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Graphene Reinforced Copper Matrix Nano-Composite for Resistance Seam Welding Electrode 石墨烯增强铜基纳米复合材料用于电阻缝焊条
Pub Date : 2021-08-01 DOI: 10.21608/TIMS.2021.191623
N. S. Mansour, H. M. Yehia, A. Ali
Five samples contain 0, 1.2, 1.4, 1.6, and 1.8 wt. % graphene (GNs) were prepared by the powder metallurgy technique. The 20 (WC-TiC-Co) wt. %, 5wt. %Ni, and the different weight percentages of the graphene (GNs) were coated by copper by the electroless coating process. The effect of the GNs on the density, hardness, compressive strength, and thermal expansion was studied. The microstructure revealed an excellent distribution for the different reinforcements and good adhesion between them. The results indicate that the hardness and the compressive resistance were significantly improved. These improvements were attributed to the remarkable mechanical and physical properties of the GNs. The thermal expansion was decreased by increasing the GNs content.
采用粉末冶金技术制备了石墨烯(GNs)含量分别为0、1.2、1.4、1.6和1.8 wt. %的5种样品。20 (WC-TiC-Co) wt. %, 5wt. %。采用化学镀铜的方法,在%Ni和不同重量百分比的石墨烯(GNs)表面镀上一层铜。研究了GNs对合金密度、硬度、抗压强度和热膨胀率的影响。显微组织显示,不同增强剂分布良好,增强剂之间具有良好的粘结性。结果表明,合金的硬度和抗压性能均有显著提高。这些改进归功于GNs卓越的机械和物理性能。随着GNs含量的增加,热膨胀率降低。
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引用次数: 2
A Comparative Study between Rhadophyta And Phyophta on Biosorption of U and Th. 横纹草和植藻对U和Th的生物吸收比较研究。
Pub Date : 2021-08-01 DOI: 10.21608/tims.2021.191717
N. Gad, J. Samaan
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引用次数: 0
Reoxidation of Direct Reduced Iron in Stagnant Air in The Temperature Range between 150 and 450°C. 直接还原铁在静止空气中150 ~ 450℃范围内的再氧化。
Pub Date : 2021-08-01 DOI: 10.21608/tims.2021.191719
S. S. Abd Elmomen
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引用次数: 2
Effect of the Pouring Temperature on Microstructure and Tensile Properties of A356 Aluminum Alloy via Semisolid Casting using Slope Cooling Plate. 浇注温度对倾斜冷却板半固态铸造A356铝合金组织和拉伸性能的影响
Pub Date : 2021-08-01 DOI: 10.21608/tims.2021.191363
W. Mabrouk, M. Moussa, S. Abdelwahab, A. Ali
The cooling slope casting process has gained significant importance for the manufacturing of semisolid feedstock aluminum alloys, which find applications in the automotive and aerospace industries. The effect of the pouring temperatures on the microstructure of A356 aluminum alloy via semisolid casting using the slope cooling plate has been investigated. The prepared alloy that becomes semisolid at the end of the cooling slope plate is consequently poured into a sand mold. Without using the slope cooling plate, the α-Al phases became coarse dendritic structure with an average length of about 287.5 μm. In case of using the slope cooling plate at the optimum pouring temperature of 640°C, The α-Al phase developed a fine globular structure with the average grain size of about 72.6 μm. The tensile properties of the investigated A356 alloy were improved by the application of semisolid casting at the optimum pouring temperature of 640°C. The ultimate tensile strength and the elongation of the investigated alloy significantly increased from 102 MPa and 1.175% without semisolid casting to 113 MPa and 3.6 % with semisolid casting at the optimum pouring temperature of 640°C, respectively then gradually decreased with further increasing the pouring temperature. The fracture mechanism has been also investigated.
