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Nanocrystalline ceria imparts better high–temperature protection 纳米晶二氧化铈提供更好的高温保护
S. Patil, S. Kuiry, S. Seal
Nanomaterials have attracted considerable interest with numerous technological developments in the last decade. Nanomaterials exhibit different physicochemical properties compared with their bulk counterparts because the diameters of the nanoparticles are less than the Bohr exciton radius. Cerium oxide based materials have been extensively studied for various technological applications. In the present study, the application of nanocrystalline cerium oxide for improvement of high–temperature–oxidation resistance of stainless steel has been studied. The role of coating of nanocrystalline cerium oxide towards improvement of high–temperature–oxidation resistance has been investigated and compared with that of the micrometre–sized cerium oxide particles. It was observed that nanocrystalline ceria improved high–temperature–oxidation resistance of AISI 304 stainless steel to a large extent compared with the micrometre–sized ceria coating. Nanocrystalline ceria coating decreased the isothermal parabolic rate constant of oxidation by more than two orders of magnitude compared with that of the bare alloy. The resistance to oxide scale spallation was also found to improve with the coating of cerium oxide nanoparticles. Secondary ion mass spectroscopy (SIMS) study of nanocrystalline ceria–coated and oxidized specimens revealed the presence of nanoceria at the outermost oxide surface, indicating a change in the oxide scale growth mechanism from outward cation diffusion to inward oxygen diffusion in the bare alloy at high temperature in dry air. The oxide scale morphology was studied using a scanning electron microscope (SEM) while a focused ion beam (FIB) technique was used to study the oxide–alloy interface. X–ray photoelectron spectroscopy (XPS) study of nanocrystalline ceria showed the presence of Ce3+ and Ce4+ oxidation states. It is proposed that the presence of the Ce3+ oxidation state in nanocrystalline ceria improves the oxidation resistance of stainless steel, and the related mechanisms are discussed.
在过去的十年中,随着技术的发展,纳米材料引起了人们的极大兴趣。由于纳米粒子的直径小于玻尔激子半径,纳米材料表现出不同于块状材料的物理化学性质。氧化铈基材料在各种技术应用方面得到了广泛的研究。本文研究了纳米晶氧化铈在提高不锈钢耐高温氧化性能中的应用。研究了纳米氧化铈涂层对提高其耐高温氧化性能的作用,并与微米级氧化铈涂层进行了比较。结果表明,纳米晶氧化铈与微米级氧化铈涂层相比,在很大程度上提高了AISI 304不锈钢的耐高温氧化性能。纳米晶氧化铈涂层使氧化等温抛物线速率常数比裸合金降低了两个数量级以上。纳米氧化铈涂层也提高了材料抗氧化垢剥落的能力。通过二次离子质谱(SIMS)研究纳米晶氧化铈包覆和氧化试样,发现氧化表面最外层存在纳米铈,表明在干燥空气高温下,裸露合金中氧化垢的生长机制由向外的阳离子扩散转变为向内的氧扩散。利用扫描电子显微镜(SEM)研究了氧化膜的形貌,利用聚焦离子束(FIB)技术研究了氧化膜与合金界面的形貌。x射线光电子能谱(XPS)研究表明纳米晶铈存在Ce3+和Ce4+氧化态。提出纳米晶铈中Ce3+氧化态的存在提高了不锈钢的抗氧化性,并讨论了相关机理。
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引用次数: 54
Review Paper. A survey of mathematical finance 评审论文。数学金融学概览
D. Hobson
Finance is one of the fastest growing areas in mathematics. In some senses it is not a discipline in its own right, but rather an application area in which mathematicians with backgrounds in probability theory, statistics, optimal control, convex and functional analysis and partial differential equations can bring to bear experiences and results from their own fields to problems of real world interest. In this survey we begin with the simplest possible financial model, and then give an account of the Black–Scholes option pricing formula, in which the key ideas are the replication of option pay–offs and pricing under the risk–neutral measure. Then we move on to discuss other important problems in finance, including the general theory for semi–martingale price processes, pricing in incomplete markets, interest–rate models and credit risk. The emphasis is on techniques and methodologies from stochastic processes.
