首页 > 最新文献

Philosophical Magazine最新文献

英文 中文
Gas in external fields: the weird case of the logarithmic trap 外部气田中的气体:对数陷阱的奇怪案例
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-02 DOI: 10.1080/14786435.2023.2285368
Loris Ferrari
The effects of an attractive logarithmic potential u(r)=u0ln⁡(r/r0) (u0>0 being the trap strength and r0 an arbitrary length scale) on a gas of N non interacting particles (Bosons or Fermions), in ...
吸引对数势u(r)=u0ln (r/r0) (u0>0为陷阱强度,r0为任意长度尺度)对N个非相互作用粒子(玻色子或费米子)气体的影响。
{"title":"Gas in external fields: the weird case of the logarithmic trap","authors":"Loris Ferrari","doi":"10.1080/14786435.2023.2285368","DOIUrl":"https://doi.org/10.1080/14786435.2023.2285368","url":null,"abstract":"The effects of an attractive logarithmic potential u(r)=u0ln⁡(r/r0) (u0>0 being the trap strength and r0 an arbitrary length scale) on a gas of N non interacting particles (Bosons or Fermions), in ...","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"52 11","pages":""},"PeriodicalIF":1.6,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A hybrid dislocation deforming two welded anisotropic crystals 一个杂化位错使两个焊接的各向异性晶体变形
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-28 DOI: 10.1080/14786435.2023.2280367
Nizar Lefi, Salem Neily, Roland Bonnet
The elastic field of an angular dislocation line that has a branch placed in a crystal of a bi-material while the other branch is along a strongly bound or welded interface, is found when the two c...
在双材料晶体中有一个分支,而另一个分支沿着强结合或焊接界面的角位错线的弹性场,当两个c…
{"title":"A hybrid dislocation deforming two welded anisotropic crystals","authors":"Nizar Lefi, Salem Neily, Roland Bonnet","doi":"10.1080/14786435.2023.2280367","DOIUrl":"https://doi.org/10.1080/14786435.2023.2280367","url":null,"abstract":"The elastic field of an angular dislocation line that has a branch placed in a crystal of a bi-material while the other branch is along a strongly bound or welded interface, is found when the two c...","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"34 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electronic, magnetic, half-Metallic, pressure-induced elastic and curie temperature predictions of Zr2RhTl Heusler alloy: DFT and EFT studies Zr2RhTl Heusler合金的电子、磁性、半金属、压力致弹性和居里温度预测:DFT和EFT研究
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-21 DOI: 10.1080/14786435.2023.2285031
Evren Görkem Özdemir, Semih Doğruer, Ziya Merdan
The DFT method investigated the total and partial magnetic moments, half-metallic characters, and pressure-dependent elastic properties of Zr2RhTl alloy. According to the ground state properties, t...
采用DFT方法研究了Zr2RhTl合金的总磁矩、偏磁矩、半金属性质和压力相关弹性性能。根据基态性质,t…
{"title":"Electronic, magnetic, half-Metallic, pressure-induced elastic and curie temperature predictions of Zr2RhTl Heusler alloy: DFT and EFT studies","authors":"Evren Görkem Özdemir, Semih Doğruer, Ziya Merdan","doi":"10.1080/14786435.2023.2285031","DOIUrl":"https://doi.org/10.1080/14786435.2023.2285031","url":null,"abstract":"The DFT method investigated the total and partial magnetic moments, half-metallic characters, and pressure-dependent elastic properties of Zr2RhTl alloy. According to the ground state properties, t...","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"43 3","pages":""},"PeriodicalIF":1.6,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Whereabouts of missing atoms in a laser-injected Si (part IV): interaction of plasma Si with dislocations in a laser-injected Si 激光注入Si中缺失原子的去向(第四部分):等离子体Si与激光注入Si中位错的相互作用
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-21 DOI: 10.1080/14786435.2023.2283115
Hiroyasu Saka, Hiroyuki Iwata
The interaction of dislocations with plasma Si in a laser-injected Si was studied comprehensively using a combination of in-situ and ex-situ heating experiments in 200 kV electron microscopes and i...
