I. Turdikulov, BN Mamadiyorov, M. Saidmuhammedova, AA Atakhanov
At present, polyolefins are a heavily produced thermoplastic, and they are used in different industries. Approximately one-third of produced plastics are used in the packing industry, and this volume will only be increased in the future.
{"title":"Obtaining and studying properties of biodestructable composite films based on polyethylene","authors":"I. Turdikulov, BN Mamadiyorov, M. Saidmuhammedova, AA Atakhanov","doi":"10.17352/ojc.000021","DOIUrl":"https://doi.org/10.17352/ojc.000021","url":null,"abstract":"At present, polyolefins are a heavily produced thermoplastic, and they are used in different industries. Approximately one-third of produced plastics are used in the packing industry, and this volume will only be increased in the future.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82486838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Kablov, V. Kochetkov, OM Novopoltseva, N. Keibal
Elastomer Fire- Heatprotective Materials (FHPM) are used in the construction, working in extreme temperatures (in the missile, aviation and space technology).
弹性体防火-热防护材料(FHPM)用于建筑，在极端温度下工作(在导弹，航空和空间技术中)。
{"title":"Elastomer Thermal Protection Materials Containing Aluminosilicate Microspheres","authors":"V. Kablov, V. Kochetkov, OM Novopoltseva, N. Keibal","doi":"10.17352/ojc.000017","DOIUrl":"https://doi.org/10.17352/ojc.000017","url":null,"abstract":"Elastomer Fire- Heatprotective Materials (FHPM) are used in the construction, working in extreme temperatures (in the missile, aviation and space technology).","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77483698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this work, effects of gamma rays on melatonin as a natural radioprotective agent, have been studied. Selected samples in the form of a) powder and b) solution, were prepared and irradiated by the use of gammacell radiation system under gamma-ray of Co-60 source, at doses from 20 to 2150Gy. The content of irradiated sample vials compared with of the control samples using LC-MS. This revealed many changes, although only in solution samples. Observed changes in the structure of melatonin in aqueous solutions, could be related to the production of free hydrogen and hydroxyl radicals; since both reduction and oxidation products were detected. Any increase in gamma ray doses would cause, proportional decrease in melatonin concentrations as well as increase in reaction products’concentrations. The lack or low impact of gamma rays on solids are related to the low collision crosssection of melatonin for photons, as compared with the water molecules in aqueous solutions.
{"title":"Liquid Chromatography-Mass Spectrometry studies on molecular structure of melatonin after Co-60 gamma irradiation","authors":"Ahmad-Reza Safdari and Mehran Babri","doi":"10.17352/ojc.000015","DOIUrl":"https://doi.org/10.17352/ojc.000015","url":null,"abstract":"In this work, effects of gamma rays on melatonin as a natural radioprotective agent, have been studied. Selected samples in the form of a) powder and b) solution, were prepared and irradiated by the use of gammacell radiation system under gamma-ray of Co-60 source, at doses from 20 to 2150Gy. The content of irradiated sample vials compared with of the control samples using LC-MS. This revealed many changes, although only in solution samples. Observed changes in the structure of melatonin in aqueous solutions, could be related to the production of free hydrogen and hydroxyl radicals; since both reduction and oxidation products were detected. Any increase in gamma ray doses would cause, proportional decrease in melatonin concentrations as well as increase in reaction products’concentrations. The lack or low impact of gamma rays on solids are related to the low collision crosssection of melatonin for photons, as compared with the water molecules in aqueous solutions.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77154895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/PSRP-OJC2019.0007
A. Rehman, M. Abbasi, S. Z. Siddiqui, S. Rasool, Sadia Jabeen, Amar Joyia, A. S. Gondal
Sulfonamides are considered to be biologically active and an important class of pharmaceutical compounds. These constitute an important class of antimicrobials, antidiabetics, anticancer and diuretics. These were the first chemotherapeutic drugs introduced to the world but their rapidly developed resistance decreased their use. In the present work, N-(2/4-substitutedphenyl)-4-(substituted)benzenesulfonamide (3a-d) and N-(tetrahydrofuran-2-ylmethyl)-4-methylbenzenesulfonamide (3e) were synthesized by the reaction of substituted aniline (1a-c) and tetrahydrofuran-2-ylmethanamine (1d) with substituted benzenesulfonyl chloride (2a-d) using 10% aqueous Na2CO3 solution as a reaction medium. In the second step, the synthesized molecules 3a-e were allowed to react different alkyl/aralkyl halides (4a-j) to synthesize the target N-substituted compounds, 5a-z,aa,bb, using lithium hydride as an activator and N,N-dimethylformamide (DMF) as a reaction medium. All the synthesized compounds were characterized by using spectral techniques such as 1H-NMR, IR and EI-MS; and further examined for their anti-bacterial activities.
