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New Innovations in Chemistry and Biochemistry Vol. 1最新文献

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Studies on the Patterns of Interferon-Gamma and Interleukin-10 Production as a Potential Immuno-biomarker for the Outcome of Mycobacterium tuberculosis Infection 干扰素- γ和白细胞介素-10的产生模式作为结核分枝杆菌感染结果的潜在免疫生物标志物的研究
Pub Date : 2021-08-20 DOI: 10.9734/bpi/nicb/v1/3328f
B. O. Akinshipe, Anthony Chukwuka Nwaobi, E. Adedeji, F. A. Ehiaghe, Herbert Obi Okpala
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引用次数: 0
Determining the Informatics and Conceptual DFT Study of Pigments Derived from Carotenoids of Marine Origin 海洋类胡萝卜素衍生色素的信息学和概念DFT研究
Pub Date : 2021-08-20 DOI: 10.9734/bpi/nicb/v1/12158d
N. Flores-Holguín, J. Frau, D. Glossman-Mitnik
The objective of this work was to assess the behavior of five density functionals, CAM-B3LYP, LC- (omega)HPBE, MN12SX, N12SX and (omega)B97XD, in connection with the Def2TZVP basis set and the SMD solvation model for the calculation of the molecular properties, chemical reactivities and solubilities of some pigments derived from the Astaxanthin, (beta)-Cryptoxanthin, Fucoxanthin, Myxol, Siphonaxanthin, Siphonein and Zeaxanthin marine carotenoids in the presence of different solvents (hexane, methanol, ethanol and water). All the chemical reactivity descriptors for the systems were calculated via Conceptual Density Functional Theory (CDFT). Finally, the potential bioavailability and druggability as well as the bioactivity scores for the marine carotenoid pigments were predicted through different methodologies already reported in the literature which have been previously validated during the study of other natural products obtained from marine sources.
本文研究了5个密度泛函CAM-B3LYP、LC- (omega) HPBE、MN12SX、N12SX和(omega) B97XD在Def2TZVP基集和SMD溶剂化模型下的行为,用于计算虾青素、(beta) -隐黄质、褐藻黄质、Myxol、Siphonaxanthin等色素的分子性质、化学反应性和溶解度。叶黄素和玉米黄质在不同溶剂(己烷、甲醇、乙醇和水)存在下的海洋类胡萝卜素。利用概念密度泛函理论(CDFT)计算了体系的化学反应性描述符。最后,通过文献中已经报道的不同方法预测了海洋类胡萝卜素色素的潜在生物利用度和药物性以及生物活性评分,这些方法在先前从海洋来源获得的其他天然产物的研究中得到了验证。
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引用次数: 0
Study on the Novel Photoluminescence Powder Synthesized from Zinc Carbonate Nanoparticles Associated with Fluorescein Dye for its Latent Fingerprint Detection 碳酸锌纳米颗粒结合荧光素染料合成新型光致发光粉体的潜在指纹检测研究
Pub Date : 2020-04-30 DOI: 10.9734/BPI/NICB/V1/11420D
K. Pattarith, R. Benchawattananon
Fingerprint verification in crime scene is a basic method, but it is very important thing to be linked to the offender. Using fluorescent powder in passive fingerprint authentication will increase the performance of fingerprint detection for an identification. In this study, the new fingerprint powder has been synthesized by solvothermal method using zinc carbonate and fluorescein dye as main precursor using ethanol as a solvent. The synthetic fluorescent powder is also inspected for trial features with various diagnostic tools. As follows, detecting a micro texture with scanning electron microscope (SEM), absorption with UV-vis diffuse reflectance spectroscopy (DRS), examining the notation characteristics with X-ray diffraction (XRD) and UV light at wavelength 254 nm and 366 nm. Testing of the synthetic fingerprint fluorescent powder is done by swiping on the surface with a latent fingerprint. For studying optimum conditions affecting the fingerprint detection, there are general following types of textures including glass, metal, plastic and ceramics, and the appearance of smooth, curve and rough surfaces. It is also studies on the effects of duration and temperature of the retention affecting the fingerprints which have been inspected by the trial. For the synthetic fluorescent powder, its inspection can be used on each surface of different types with a good surface appearance. It has a long retention period of more than 30 days at room temperature and more than 15 days at a temperature of 90oC, and it can also be used to detect the fingerprints with a clear overlap. From this study, it is demonstrated that the synthetic fluorescent powder has a very excellent performance and has high possibility to be used to detect the passive fingerprints as an object witness in forensic processes.
指纹识别是犯罪现场的一种基本方法,但与犯罪嫌疑人的联系是非常重要的。将荧光粉末应用于被动指纹认证中,可以提高指纹检测的性能。本研究以碳酸锌和荧光素染料为主要前驱体,以乙醇为溶剂,采用溶剂热法制备了新型指纹粉。还用各种诊断工具检查了合成荧光粉的试验特征。利用扫描电镜(SEM)对其微观结构进行检测,利用紫外-可见漫反射光谱(DRS)对其进行吸收,利用x射线衍射(XRD)和波长分别为254 nm和366 nm的紫外光对其符号特征进行检测。合成指纹荧光粉的测试是通过用潜在指纹在表面上滑动来完成的。为了研究影响指纹检测的最佳条件,一般有以下几种纹理类型,包括玻璃、金属、塑料和陶瓷,以及光滑、曲线和粗糙表面的外观。本文还研究了保存时间和温度对试验检测的指纹的影响。对于合成荧光粉,其检测可用于不同类型的各个表面,具有良好的表面外观。常温下保存期30天以上,90℃温度下保存期15天以上,还可用于检测重叠明显的指纹。本研究表明,合成荧光粉末具有非常优异的性能,具有很高的可能性作为物证在法医过程中用于被动指纹的检测。
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引用次数: 0
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New Innovations in Chemistry and Biochemistry Vol. 1
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