首页 > 最新文献

Polish Journal of Environmental Studies最新文献

英文 中文
Thermal Decomposition Behavior of PolylacticAcid-Based Polyurethane Resin 聚乳酸基聚氨酯树脂的热分解行为
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-06 DOI: 10.15244/pjoes/172833
Xuefeng Lei, Yiwei Ou, Yuehui Wang, Junxian Ma, Qiulian Lin
The thermal degradation performance of the polylactic acid (PLA)-based polyurethane resin was investigated by thermogravimetric analysis (TGA), thermogravimetric analysis combined with Fourier transform infrared spectroscopy (TG-FTIR) and thermal cracking gas chromatography/mass spectrometry (PY-GC/MS), while the thermal decomposition mechanism and activation energy were analyzed by different degradation mechanism models. The result demonstrates that the PLA-based polyurethane resin conforms to A2 (nuclear growth) mechanism, and the activation energy of the reaction gradually decreases as the conversion rates increases. The main degradation of polyurethane resin is the decomposition of carbamate, ester group, amide and urea group by comparing the results of the data, and the products of the thermal decomposition are mainly small molecules of primary amine, carbon dioxide, enol, enolic acid and aldehydes.
采用热重分析(TGA)、热重分析结合傅里叶变换红外光谱(TG-FTIR)和热裂解气相色谱/质谱分析(PY-GC/MS)研究了聚乳酸(PLA)基聚氨酯树脂的热降解性能,并采用不同的降解机理模型分析了热分解机理和活化能。结果表明,聚乳酸基聚氨酯树脂符合A2(核生长)机理,反应活化能随着转化率的提高而逐渐降低。通过对数据结果的比较,聚氨酯树脂的主要降解是氨基甲酸酯、酯基、酰胺和尿素基的分解,热分解的产物主要是伯胺、二氧化碳、烯醇、烯醇酸和醛类小分子。
{"title":"Thermal Decomposition Behavior of Polylactic\u0000Acid-Based Polyurethane Resin","authors":"Xuefeng Lei, Yiwei Ou, Yuehui Wang, Junxian Ma, Qiulian Lin","doi":"10.15244/pjoes/172833","DOIUrl":"https://doi.org/10.15244/pjoes/172833","url":null,"abstract":"The thermal degradation performance of the polylactic acid (PLA)-based polyurethane resin was investigated by thermogravimetric analysis (TGA), thermogravimetric analysis combined with Fourier transform infrared spectroscopy (TG-FTIR) and thermal cracking gas chromatography/mass spectrometry (PY-GC/MS), while the thermal decomposition mechanism and activation energy were analyzed by different degradation mechanism models. The result demonstrates that the PLA-based polyurethane resin conforms to A2 (nuclear growth) mechanism, and the activation energy of the reaction gradually decreases as the conversion rates increases. The main degradation of polyurethane resin is the decomposition of carbamate, ester group, amide and urea group by comparing the results of the data, and the products of the thermal decomposition are mainly small molecules of primary amine, carbon dioxide, enol, enolic acid and aldehydes.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"40 2","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138596403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties of Binary and Ternary Blended Cementcontaining Pond Ash and Ground GranulatedBlast Furnace Slag 含池塘灰和研磨粒化高炉矿渣的二元和三元混合水泥的性能
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-06 DOI: 10.15244/pjoes/170852
D. Velumani, P. Mageshkumar, K. Yuvaraj
Fly ash is a fine powdery particle collected from the unit operations of coal combustion furnaces in thermal power plants. Retained fly ash at bottom of hopper has been mixed with water and dumped in lagoons in form of slurry as pond ash (PA) or lagoon ash. Ground Granulated Blast Furnace Slag (GGBS) is a by-product obtained from steel industry. In this study, three phase of concrete specimens were prepared. In first phase, the specimens were prepared using 100% cement with various water-to-cementitious ratios. In second phase, specimens were prepared with varying water-to-cementitious ratios and PA contents ranging from 0 to 20%. Finally, the third phase, specimens were prepared to determine the optimal PA content, with GGBS ranging from 0 to 25%. The mechanical and rheological properties of different proportions of PA and GGBS have been experimentally investigated at 28 days. In addition, the flow ability and packing density of different proportions of PA and GGBS various mixes were tested. The test results revealed that combination of PA and GGBS up to 27% would enhance the fresh and harden properties of cementitious material. The rheological behaviour of optimal PA and GGBS concrete were tested at 28 days using scanning electron microscope (SEM). The results confirmed that the addition of PA and GGBS resulting in a denser, less porous, and more compact CSH microstructure in concrete.