采用原位加热和非原位加热相结合的方法,在200 kV电子显微镜和等离子体等离子体上对激光注入Si中位错与等离子体Si的相互作用进行了全面研究。
{"title":"Whereabouts of missing atoms in a laser-injected Si (part IV): interaction of plasma Si with dislocations in a laser-injected Si","authors":"Hiroyasu Saka, Hiroyuki Iwata","doi":"10.1080/14786435.2023.2283115","DOIUrl":"https://doi.org/10.1080/14786435.2023.2283115","url":null,"abstract":"The interaction of dislocations with plasma Si in a laser-injected Si was studied comprehensively using a combination of in-situ and ex-situ heating experiments in 200 kV electron microscopes and i...","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"30 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An EBSD analysis of a commercial immiscible Cu43%Cr alloy after high-pressure torsion processing and annealing 一种非混相Cu43%Cr合金经高压扭转加工退火后的EBSD分析
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-16 DOI: 10.1080/14786435.2023.2282023
I. Bibimoune, K. Abib, T. Baudin, F. Brisset, Y. Huang, D. Bradai, T. G. Langdon
The influence of high-pressure torsion (HPT) and annealing on microstructure, texture and thermal stability of an immiscible composite Cu43%Cr alloy was studied using electron backscatter diffracti...
采用电子背散射衍射技术研究了高压扭转(HPT)和退火对非混相复合Cu43%Cr合金组织、织构和热稳定性的影响。
{"title":"An EBSD analysis of a commercial immiscible Cu43%Cr alloy after high-pressure torsion processing and annealing","authors":"I. Bibimoune, K. Abib, T. Baudin, F. Brisset, Y. Huang, D. Bradai, T. G. Langdon","doi":"10.1080/14786435.2023.2282023","DOIUrl":"https://doi.org/10.1080/14786435.2023.2282023","url":null,"abstract":"The influence of high-pressure torsion (HPT) and annealing on microstructure, texture and thermal stability of an immiscible composite Cu43%Cr alloy was studied using electron backscatter diffracti...","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"30 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ti-Al-based alloys with Mo: high-temperature phase equilibria and microstructures in the ternary system 含Mo的ti - al基合金:三元体系的高温相平衡和显微组织
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-09 DOI: 10.1080/14786435.2023.2279575
Benedikt Distl, Frank Stein
Molybdenum is one of the major alloying elements in TiAl-based alloys for high-temperature structural applications developed over the last decades. This is due to its stabilising effect on the (βTi) phase at high-temperatures, which crucially improves the hot-workability of such alloys. For further alloy development, an exact knowledge of the phase equilibria in the Ti–Al–Mo system is essential. However, there are still uncertainties and inconsistencies related to the ternary phase diagram. In this study, a series of ternary alloys was produced and heat-treated between 700 and 1300 °C. Composition, structure, and thermal stability of the phases were analysed and the resulting phase equilibria were established by applying a combination of scanning electron microscopy (SEM), electron probe microanalysis (EPMA), differential scanning calorimetry (DSC), and high-energy X-ray diffraction (HEXRD). From these results, a series of partial isothermal sections is obtained illustrating the phase equilibria in the Ti-rich part of the Ti–Al–Mo system.