{"title":"Synthesis, spectral evaluation and pharmacological screening of some sulfa drugs","authors":"A. Rehman, M. Abbasi, S. Z. Siddiqui, S. Rasool, Sadia Jabeen, Amar Joyia, A. S. Gondal","doi":"10.30538/PSRP-OJC2019.0007","DOIUrl":"https://doi.org/10.30538/PSRP-OJC2019.0007","url":null,"abstract":"Sulfonamides are considered to be biologically active and an important class of pharmaceutical compounds. These constitute an important class of antimicrobials, antidiabetics, anticancer and diuretics. These were the first chemotherapeutic drugs introduced to the world but their rapidly developed resistance decreased their use. In the present work, N-(2/4-substitutedphenyl)-4-(substituted)benzenesulfonamide (3a-d) and N-(tetrahydrofuran-2-ylmethyl)-4-methylbenzenesulfonamide (3e) were synthesized by the reaction of substituted aniline (1a-c) and tetrahydrofuran-2-ylmethanamine (1d) with substituted benzenesulfonyl chloride (2a-d) using 10% aqueous Na2CO3 solution as a reaction medium. In the second step, the synthesized molecules 3a-e were allowed to react different alkyl/aralkyl halides (4a-j) to synthesize the target N-substituted compounds, 5a-z,aa,bb, using lithium hydride as an activator and N,N-dimethylformamide (DMF) as a reaction medium. All the synthesized compounds were characterized by using spectral techniques such as 1H-NMR, IR and EI-MS; and further examined for their anti-bacterial activities.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86844273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/PSRP-OJC2019.0010
M. Abbasi, Seong-Hui Eo, A. Rehman, S. Z. Siddiqui, Yohan Han, Seon-Mi Yu, Song-Ja Kim, Mubashir Hassan, H. Raza, S. A. Shah, S. Seo, Bandar Puncak Alam Selangor Darul Ehsan Malaysia. Puncak Alam Campus
Matrix metalloproteinases-2 and -9 (MMP-2/-9) are key tissue remodeling enzymes that have multiple overlapping activities critical for wound healing and tumor progression. In search of new anti-tumor agents, indole-oxadiazole containing butanamides (1-5) were evaluated with B16F10 mouse melanoma cells in this study. The results showed that compounds 1, 2 and 3 inhibited the cell proliferation in a considerable manner at concentrations ranging from 0-44 ?M. The possible migration inhibitory effects of these melanoma cells were further evaluated through gelatinolytic activity of MMP-2 and MMP-9 secreted from B16F10 cells and it was inferred that compounds 1, 2 and 3 affected the expression and activity of these enzymes in a dose dependent manner while compound 1 can be regarded as promising anti-tumor agent.
{"title":"Anti-proliferative and migratory inhibition study of b16f10 in mouse melanoma cells induced by synthetic indole-oxadiazole bearing butanamides","authors":"M. Abbasi, Seong-Hui Eo, A. Rehman, S. Z. Siddiqui, Yohan Han, Seon-Mi Yu, Song-Ja Kim, Mubashir Hassan, H. Raza, S. A. Shah, S. Seo, Bandar Puncak Alam Selangor Darul Ehsan Malaysia. Puncak Alam Campus","doi":"10.30538/PSRP-OJC2019.0010","DOIUrl":"https://doi.org/10.30538/PSRP-OJC2019.0010","url":null,"abstract":"Matrix metalloproteinases-2 and -9 (MMP-2/-9) are key tissue remodeling enzymes that have multiple overlapping activities critical for wound healing and tumor progression. In search of new anti-tumor agents, indole-oxadiazole containing butanamides (1-5) were evaluated with B16F10 mouse melanoma cells in this study. The results showed that compounds 1, 2 and 3 inhibited the cell proliferation in a considerable manner at concentrations ranging from 0-44 ?M. The possible migration inhibitory effects of these melanoma cells were further evaluated through gelatinolytic activity of MMP-2 and MMP-9 secreted from B16F10 cells and it was inferred that compounds 1, 2 and 3 affected the expression and activity of these enzymes in a dose dependent manner while compound 1 can be regarded as promising anti-tumor agent.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89067842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/psrp-ojc2019.0013
Masood Khan, Z. Sarfraz, H. Rehman
We explore the possibility of using an iron-based anodic material (α-hematite) synthesized with a hierarchical 3D urchin-like morphology, as an OER catalyst. The electrodes are prepared by pulsed laser deposition followed by thermal annealing leading to the hierarchical 3D urchin-like morphology. The effect of the deposition parameter on the catalyst phase and morphology are investigated by microRaman spectroscopy and scanning electron microscopy, while the electrode metrics are determined by voltammetric methods and Tafel analysis. We observe that the material is highly electroactive towards the OER, with performance in-line with that of noble-metal based state-of-the-art catalysts.
