М. Hladkyi, S. Bys
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引用次数: 0
Effect of Al2(SO4)3 Additive on the Properties of Calcined Gypsum Prepared from Flue Gas Desulfurization Al2(SO4)3 添加剂对烟气脱硫制备的煅烧石膏性能的影响
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.34396
Guanji Cheng, Jian-wei Hao, Bing Guo, Tao Hu, Shengchang Wang
In order to upgrade the utilization of flue gas desulfurization (FGD) gypsum, crystal modifier aluminum sulfate (Al2(SO4)3) was added into FGD gypsum to prepare calcined gypsum by calcining at normal pressure, and the effect of Al2(SO4)3 addition on the performance of calcined gypsum was studied. The results show that the addition of Al2(SO4)3 to FGD gypsum is slightly beneficial to promote the crystallization of hemihydrate gypsum (HH) along the a-axis direction. The Al2(SO4)3 addition also has a quick-setting effect on gypsum plaster during the hydration process, meanwhile inhibiting the growth of the (020) crystal plane of dihydrate gypsum (DH), then promoting uniform growth and aggregation along the c-axis. The close stacking makes hardened gypsum body dense and improves the strength of calcined gypsum. The strength of calcined gypsum prepared by calcining FGD gypsum with Al2(SO4)3 of 0.6 wt.% at 170 ℃ for 2 h is the highest. 2 h and 7 d flexural strength are 3.80 MPa and 7.20 MPa, and 2 h and 7 d compressive strength are 9.05 MPa and 19.23 MPa, respectively. In addition, 2 h flexural and compressive strength of the calcined gypsum with 0.6 ~ 1.0 wt.% of Al2(SO4)3 prepared at 170 ~ 180 ℃ for 2 h increase by 16 ~ 22 % and 20 ~ 33 %, respectively, which is very advantageous for the high value-added reuse of FGD gypsum for the preparation of high-quality calcined gypsum.
为了提高烟气脱硫石膏的利用率,在烟气脱硫石膏中加入晶体改性剂硫酸铝(Al2(SO4)3),采用常压煅烧法制备煅烧石膏,并研究了Al2(SO4)3的加入对煅烧石膏性能的影响。结果表明:在脱硫石膏中添加Al2(SO4)3对半水石膏(HH)沿a轴方向的结晶有轻微的促进作用;在水化过程中,Al2(SO4)3的加入对石膏也有快凝作用,同时抑制二水石膏(DH)的(020)晶面生长,促进石膏沿c轴均匀生长和聚集。紧密堆积使硬化石膏体致密,提高了煅烧石膏的强度。用0.6 wt.%的Al2(SO4)3煅烧FGD石膏,在170℃下焙烧2 h所得的煅烧石膏强度最高。2 h和7 d抗弯强度分别为3.80 MPa和7.20 MPa, 2 h和7 d抗压强度分别为9.05 MPa和19.23 MPa。此外,在170 ~ 180℃下煅烧2h, Al2(SO4)3含量为0.6 ~ 1.0 wt.%时,煅烧石膏的抗折强度和抗压强度分别提高了16 ~ 22%和20 ~ 33%,这对脱硫石膏的高附加值回用非常有利,可用于制备高质量的煅烧石膏。
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引用次数: 0
Thermal Properties and Characterization of n-Decanol-Capric Acid/Expanded Graphite/Boron Nitride for Thermal Energy Storage 用于热能储存的正癸醇-癸酸/膨胀石墨/氮化硼的热性能和特性分析
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.33351
TongQiang Liang, Piaopiao Huang, Yanghua Chen, Junkang Wu
To find a low temperature phase change material (PCM) that can be applied to the middle constant temperature chamber of the three chamber refrigerator, this study proposes a binary eutectic PCM of n-decanol and capric acid as a base liquid, expanded graphite as a support material, and boron nitride as a thermal conductivity enhanced particle to modify the material. The composite PCM with suitable phase change temperature and high phase change latent heat is prepared by the solution blending method. The leakage rate experiment determines the maximum adsorption ratio of expanded graphite to be 92 %. The chemical structure, microstructure and thermodynamic properties are characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, scanning electron microscopy, thermal conductivity analyzer and thermogravimetric analyzer. The results show that the n-decanol and capric acid binary eutectic PCM is fully wrapped in the porous structure of expanded graphite, and boron nitride thermal conductivity enhanced particles are well adsorbed on the surface and pores of expanded graphite. The n-decanol and capric acid phase change material, boron nitride thermal conductivity enhanced particles and expanded graphite support material are only physically combined and no chemical reaction occurred. The phase change temperature of CPCM-2 with 3 % boron nitride thermal conductivity enhanced particles is -3.68 °C, the phase change latent heat is 129.2 J/g, and the thermal conductivity is 0.75 W/m·K. It has good thermal stability and reliability in the application temperature range.