粉煤灰是一种细小的粉状颗粒,来自火力发电厂燃煤炉的单元操作。在料斗底部保留的飞灰与水混合后以浆料的形式倾倒在泻湖中,即池塘灰(PA)或泻湖灰。粉状高炉渣是钢铁工业生产的副产物。本研究共制备了3期混凝土试件。在第一阶段,用不同水胶比的100%水泥制备样品。在第二阶段,制备了不同水胶比的样品,PA含量从0到20%不等。最后,第三阶段制备标本,确定最佳PA含量,GGBS范围为0 ~ 25%。实验研究了不同比例的PA和GGBS在28天的力学和流变特性。此外,还测试了不同比例的PA和GGBS混合料的流动能力和堆积密度。试验结果表明,PA和GGBS的掺量达到27%,可提高胶凝材料的新鲜度和硬化性。采用扫描电镜(SEM)对最佳PA和GGBS混凝土在28 d时的流变特性进行了测试。结果证实,PA和GGBS的加入使混凝土中的CSH微观结构更致密、孔隙更少、更致密。
{"title":"Properties of Binary and Ternary Blended Cement\u0000containing Pond Ash and Ground Granulated\u0000Blast Furnace Slag","authors":"D. Velumani, P. Mageshkumar, K. Yuvaraj","doi":"10.15244/pjoes/170852","DOIUrl":"https://doi.org/10.15244/pjoes/170852","url":null,"abstract":"Fly ash is a fine powdery particle collected from the unit operations of coal combustion furnaces in thermal power plants. Retained fly ash at bottom of hopper has been mixed with water and dumped in lagoons in form of slurry as pond ash (PA) or lagoon ash. Ground Granulated Blast Furnace Slag (GGBS) is a by-product obtained from steel industry. In this study, three phase of concrete specimens were prepared. In first phase, the specimens were prepared using 100% cement with various water-to-cementitious ratios. In second phase, specimens were prepared with varying water-to-cementitious ratios and PA contents ranging from 0 to 20%. Finally, the third phase, specimens were prepared to determine the optimal PA content, with GGBS ranging from 0 to 25%. The mechanical and rheological properties of different proportions of PA and GGBS have been experimentally investigated at 28 days. In addition, the flow ability and packing density of different proportions of PA and GGBS various mixes were tested. The test results revealed that combination of PA and GGBS up to 27% would enhance the fresh and harden properties of cementitious material. The rheological behaviour of optimal PA and GGBS concrete were tested at 28 days using scanning electron microscope (SEM). The results confirmed that the addition of PA and GGBS resulting in a denser, less porous, and more compact CSH microstructure in concrete.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"13 12","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138596632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable Influence Mechanism of TechnologicalInnovation Diffusion on Intelligent Transformationof Manufacturing Enterprises Basedon Competitive Advantage and Value ChainCan Regulate Mediation Effect Analysis 基于竞争优势和价值链的技术创新扩散对制造企业智能化转型的可持续影响机制可调节中介效应分析
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-06 DOI: 10.15244/pjoes/173439
Yanna Yin, Ziwan Zhang, Kening Da, Xin Wen
As the main direction of a new round of industrial technology reform, the intelligent manufacturing industry has become an important trend in the transformation and development of China's manufacturing industry. It provides a new way for manufacturing industry in China to get rid of the low-end position in the global value chain distribution, enhance its competitive advantage, and realize the fundamental reversal from the low-end to the high-end. The continuous realization of intelligent process is inseparable from the innovation and diffusion of intelligent technology. Based on this, the moderated mediation model was constructed to study the sustainable mechanism of technological innovation diffusion on the intelligent transformation of manufacturing enterprises, and the specific path of technological innovation diffusion influencing the intelligent transformation of manufacturing enterprises was clarified, through the rise of value chains under the effect of competitive advantage. Using 257 valid samples of survey data to test the moderating effect model with mediation. The results show that: (1) Technological innovation diffusion has a significantly positive impact on the intelligent transformation of manufacturing enterprises; (2) The climbing of value chains can partially mediate the sustainable mechanism between technological innovation diffusion and intelligent transformation; (3) Competitive advantage plays a moderating role in the process of technological innovation diffusion, influencing value-chain climbing. With the continuous improvement of enterprise competitive advantage, the impact of technological innovation diffusion on the rise of the value chain gradually decreases; (4) The intermediary role of value chain climbing