冷却斜坡铸造工艺对于制造半固态原料铝合金具有重要意义,在汽车和航空航天工业中得到了应用。研究了倾斜冷却板半固态铸造A356铝合金的浇注温度对组织的影响。所制备的合金在冷却坡板的末端变成半固态,然后将其倒入砂型中。在不使用坡面冷却板的情况下,α-Al相变为粗枝晶结构,平均长度约为287.5 μm。在最佳浇注温度为640℃时,采用倾斜冷却板浇注时,α-Al相形成细小的球状组织,平均晶粒尺寸约为72.6 μm。在最佳浇注温度为640℃的条件下,采用半固态铸造工艺提高了A356合金的拉伸性能。在最佳浇注温度为640℃时,合金的极限抗拉强度和伸长率分别从未采用半固态铸造时的102 MPa和1.175%显著提高到采用半固态铸造时的113 MPa和3.6%,然后随着浇注温度的进一步升高逐渐降低。对断裂机理也进行了研究。
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引用次数: 0
Recovery of Some Valuable Elements from Highly Ferruginous Shale, Um Bogma Formation, Wadi Um Hamed, South Western Sinai, Egypt. 埃及西奈半岛西南部Wadi Um Hamed Um Bogma组高铁页岩中一些有价元素的回收
Pub Date : 2021-08-01 DOI: 10.21608/tims.2021.191718
H. A. Radwan, A. Faheim, E. El-Sheikh, Z. A. Abd El‐Wahab, M. Gado
The present work describes a study of the acidic pug leaching technique for Uextraction in addition to some associated valuable metals from a collected technological sample of ferruginous shale from Wadi Um Hamed of Um Bogma Formation at Abu Thor locality of southwestern Sinai, Egypt. A representative sample of the ore material was found to assay 900, 700 and 400 ppm of REEs, U and Cu, respectively in addition to some major and minor oxides. Numerous steps were perform upon the studied sample to process parametric studies like sulfuric acid concentration (50-150 kg/ton), curing time (0.5-5.0 h) and curing temperature (50150°C) in order to assess the best one giving the optimum conditions. Under the optimal conditions (150 kg/ton sulfuric acid for 4.0 h at 150°C), the first step involved Fe-removal as hydroxide from the pregnant leaching solution using pH adjustment method followed by Urecovery through sorption / desorption and precipitation steps with the help of Amberlite IRA400-Cl (strongly basic anion exchange resin) via column method. In the third step, REEsrecovery from Ufree effluent was investigated using oxalic acid precipitation process while Curecovery by precipitation as hydroxide with ammonia solution was tack place.
本文描述了从埃及西奈西南部Abu Thor地区的Um Bogma组的Wadi Um Hamed组的含铁页岩中收集的技术样品中提取Uextraction的酸性pug浸出技术以及一些相关的有价金属的研究。在该矿石的代表性样品中,除了一些主要和次要的氧化物外,稀土、铀和铜的含量分别为900、700和400 ppm。对所研究的样品进行了许多步骤,以处理参数研究,如硫酸浓度(50-150 kg/吨),固化时间(0.5-5.0 h)和固化温度(50150°C),以评估给出最佳条件的最佳方案。在最佳条件下(150 kg/t硫酸,150°C, 4.0 h),第一步是通过pH调节法将fe作为氢氧化物从浸出液中去除,然后通过柱法在Amberlite IRA400-Cl(强碱性阴离子交换树脂)的帮助下通过吸附/解吸和沉淀步骤回收u。第三步,采用草酸沉淀法对Ufree出水进行res回收,同时采用氢氧化物与氨溶液沉淀法对cu进行回收。
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引用次数: 0
Preparation of Highly Pure Y2O3 from Rees Concentrate of Gabal El-Faliq Granitoid Rocks, South Eastern Desert, Egypt. 从埃及东南部沙漠Gabal El-Faliq花岗岩中提取稀土精矿制备高纯Y2O3
Pub Date : 2019-01-01 DOI: 10.21608/tims.2019.189874
D. Zaki
The present work aims to study the processing characteristics of the geologic ore material under consideration to prepare leach liquor suitable for the recovery of highly pure Y oxide concentrate. Ammonium sulfate roasting method was applied upon the study geologic ore material and selectively recovers 88.6% of total REEs. Several roasting parameters were investigated to optimize the selective dissolution of REEs. Since, from the foregoing results, it can be concluded that, the maximum dissolution efficiency, % of REEs from Gabal (G.) El-Faliq ore material by roasting with (NHR4R)R2RSOR4R was conducted at Solid/Reagent ratio: 1/2, Roasting time: 2 hrs. and Roasting temperature: 600°C. From the latter, 91% of Y content from prepared RE(NOR3R)R3R solution using 2M TBP, has been recovered at pH of 1.5 by using 2M of TBP / Kerosene for 9 min. as contact time and O/A ratio of 1/1. More than 98% of the loaded Y was regenerated using 3M HR2RSOR4R at A/O ratio of 2/1 and contact time of 25 min. From the latter, highly pure YR2ROR3 Rwas prepared after oxalate precipitation.