{"title":"Investigation of nanostructured iron oxides as anodic material for water splitting","authors":"Masood Khan, Z. Sarfraz, H. Rehman","doi":"10.30538/psrp-ojc2019.0013","DOIUrl":"https://doi.org/10.30538/psrp-ojc2019.0013","url":null,"abstract":"We explore the possibility of using an iron-based anodic material (α-hematite) synthesized with a hierarchical 3D urchin-like morphology, as an OER catalyst. The electrodes are prepared by pulsed laser deposition followed by thermal annealing leading to the hierarchical 3D urchin-like morphology. The effect of the deposition parameter on the catalyst phase and morphology are investigated by microRaman spectroscopy and scanning electron microscopy, while the electrode metrics are determined by voltammetric methods and Tafel analysis. We observe that the material is highly electroactive towards the OER, with performance in-line with that of noble-metal based state-of-the-art catalysts.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"27 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83309831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/PSRP-OJC2019.0009
A. Shamim, Zaheer Ahmad, S. Mahmood, Umair Ali, T. Mahmood, Zamir Ahmad Nizami
The under consideration study focuses on synthesis and characterization of Nickel oxide (NiO) nanoparticles. Nanosized Nickel oxide powder was successfully synthesized using a simple and low cast sol-gel method. This method is environment friendly requiring no expensive chemicals and is time saving. The sol-gel method was accompanied by the formation of precipitates which were dried and calcined at 550oC to get nickel oxide nanoparticles. The synthesized nanopowder was characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDX).
{"title":"Synthesis of nickel nanoparticles by sol-gel method and their characterization","authors":"A. Shamim, Zaheer Ahmad, S. Mahmood, Umair Ali, T. Mahmood, Zamir Ahmad Nizami","doi":"10.30538/PSRP-OJC2019.0009","DOIUrl":"https://doi.org/10.30538/PSRP-OJC2019.0009","url":null,"abstract":"The under consideration study focuses on synthesis and characterization of Nickel oxide (NiO) nanoparticles. Nanosized Nickel oxide powder was successfully synthesized using a simple and low cast sol-gel method. This method is environment friendly requiring no expensive chemicals and is time saving. The sol-gel method was accompanied by the formation of precipitates which were dried and calcined at 550oC to get nickel oxide nanoparticles. The synthesized nanopowder was characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDX).","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83508305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/psrp-ojc2019.0011
S. Aluvihara, J. Premachandra
Abstract: Metals play predominant prefaces regarding most of industrial components such as the crude oil refining industry although corrosion performed some banes. In the current research it was expected to investigate to compare the effect of corrosive properties of two different crude oils on the rates of corrosion in seven different types of ferrous metals. The contents of sulfur, mercaptans, organic acids, salt in both crude oils and chemical compositions of ferrous metals were determined by standard methods and instruments. A batch of similar sized metal coupons was prepared and immersed in both crude oils separately. The corrosion rate of each metal coupon was determined by the weight loss method in order to after 15, 30 and 45 days while observing the corroded metal surfaces by the optical microscope. The decayed concentrations of copper and ferrous in each crude oil sample were tested and the both initial and final hardness of each metal coupon were tested. According to the results there were observed lower corrosion rates from stainless steels, relatively higher impact from salts on the corrosion, formation corrosion compounds, corrosion cracks, pitting corrosion on metal surfaces and there were observed a slight reduction of hardness in each metal coupon eventually.
