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Experimental investigation of the impact of soybean oil-derived surfactant as a surface-active agent during gas well deliquification 气井脱胶过程中大豆油衍生表面活性剂作为表面活性剂的影响实验研究
Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.1016/j.ptlrs.2024.03.007
Gbadegesin Abioun Adeyemi, Kegang Ling, Adesina Fadairo
The inability of the gas rate to overcome the gas critical (minimum) flow rate leads to liquid loading in a gas well. To avoid premature well shut-in, the injection of surfactants is one of the standard methods used in gas well deliquification, although many commercial surfactants pose environmental toxicity concerns. This project investigates the suitability of biosurfactants in generating foam that will reduce the surface tension of the liquid by adsorbing at the liquid-gas interface to create a more significant mass than the liquid droplets which can be easily extracted from the walls of the wellbore. An experimental setup simulating gas well conditions introduce a surfactant derived from soybean oil, subjecting it to tests for foam stability, unloading efficiency, and dynamic surface tension. The results from the modified ASTM D-892 test show that Soybean Oil Derived Surfactant (SODS) exhibits promising surface tension reduction properties and effectively alters the gas-liquid interface. With the increase in concentration from 200 ppm, 400 ppm, and 600 ppm, the expelled water increased from 17%, 28%, and 70% respectively. Similarly, Gao-Rosen adsorption isotherms confirmed SODS appropriate for the prediction of the adsorption from solution with the R2 values of approximately 1.0. This study introduces a cost-effective and environmentally friendly surfactant that performs favorably for gas well deliquification.
气体流速无法超过气体临界(最小)流速会导致气井中出现液体负载。为避免气井过早关闭,注入表面活性剂是气井脱液的标准方法之一,但许多商用表面活性剂会对环境产生毒性。本项目研究了生物表面活性剂在产生泡沫方面的适用性,这种泡沫可通过吸附在液体-气体界面来降低液体的表面张力,从而产生比液滴更大的质量,而液滴可以很容易地从井筒壁上提取出来。模拟气井条件的实验装置引入了一种从大豆油中提取的表面活性剂,对其进行了泡沫稳定性、卸载效率和动态表面张力测试。修改后的 ASTM D-892 试验结果表明,大豆油衍生表面活性剂(SODS)具有良好的降低表面张力特性,能有效改变气液界面。随着浓度从 200 ppm、400 ppm 到 600 ppm 的增加,排出的水分分别增加了 17%、28% 和 70%。同样,高-罗森吸附等温线证实 SODS 适合预测溶液中的吸附量,R2 值约为 1.0。这项研究介绍了一种成本效益高且环保的表面活性剂,它在气井脱胶方面表现出色。
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引用次数: 0
Reservoir identification of marine facies carbonate shoals in the Middle Permian in the Sichuan Basin 四川盆地中二叠统海相碳酸盐滩涂储层识别
Q1 Earth and Planetary Sciences Pub Date : 2024-03-27 DOI: 10.1016/j.ptlrs.2024.03.009
Yunbo Zhang , Yan Feng , Miao Miao , Xingying Yu , Xufeng Liu , Mingjian Wang , Li Sun
Controlled by the base level change cycle, the carbonates exposed from the periodically shallowed water body at the top of the high-frequency sequence develops multiple sets of thin reservoirs. Such reservoir identification has always been tricky in the prediction of carbonate reservoirs. Based on the Middle Permian strata from the Sichuan Basin, this paper established a forecasting approach of high-frequency-sequence-controlled carbonate thin reservoir. The steps are as follows: (1) Combine the measured results of samples from the typical outcrops with changes of carbon and oxygen isotopes, thus to construct a division program for the 3rd-order sequence of the Middle Permian strata. (2) Compare the carbon and oxygen isotope changes and the global sea level change trend, determine the controlling factors of the 3rd-order sequences. (3) Carry out spectrum analysis based on the natural gamma energy spectrum logging (ln (Th/K)) curves of Wells Long-17 and Anping-1 to establish a high-frequency sequence framework division program, and then apply the logging curve characteristics to correct the top interface positions of the high-frequency sequences, which is the potential location of carbonate reservoir. The research results suggest that the Middle Permian in the Sichuan Basin can be divided into three 3rd-order sequences, which are PSQ1, PSQ2 and PSQ3 from bottom to top. Among which, PSQ1 is mainly affected by global sea level (GSL) changes, and the changes originated from its tuning curve can be directly applied to the division of high-frequency sequences and reservoir prediction. PSQ2 and PSQ3 are jointly controlled by global sea level changes and regional tectonics. In cope with the influence of regional tectonics, the positions of the four-level sequence interface established according to the tuning curve need to be fully considered, and good results were achieved through systematical correction. This method can effectively reduce the risk of reservoir prediction caused by marine carbonate heterogeneity, and provide scientific foundation for the prediction of high-frequency cyclic reservoirs of platform facies and platform margin subfacies in other marine carbonate sedimentary basins.
在基底变化周期的控制下,高频序列顶部周期性浅水水体出露的碳酸盐岩发育多套薄储层。这种储层识别一直是碳酸盐岩储层预测中的棘手问题。本文以四川盆地中二叠统地层为基础,建立了高频序列控制的碳酸盐岩薄储层预测方法。具体步骤如下(1)将典型露头样品的实测结果与碳、氧同位素变化相结合,构建中二叠统地层三阶序列的划分方案。(2)将碳氧同位素变化与全球海平面变化趋势进行对比,确定三阶序列的控制因素。(3)根据龙-17井和安平-1井天然伽马能谱测井(ln(Th/K))曲线进行能谱分析,建立高频层序框架划分方案,并应用测井曲线特征校正高频层序顶界面位置,即碳酸盐岩储层的潜在位置。研究结果表明,四川盆地中二叠统可划分为三个三阶序列,自下而上依次为 PSQ1、PSQ2 和 PSQ3。其中,PSQ1 主要受全球海平面(GSL)变化的影响,其调谐曲线的变化可直接用于高频序列的划分和储层预测。PSQ2 和 PSQ3 受全球海平面变化和区域构造的共同控制。在应对区域构造的影响时,需要充分考虑根据调谐曲线建立的四级序列界面的位置,并通过系统校正取得了良好的效果。该方法可有效降低海相碳酸盐岩异质性带来的储层预测风险,为其他海相碳酸盐岩沉积盆地平台面和平台边缘亚面高频周期储层预测提供科学依据。
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引用次数: 0
Optimization of gas lift system for well performance improvement in Asmari formation: A techno-economic perspective 优化气举系统,提高阿斯马拉地层的油井性能:技术经济视角
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.08.003
Hari Sreenivasan, Jash Patel, Dev Jain, Setu Patel, Isaac Wilson, Shanker Krishna