为了寻找一种适用于三室制冷机中恒温箱的低温相变材料(PCM),本研究提出了以正癸醇和癸酸为基液,膨胀石墨为支撑材料,氮化硼作为导热增强颗粒对材料进行改性的二元共晶PCM。采用溶液共混法制备了相变温度适宜、相变潜热高的复合相变材料。泄漏率实验确定膨胀石墨的最大吸附比为92%。采用傅里叶变换红外光谱、差示扫描量热仪、扫描电镜、热导仪和热重分析仪对其化学结构、微观结构和热力学性质进行了表征。结果表明:正癸醇和癸酸二元共晶PCM被膨胀石墨的多孔结构完全包裹,氮化硼导热增强颗粒在膨胀石墨表面和孔隙上吸附良好;正癸醇-癸酸相变材料、氮化硼导热增强颗粒和膨胀石墨支撑材料只是物理结合,没有发生化学反应。含3%氮化硼导热增强颗粒的CPCM-2相变温度为-3.68℃,相变潜热为129.2 J/g,导热系数为0.75 W/m·K。在应用温度范围内具有良好的热稳定性和可靠性。
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引用次数: 0
Effect of Gradation Variation on Mixture Properties in Stone Mastic Asphalt Mixtures with Carbon Fiber and Hybrid Aggregate 级配变化对含碳纤维和混合骨料的石子胶凝沥青混合料性能的影响
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.33128
C. Gürer, Ayfer ELMACI KORKMAZ, B. E. Korkmaz, Serhat Düzağaç
Due to advantages like abrasion resistance, increased operating and service life, high coarse aggregate content and high resistance to deformation, increased fatigue life, and others, stone mastic asphalt (SMA) mixtures have recently become a popular asphalt pavement type in road sections such as highways, tunnels, and bridges. There hasn't been much research on the topic, despite the fact that gradation significantly affects the performance of SMA combinations. In this study, the experimental findings of three distinct gradations of SMA mixtures with hybrid materials (basalt coarse aggregate, limestone fine aggregate) and carbon fiber were compared. As a result, it was concluded that the hybrid aggregate used with carbon fiber, maximum aggregate size, and coarse aggregate % had a positive impact SMA mixtures.
由于具有耐磨性好、使用寿命长、粗集料含量高、抗变形能力强、疲劳寿命长等优点,石胶泥沥青(SMA)混合料近年来已成为公路、隧道、桥梁等路段常用的沥青路面类型。尽管梯度显著影响SMA组合的性能,但关于该主题的研究并不多。在本研究中,比较了混合材料(玄武岩粗骨料、石灰石细骨料)和碳纤维的三种不同级配SMA混合料的实验结果。综上所述,碳纤维混合骨料、最大骨料粒径和粗骨料%对SMA混合料性能有积极影响。
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引用次数: 0
Characterization of Fiber Metal Laminates for the Development of Subsea Housing 用于开发海底房屋的金属纤维层压板的特性分析
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.34097
Thirunavukkarasu Ayyadurai, Shanmugasundaram Karibeeran, Latha Ganesan
Fiber Metal Laminates (FML) are hybrid composites comprising metals and Fiber Reinforced Plastics (FRP). FMLs are the most widely used in aerospace, defence and automotive sectors due to their superior qualities like light weight, tensile, compression, flexural, excellent fatigue and impact resistance. The properties like strength-to-weight ratio, susceptibility to corrosion and good heat conduction of FML make it suitable for subsea applications. Commonly, FML with a combination of aluminium (Al), titanium (Ti), stainless steel (SS) alloys and FRP are widely used for ocean applications. Compared to other FML, the SS alloy-based FML is typically used in subsea applications as it has more creep and excellent corrosion resistance. In India, under the Ocean Acoustics programme of the National Institute of Ocean Technology (NIOT), an autonomous underwater Ambient Noise Measurement System (ANMS) has been developed and deployed in the shallow waters of Indian seas for the past 12 years to study the background noise prevailing in the sea. To accommodate electronics and power packs for the measurement of ambient noise at an ocean depth of 100 m, subsea housing with stainless steel 316L (SS316L) material for a pressure rating of 1 MPa has been developed. The objective of this study is to develop the FML with SS316L and FRP for reducing the weight of the housing. Based on the literature studies and Classical Laminate Theory (CLT), the FML has been fabricated as a 0.45 m (450 mm) panel with a sequence of SS316L as outer layers and E-glass fibre and carbon as the inner layers. The total thickness of the laminates is 0.006 m (6 mm). The developed FMLs are processed with water jet cutting machines to carry out various testing such as tensile, compression and flexural, which are relevant to the characterization of FML and the experimental results are described in the paper.