钼是近几十年来发展起来的用于高温结构的钛基合金的主要合金元素之一。这是由于它在高温下对(βTi)相的稳定作用,这关键地提高了这种合金的热加工性。对于进一步的合金开发,在Ti-Al-Mo系统相平衡的确切知识是必不可少的。然而,三元相图仍然存在不确定性和不一致性。在本研究中,制备了一系列三元合金,并在700 ~ 1300℃之间进行热处理。采用扫描电子显微镜(SEM)、电子探针微分析(EPMA)、差示扫描量热法(DSC)和高能x射线衍射(HEXRD)等方法,分析了相的组成、结构和热稳定性,并建立了相平衡。根据这些结果,得到了一系列的部分等温截面,说明了Ti-Al-Mo体系中富钛部分的相平衡。
{"title":"Ti-Al-based alloys with Mo: high-temperature phase equilibria and microstructures in the ternary system","authors":"Benedikt Distl, Frank Stein","doi":"10.1080/14786435.2023.2279575","DOIUrl":"https://doi.org/10.1080/14786435.2023.2279575","url":null,"abstract":"Molybdenum is one of the major alloying elements in TiAl-based alloys for high-temperature structural applications developed over the last decades. This is due to its stabilising effect on the (βTi) phase at high-temperatures, which crucially improves the hot-workability of such alloys. For further alloy development, an exact knowledge of the phase equilibria in the Ti–Al–Mo system is essential. However, there are still uncertainties and inconsistencies related to the ternary phase diagram. In this study, a series of ternary alloys was produced and heat-treated between 700 and 1300 °C. Composition, structure, and thermal stability of the phases were analysed and the resulting phase equilibria were established by applying a combination of scanning electron microscopy (SEM), electron probe microanalysis (EPMA), differential scanning calorimetry (DSC), and high-energy X-ray diffraction (HEXRD). From these results, a series of partial isothermal sections is obtained illustrating the phase equilibria in the Ti-rich part of the Ti–Al–Mo system.","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":" 9","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135291023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phase transformation kinetics in a homogenised cast alloy 625 and its impact on deformation micromechanisms 625均相铸造合金相变动力学及其对变形微观机制的影响
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-09 DOI: 10.1080/14786435.2023.2276693
Sonika Chahar, Ashwin Kumar Godasu, Arunansu Haldar, Suhrit Mula
ABSTRACTThis study focuses on understanding the impact of sequential ageing on the microstructural evolution of a large-grained structure homogenised cast alloy 625 and its effect on mechanical properties. SEM and TEM analyses of aged samples were conducted to comprehend various precipitation micromechanisms such as (i) nucleation and growth kinetics of γ′′ phase and (ii) transformation of primary carbides and grain boundary phase(s) evolved. The MC-based primary carbides are ascertained to transform into M23C6 secondary carbides following two completely different pathways: (I) MC + γ→ M23C6 + δ (mainly at grain boundary) and (II) MC + γ→M23C6 + γ″ (mainly within matrix). Furthermore, all three variants of γ″ phase are detected to evolve in the matrix displaying a crystallographic orientation of [001]γ″ // < 001>γ, and {100}γ″ // {100}γ. The formation of γ″ phase gradually improves the hardness of the material up to 650 h (224 HV) of ageing with a corresponding average precipitate size of 61 nm. The growth of γ″ particles complies with the Lifshitz–Slyozov–Wagner (LSW) theory of diffusion-controlled precipitate coarsening during the entire ageing period. Surprisingly, the hardness declined significantly beyond 650 h of ageing, even though the γ″ phase remained coherent with the matrix despite its coarsening (106 nm after 1000 h of ageing) and evidence of γ″→δ (mainly incoherent) transformation is not detectible throughout the ageing treatment. This lowering of hardness is attributed to a non-conventional slip-to-twin transition in the deformation mode of coherent γ″ particles after prolonged ageing, which is confirmed through tensile deformation micromechanisms analysis of the 650 and 1000 h aged samples.KEYWORDS: Alloy 625ageing characteristicscoherent precipitategrain boundary carbidesneedle-like δ phaseelectron microscopy AcknowledgementThe authors highly acknowledge financial support by Science and Engineering Research Board, Government of India, through