{"title":"The primary corrosiveness of crude oils and destructions of metals","authors":"S. Aluvihara, J. Premachandra","doi":"10.30538/psrp-ojc2019.0011","DOIUrl":"https://doi.org/10.30538/psrp-ojc2019.0011","url":null,"abstract":"Abstract: Metals play predominant prefaces regarding most of industrial components such as the crude oil refining industry although corrosion performed some banes. In the current research it was expected to investigate to compare the effect of corrosive properties of two different crude oils on the rates of corrosion in seven different types of ferrous metals. The contents of sulfur, mercaptans, organic acids, salt in both crude oils and chemical compositions of ferrous metals were determined by standard methods and instruments. A batch of similar sized metal coupons was prepared and immersed in both crude oils separately. The corrosion rate of each metal coupon was determined by the weight loss method in order to after 15, 30 and 45 days while observing the corroded metal surfaces by the optical microscope. The decayed concentrations of copper and ferrous in each crude oil sample were tested and the both initial and final hardness of each metal coupon were tested. According to the results there were observed lower corrosion rates from stainless steels, relatively higher impact from salts on the corrosion, formation corrosion compounds, corrosion cracks, pitting corrosion on metal surfaces and there were observed a slight reduction of hardness in each metal coupon eventually.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"172 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79510916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/psrp-ojc2019.0012
Francesco Sinopoli, A. Sinopoli
Nuclear Magnetic Resonance spectroscopy, commonly referred as NMR spectroscopy, is a widely used technique for determining the structure of organic compounds and metallorganic complexes. The NMR characterization process can be done automatically by specific tools integrated into the main NMR dedicated software, however it is commonly subjected to user’s interpretation therefore it still remains a manual process. In relationship with the number of signals to interpret and the complexity of the spectrum, the user usually spends between ten minutes and one hour to manually generate an NMR report, which can be clearly affected by typos or format mismatches. Here we report an Excel sheet-based NMR data reporting tool which, thanks to ad hoc macros, generates as output a formatted NMR report, ready to be directly pasted into any manuscript. ASpin tool leaves to the users the full possibility to interpret the spectrum in this way they can gain more experience in the interpretation process, without giving up the time saving.
{"title":"ASpin-NMR data reporting tool","authors":"Francesco Sinopoli, A. Sinopoli","doi":"10.30538/psrp-ojc2019.0012","DOIUrl":"https://doi.org/10.30538/psrp-ojc2019.0012","url":null,"abstract":"Nuclear Magnetic Resonance spectroscopy, commonly referred as NMR spectroscopy, is a widely used technique for determining the structure of organic compounds and metallorganic complexes. The NMR characterization process can be done automatically by specific tools integrated into the main NMR dedicated software, however it is commonly subjected to user’s interpretation therefore it still remains a manual process. In relationship with the number of signals to interpret and the complexity of the spectrum, the user usually spends between ten minutes and one hour to manually generate an NMR report, which can be clearly affected by typos or format mismatches. Here we report an Excel sheet-based NMR data reporting tool which, thanks to ad hoc macros, generates as output a formatted NMR report, ready to be directly pasted into any manuscript. ASpin tool leaves to the users the full possibility to interpret the spectrum in this way they can gain more experience in the interpretation process, without giving up the time saving.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72716592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-31DOI: 10.30538/PSRP-OJC2019.0008
F. Khan, S. Mahmood, Zaheer Ahmad, T. Mahmood, Zamir Ahmad Nizami
The graphene and graphene oxide are latest and advanced materials with wide applications in environment, medical applications, industries, defense applications. We have synthesized graphene oxide from graphite flakes by modifying Hummer method in which we used NaNO2 instead of NaNO3. Then we characterized our samples with X-Ray Diffractometry (XRD), Scanning-Electron Microscopy (SEM) and Fourier-Transform Infrared-Spectroscopy (FT-IR). These results confirmed the formation of graphene oxide also through this process. This graphene oxide can further be used for future applications in wastewater treatment and biomedical applications.
{"title":"Graphene oxide synthesis by facile method and its characterization","authors":"F. Khan, S. Mahmood, Zaheer Ahmad, T. Mahmood, Zamir Ahmad Nizami","doi":"10.30538/PSRP-OJC2019.0008","DOIUrl":"https://doi.org/10.30538/PSRP-OJC2019.0008","url":null,"abstract":"The graphene and graphene oxide are latest and advanced materials with wide applications in environment, medical applications, industries, defense applications. We have synthesized graphene oxide from graphite flakes by modifying Hummer method in which we used NaNO2 instead of NaNO3. Then we characterized our samples with X-Ray Diffractometry (XRD), Scanning-Electron Microscopy (SEM) and Fourier-Transform Infrared-Spectroscopy (FT-IR). These results confirmed the formation of graphene oxide also through this process. This graphene oxide can further be used for future applications in wastewater treatment and biomedical applications.","PeriodicalId":19563,"journal":{"name":"Open journal of physical chemistry","volume":"16 5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85470987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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