Well productivity in the Asmari carbonate formation of southwest Iran has decreased in recent years as a result of production issues. The production rate must be maintained below 1500 STB/day to prevent water coning. In this study, a gas lift well is modeled using data from one of the producing wells of this field. Nodal analysis is performed using lift-gas injection rates and wellhead pressures at different reservoir pressures and water cut conditions to optimize production. Economic aspects are considered to optimize the artificial gas injection rates at different tubing head pressures and water cut conditions. Increasing the lift-gas injection rate from 0.4 MMscf/day to 1 MMscf/day enhances the oil production rate by 37.71% and 43.89% for 10% and 30% water cut conditions, respectively. Gas injection rates of 5.2 MMscf/day and 5.4 MMscf/day are determined to be economically optimal for 30% water cut with tubing head pressures of 260 psig and 270 psig, respectively.

由于生产问题,伊朗西南部阿斯马拉碳酸盐岩层的油井生产率近年来有所下降。生产率必须保持在 1500 STB/天以下,以防止出现水锥。本研究利用该油田一口生产井的数据,对气举井进行建模。利用不同储层压力和断水条件下的气举注入率和井口压力进行节点分析,以优化生产。考虑了经济因素,以优化不同油管头压力和断水条件下的人工注气率。将举升注气率从 0.4 MMscf/day 提高到 1 MMscf/day,在 10% 和 30% 的断水条件下,石油生产率分别提高了 37.71% 和 43.89%。在油管头压力分别为 260 psig 和 270 psig 的情况下,确定 5.2 MMscf/day 和 5.4 MMscf/day 的注气量为 30% 断水时的最佳经济注气量。
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引用次数: 0
A contrasting analysis of CO2 and N2 foam flood for enhanced oil recovery and geological storage of CO2 CO2与N2泡沫驱提高采收率及CO2地质封存效果对比分析
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.07.003
Alireza Roozbahani , Farshad Soofivand , Ali Sagban Hassoon Al-Tameemi , Hadi Abdollahi , Sogand Saatchi , Abdolhamid Ansari