grant number. CRG/2019/000949 as well as the assistance of the material from MIDHANI LTD., Hyderabad, India. The authors are also thankful to the Metallurgical and Materials Engineering Department, IIT Roorkee, for the support of different experimental and characterization facilities.Disclosure statementNo potential conflict of interest was reported by the author(s).Credit authorship contribution statementSonika Chahar: Experimental, Conceptualisation, Methodology, Visualisation, Validation, Writing – original draft.Ashwin Kumar Godasu: Conceptualisation, Methodology, Visualisation.Arunansu Haldar: Draft review and editing.Suhrit Mula: Conceptualisation, Supervision, Validation, Review and editing.Data availabilityData will be available on request.Additional informationFundingThe authors highly acknowledge financial funding by Science and Engineering Research Board, Government of India, through grant number CRG/2019/000949 as well as the assistance of the material from MIDHANI LTD., Hyderabad
摘要研究了顺序时效对大晶粒组织均质铸造合金625微观组织演变的影响及其对力学性能的影响。通过对时效样品的SEM和TEM分析,了解了不同的析出微观机制,如(i) γ′相的形核和生长动力学,(ii)初生碳化物的转变和晶界相的演化。MC基原生碳化物转变为M23C6次生碳化物的途径完全不同:(I) MC + γ→M23C6 + δ(主要在晶界处)和(II) MC + γ→M23C6 + γ″(主要在基体内)。此外,所有三种γ″相的变体都在基体中进化,显示出[001]γ″// < 001>γ和{100}γ″// {100}γ的晶体取向。时效至650 h (224 HV)时,γ″相的形成逐渐提高了材料的硬度,相应的平均析出尺寸为61 nm。在整个时效过程中,γ″粒子的生长符合Lifshitz-Slyozov-Wagner (LSW)扩散控制沉淀粗化理论。令人惊讶的是,时效650 h后,硬度显著下降,尽管γ″相在时效1000 h后粗化(106 nm),但仍与基体保持一致,并且在整个时效处理过程中未检测到γ″→δ(主要是不一致的)转变的证据。这种硬度的降低是由于在长时效后,相干γ″颗粒的变形模式发生了非常规的滑移到孪晶转变,这一点通过650和1000 h时效样品的拉伸变形微观机制分析得到了证实。关键词:625合金;时效特征;均匀析出;晶界碳化物;CRG/2019/000949以及来自印度海得拉巴MIDHANI LTD.的材料协助。作者也感谢冶金与材料工程系,IIT Roorkee,为不同的实验和表征设施的支持。披露声明作者未报告潜在的利益冲突。信用作者贡献声明sonika Chahar:实验,概念化,方法论,可视化,验证,写作-原稿。Ashwin Kumar Godasu:概念化,方法论,可视化。Arunansu Haldar:草案审查和编辑。Suhrit Mula:概念化,监督,验证,审查和编辑。数据可得性应要求提供数据。作者高度感谢印度政府科学与工程研究委员会的财政资助,资助号为CRG/2019/000949,并感谢印度海得拉巴MIDHANI LTD.提供的材料。
{"title":"Phase transformation kinetics in a homogenised cast alloy 625 and its impact on deformation micromechanisms","authors":"Sonika Chahar, Ashwin Kumar Godasu, Arunansu Haldar, Suhrit Mula","doi":"10.1080/14786435.2023.2276693","DOIUrl":"https://doi.org/10.1080/14786435.2023.2276693","url":null,"abstract":"ABSTRACTThis study focuses on understanding the impact of sequential ageing on the microstructural evolution of a large-grained structure homogenised cast alloy 625 and its effect on mechanical properties. SEM and TEM analyses of aged samples were conducted to comprehend various precipitation micromechanisms such as (i) nucleation and growth kinetics of γ′′ phase and (ii) transformation of primary carbides and grain boundary phase(s) evolved. The MC-based primary carbides are ascertained to transform into M23C6 secondary carbides following two completely different pathways: (I) MC + γ→ M23C6 + δ (mainly at grain boundary) and (II) MC + γ→M23C6 + γ″ (mainly within matrix). Furthermore, all three variants of γ″ phase are detected to evolve in the matrix displaying a crystallographic orientation of [001]γ″ // &lt; 001&gt;γ, and {100}γ″ // {100}γ. The formation of γ″ phase gradually improves the hardness of the material up to 650 h (224 HV) of ageing with a corresponding average precipitate size of 61 nm. The growth of γ″ particles complies with the Lifshitz–Slyozov–Wagner (LSW) theory of diffusion-controlled precipitate coarsening during the entire ageing period. Surprisingly, the hardness declined significantly beyond 650 h of ageing, even though the γ″ phase remained coherent with the matrix despite its coarsening (106 nm after 1000 h of ageing) and evidence of γ″→δ (mainly incoherent) transformation is not detectible throughout the ageing treatment. This lowering of hardness is attributed to a non-conventional slip-to-twin transition in the deformation mode of coherent γ″ particles after prolonged ageing, which is confirmed through tensile deformation micromechanisms analysis of the 650 and 1000 h aged samples.KEYWORDS: Alloy 625ageing characteristicscoherent precipitategrain boundary carbidesneedle-like δ phaseelectron microscopy