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Ultra-sensitive simultaneous electrochemical detection of sulfamethoxazole and trimethoprim based on the flower-like-nanostructures-modified screen-printed electrode 基于花状纳米结构修饰的丝网印刷电极的磺胺甲恶唑和甲氧苄啶的超灵敏同时电化学检测
Pub Date : 2023-09-22 DOI: 10.1007/s00706-023-03125-9
Ali Amir Poursaeed, Shohreh Jahani, Mehran Moradalizadeh, Mehdi Shahidi Zandi, Mohammad Mehdi Foroughi
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引用次数: 0
The synthesis of disubstituted 4-methyl-N,N-dipropylbenzenamine derivatives bearing identical azolethione(thiol) moieties as antioxidant agents 以相同的唑硫酮(硫醇)为抗氧化剂的4-甲基- n, n -二丙基苯胺衍生物的合成
Pub Date : 2023-09-20 DOI: 10.1007/s00706-023-03119-7
Ingrida Tumosienė, Ilona Jonuškienė, Sergey Belyakov, Kristina Kantminienė
{"title":"The synthesis of disubstituted 4-methyl-N,N-dipropylbenzenamine derivatives bearing identical azolethione(thiol) moieties as antioxidant agents","authors":"Ingrida Tumosienė, Ilona Jonuškienė, Sergey Belyakov, Kristina Kantminienė","doi":"10.1007/s00706-023-03119-7","DOIUrl":"https://doi.org/10.1007/s00706-023-03119-7","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"179 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136313140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, antimicrobial and antioxidant activity of novel 1-oxo-1,2,3,4-tetrahydropyrrolo[1,2-a]pyrazine-8-carboxylic acids, esters, and amides thereof 新型1-氧-1,2,3,4-四氢吡咯[1,2-a]吡嗪-8-羧酸、酯和酰胺的合成、抗菌和抗氧化活性
Pub Date : 2023-09-13 DOI: 10.1007/s00706-023-03118-8
Mariia B. Litvinchuk, Anton V. Bentya, Alina M. Grozav, Nina D. Yakovychuk, Alina O. Palamar, Lesya M. Saliyeva, Nataliia Yu. Slyvka, Svitlana V. Shishkina, Mykhailo V. Vovk
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引用次数: 0
S-shaped adsorption isotherms modeled by the Frumkin–Fowler–Guggenheim and Hill–de Boer equations 用Frumkin-Fowler-Guggenheim方程和Hill-de Boer方程模拟s形吸附等温线
Pub Date : 2023-09-11 DOI: 10.1007/s00706-023-03116-w
Khim Hoong Chu, Mohd Ali Hashim, Hai Nguyen Tran, Jean-Claude Bollinger
In this study, we used the Frumkin–Fowler–Guggenheim (FFG) and Hill–de Boer (HDB) isotherm models to describe previously published S-shaped isotherms involving water contaminant adsorption, specifically auramine-O and ortho-nitrophenol, onto solid materials. Although the two models differ in their mathematical formulations, they share three key parameters: the monolayer adsorption capacity (qm), the equilibrium constant representing adsorbate−adsorbent interactions, and the equilibrium constant representing adsorbate–adsorbate interactions. Upon comparing the data fitting capabilities of the FFG and HDB models, we found minimal differences. However, substantial discrepancies emerged in the fitted qm values. The FFG model yielded qm values that aligned with the plateaus evident in the auramine-O and ortho-nitrophenol isotherms, whereas the HDB model did not. This inconsistency in the HDB model was also observed when analyzing a hyperbolic tetracycline isotherm. In addition, we delved into the impact of the adsorbate−adsorbent and adsorbate–adsorbate interaction constants on simulated isotherm curves. Our findings revealed that the adsorbate−adsorbent interaction constant influenced the steepness of the simulated curves, while the adsorbate–adsorbate interaction constant determined the nature of isotherm curve generated by the two models (S-shaped or hyperbolic).