Foam flooding using CO2 has emerged as a promising method for both enhanced oil recovery (EOR) and the storage of CO2 in geological reservoirs. This study conducts a thorough analysis of the behavior of CO2 and N2 foams in bulk and porous media, utilizing bubble-scale analyses and foam flooding experiments. The study compares the foamability and longevity of CO2 and N2 foams, with findings indicating that N2 foam bubbles tend to be smaller and less varied in size than CO2 foam bubbles, leading to increased foam stability. Additionally, the study compares the half-lives of CO2 and N2 foams generated through sparging and winding methods, showing that N2 foam has half-lives 22 and 10 times greater than CO2 foam when produced using the sparging and winding methods, respectively. Furthermore, CO2 foam generated through the sparging method had a lower foaming volume than N2 foam due to CO2's solubility. In the foam flooding experiments, N2 foam proved more effective in recovering oil from porous media than CO2 foam, thus demonstrating the effectiveness of the foam injection procedure. These results offer valuable insights into the differing performance of N2 and CO2 foam floods for EOR and CO2 geological storage.

使用二氧化碳进行泡沫淹没已成为提高石油采收率(EOR)和在地质储层中封存二氧化碳的一种可行方法。本研究利用气泡尺度分析和泡沫淹没实验,对二氧化碳和 N2 泡沫在块状和多孔介质中的行为进行了全面分析。研究比较了二氧化碳和 N2 泡沫的可发泡性和寿命,结果表明,N2 泡沫的气泡往往比二氧化碳泡沫的气泡更小、尺寸变化更少,从而提高了泡沫的稳定性。此外,该研究还比较了通过喷射和缠绕方法产生的二氧化碳和二氧化氮泡沫的半衰期,结果表明,使用喷射和缠绕方法产生的二氧化氮泡沫的半衰期分别是二氧化碳泡沫的 22 倍和 10 倍。此外,由于二氧化碳的溶解性,通过喷射法产生的二氧化碳泡沫的发泡量低于 N2 泡沫。在泡沫淹没实验中,事实证明 N2 泡沫比 CO2 泡沫更能有效地从多孔介质中回收石油,从而证明了泡沫注入程序的有效性。这些结果为了解 N2 和 CO2 泡沫在 EOR 和 CO2 地质封存方面的不同性能提供了宝贵的见解。
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引用次数: 0
Diverting agents in the oil and gas industry: A comprehensive analysis of their origins, types, and applications 石油和天然气工业中的分流剂:对其起源、类型和应用的全面分析
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.09.004
Namrata Bist , Abhishek Nair , Kriti Yadav , Anirbid Sircar

During the life of a well, treatments are carried out to boost productivity by stimulating initially unproduced zones. These treatments include hydraulic fracturing, matrix acidization, and acid fracturing, among others. Hydraulic fracturing treatment is generally applied to deeper reservoirs of oil or natural gas for enhanced recovery. By infusing proppant, water, and chemicals under extreme pressure during the fracturing procedure, fissures in and beneath the reservoir layer can be accessed and expanded. Another stimulating procedure, matrix acidization, involves injecting acid down the drilling hole to permeate the rock fissures at stresses lower than the fracture stress. In addition, carbonate reservoir acid fracturing stimulation is commonly used as an acid treatment technique whereby a pressure greater than the formation disintegration pressure or spontaneous fracture closure pressure is used to compress acid into the reservoir. These treatments allow existing wells to sustain hydrocarbon production without new wells being drilled. Diverters, when employed efficiently, can prevent the need to use a rig to provide momentary physical barriers, thus lowering the cost of the workover. Recent improvements in diversion technology make use of a variety of degradable particles that act as momentary bridges, either at the perforation entries or inside the existing fractures. The aim of this study is to introduce different types of mechanical and chemical diverters used to enhance the productivity of wells. This study explains the concepts of different types of diverters and their applications in several formations, it will also help readers to understand the selection procedures based on the suitability and requirements of diverter use by case studies from around the world.