智能制造业作为新一轮工业技术改革的主旋律,已成为中国制造业转型发展的重要趋势。它为中国制造业摆脱在全球价值链分布中的低端地位,提升竞争优势,实现从低端向高端的根本逆转提供了新的途径。智能过程的不断实现离不开智能技术的创新和扩散。在此基础上,构建有调节的中介模型,研究技术创新扩散对制造企业智能转型的可持续机制,明确技术创新扩散在竞争优势作用下通过价值链上升影响制造企业智能转型的具体路径。采用257份有效调查数据样本,对具有中介作用的调节效应模型进行检验。研究结果表明:(1)技术创新扩散对制造业企业智能转型具有显著的正向影响;(2)价值链的攀升可以部分中介技术创新扩散与智能转型之间的持续机制;(3)竞争优势在技术创新扩散过程中起调节作用,影响价值链攀升。随着企业竞争优势的不断提升,技术创新扩散对价值链上升的影响逐渐减弱;(4)价值链攀升的中介作用
{"title":"Sustainable Influence Mechanism of Technological\u0000Innovation Diffusion on Intelligent Transformation\u0000of Manufacturing Enterprises Based\u0000on Competitive Advantage and Value Chain\u0000Can Regulate Mediation Effect Analysis","authors":"Yanna Yin, Ziwan Zhang, Kening Da, Xin Wen","doi":"10.15244/pjoes/173439","DOIUrl":"https://doi.org/10.15244/pjoes/173439","url":null,"abstract":"As the main direction of a new round of industrial technology reform, the intelligent manufacturing industry has become an important trend in the transformation and development of China's manufacturing industry. It provides a new way for manufacturing industry in China to get rid of the low-end position in the global value chain distribution, enhance its competitive advantage, and realize the fundamental reversal from the low-end to the high-end. The continuous realization of intelligent process is inseparable from the innovation and diffusion of intelligent technology. Based on this, the moderated mediation model was constructed to study the sustainable mechanism of technological innovation diffusion on the intelligent transformation of manufacturing enterprises, and the specific path of technological innovation diffusion influencing the intelligent transformation of manufacturing enterprises was clarified, through the rise of value chains under the effect of competitive advantage. Using 257 valid samples of survey data to test the moderating effect model with mediation. The results show that: (1) Technological innovation diffusion has a significantly positive impact on the intelligent transformation of manufacturing enterprises; (2) The climbing of value chains can partially mediate the sustainable mechanism between technological innovation diffusion and intelligent transformation; (3) Competitive advantage plays a moderating role in the process of technological innovation diffusion, influencing value-chain climbing. With the continuous improvement of enterprise competitive advantage, the impact of technological innovation diffusion on the rise of the value chain gradually decreases; (4) The intermediary role of value chain climbing","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"5 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138597201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the Spatial-Temporal PatternEvolution and Driving Force of EcologicalEnvironment Quality in Kunming CityBased on Remote Sensing EcologicalEnvironment Index in the Past 25 Years 基于近 25 年遥感生态环境指数的昆明市生态环境质量时空格局演变及驱动力研究
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-06 DOI: 10.15244/pjoes/173102
Xue Ding, Xin Shao, Jinliang Wang, Shuangyun Peng, Juncheng Shi
Kunming is the capital city of Yunnan Province and a bridgehead city facing South Asia and Southeast Asia. With the rapid development of Kunming‘s economy and society, the urbanization rate continues to increase, and the quality of the ecological environment in this area is also changing rapidly. How to quickly and accurately obtain the temporal and spatial pattern evolution of Kunming‘s ecological environment quality and explore the driving factors is of great significance to the realization of ecological environmental protection and sustainable development of Kunming. In this paper, the Google Earth Engine (GEE) platform is used to use the long-term Landsat remote sensing image data to mask the water body, extract greenness, dryness, humidity and heat, and construct the remote sensing ecological index RSEI through PCA. Using spatial analysis methods such as cold and hot spot analysis and center of gravity migration to explore the evolution of the spatio-temporal pattern of ecological environment quality in Kunming from 2000 to 2019, and use single-factor analysis and interactive detection in geographic detectors to analyze its internal driving forces. The results show,