AcknowledgementThe authors highly acknowledge financial support by Science and Engineering Research Board, Government of India, through grant number. CRG/2019/000949 as well as the assistance of the material from MIDHANI LTD., Hyderabad, India. The authors are also thankful to the Metallurgical and Materials Engineering Department, IIT Roorkee, for the support of different experimental and characterization facilities.Disclosure statementNo potential conflict of interest was reported by the author(s).Credit authorship contribution statementSonika Chahar: Experimental, Conceptualisation, Methodology, Visualisation, Validation, Writing – original draft.Ashwin Kumar Godasu: Conceptualisation, Methodology, Visualisation.Arunansu Haldar: Draft review and editing.Suhrit Mula: Conceptualisation, Supervision, Validation, Review and editing.Data availabilityData will be available on request.Additional informationFundingThe authors highly acknowledge financial funding by Science and Engineering Research Board, Government of India, through grant number CRG/2019/000949 as well as the assistance of the material from MIDHANI LTD., Hyderabad","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":" 46","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135241630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on discontinuous precipitation behaviour and performance change of Cu–Ti–Ni during aging 时效过程中Cu-Ti-Ni的不连续析出行为及性能变化研究
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-25 DOI: 10.1080/14786435.2023.2270489
Guangming Cao, Ruixiang Li, Zhanjie Gao, Chenggang Li, Hao Wang
ABSTRACTThe discontinuous precipitation behaviour and properties of Cu–Ti–Ni alloy during aging precipitation were studied by means of electron backscatter diffraction (EBSD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The results show that β'-Cu4Ti was formed in the matrix during the aging process of Cu–4Ti–1Ni alloy, and the cellular structure grows at the grain boundary in the form of discontinuous precipitation in the middle and late stages of aging, and expands to the interior of the grains with the aging time until the grains were completely covered, then a uniform Cu3Ti structure was formed. In addition, the coverage area of cellular tissue increases with aging time and temperature. Under different aging temperature conditions, the hardness of the alloy increases first and then decreases with the aging time, with a peak value of 319.8 HV and a strength of 782.2 MPa. The electrical conductivity increases rapidly and then increases slowly with aging time, reaching 15.5 IACS after aging at 500°C for 10 h. Based on the Avrami equation, the kinetic analysis of discontinuous precipitation at different temperatures was established.KEYWORDS: Cu-Ti-Ni alloyaging strengtheningdiscontinuous precipitationperformance changes Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by Science and Technology Special Projects of Liaoning Province [grant number 2022JH25/10200001]; Postdoctoral Science Foundation of China [grant number 2022T150205]; National Key Research and Development Program of China [grant number 2022YFB3304800].
摘要采用电子背散射衍射(EBSD)、扫描电镜(SEM)、透射电镜(TEM)和x射线衍射(XRD)等手段研究了Cu-Ti-Ni合金时效析出过程中的不连续析出行为和性能。结果表明:Cu-4Ti-1Ni合金在时效过程中在基体中形成β′-Cu4Ti,时效中后期在晶界处以不连续析出的形式生长胞状组织,随着时效时间的延长向晶粒内部扩展,直至晶粒被完全覆盖,形成均匀的Cu3Ti组织;此外,细胞组织的覆盖面积随老化时间和温度的增加而增加。在不同时效温度条件下,合金硬度随时效时间先升高后降低,峰值为319.8 HV,强度为782.2 MPa。随着时效时间的延长,电导率先快速增大后缓慢增大,在500℃时效10 h后达到15.5 IACS。基于Avrami方程,建立了不同温度下不连续析出的动力学分析。关键词:Cu-Ti-Ni合金化强化不连续沉淀性能变化披露声明作者未报告潜在利益冲突。本研究由辽宁省科技专项资助[批准号2022JH25/10200001];中国博士后科学基金项目[批准号2022T150205];国家重点研发计划项目[批准号2022YFB3304800]。