在油井寿命期间,通过刺激最初未开采的区域来提高生产率。这些处理方法包括水力压裂、基质酸化和酸性压裂等。水力压裂处理一般用于较深的石油或天然气储层,以提高采收率。在压裂过程中,通过在极高压力下注入支撑剂、水和化学品,可以进入并扩大储层中和储层下的裂缝。另一种刺激程序是基质酸化,即在钻孔中注入酸液,以低于裂缝应力的应力渗透岩石裂缝。此外,碳酸盐岩储层酸化致裂通常被用作一种酸处理技术,利用大于地层解体压力或自发裂缝闭合压力的压力将酸压缩到储层中。这些处理方法可使现有油井在不钻新井的情况下维持碳氢化合物的生产。有效使用分流器可以避免使用钻机提供瞬间物理屏障,从而降低修井成本。分流技术的最新改进利用了各种可降解颗粒,它们可以在射孔入口处或现有裂缝内起到瞬间桥梁的作用。本研究旨在介绍用于提高油井生产率的各种机械和化学分流器。本研究解释了不同类型分流器的概念及其在多种地层中的应用,还将通过世界各地的案例研究,帮助读者了解根据分流器的适用性和使用要求进行选择的程序。
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引用次数: 0
Voids size distribution in gelled waxy crude oil under dynamic and static cooling 动、静态冷却条件下胶凝含蜡原油孔隙尺寸分布
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.08.001
Girma T. Chala , Shaharin A. Sulaiman

Waxy crude oil is known for its high wax contents that can potentially result in gelling following sufficient cooling of the transportation line in the subsea bed at offshore fields. The gelling over the entire lines requires an accurately predicted restart pressure to restart the clogged and idle system. However, the common way of predicting the restart pressure has been reported to result in over-designed and predicted piping parameters. Recent research findings evidenced the formation of voids which would reduce the restart pressure significantly. The study conducted in this paper is aimed at investigating the voids size distribution in gelled crude oil across and along transportation pipelines. Sets of experiments simulating crude oil transportation during both static and dynamic cooling were conducted. The gelled crude oil below the pour point temperature was then scanned using a Magnetic Resonance Imaging (MRI) system to detect the voids formed. The resulting voids at each scanning cross-section were quantified, and their distributions were investigated. It was observed that dynamic cooling had minimal impacts on the voids size difference along the pipeline with the difference in voids areas within 10 mm2 to be twice and uniform for the entire flow rates tested. However, voids size in statically cooled waxy crude oil was found to be highly distributed with a maximum of 6 voids size distribution in 10 mm2 ranges. The low-end temperature had the highest size difference while the difference was decreasing with higher end temperatures. This study shows that the voids amount in dynamically cooled waxy crude oil could also be estimated with lower numbers of cross-sectional voids areas. However, the higher cross-sectional voids detection is recommended while estimating voids in statically cooled waxy crude oil.

众所周知,含蜡原油的含蜡量很高,在近海油田的海底油层中,当运输管道充分冷却后,可能会出现胶凝现象。整个管线的胶化需要一个准确预测的重启压力,以重启堵塞和闲置的系统。然而,据报道,预测重启压力的常见方法会导致过度设计和预测管道参数。最近的研究结果表明,空隙的形成会大大降低重新启动压力。本文的研究旨在调查胶凝原油在运输管道上和管道沿线的空隙大小分布。实验模拟了原油在静态和动态冷却过程中的运输情况。然后使用磁共振成像(MRI)系统对低于倾点温度的胶凝原油进行扫描,以检测形成的空隙。对每个扫描截面上形成的空隙进行量化,并研究其分布情况。结果表明,动态冷却对管道沿线空隙大小差异的影响极小,在整个测试流速范围内,10 平方毫米以内的空隙面积差异为两倍且均匀。然而,静态冷却的含蜡原油中的空隙大小分布很广,在 10 平方毫米范围内最多有 6 个空隙大小分布。低端温度下的尺寸差异最大,而随着温度的升高,差异逐渐减小。这项研究表明,动态冷却含蜡原油中的空隙量也可以用较少的横截面空隙面积来估算。不过,在估算静态冷却含蜡原油的空隙时,建议采用较高的横截面空隙检测。
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引用次数: 0
Employment of mud-pulse generator for improvement of efficiency of a wellbore producing in complex mining and geological conditions 利用泥浆脉冲发生器提高复杂开采地质条件下井筒生产效率
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.07.004
Bibinur Akhymbayeva