金融是数学中发展最快的领域之一。从某种意义上说,它本身并不是一门学科,而是一个应用领域,在这个领域中,具有概率论、统计学、最优控制、凸分析和泛函分析以及偏微分方程背景的数学家可以将他们自己领域的经验和结果带到现实世界中感兴趣的问题上。在本次调查中,我们从最简单的金融模型开始,然后给出了布莱克-斯科尔斯期权定价公式的说明,其中的关键思想是期权支付的复制和风险中性措施下的定价。然后我们继续讨论金融中的其他重要问题,包括半鞅价格过程的一般理论,不完全市场的定价,利率模型和信用风险。重点是随机过程的技术和方法。
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引用次数: 13
Compositional convection in the presence of a magnetic field. I. A single interface 有磁场存在的成分对流。一、单一接口
I. Eltayeb, E. A. Hamza, J. Jervase, E. Krishnan, D. Loper
We investigate the stability of a vertical interface separating two semi–infinite fluids with differing composition of light material and permeated by a magnetic field. Both fluids possess finite kinematic viscosity, ν, thermal diffusivity, κ, magnetic diffusivity, η, and negligible material diffusion. The stability depends on six dimensionless parameters: the Prandtl number, σ (where σ = ν/ κ), the magnetic Prandtl number, σm = ν/η, the Chandrasekhar number, Qc, the Reynolds number, Re, and the ratios, Bv, Γ of the vertical and normal components to the lateral component of field. A comprehensive study of the dependence of the stability on the parameters is made when Re is small. The presence of a horizontal magnetic field tends to reduce the growth rate of the non–magnetic modes and can also give rise to new modes of instability. The addition of a vertical component of field can completely counteract the stabilizing influence of the horizontal component. For field strengths in excess of some value dependent on σ, σm and Bv, the non–magnetic unstable mode is replaced by one of two magnetic modes, one of which is a roll aligned with the field and the other inclined to it. The helicity and α–effect of the small–scale unstable motions are also discussed.
我们研究了两种不同轻物质组成的半无限流体在磁场作用下的垂直界面的稳定性。两种流体都具有有限的运动粘度、ν、热扩散系数、κ、磁扩散系数、η和可忽略的物质扩散。稳定性取决于6个无量纲参数:普朗特数σ(其中σ = ν/ κ)、磁普朗特数σm = ν/η、钱德拉塞卡数Qc、雷诺数Re以及垂直分量和法向分量与场横向分量之比Bv Γ。在Re较小时,全面研究了稳定性对参数的依赖关系。水平磁场的存在往往会降低非磁性模态的增长率,也会产生新的不稳定模态。增加垂直分量的场可以完全抵消水平分量的稳定作用。当磁场强度超过与σ、σm和Bv有关的某一值时,非磁性不稳定模式被两种磁性模式中的一种所取代,其中一种是与磁场成直线的辊,另一种是与磁场倾斜的辊。讨论了小尺度不稳定运动的螺旋度和α -效应。
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引用次数: 16
Oblique scattering of plane flexural–gravity waves by heterogeneities in sea–ice 海冰非均质性对平面弯曲重力波的斜散射
T. Williams, V. Squire
Ocean waves propagating beneath a sea–ice sheet encounter a variety of inhomogeneities, which normally arise because of the dynamic nature of the ice veneer over large physical scales. Zones of thinner, thicker, rougher or ridged ice, changes of material property, and abrupt transitions into and from open water, for example, each have their own distinctive scattering kernel that modifies the incoming wave energy spectrum as it progresses further into the ice cover. Here we present a theoretical analysis of wave propagation beneath sea–ice, where the ice is allowed to vary spatially. Isolated irregularities such as pressure ridges, rafted regions, ice islands that have become trapped in the sea–ice, open and refrozen leads, etc., are considered, as well as groups of such features, with their peripheries either welded to the surrounding ice sheet or separated from it by a free crack. Reflection and transmission coefficients, plotted as functions of wave period or wavelength, reveal considerable fine structure, including in some cases a comb of wave frequencies at which perfect transmission occurs. The work generalizes and extends work by Squire & Dixon, Williams & Squire and Evans & Porter, which all deal with abrupt transitions, to properly allow for inhomogeneity in the ice cover. For the multiple, randomly shaped, oriented and spaced irregularities observed in a real ice sheet, good agreement is found between the full solution, a wide–spacing approximation that neglects the evanescent parts of the wave field in subsequent interactions, and a simple serial approach where interactions between features are neglected and the effect of each irregularity is computed in sequence.