{"title":"Study on discontinuous precipitation behaviour and performance change of Cu–Ti–Ni during aging","authors":"Guangming Cao, Ruixiang Li, Zhanjie Gao, Chenggang Li, Hao Wang","doi":"10.1080/14786435.2023.2270489","DOIUrl":"https://doi.org/10.1080/14786435.2023.2270489","url":null,"abstract":"ABSTRACTThe discontinuous precipitation behaviour and properties of Cu–Ti–Ni alloy during aging precipitation were studied by means of electron backscatter diffraction (EBSD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The results show that β'-Cu4Ti was formed in the matrix during the aging process of Cu–4Ti–1Ni alloy, and the cellular structure grows at the grain boundary in the form of discontinuous precipitation in the middle and late stages of aging, and expands to the interior of the grains with the aging time until the grains were completely covered, then a uniform Cu3Ti structure was formed. In addition, the coverage area of cellular tissue increases with aging time and temperature. Under different aging temperature conditions, the hardness of the alloy increases first and then decreases with the aging time, with a peak value of 319.8 HV and a strength of 782.2 MPa. The electrical conductivity increases rapidly and then increases slowly with aging time, reaching 15.5 IACS after aging at 500°C for 10 h. Based on the Avrami equation, the kinetic analysis of discontinuous precipitation at different temperatures was established.KEYWORDS: Cu-Ti-Ni alloyaging strengtheningdiscontinuous precipitationperformance changes Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by Science and Technology Special Projects of Liaoning Province [grant number 2022JH25/10200001]; Postdoctoral Science Foundation of China [grant number 2022T150205]; National Key Research and Development Program of China [grant number 2022YFB3304800].","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"145 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135111314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic property of one-dimensional hydrogenic impurity in Nitride semiconductor quantum well 氮半导体量子阱中一维氢杂质的热力学性质
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-25 DOI: 10.1080/14786435.2023.2270436
Xue Liu, De-hua Wang, Xin-yu Xie, Bin-hua Chu, Shu-fang Zhang, Gang Zhao
ABSTRACTThe thermodynamic properties of one-dimensional (1-D) hydrogenic impurity in Nitride semiconductor quantum well have been investigated. Firstly, using a combination of the linear variational approach and the effective mass approximation, we obtain the eigen-energy of hydrogenic impurity states in AlN, GaN and InN quantum wells. Subsequently, we explore the quantum size effect on the thermodynamic properties of these low-dimensional semiconductor structures, revealing some novel and intriguing phenomena. It is found as the width of the quantum well is increased, the energy of hydrogenic impurity gets decreased, however, the thermodynamic parameters, such as the average energy, entropy and heat capacity of the hydrogenic impurity become increased. The physical origins of these peculiar phenomena are attributed to the competitive mechanism between the quantum confinement effect and Coulombic interaction between the electron and impurity. Finally, by conducting a comprehensive comparison of the thermodynamic parameters among GaN, InN, and AlN quantum wells, we propose an innovative strategy for modulating the thermodynamic properties of these low-dimensional semiconductor structures. This manipulation can be achieved not only through external factors such as temperature and quantum well size, but also by altering internal variables like the effective mass and relative dielectric constant of the semiconductor material. This study not only advances our understanding of the thermodynamic properties of hydrogenic impurities in semiconductor quantum wells, but also provides some theoretical guidance for practical applications in fields such as semiconductor physics, condensed matter physics, chemical physics, etc.KEYWORDS: Thermodynamic propertyhydrogenic impuritysemiconductor quantum welllow-dimensional structure AcknowledgementWe also thank the referees for their valuable suggestions.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by the Natural Science Foundation of Shandong Province, China (Grant Nos.ZR2019MA066 and ZR2020MF103), the Taishan Scholar Project of Shandong Province (grant number tsqn201812098), and the National Natural Science Foundation of China (Grant Nos. 11874191 and 62275115).