在本研究中,我们使用Frumkin-Fowler-Guggenheim (FFG)和Hill-de Boer (HDB)等温线模型来描述先前发表的涉及水污染物吸附的s形等温线,特别是auramine-O和邻硝基苯酚在固体材料上的吸附。虽然这两种模型的数学公式不同,但它们有三个关键参数:单层吸附容量(qm),代表吸附质-吸附剂相互作用的平衡常数,以及代表吸附质-吸附质的相互作用的平衡常数。通过比较FFG和HDB模型的数据拟合能力,我们发现差异很小。然而,在拟合的qm值中出现了实质性的差异。FFG模型得出的qm值与auramine-O和邻硝基酚等温线中明显的高原一致,而HDB模型则没有。在分析双曲四环素等温线时,也观察到HDB模型中的这种不一致性。此外,我们还深入研究了吸附质-吸附剂和吸附质-吸附质的相互作用常数对模拟等温线的影响。研究结果表明,吸附-吸附剂相互作用常数影响模拟曲线的陡峭度,而吸附-吸附相互作用常数决定了两种模型生成的等温线曲线的性质(s型或双曲型)。
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引用次数: 0
Selected papers from the 74th Congress of Chemists 第74届化学家大会论文选集
Pub Date : 2023-09-11 DOI: 10.1007/s00706-023-03120-0
Jan Petr, Jana Skopalová, Tomáš Navrátil
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引用次数: 0
Facile synthesis of 5-aminopyrazolo-quinolones 5-氨基吡唑啉喹诺酮类药物的简易合成
Pub Date : 2023-09-01 DOI: 10.1007/s00706-023-03112-0
M. A. Elbastawesy, A. Aly, Yaseen A. M. M. El-Shaier, Alan B. Brown, G. E. Abuo-Rahma, Mohamed Samir, M. Ramadan
{"title":"Facile synthesis of 5-aminopyrazolo-quinolones","authors":"M. A. Elbastawesy, A. Aly, Yaseen A. M. M. El-Shaier, Alan B. Brown, G. E. Abuo-Rahma, Mohamed Samir, M. Ramadan","doi":"10.1007/s00706-023-03112-0","DOIUrl":"https://doi.org/10.1007/s00706-023-03112-0","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"384 1","pages":"1197-1204"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80739653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly chemo/regioselective alkoxycarbonylation of terminal allenes catalyzed by Ru/N-ligand system Ru/ n -配体体系催化末端烯基的高度化学/区域选择性烷氧羰基化
Pub Date : 2023-08-29 DOI: 10.1007/s00706-023-03117-9
Pengpeng Wang, Huibing Shi, B. Feng, Deming Zhao, Haigang Wu
{"title":"Highly chemo/regioselective alkoxycarbonylation of terminal allenes catalyzed by Ru/N-ligand system","authors":"Pengpeng Wang, Huibing Shi, B. Feng, Deming Zhao, Haigang Wu","doi":"10.1007/s00706-023-03117-9","DOIUrl":"https://doi.org/10.1007/s00706-023-03117-9","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"28 1","pages":"1189 - 1195"},"PeriodicalIF":0.0,"publicationDate":"2023-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87986153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior 新型苯丙二酸异寡配物Ni(II):合成、结构和热行为
Pub Date : 2023-08-19 DOI: 10.1007/s00706-023-03114-y
Anna K. Matiukhina, A. Chistyakov, E. Zorina-Tikhonova, N. V. Gogoleva, A. Vologzhanina, M. Kiskin, I. Eremenko
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引用次数: 0
Sensitive voltammetric detection of acetaminophen at electropolymerized bromophenol red film-coated pencil graphite 对乙酰氨基酚在电聚合溴酚红涂膜铅笔石墨上的灵敏伏安检测
Pub Date : 2023-08-16 DOI: 10.1007/s00706-023-03115-x
M. Güneş
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引用次数: 0
Electrochemical sensors: basic principles, engineering, and state of the art 电化学传感器:基本原理、工程和最新进展
Pub Date : 2023-08-11 DOI: 10.1007/s00706-023-03113-z
Heru Agung Saputra
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引用次数: 0
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