在冰盖下传播的海浪遇到了各种各样的不均匀性,这通常是由于大物理尺度上冰盖的动态性质造成的。例如,更薄、更厚、更粗糙或脊状冰的区域,物质性质的变化,以及进入和离开开阔水域的突然转变,每一个都有自己独特的散射核,当入射波进一步进入冰盖时,散射核会改变入射波的能谱。在这里,我们提出了一个理论分析,在海冰下,波的传播是允许空间变化的。孤立的不规则现象,如压力脊、漂流区、被困在海冰中的冰岛、开放和重新冻结的铅等,以及这些特征的群体,它们的外围要么与周围的冰盖焊接在一起,要么被自由裂缝与冰盖分离。以波周期或波长的函数表示的反射和透射系数揭示了相当精细的结构,包括在某些情况下出现完美透射的梳状波频率。这项工作概括和扩展了Squire & Dixon, Williams & Squire和Evans & Porter的工作,这些工作都处理突变,以适当地考虑冰盖的不均匀性。对于在真实冰盖中观测到的多种、随机形状、定向和间隔的不规则性,在完整解、忽略波场在随后相互作用中消失部分的宽间距近似和忽略特征之间相互作用并按顺序计算每个不规则性影响的简单串行方法之间发现了很好的一致性。
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引用次数: 50
Thermal cook–off response of confined PBX 9501 受限PBX 9501的热熄火响应
P. Dickson, B. Asay, B. Henson, L. Smilowitz
The thermal cook–off response of energetic materials (ignition resulting from direct, bulk thermal heating) is important from a safety point of view, but also challenges our understanding of these materials. Explosives are not designed to be cooked off, and, especially in the case of slow cook–off, by the time the material ignites it is substantially different, both chemically and physically, from its original state. In attempting to model such a process numerically, it has generally been assumed that combustion proceeds, from an ignition point, in a more or less planar manner, as has been observed many times in pristine energetic materials at room temperature. To investigate directly the spread of reaction following cook–off in one such energetic material (PBX 9501), small discs of PBX 9501 were heated with a confining glass or sapphire window through which the early stages of the combustion process could be observed directly by high–speed photography. The resulting combustion was found to vary with temperature of ignition, but in all cases was quite different to the laminar burn model. The results of these tests are presented, together with some possible explanations of the behaviour and discussion of the implications to modelling this response.
从安全的角度来看,含能材料的热烧退反应(由直接、大量热加热引起的点火)很重要,但也挑战了我们对这些材料的理解。炸药不是被设计用来煮掉的,尤其是在缓慢煮掉的情况下,当材料被点燃时,它在化学上和物理上都与原始状态有很大的不同。在试图对这一过程进行数值模拟时,通常假设燃烧从一个着火点开始,以或多或少的平面方式进行,正如在室温下的原始含能材料中多次观察到的那样。为了直接研究一种含能材料(PBX 9501)燃烧后反应的扩散,我们用一个封闭玻璃或蓝宝石窗加热PBX 9501的小圆盘,通过高速摄影可以直接观察到燃烧过程的早期阶段。结果发现,燃烧随著着火温度的变化而变化,但在所有情况下都与层流燃烧模型有很大不同。提出了这些测试的结果,以及对这种行为的一些可能的解释,并讨论了对这种反应建模的影响。
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引用次数: 33
Second–order multivalued stochastic differential equations on Riemannian manifolds 黎曼流形上的二阶多值随机微分方程
F. Bernardin, M. Schatzman, C. Lamarque
The existence and uniqueness of solutions to multivalued stochastic differential equations of the second order on Riemannian manifolds are proved. The class of problem is motivated by rigid body and multibody dynamics with friction and an application to the spherical pendulum with friction is presented.
证明了黎曼流形上二阶多值随机微分方程解的存在唯一性。这类问题是由刚体和多体摩擦动力学驱动的,并给出了一个在有摩擦的球摆上的应用。
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引用次数: 7
On the boundary–layer equations for power–law fluids 幂律流体边界层方程的研究
J. Denier, P. Dabrowski
We reconsider the problem of the boundary–layer flow of a non-Newtonian fluid whose constitutive law is given by the classical Ostwald–de Waele power–law model. The boundary–layer equations are solved in similarity form. The resulting similarity solutions for shear–thickening fluids are shown to have a finite–width crisis resulting in the prediction of a finite–width boundary layer. A secondary viscous adjustment layer is required in order to smooth out the solution and to ensure correct matching with the far–field boundary conditions. In the case of shear–thinning fluids, the similarity forms have solutions whose decay into the far field is strongly algebraic. Smooth matching between these inner algebraically decaying solutions and an outer uniform flow is achieved via the introduction of a viscous diffusion layer.
我们重新考虑了本构律由经典Ostwald-de Waele幂律模型给出的非牛顿流体的边界层流动问题。边界层方程以相似形式求解。所得到的剪切增稠流体的相似解具有有限宽度危机,从而导致有限宽度边界层的预测。为了使解平滑并保证与远场边界条件的正确匹配,需要一个二次粘性调整层。在剪切变薄流体的情况下,相似形式的解在远场的衰减是强代数的。通过引入粘性扩散层,实现了这些内部代数衰变解与外部均匀流之间的平滑匹配。
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引用次数: 91
Structure of boundary blow-up for higher-order quasilinear parabolic equations 高阶拟线性抛物型方程的边界爆破结构
V. Galaktionov, A. Shishkov
Singularity formation phenomena for 2mth–order quasilinear parabolic equations are studied by using energy estimates related to Saint–Venant's principle. Sharp estimates of propagation of singularities generated by boundary global and regional blow-up regimes are established.