摘要研究了氮化物半导体量子阱中一维氢杂质的热力学性质。首先,采用线性变分方法和有效质量近似相结合的方法,得到了AlN、GaN和InN量子阱中氢杂质态的本征能。随后,我们探索了量子尺寸对这些低维半导体结构热力学性质的影响,揭示了一些新颖而有趣的现象。结果表明,随着量子阱宽度的增大,含氢杂质的能量减小,但含氢杂质的平均能量、熵和热容等热力学参数增大。这些奇特现象的物理根源是量子约束效应和电子与杂质之间的库仑相互作用之间的竞争机制。最后,通过对GaN、InN和AlN量子阱的热力学参数进行全面比较,我们提出了一种创新的策略来调节这些低维半导体结构的热力学特性。这种操作不仅可以通过温度和量子阱大小等外部因素实现,还可以通过改变半导体材料的有效质量和相对介电常数等内部变量来实现。本研究不仅加深了我们对半导体量子阱中含氢杂质热力学性质的认识,而且为半导体物理、凝聚态物理、化学物理等领域的实际应用提供了一定的理论指导。关键词:热力学性质;含氢杂质;半导体量子阱;低维结构披露声明作者未报告潜在的利益冲突。基金资助:山东省自然科学基金项目(批准号:zr2019ma066和ZR2020MF103)、山东省泰山学者计划项目(批准号:tsqn201812098)和国家自然科学基金项目(批准号:11874191和62275115)。
{"title":"Thermodynamic property of one-dimensional hydrogenic impurity in Nitride semiconductor quantum well","authors":"Xue Liu, De-hua Wang, Xin-yu Xie, Bin-hua Chu, Shu-fang Zhang, Gang Zhao","doi":"10.1080/14786435.2023.2270436","DOIUrl":"https://doi.org/10.1080/14786435.2023.2270436","url":null,"abstract":"ABSTRACTThe thermodynamic properties of one-dimensional (1-D) hydrogenic impurity in Nitride semiconductor quantum well have been investigated. Firstly, using a combination of the linear variational approach and the effective mass approximation, we obtain the eigen-energy of hydrogenic impurity states in AlN, GaN and InN quantum wells. Subsequently, we explore the quantum size effect on the thermodynamic properties of these low-dimensional semiconductor structures, revealing some novel and intriguing phenomena. It is found as the width of the quantum well is increased, the energy of hydrogenic impurity gets decreased, however, the thermodynamic parameters, such as the average energy, entropy and heat capacity of the hydrogenic impurity become increased. The physical origins of these peculiar phenomena are attributed to the competitive mechanism between the quantum confinement effect and Coulombic interaction between the electron and impurity. Finally, by conducting a comprehensive comparison of the thermodynamic parameters among GaN, InN, and AlN quantum wells, we propose an innovative strategy for modulating the thermodynamic properties of these low-dimensional semiconductor structures. This manipulation can be achieved not only through external factors such as temperature and quantum well size, but also by altering internal variables like the effective mass and relative dielectric constant of the semiconductor material. This study not only advances our understanding of the thermodynamic properties of hydrogenic impurities in semiconductor quantum wells, but also provides some theoretical guidance for practical applications in fields such as semiconductor physics, condensed matter physics, chemical physics, etc.KEYWORDS: Thermodynamic propertyhydrogenic impuritysemiconductor quantum welllow-dimensional structure AcknowledgementWe also thank the referees for their valuable suggestions.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by the Natural Science Foundation of Shandong Province, China (Grant Nos.ZR2019MA066 and ZR2020MF103), the Taishan Scholar Project of Shandong Province (grant number tsqn201812098), and the National Natural Science Foundation of China (Grant Nos. 11874191 and 62275115).","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"65 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135111479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Diffusion mechanism in liquid Al–Cu melt under high magnetic field 强磁场下液态铝铜熔体扩散机理研究
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-25 DOI: 10.1080/14786435.2023.2271427
Wenhao Lin, Meilong Feng, Ying Liu, Hao Cai, Zhe Shen, Chunmei Liu, Tianxiang Zheng, Bangfei Zhou, Yunbo Zhong
ABSTRACTHigh static magnetic field (HMF) is now a widely used technique to tailor materials. However, as one of the most fundamental properties in liquid alloy melts, atomic diffusion under HMF still lacks understanding. By using a novel gravity-assisted automatic docking device, the interdiffusion coefficient (IDC) in liquid Al–Cu alloy at various temperatures has been studied under HMF. It is found that HMF reduces the IDC. When HMF is larger than 5 T, the value of IDC remains constant at a certain temperature, which indicates HMF changes the diffusion mechanism from convective dominated mass transfer to a diffusive limited state in the liquid melt. For various temperatures, we find that a decrease of the frequency factor of atoms is the main reason for IDC decreasing under a certain HMF. The diffusion mechanism in liquid melt is similar to the vacancy mechanism in solids. This work provides a deep insight for atomic diffusion in a liquid melt by considering the interaction between temperature and HMF.KEYWORDS: Al–Cu alloyatomic diffusionhigh magnetic fieldactivation energyfrequency factor Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors gratefully acknowledge the financial support of the National Natural Science Foundation of China [U1732276], Natural Science Foundation of Shanghai [21ZR1424400], Open Project of State Key Laboratory of Advanced Special Steel Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University [SKLASS 2021-Z06], Changjiang Scholars Program of China, China Association for Science and Technology Young Talent Support Project.