金属纤维层压板(FML)是由金属和纤维增强塑料(FRP)组成的混合复合材料。fml由于其重量轻、抗拉伸、抗压缩、抗弯曲、优异的抗疲劳和抗冲击性等优良品质,在航空航天、国防和汽车领域的应用最为广泛。FML的强度重量比、耐腐蚀性能和良好的热传导性能使其适合海底应用。通常,FML与铝(Al),钛(Ti),不锈钢(SS)合金和FRP的组合被广泛用于海洋应用。与其他FML相比,基于SS合金的FML通常用于海底应用,因为它具有更强的蠕变和优异的耐腐蚀性。在印度,根据国家海洋技术研究所(NIOT)的海洋声学计划,一个自主水下环境噪声测量系统(ANMS)已经开发出来,并在过去的12年里在印度洋浅水区部署,以研究海洋中普遍存在的背景噪声。为了容纳用于测量100米海洋深度环境噪声的电子设备和电源包,海底外壳采用不锈钢316L (SS316L)材料,额定压力为1 MPa。本研究的目的是开发使用SS316L和FRP的FML,以减轻壳体的重量。基于文献研究和经典层压理论(CLT),以SS316L序列为外层,e -玻璃纤维和碳为内层,将FML制成0.45 m (450 mm)的面板。层压板的总厚度为0.006 m (6 mm)。利用水射流切割机对所研制的FML进行了拉伸、压缩、弯曲等与FML表征相关的各种测试,并对实验结果进行了描述。
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引用次数: 0
Experimental Determination of a Strain State in a Bulk Forming of a Low Carbon Steel 低碳钢批量成形过程中应变状态的实验测定
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.34605
P. Skakun, D. Rajnović, P. Janjatović, D. Movrin, Miroslav Dramicanin, Lucijano Berus, M. Ficko
An experimental metallographic method for determining strain distribution in a cold formed workpiece is presented in this paper. The method, based on the dependence of recrystallized grain size on prior deformation, was applied to a bulk formed element made of low carbon steel. Strain distribution was obtained by the calibration curve which gives the relation between recrystallized grain size and prior deformation. To determine strain values, the average grain size was measured in the longitudinal cross-section of the formed element. To accurately differentiate deformation zones, additional observation of carbides and nonmetallic inclusions morphology was utilized, also. The grain size and strain noticeably differ through the cross-section. It is observed that in the middle part, material flows freely through the die opening without significant deformation. From this zone, strain increases gradually, reaching the highest value at the contact surface of the die slope, while the top part flows radially having intermediate values of strain.