In this study, the employment of mud-pulse generators to improve the efficiency of wellbores under complex mining and geological conditions is examined. A systemic analysis is made of the primary theoretical basis of the study. The benefits of a mud-pulse generator (a high-impulse hydraulic hammer) for wellbore production are stated based on the presented theoretical basis. The results not only show the benefits of mud-pulse generator employment but also provide an analysis of methods that can be used to improve the high-impulse hydraulic hammer efficiency. The acquired results have a substantial practical value not only for specialists, who research, develop, and manage wellbore operations, but also for engineers, who improve the process and modernize existing wellbores, and other experts in the field of wellbore production.

本研究探讨了在复杂的采矿和地质条件下使用泥浆脉冲发生器提高井筒效率的问题。对研究的主要理论基础进行了系统分析。在此理论基础上,阐述了泥浆脉冲发生器(高脉冲液压锤)对井筒生产的益处。研究结果不仅显示了使用泥浆脉冲发生器的好处,还分析了可用于提高高脉冲液压锤效率的方法。这些成果不仅对研究、开发和管理井筒作业的专家具有重要的实用价值,而且对改进现有井筒工艺和使其现代化的工程师以及井筒生产领域的其他专家也具有重要的实用价值。
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引用次数: 0
Characteristics and genesis of tuffaceous shale oil lithofacies:A case study of Lucaogou Formation in Santanghu Basin 凝灰岩页岩油岩层的特征与成因:三塘湖盆地芦草沟地层个案研究
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.11.003
Dongsheng Xiao, Xiong fei Xu, Jilun Kang, Yiting Zhang

Lucaogou Formation in the Santanghu Basin is a special lacustrine fine-grained sedimentary deposits rich in volcanic debris and carbonate, with abundant shale oil resources. However, understanding of shale oil characteristics and genesis remains unclear. Lithofacies, sedimentary environment, and formation mechanisms of tuffaceous shale oil are investigated based on core and thin section observations, X-ray diffraction, field emission SEM and geochemical analysis. Results show that three mixed lithofacies types are developed in Lucaogou Formation: blocky tuff, laminated tuffaceous dolomite, and laminated dolomitic tuff. These lithofacies types are characterized by high content of felsic and dolostone, widespread organic matter, and low clay content. Formation of tuffaceous shale oil sweet spots is primarily influenced by four factors: inputting of volcanic ash as a high-quality source rocks and reservoirs provides good material basis; devitrification of volcanic glass, calcitization, and dissolution are crucial for formation of reservoirs; expulsion of source rocks with high-abundance organic matter expulsion facilitates migration and accumulation of hydrocarbon in adjacent reservoirs; fracture development improves reservoir permeability to form highly productive sweet spots. By analyzing characteristics and genesis of tuffaceous shale oil, the main controlling factors of reservoir physical property and oil saturation are clarified, which is of great significance for selection of shale oil exploration zones.