摘要:静态磁场(HMF)是目前广泛应用的材料裁剪技术。然而,作为液态合金熔体中最基本的特性之一,原子扩散在HMF作用下仍缺乏认识。利用一种新型重力辅助自动对接装置,研究了液体Al-Cu合金在HMF作用下不同温度下的相互扩散系数。发现HMF降低了IDC。当HMF大于5 T时,IDC值在一定温度下保持不变,表明HMF使液相熔体中的扩散机制由对流为主的传质转变为扩散受限状态。在不同温度下,我们发现原子频率因子的降低是一定HMF下IDC降低的主要原因。液相熔体中的扩散机制与固体中的空位机制相似。这项工作通过考虑温度和HMF之间的相互作用,对液体熔体中的原子扩散提供了深入的了解。关键词:Al-Cu合金原子扩散高磁场激活能量频率因子披露声明作者未报告潜在利益冲突。作者感谢国家自然科学基金[U1732276]、上海市自然科学基金[21ZR1424400]、上海大学先进特殊钢国家重点实验室开放项目[SKLASS 2021-Z06]、中国长江学者奖励计划、中国科学会青年人才支持项目的资助。
{"title":"Diffusion mechanism in liquid Al–Cu melt under high magnetic field","authors":"Wenhao Lin, Meilong Feng, Ying Liu, Hao Cai, Zhe Shen, Chunmei Liu, Tianxiang Zheng, Bangfei Zhou, Yunbo Zhong","doi":"10.1080/14786435.2023.2271427","DOIUrl":"https://doi.org/10.1080/14786435.2023.2271427","url":null,"abstract":"ABSTRACTHigh static magnetic field (HMF) is now a widely used technique to tailor materials. However, as one of the most fundamental properties in liquid alloy melts, atomic diffusion under HMF still lacks understanding. By using a novel gravity-assisted automatic docking device, the interdiffusion coefficient (IDC) in liquid Al–Cu alloy at various temperatures has been studied under HMF. It is found that HMF reduces the IDC. When HMF is larger than 5 T, the value of IDC remains constant at a certain temperature, which indicates HMF changes the diffusion mechanism from convective dominated mass transfer to a diffusive limited state in the liquid melt. For various temperatures, we find that a decrease of the frequency factor of atoms is the main reason for IDC decreasing under a certain HMF. The diffusion mechanism in liquid melt is similar to the vacancy mechanism in solids. This work provides a deep insight for atomic diffusion in a liquid melt by considering the interaction between temperature and HMF.KEYWORDS: Al–Cu alloyatomic diffusionhigh magnetic fieldactivation energyfrequency factor Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors gratefully acknowledge the financial support of the National Natural Science Foundation of China [U1732276], Natural Science Foundation of Shanghai [21ZR1424400], Open Project of State Key Laboratory of Advanced Special Steel Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University [SKLASS 2021-Z06], Changjiang Scholars Program of China, China Association for Science and Technology Young Talent Support Project.","PeriodicalId":19856,"journal":{"name":"Philosophical Magazine","volume":"37 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134973922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Philosophical Magazine
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1