本文提出了一种测定冷成形工件应变分布的金相实验方法。该方法基于再结晶晶粒尺寸与预先变形的关系,应用于低碳钢块体成形元件。通过标定曲线得到应变分布,给出了再结晶晶粒尺寸与预先变形的关系。为了确定应变值,在成形单元的纵向截面上测量了平均晶粒尺寸。为了准确区分变形区,还利用了额外的碳化物和非金属夹杂物形貌观察。晶粒尺寸和应变在横截面上有明显差异。观察到,在中间部分,材料自由地流过模口,没有明显的变形。从该区域开始,应变逐渐增大,在模具坡面接触面处达到最大值,顶部径向流动,应变处于中间值。
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引用次数: 0
Influence of Accelerated Electron-Irradiation on Sorption Properties of Latvian Darkhead Sheep Wool Fibers 加速电子辐照对拉脱维亚黑头绵羊毛纤维吸附特性的影响
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.34843
L. Avotina, A. Zarins, Nadina Tina Vanaga, A. Petjukevičs, M. Rzepna, Antons Podjava, Vilnis Peipins, G. Kizane
Latvian Darkhead (LD) is a local sheep breed and a genetic resource in Latvia. Preservation and development of the sheep population in the local region is important for the recultivation of fields, it serves as a source for export and local use, as well as waste wool can be applied for developing new products, for example, sorbents for volatile organic pollutants. Therefore, investigation of the sorption properties of the LD sheep wool fibers is under interest. In addition, modification options of the wool for improvement of properties are viewed. Therefore, in the present work, sheep wool fibers as well as accelerated electron-irradiated fibers are analyzed and compared. Fourier transform infrared (FTIR) spectrometry is applied to develop the sorption testing system of volatile organic compounds. An analytical system consisting of a volatile organic compound source, sheep wool filter, and FTIR spectrometry cell is tested and applied for analysis of wool sorption properties for acetone molecules. Registration of the FTIR spectra was performed within the range of 600-4000 cm-1, in the nitrogen flow of about 150mL/min. FTIR analysis shows, that the accelerated electron irradiated sheep wool fibers absorb acetone of about 33% more than non-irradiated fibers. The obtained results will be used for developing recommendations for filter producers to fabricate filter components containing LD sheep wool fibers.
拉脱维亚黑头羊(LD)是拉脱维亚当地的绵羊品种和遗传资源。保护和发展当地绵羊种群对农田的再耕作很重要,它可以作为出口和当地使用的来源,并且废羊毛可以用于开发新产品,例如挥发性有机污染物的吸附剂。因此,对LD羊毛纤维的吸附性能进行了研究。此外,还探讨了改善羊毛性能的各种改性方法。因此,本文对羊毛纤维和加速电子辐照纤维进行了分析和比较。应用傅里叶变换红外光谱法(FTIR)建立了挥发性有机化合物的吸附测试系统。采用挥发性有机化合物源、羊毛过滤器和FTIR光谱分析仪组成的分析系统,对羊毛对丙酮分子的吸附特性进行了测试和应用。FTIR光谱在600 ~ 4000 cm-1范围内进行配准,氮气流量约150mL/min。FTIR分析表明,经加速电子辐照的羊毛纤维比未辐照的纤维对丙酮的吸收多33%左右。所获得的结果将用于为过滤器生产商制定建议,以制造含有LD羊毛纤维的过滤器组件。
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引用次数: 0
Effects of Dosing and Mechanical Activation on the Performance of Reservoir Sediment-Cement Composite Cementitious Material 配料和机械活化对水库沉积物-水泥复合胶凝材料性能的影响
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-07 DOI: 10.5755/j02.ms.33947
Yancang Li, Chunyuan Zhang, Zihe Zhang, Huawang Shi, Shenglei Feng
To solve the problem of reservoir sediment accumulation, this paper intends to study the feasibility of preparing reservoir sediment-cement composite cementitious material by partially replacing cement with reservoir sediment. Using the single factor test method, the replacement rate of reservoir sediment and mechanical activation time were selected as variables to explore the effects of water requirement of normal consistency, setting time, mortar fluidity, and mechanical properties of mortar specimens. The results show that with the increase of sediment replacement rate, the water requirement of normal consistency of composite cementitious material paste increases, the setting time increases, the fluidity of mortar decreases, and the mechanical properties of mortar specimens decrease significantly. With the increase of mechanical activation time, the water requirement of normal consistency decreases, the setting time decreases, the fluidity of mortar increases, and the mechanical properties of the mortar specimen increase. The microcosmic results show that mechanical activation can promote the formation of C-S-H gel in reservoir sediment, and fill each other with unreacted reservoir sediment particles, resulting in a denser microstructure. The purpose of this paper is to provide theoretical support for the preparation of reservoir mud-cement composite cementitious material.