昆明是云南省省会,也是面向南亚和东南亚的桥头堡城市。随着昆明经济社会的快速发展,城市化率不断提高,该地区的生态环境质量也在快速变化。如何快速准确地获取昆明市生态环境质量的时空格局演变并探索其驱动因素,对实现昆明生态环境保护和可持续发展具有重要意义。本文利用Google Earth Engine (GEE)平台,利用长期Landsat遥感影像数据对水体进行掩膜,提取水体的绿度、干度、湿度和热量,通过主成分分析法构建遥感生态指数RSEI。利用冷热点分析、重心迁移等空间分析方法,探索2000 - 2019年昆明市生态环境质量时空格局演变,并利用地理探测器中的单因素分析和交互检测分析其内在驱动力。结果表明,
{"title":"Research on the Spatial-Temporal Pattern\u0000Evolution and Driving Force of Ecological\u0000Environment Quality in Kunming City\u0000Based on Remote Sensing Ecological\u0000Environment Index in the Past 25 Years","authors":"Xue Ding, Xin Shao, Jinliang Wang, Shuangyun Peng, Juncheng Shi","doi":"10.15244/pjoes/173102","DOIUrl":"https://doi.org/10.15244/pjoes/173102","url":null,"abstract":"Kunming is the capital city of Yunnan Province and a bridgehead city facing South Asia and Southeast Asia. With the rapid development of Kunming‘s economy and society, the urbanization rate continues to increase, and the quality of the ecological environment in this area is also changing rapidly. How to quickly and accurately obtain the temporal and spatial pattern evolution of Kunming‘s ecological environment quality and explore the driving factors is of great significance to the realization of ecological environmental protection and sustainable development of Kunming. In this paper, the Google Earth Engine (GEE) platform is used to use the long-term Landsat remote sensing image data to mask the water body, extract greenness, dryness, humidity and heat, and construct the remote sensing ecological index RSEI through PCA. Using spatial analysis methods such as cold and hot spot analysis and center of gravity migration to explore the evolution of the spatio-temporal pattern of ecological environment quality in Kunming from 2000 to 2019, and use single-factor analysis and interactive detection in geographic detectors to analyze its internal driving forces. The results show,","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"65 40","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138594752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Drought-Induced Changes in Leaf Morphology and Anatomy: Overview, Implications and Perspectives 干旱引起的叶片形态和解剖学变化:概述、影响和前景
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-06 DOI: 10.15244/pjoes/174476
I. Yavas, Muhammad Asif Jamal, Kaleem Ul Din, Safdar Ali, Saddam Hussain, Muhammad Farooq
The global climate change scenario intensified various environmental factors, especially in arid and semi-arid regions. Drought is one of the most severe environmental stresses affecting plant productivity. Plants in the Mediterranean climate zone are exposed to heat and drought in summer, and these conditions have a significant effect on plant growth and development. However, in this case, the entry of CO 2 into mesophyll cells is prevented and therefore the rate of photosynthesis decreases which ultimately causes a reduction in plant growth. In order to acclimate to stressful environmental conditions, plants exhibit several structural modifications to cope with these harmful conditions. This review highlights some aspects of anatomical adaptive changes in plants under drought stresssuch as a reduction in leaf size and angle, stomatal position, epidermal thickness and deposition of the cuticle to prevent the loss of water from the leaf surface. Furthermore, it elaborates the role of buliform cells in leaf rolling, structural adaptation in the mesophyll cells, and the presence of trichomes. Mesophyll cells and bulliform cells provide easier rolling of leaves in case of intense drought. In arid conditions, the economical use of water by plants is possible by closing the stomata and reducing transpiration.