三塘湖盆地芦草沟地层是一种特殊的湖相细粒沉积矿床,富含火山碎屑和碳酸盐岩,页岩油资源丰富。然而,对页岩油特征和成因的认识仍不清楚。基于岩芯和薄片观察、X 射线衍射、场发射扫描电镜和地球化学分析,对凝灰岩页岩油的岩相、沉积环境和形成机制进行了研究。结果表明,卢卡沟地层发育有三种混合岩性类型:块状凝灰岩、层状凝灰质白云岩和层状白云质凝灰岩。这些岩性类型的特点是长石和白云石含量高、有机质广泛存在、粘土含量低。凝灰岩页岩石油甜点的形成主要受四个因素的影响:作为优质源岩和储层的火山灰的输入提供了良好的物质基础;火山玻璃的脱卤、钙化和溶解是储层形成的关键;高含量有机质驱逐源岩有利于油气在邻近储层的迁移和积累;裂缝发育提高了储层的渗透性,从而形成高产甜点。通过分析凝灰岩页岩油的特征和成因,阐明了储层物性和含油饱和度的主要控制因素,对页岩油勘探区的选择具有重要意义。
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引用次数: 0
n-Alkane bound biomarker fingerprints from asphaltenes in the bitumens of Eastern Dahomey Basin, Nigeria: Source and genetic implications 尼日利亚达荷美盆地东部沥青质中正烷烃结合生物标志物指纹:来源和遗传学意义
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.07.005
Modupe A. Egbeola , Olubunmi C. Adeigbe , Olajide J. Adamolekun

The asphaltene fractions of the bitumens of Eastern Dahomey Basin in Nigeria, were analyzed by flash pyrolysis-gas chromatography (Py-GC) method in order to unravel its geochemical history and properties. The distributions of the initial biomarkers of the original oils from the pyrolysates are related to the assessment of organic matter source, paleo-redox conditions and source environment during deposition. Also, it effectively establishes the genetic relationship of the bitumens. The n-alkane distributions in the pyrolysates reveal nC9-nC32 n-alkanes, maximizing at nC14, isoprenoids-pristane (Pr) and phytane (Ph), and some n-alkene peaks. High peaks of low to medium-weight nC9-nC20 n-alkanes and low peaks of nC21+ n-alkanes characterize the distributions. These reveal that abundant algal organic matter with some terrigenous inputs contributed to the source rock of the bitumens. The high concentration of marine organic matter inputs to the source rock is further confirmed by the nC17/nC27 ratios which range from 5.39 to 19.82 and shows the predominance of nC17 alkanes. The general unimodal n-alkane distributions in the bitumens indicate derivation from similar organic matter types showing that they are genetically related. The anoxic to suboxic environmental conditions that prevailed during the deposition of the sediments is revealed by the isoprenoids, Pr/Ph ratios (0.72–1.28). Pristane/nC17 and Phytane/nC18 range from 0.16 to 0.33 and 0.22 to 0.56, revealing that the bitumens were from predominantly marine organic matter (type II kerogen) preserved in a reducing environment with no evidence of biodegradation. However, the Ph/nC18 ratio and the cross plot of Pr+Ph/nC17+nC18 allow the classification of the bitumens into two subfamilies/groups (A and B). The bitumen samples have low wax content as indicated by the degree of waxiness ranging from 0.21 to 0.38 which confirms low terrigenous input. Based on the carbon preference index (CPI: 0.92 to 1.55) and odd-even predominance (OEP: 0.70 to 1.36), it is concluded that the bitumens are immature to marginally mature.

采用闪速热解-气相色谱法(Py-GC)分析了尼日利亚东达荷美盆地沥青质馏分,以揭示其地球化学历史和特性。热解产物中原始油类的初始生物标志物的分布与有机物质来源、古氧化还原条件和沉积过程中的来源环境评估有关。此外,它还有效地确定了沥青质的遗传关系。热解产物中的正构烷烃分布显示出 nC9-nC32 正构烷烃(在 nC14 处达到最大)、异戊烷--四烷(Pr)和植烷(Ph)以及一些正构烯烃峰。中低含量的 nC9-nC20 正构烷烃的峰值较高,而 nC21+ 正构烷烃的峰值较低,这些都是正构烷烃分布的特点。这表明,沥青源岩中含有丰富的藻类有机物和一些陆生有机物。nC17/nC27 比率从 5.39 到 19.82 不等,表明 nC17 烷烃占主导地位,这进一步证实了源岩中海洋有机物的高浓度输入。沥青中 nC17/nC27 的比例范围为 5.39 到 19.82,表明 nC17 烷烃占主导地位。沥青中 nC17 烷烃的分布总体上呈单峰状,表明它们来自相似的有机物类型,显示出它们在遗传上是相关的。沉积物中的异丙烯酸、Pr/Ph 比值(0.72-1.28)显示了沉积物沉积期间的缺氧至亚缺氧环境条件。Pristane/nC17 和 Phytane/nC18 分别为 0.16 至 0.33 和 0.22 至 0.56,表明沥青主要来自保存在还原环境中的海洋有机物(第二类角质),没有生物降解的迹象。然而,根据 Ph/nC18 比率和 Pr+Ph/nC17+nC18 的交叉图,可以将沥青分为两个亚家族/组(A 和 B)。沥青样品的含蜡量较低,蜡度范围在 0.21 至 0.38 之间,这证实了土著输入量较低。根据碳偏好指数(CPI:0.92 至 1.55)和奇偶偏好度(OEP:0.70 至 1.36),可以得出结论,这些沥青为未成熟至微熟沥青。
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引用次数: 0
Effects of synthesis parameters on the performance of crosslinked Co-polymers with clays for conformance control 合成参数对粘土交联共聚物一致性控制性能的影响
Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.1016/j.ptlrs.2023.07.006
A.A. Roslan , N.A.A. Aziz , N.F.A. Deraman , I. Dzulkarnain