为解决水库泥沙淤积问题,本文拟研究用水库泥沙部分替代水泥制备水库泥沙-水泥复合胶凝材料的可行性。采用单因素试验方法,以水库泥沙置换率和力学激活时间为变量,探讨正常稠度需水量、凝结时间、砂浆流动性和砂浆试件力学性能的影响。结果表明:随着泥沙置换率的增加,复合胶凝材料膏体正常稠度需水量增加,凝结时间增加,砂浆流动性降低,砂浆试件力学性能显著降低;随着机械活化时间的延长,砂浆正常稠度需水量减小,凝结时间减小,砂浆流动性增大,砂浆试件力学性能提高。微观结果表明,机械活化可促进储层沉积物中C-S-H凝胶的形成,并与未反应的储层沉积物颗粒相互填充,使其微观结构更加致密。本文的目的是为油藏泥浆-水泥复合胶凝材料的制备提供理论支持。
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引用次数: 0
FEATURES OF COMPACTIBILITY AND CONSOLIDATION OF WORKPIECES MADE OF MECHANOSYNTHESIZED DYSPROSIUM MOLYBDENUM POWDER 机械合成镝钼粉工件的可压缩性和固结特性
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-30 DOI: 10.31044/1684-579x-2023-0-11-19-23
Guzel Sharipzyanova, Zh.V. Eremeeva
Dysprosium molybdate powder was prepared by the mechanochemical method from a stoichiometric mixture of molybdenum oxide and dysprosium oxide. The XRF, TEM and SEM methods showed that during mechanochemical treatment for 30 minutes, due to mechanochemical reactions between the initial powders, a fine powder of the Dy2MoO6 compound containing up to 8% Dy2(MoO4)3 was formed. The technological properties (fluidity, compactibility) of the mechanosynthesized dysprosium molybdenum powder, as well as its microstructure after sintering, have been investigated.
用机械化学法从氧化钼和氧化镝的化学计量混合物中制备了钼酸镝粉末。XRF、TEM 和 SEM 方法表明,在机械化学处理 30 分钟期间,由于初始粉末之间的机械化学反应,形成了含高达 8% Dy2(MoO4)3 的 Dy2MoO6 复合物细粉。研究了机械合成镝钼粉末的技术特性(流动性、致密性)及其烧结后的微观结构。
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引用次数: 0
Dynamic Characteristics of Magnetorheological Mounted Metal Rubber Structures Under Multi-physics Coupling Conditions 多物理耦合条件下磁流变安装金属橡胶结构的动态特性
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-25 DOI: 10.5755/j02.ms.34901
Bo Peng, Jintao Su, Jinquan Nie
To accurately predict the dynamic characteristics of MR mounting, the nonlinear electromagnetic coupling law between MR liquid and soft magnetic material and the solid-liquid interaction, the electromagnetic coupling and fluid-structure coupling mathematical models and numerical simulation models of MR mounting are established. Through the magnetorheological mounting test, the simulation results are compared with the experimental results, and the validity of the numerical simulation model is verified. On this basis, the distribution effect of electromagnetic coupling in a magnetic circuit is analyzed. According to the Bingham model, the variation rule of magnetorheological fluid damping force was deduced. The magnetic field simulation results are introduced into the fluid model and the fluid-solid model, and the fluid-solid coupling effect of the numerical model of magnetorheological mounting is calculated. The dynamic and static characteristics of magnetorheological mounting under different current excitation conditions are simulated. It provides the basis for designing and simulating multi-physical field simulation of MR mounting.
为了准确预测磁流变安装的动态特性,建立了磁流变液体与软磁材料之间的非线性电磁耦合规律和固液相互作用、电磁耦合和流固耦合数学模型以及磁流变安装的数值模拟模型。通过磁流变安装试验,将模拟结果与实验结果进行对比,验证了数值模拟模型的有效性。在此基础上,分析了电磁耦合在磁路中的分布效应。根据宾厄姆模型,推导出了磁流变流体阻尼力的变化规律。将磁场模拟结果引入流体模型和流固模型,计算了磁流变安装数值模型的流固耦合效应。模拟了磁流变安装在不同电流激励条件下的动态和静态特性。它为磁流变安装的多物理场仿真设计和仿真提供了基础。
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引用次数: 0
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