全球气候变化加剧了各种环境因素,尤其是在干旱和半干旱地区。干旱是影响植物生产力的最严重的环境压力之一。地中海气候区的植物在夏季会受到高温和干旱的影响,这些条件对植物的生长和发育有很大的影响。然而,在这种情况下,二氧化碳进入叶肉细胞受到阻碍,因此光合作用速率下降,最终导致植物生长减弱。为了适应恶劣的环境条件,植物会进行一些结构改造,以应对这些有害的条件。本综述重点介绍了植物在干旱胁迫下发生的一些解剖学适应性变化,如缩小叶片尺寸和角度、气孔位置、表皮厚度和沉积角质层,以防止水分从叶片表面流失。此外,它还阐述了鼓形细胞在叶片卷曲中的作用、叶肉细胞的结构适应以及毛状体的存在。叶肉细胞和鼓形体细胞使叶片在严重干旱时更容易卷曲。在干旱条件下,植物可以通过关闭气孔和减少蒸腾作用来节约用水。
{"title":"Drought-Induced Changes in Leaf Morphology and Anatomy: Overview, Implications and Perspectives","authors":"I. Yavas, Muhammad Asif Jamal, Kaleem Ul Din, Safdar Ali, Saddam Hussain, Muhammad Farooq","doi":"10.15244/pjoes/174476","DOIUrl":"https://doi.org/10.15244/pjoes/174476","url":null,"abstract":"The global climate change scenario intensified various environmental factors, especially in arid and semi-arid regions. Drought is one of the most severe environmental stresses affecting plant productivity. Plants in the Mediterranean climate zone are exposed to heat and drought in summer, and these conditions have a significant effect on plant growth and development. However, in this case, the entry of CO 2 into mesophyll cells is prevented and therefore the rate of photosynthesis decreases which ultimately causes a reduction in plant growth. In order to acclimate to stressful environmental conditions, plants exhibit several structural modifications to cope with these harmful conditions. This review highlights some aspects of anatomical adaptive changes in plants under drought stresssuch as a reduction in leaf size and angle, stomatal position, epidermal thickness and deposition of the cuticle to prevent the loss of water from the leaf surface. Furthermore, it elaborates the role of buliform cells in leaf rolling, structural adaptation in the mesophyll cells, and the presence of trichomes. Mesophyll cells and bulliform cells provide easier rolling of leaves in case of intense drought. In arid conditions, the economical use of water by plants is possible by closing the stomata and reducing transpiration.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"21 2","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139186235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Combinations of Green Roof Substratewith Vegetation Coverage on RainwaterQuality Improvement 屋顶绿化基质与植被覆盖相结合对改善雨水质量的影响
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-04 DOI: 10.15244/pjoes/173116
Xue Hu, Xinyi Song, Shanshan Song, Xiaoyan Li, Cheng Li, Zhi Zhang, Guirong Li, Qiang Chen
The significance of green roofs in stormwater management cannot be overlooked, as they have become an integral component in the creation of sustainable cities. This study not only examined the purifying effects of substrates
绿色屋顶在雨水管理中的重要性不容忽视,因为它们已成为创建可持续城市不可或缺的组成部分。本研究不仅考察了底物的净化作用
{"title":"Effect of Combinations of Green Roof Substrate\u0000with Vegetation Coverage on Rainwater\u0000Quality Improvement","authors":"Xue Hu, Xinyi Song, Shanshan Song, Xiaoyan Li, Cheng Li, Zhi Zhang, Guirong Li, Qiang Chen","doi":"10.15244/pjoes/173116","DOIUrl":"https://doi.org/10.15244/pjoes/173116","url":null,"abstract":"The significance of green roofs in stormwater management cannot be overlooked, as they have become an integral component in the creation of sustainable cities. This study not only examined the purifying effects of substrates","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"84 16","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138604436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mild Acid-Alkali Modification of Ceramsite:a Low-Cost Adsorbent for Lead Removal 轻度酸碱改性陶瓷石:一种低成本的脱铅吸附剂
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-04 DOI: 10.15244/pjoes/173168
Xingbo Yuan, Ziqiu Wang, Chuan Wang
In order to improve the adsorption capacity of waste-based ceramsite, this study proposed to use acid-alkali surface modification to enhance the adsorption capacity of ceramsite for heavy metals. In acid treatment, the ceramsite surface generated a composite pore structure, thus the specific surface area of ceramsite is significantly increased through acid treatment. In alkaline treatment, hydroxyl functional groups were loaded on the surface of the ceramsite, therefore the adsorption capacity for heavy metals was significantly improved. The surface of modified ceramic particles carries a negative charge, which is beneficial for the adsorption of cations. Taking lead ions as an example, the adsorption performance of ceramic particles on heavy metals was tested, and the maximum adsorption capacity reached 33.2 mg/g. Furthermore, the modified ceramic particles exhibit good desorption and regeneration properties. The modified ceramsite offers advantages in terms of raw material sources and production costs compared to natural zeolite.