利用与圣维南原理相关的能量估计,研究了二阶拟线性抛物方程的奇点形成现象。建立了由边界、全局和区域爆炸机制产生的奇点传播的尖锐估计。
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引用次数: 17
Review Paper. Characterization and stability of two–phase piecewise–homogeneous deformations 评审论文。两相分段均匀变形的表征与稳定性
Yibin Fu, A. Freidin
Many solid materials exhibit stress–induced phase transformations. Such phenomena can be modelled with the aid of the nonlinear elasticity theory with appropriate choices of the strain–energy function. It is known that if a two–phase deformation (with gradient F) in a finite elastic body is a local energy minimizer, then given any point p of the surface of discontinuity, the piecewise–homogeneous deformation corresponding to the two values F±(p) of F(p) is a global energy minimizer. Thus, instability of the latter state would imply instability of the former state. In this paper we investigate the stability properties of such piecewise–homogeneous deformations. More precisely, we are concerned with two joined half–spaces that correspond to two different phases of the same material. We first show how such a two–phase deformation can be constructed. Then the stability of the piecewise–homogeneous deformation is investigated with the aid of two test criteria. One is a kinetic stability criterion based on a quasi–static approach and on the growth/decay behaviour of the interface in the undeformed configuration when it is perturbed; the other, referred to as the energy criterion, is used to determine whether the deformation is a minimizer of the total energy with respect to perturbations of the interface in both the current and undeformed configurations. We clarify the differences between the two criteria, and provide a compact formula which can be used to establish the stability/instability of any two–phase piecewise–homogeneous deformations.
许多固体材料表现出应力引起的相变。这种现象可以借助非线性弹性理论进行建模,并适当选择应变-能函数。已知,如果有限弹性体的两相变形(梯度为F)是局部能量最小值,则给定不连续曲面的任意点p,则F(p)的两个值F±(p)对应的分段均匀变形是全局能量最小值。因此,后一种状态的不稳定意味着前一种状态的不稳定。本文研究了这类分段均匀变形的稳定性。更准确地说,我们关注的是两个连接在一起的半空间,它们对应于同一材料的两个不同相。我们首先展示了如何构造这样的两相变形。在此基础上,采用两种试验准则对分段均匀变形的稳定性进行了研究。一种是基于准静态方法的动力学稳定性判据,该判据基于受扰动时界面在未变形构型中的生长/衰减行为;另一种称为能量准则,用于确定在当前和未变形构型中,相对于界面的扰动,变形是否是总能量的最小值。我们澄清了两个标准之间的差异,并提供了一个紧凑的公式,可用于建立任何两相分段均匀变形的稳定性/不稳定性。
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引用次数: 48
Buckling of a critically tapered rod: properties of some global branches of solutions 临界锥杆的屈曲:解的一些整体分支的性质
C. Stuart, G. Vuillaume
This paper, which is a continuation of C. A. Stuart & G. Vuillaume (2003 Proc. R. Soc. Lond. A459, 1863–1889), is concerned with the study of the buckling of a tapered rod. This physical phenomenon leads to the nonlinear eigenvalue problem: {A(s)u'(s)}'+μsinu(s)=0s∈(0,1), u(1)= lim s→0 A(s)u'(s)=0 ∫ 0 1 A(s)u' (s) 2 ds <∞, where A(s) ε C([0,1]) is such that A(s) > 0 for all s > 0 and lims→0A(s)/sp = L for some constants p ⩾ 0 and L ε (0,∞). We deal with the critical case p= 2 and study the set of all the solutions of the problem. In Stuart & Vuillaume (2003) and under additional assumptions on A, we found a set of points {μi , i ε I ⫅ N* ={1,2,3,...}} ⊂ R+ such that a global branch of non–trivial solutions emanates from each μi , iε I. In this paper, we provide more detailed information about these global branches of solutions.
本文是C. a . Stuart & G. Vuillaume (2003 Proc. R. Soc)的延续。Lond。A459, 1863-1889),是关于锥形棒的屈曲的研究。这种物理现象导致非线性特征值问题:{A(s)u'(s)}'+μsinu(s)=0s∈(0,1),u(1)= lims→0A(s) u'(s)=0∫1 A(s)u'(s) 2 ds 0对于所有s > 0和lims→0A(s)/sp = L对于某些常数p大于或等于0和L ε(0,∞)。我们处理了临界情况p= 2,并研究了问题所有解的集合。在Stuart & Vuillaume(2003)中,在A的附加假设下,我们发现了点{μi, i ε i⫅N* ={1,2,3,…}}∧R+使得非平凡解的全局分支从每个μi, ε i中发散出来,在本文中,我们提供了关于这些解的全局分支的更详细的信息。
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引用次数: 12
期刊
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
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