Conformance control or water shut-off is a technique used to improve oil recovery. During conformance control, polymers block high permeability water areas and redistribute water drive toward unswept oil zones. In this study, co-polymers (denoted ATP-PGV/AM-co-AMPS) were synthesized using acrylamide (AM) and 2-acrylamide-2-methylpropane sulfonic acid (AMPS) as the monomers, polyethylene glycol (PEG)-200 and methylenebisacrylamide (MBA) as the crosslinkers, attapulgite (ATP) and bentonite (PGV) as the clay types, and ammonium persulfate (APS) as the initiator, in addition to paraffin oil and surfactants. Samples were synthesized using inverse emulsion polymerization with different concentrations of monomers, crosslinkers, and clays, and they were characterized using Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). FTIR spectra of the samples confirmed the existence of sulfonate and hydroxyl groups, which are important for polymer swelling. SEM-EDX images indicated that the morphology and elemental composition were different before and after swelling, confirming the occurrence of swelling. Moreover, samples were placed in sodium chloride solution (20,000 ppm) for 7 days to evaluate swelling at both room temperature and 90 °C. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to determine the thermal characteristics of the microparticles. Finally, rheological measurements were used to assess the deformation and rheological behavior of the hydrogels. The results showed that after 1 day, good swelling without loss of mechanical strength was achieved with the composite synthesized using 10% AM, 15% AMPS, 6% PGV, and 10% ATP.

一致性控制或断水是一种用于提高石油采收率的技术。在一致性控制过程中,聚合物会阻断高渗透率水区,并将水驱重新分配到未渗透油区。本研究以丙烯酰胺(AM)和 2-丙烯酰胺-2-甲基丙烷磺酸(AMPS)为单体,合成了共聚合物(ATP-PGV/AM-co-AMPS)、聚乙二醇 (PEG)-200 和亚甲基双丙烯酰胺 (MBA) 作为交联剂,阿塔波利土 (ATP) 和膨润土 (PGV) 作为粘土类型,过硫酸铵 (APS) 作为引发剂,此外还有石蜡油和表面活性剂。使用不同浓度的单体、交联剂和粘土,通过反乳液聚合法合成了样品,并使用傅立叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)以及能量色散 X 射线光谱(EDX)对样品进行了表征。样品的傅立叶变换红外光谱证实了磺酸基和羟基的存在,这对聚合物的溶胀非常重要。SEM-EDX 图像显示,溶胀前后的形态和元素组成不同,证实了溶胀的发生。此外,将样品在氯化钠溶液(20,000 ppm)中放置 7 天,以评估在室温和 90 °C 下的溶胀情况。热重分析(TGA)和差示扫描量热法(DSC)用于确定微颗粒的热特性。最后,流变学测量用于评估水凝胶的变形和流变行为。结果表明,使用 10% AM、15% AMPS、6% PGV 和 10% ATP 合成的复合材料在 1 天后实现了良好的溶胀,且不会失去机械强度。
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引用次数: 0
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Petroleum Research
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