为了提高废基陶粒的吸附能力,本研究提出采用酸碱表面改性的方法来提高陶粒对重金属的吸附能力。在酸处理下,陶粒表面产生复合孔隙结构,因此经酸处理陶粒的比表面积显著增加。在碱性处理下,陶粒表面负载羟基官能团,对重金属的吸附能力显著提高。改性陶瓷颗粒表面带负电荷,有利于阳离子的吸附。以铅离子为例,测试了陶瓷颗粒对重金属的吸附性能,最大吸附量达到33.2 mg/g。此外,改性后的陶瓷颗粒具有良好的脱附和再生性能。与天然沸石相比,改性陶粒在原料来源和生产成本方面具有优势。
{"title":"Mild Acid-Alkali Modification of Ceramsite:\u0000a Low-Cost Adsorbent for Lead Removal","authors":"Xingbo Yuan, Ziqiu Wang, Chuan Wang","doi":"10.15244/pjoes/173168","DOIUrl":"https://doi.org/10.15244/pjoes/173168","url":null,"abstract":"In order to improve the adsorption capacity of waste-based ceramsite, this study proposed to use acid-alkali surface modification to enhance the adsorption capacity of ceramsite for heavy metals. In acid treatment, the ceramsite surface generated a composite pore structure, thus the specific surface area of ceramsite is significantly increased through acid treatment. In alkaline treatment, hydroxyl functional groups were loaded on the surface of the ceramsite, therefore the adsorption capacity for heavy metals was significantly improved. The surface of modified ceramic particles carries a negative charge, which is beneficial for the adsorption of cations. Taking lead ions as an example, the adsorption performance of ceramic particles on heavy metals was tested, and the maximum adsorption capacity reached 33.2 mg/g. Furthermore, the modified ceramic particles exhibit good desorption and regeneration properties. The modified ceramsite offers advantages in terms of raw material sources and production costs compared to natural zeolite.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"17 12","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138604124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineering Characteristics of UnsaturatedCohesive Foundation Soil at High-Plateau Airportwith Considering the EmbankmentFilling Interval 考虑路堤填筑间隔的高原机场非饱和粘性地基土的工程特性
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-04 DOI: 10.15244/pjoes/173992
Jun Feng, Yanjun Liu, Xiaomei Lu, Zikang Chen, Jian Wu, Jizhe He, Zhuoya Zhao
Most of the foundation soil in airport engineering belongs to unsaturated soil. The subsidence law and stress change rule of unsaturated soil foundation in the filling phase of embankment were analyzed by the software of Midas/GTS. The one-dimensional consolidation theory of unsaturated soil and the Van Genuchten model of soil water characteristics were considered in the programs. The results showed the stress decreased with depth increased and they could be seen as two straight lines. The interval time in filling phase of unsaturated soil had little impact on the stress. The depth-settlement curves had big difference between the overall filling and layered filling that the settlement of layered filling was far greater than the overall filling. In the layered filling, the curves of depth-settlement were similar with different interval time that could be approximately separated into two phases and the largest settlement appeared on the surface of the ground.
机场工程地基土多为非饱和土。利用Midas/GTS软件分析了路基填筑阶段非饱和土地基的沉降规律和应力变化规律。程序考虑了非饱和土一维固结理论和土壤水分特征的Van Genuchten模型。结果表明,应力随深度的增加而减小,呈两条直线。非饱和土充填阶段的间隔时间对应力影响不大。整体充填与分层充填的深度沉降曲线差异较大,分层充填的沉降远大于整体充填。分层充填时,不同间隔时间的深度沉降曲线相似,可近似分为两个阶段,地表沉降最大。
{"title":"Engineering Characteristics of Unsaturated\u0000Cohesive Foundation Soil at High-Plateau Airport\u0000with Considering the Embankment\u0000Filling Interval","authors":"Jun Feng, Yanjun Liu, Xiaomei Lu, Zikang Chen, Jian Wu, Jizhe He, Zhuoya Zhao","doi":"10.15244/pjoes/173992","DOIUrl":"https://doi.org/10.15244/pjoes/173992","url":null,"abstract":"Most of the foundation soil in airport engineering belongs to unsaturated soil. The subsidence law and stress change rule of unsaturated soil foundation in the filling phase of embankment were analyzed by the software of Midas/GTS. The one-dimensional consolidation theory of unsaturated soil and the Van Genuchten model of soil water characteristics were considered in the programs. The results showed the stress decreased with depth increased and they could be seen as two straight lines. The interval time in filling phase of unsaturated soil had little impact on the stress. The depth-settlement curves had big difference between the overall filling and layered filling that the settlement of layered filling was far greater than the overall filling. In the layered filling, the curves of depth-settlement were similar with different interval time that could be approximately separated into two phases and the largest settlement appeared on the surface of the ground.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"68 5","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138604917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Digital Technology and Green TotalFactor Productivity 数字技术和绿色全要素生产率
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-04 DOI: 10.15244/pjoes/172849
Yan Li, Rui Sun, Yitong Rao
Along with the rapid development of digital economy and the urgency of green development, more studies focus on the relationship between digital economy and green development. However, the existing research focuses on the impact of digital economy on green total factor productivity, ignoring digital technology, which is a key technology for improving efficiency to achieve green development. Exploring the impact of digital technologies on green total factor productivity helps to understand the impact of digital economic development on green development from an internal perspective of the digital economy. This paper uses an SBM-GML index to measure regional green total factor productivity based on provincial level data and innovatively constructs digital technology indicators based on micro-level ICT patent data in China. Fixed-effects model is used to study the impact of digital technology on green total factor productivity and moderating model is used to examine the moderating effect of capital accumulation. The results indicate that: (1) At the national level, digital technology is conducive to the improvement of green total factor productivity, and the result passes the robustness test. From a dynamic long-term impact perspective, the effect of digital technology development on green total factor productivity is showing an increasing trend. (2) Digital technology’s effect on green total factor productivity is heterogenous. The results of the subregional heterogeneity analysis indicate that the effect is greater in the coastal regions and southern regions. The results of the heterogeneity analysis of the external environment indicate that the effect is greater in regions with smaller economies, regions with lower external economic dependence, and regions with lower government fiscal intervention. (3) Capital accumulation has moderating effect in the process of digital technology affecting green total factor productivity which will inhibit the improvement of digital technology development on green total factor productivity. Based on the conclusions, to better utilize the role of digital technology in promoting green development, it is necessary for the government to build a digital technology exchange platform, promote the balanced development of digital technology, and expand domestic demand to reduce the dependence on capital accumulation.
随着数字经济的快速发展和绿色发展的迫切性,越来越多的研究关注数字经济与绿色发展的关系。然而,现有的研究主要集中在数字经济对绿色全要素生产率的影响上,忽视了数字技术,而数字技术是提高效率实现绿色发展的关键技术。探讨数字技术对绿色全要素生产率的影响,有助于从数字经济的内部视角理解数字经济发展对绿色发展的影响。本文采用基于省级数据的SBM-GML指数测度区域绿色全要素生产率,创新构建了基于中国微观层面ICT专利数据的数字技术指标。采用固定效应模型研究数字技术对绿色全要素生产率的影响,采用调节效应模型考察资本积累的调节效应。结果表明:(1)在国家层面上,数字技术有利于绿色全要素生产率的提高,且结果通过稳健性检验。从动态长期影响的角度看,数字技术发展对绿色全要素生产率的影响呈增强趋势。(2)数字技术对绿色全要素生产率的影响具有异质性。分区域异质性分析结果表明,沿海地区和南方地区的影响更大。外部环境的异质性分析结果表明,经济规模较小的地区、外部经济依存度较低的地区和政府财政干预程度较低的地区的影响更大。(3)资本积累在数字技术对绿色全要素生产率的影响过程中具有调节作用,会抑制数字技术发展对绿色全要素生产率的提升。综上所述,为了更好地发挥数字技术在促进绿色发展中的作用,政府需要构建数字技术交流平台,促进数字技术的平衡发展,扩大内需以减少对资本积累的依赖。
{"title":"Digital Technology and Green Total\u0000Factor Productivity","authors":"Yan Li, Rui Sun, Yitong Rao","doi":"10.15244/pjoes/172849","DOIUrl":"https://doi.org/10.15244/pjoes/172849","url":null,"abstract":"Along with the rapid development of digital economy and the urgency of green development, more studies focus on the relationship between digital economy and green development. However, the existing research focuses on the impact of digital economy on green total factor productivity, ignoring digital technology, which is a key technology for improving efficiency to achieve green development. Exploring the impact of digital technologies on green total factor productivity helps to understand the impact of digital economic development on green development from an internal perspective of the digital economy. This paper uses an SBM-GML index to measure regional green total factor productivity based on provincial level data and innovatively constructs digital technology indicators based on micro-level ICT patent data in China. Fixed-effects model is used to study the impact of digital technology on green total factor productivity and moderating model is used to examine the moderating effect of capital accumulation. The results indicate that: (1) At the national level, digital technology is conducive to the improvement of green total factor productivity, and the result passes the robustness test. From a dynamic long-term impact perspective, the effect of digital technology development on green total factor productivity is showing an increasing trend. (2) Digital technology’s effect on green total factor productivity is heterogenous. The results of the subregional heterogeneity analysis indicate that the effect is greater in the coastal regions and southern regions. The results of the heterogeneity analysis of the external environment indicate that the effect is greater in regions with smaller economies, regions with lower external economic dependence, and regions with lower government fiscal intervention. (3) Capital accumulation has moderating effect in the process of digital technology affecting green total factor productivity which will inhibit the improvement of digital technology development on green total factor productivity. Based on the conclusions, to better utilize the role of digital technology in promoting green development, it is necessary for the government to build a digital technology exchange platform, promote the balanced development of digital technology, and expand domestic demand to reduce the dependence on capital accumulation.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"17 2","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138601655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strength Characteristic of Unsaturated MoraineSoil at High-plateau Airport 高原机场非饱和碛土的强度特征
IF 1.8 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-04 DOI: 10.15244/pjoes/173994
Jun Feng, Zikang Chen, Jian Wu, Jizhe He, Zhuoya Zhao, Yanjun Liu, Xiaomei Lu
Triaxial tests were performed on samples of unsaturated moraine soil at a high-plateau airport of China by using the unsaturated soil triaxial apparatus. In the tests, the matric suction and net confining pressure were controlled. In the scheme of the tests, the matric suctions were controlled at 0 kPa, 50 kPa, 100 kPa and 200 kPa. The net confining pressures were controlled at 100 kPa, 200 kPa, 300 kPa and 400 kPa. The results showed that for the unsaturated moraine soil, c' and φ ' increase in the matric suction and their growth rates were similar. The relationship between volumetric strain and net confining pressure showed that the specimens were in a state of dilatancy with a small net confining pressure and the amount of dilatancy rapidly decreased and developed into a shear shrinkage state with an increase in net confining pressure. The last amount of shrinkage was stable at approximately 0.6%. Also, the soil suction characteristic curve for the studied soil was obtained by the tests and the suction stress increased with the matric suction.
利用非饱和土三轴仪对高原机场非饱和冰碛土样品进行了三轴试验。试验中对基质吸力和净围压进行了控制。在试验方案中,基质吸力分别控制在0 kPa、50 kPa、100 kPa和200 kPa。净围压分别控制在100 kPa、200 kPa、300 kPa和400 kPa。结果表明:在非饱和冰碛土中,c′和φ′的基质吸力增大,且其增长速率相似;体应变与净围压关系表明,试样在较小的净围压下处于剪胀状态,随着净围压的增大,剪胀量迅速减小,并发展为剪切收缩状态。最后的收缩量稳定在0.6%左右。试验得到了土的吸力特性曲线,吸力应力随基质吸力增大而增大。
{"title":"Strength Characteristic of Unsaturated Moraine\u0000Soil at High-plateau Airport","authors":"Jun Feng, Zikang Chen, Jian Wu, Jizhe He, Zhuoya Zhao, Yanjun Liu, Xiaomei Lu","doi":"10.15244/pjoes/173994","DOIUrl":"https://doi.org/10.15244/pjoes/173994","url":null,"abstract":"Triaxial tests were performed on samples of unsaturated moraine soil at a high-plateau airport of China by using the unsaturated soil triaxial apparatus. In the tests, the matric suction and net confining pressure were controlled. In the scheme of the tests, the matric suctions were controlled at 0 kPa, 50 kPa, 100 kPa and 200 kPa. The net confining pressures were controlled at 100 kPa, 200 kPa, 300 kPa and 400 kPa. The results showed that for the unsaturated moraine soil, c' and φ ' increase in the matric suction and their growth rates were similar. The relationship between volumetric strain and net confining pressure showed that the specimens were in a state of dilatancy with a small net confining pressure and the amount of dilatancy rapidly decreased and developed into a shear shrinkage state with an increase in net confining pressure. The last amount of shrinkage was stable at approximately 0.6%. Also, the soil suction characteristic curve for the studied soil was obtained by the tests and the suction stress increased with the matric suction.","PeriodicalId":20363,"journal":{"name":"Polish Journal of Environmental Studies","volume":"24 4","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138601939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Polish Journal of Environmental Studies
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1