本文旨在研究地质矿石的选矿特性,制备出适合回收高纯氧化钇精矿的浸出液。采用硫酸铵焙烧法对研究地质矿石进行焙烧,选择性地回收了88.6%的稀土元素。研究了几种焙烧参数,以优化稀土的选择性溶解。由于,从上述结果可以得出结论,从Gabal (G.)中获得的ree的最大溶解效率为%。采用(NHR4R)R2RSOR4R焙烧El-Faliq矿石,料剂比为1/2,焙烧时间为2h。烘烤温度:600°C。用2M TBP /煤油在pH = 1.5条件下,以2M TBP /煤油为接触时间9 min, O/A比为1/1,可回收制备的RE(NOR3R)R3R溶液中91%的Y含量。在A/O比为2/1、接触时间为25 min的条件下,利用3M HR2RSOR4R再生负载Y的98%以上。后者经草酸盐沉淀制备出高纯度的yr2ror3r。
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引用次数: 0
Relationship between the Uranium Concentration and the Upgrading of El-Sibaeya Phosphate Ore by New Physical Processes. 铀浓度与El-Sibaeya磷矿新物理工艺提质的关系
Pub Date : 2019-01-01 DOI: 10.21608/tims.2019.191204
A. A. El-Shennawy
Phosphate plays a significant economic role in developing countries because the phosphate rock is consumed in the agricultural sector as fertilizers and animal feedstocks as well as used in the manufacture of high-grade phosphoric acid used in the manufacture used in pharmaceuticals, detergents, food products and other industrial uses. So, this research focus is represented in how to apply some new physical concentration processes derived from ore dressing to arise the concentration of P2O5 (21.14%) in sample of 10 Kg of low grade Egyptian phosphate ore was collected from East El-Sibaeya region as an alternative method to the existing calcination method, which is not friendly environment and has several disadvantages and accordingly the find relationship between the uranium concentration and the upgrading of El-Sibaeya phosphate ore. Upgrading the phosphate ore is done through crushing, screening, up current Classifiers, gravimetric separation and hydraulic separation. The results of this study led to achieve the desired product (high grade of phosphate) which is imperative to meeting market requirements, and at optimum conditions gave a product which analyzed P2O5 (33.63%), CaO (47.66%), MgO (0.57%), SiO2 (4.91%), NaO2 (0.49%), K2O (0.89%), Al2O3 (0.64%), Fe2O3 (1.25%) and U (172.12 ppm).
磷酸盐在发展中国家起着重要的经济作用,因为磷矿在农业部门被用作肥料和动物饲料,以及用于制造用于制药、洗涤剂、食品和其他工业用途的高级磷酸。因此,本文的研究重点是如何应用选矿产生的一些新的物理富集工艺来提高从East El-Sibaeya地区收集的10 Kg低品位埃及磷矿样品中P2O5的浓度(21.14%),作为现有煅烧法的替代方法。通过对El-Sibaeya磷矿进行破碎、筛分、上流分级机、重选、水力选别等工序对磷矿进行选别。在最佳条件下,得到了P2O5(33.63%)、CaO(47.66%)、MgO(0.57%)、SiO2(4.91%)、NaO2(0.49%)、K2O(0.89%)、Al2O3(0.64%)、Fe2O3(1.25%)和U (172.12 ppm)的分析产物。
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引用次数: 0
Purification of Lanthanum Oxide by Magnetic Nano-Composite Alginate Beads after Its Concentration from Acidic Monazite Leach Liquor. 磁性纳米复合海藻酸微球富集氧化镧对酸性独居石浸出液的净化作用。
Pub Date : 2019-01-01 DOI: 10.21608/tims.2019.189866
A. A. Abd El-Fatah
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引用次数: 1
Selective Precipitation of Yttrium From Monazite Acid Leach Liquor by Using Carbonates Precipitation Method. 碳酸盐沉淀法选择性沉淀独居石酸浸液中的钇。
Pub Date : 2019-01-01 DOI: 10.21608/tims.2019.190142
M. El-awady, A. Abd-elfatah, S. M. Abd-Elwahab, A. H. Mahmoud, O. Helaly
Rare earth elements (REE) solubility with carbonate salts vary greatly from element to element. The heavy rare earth elements (HRE) being more soluble than the light rare earth elements. Their solubility is a function of the carbonate concentration and the kind of carbonate as sodium, potassium and ammonium. In this work, it is explored the ability of the carbonate for the precipitation of the REE and an easy separation of yttrium was achieved using sodium carbonate to form complex yttrium carbonate followed by oxalic acid precipitation. Form this work REEs concentrate containing (%) 1.8 YR2ROR3R, 1.6 GdR2ROR3R, 23.4 CeOR2R, 7.6 NdR2ROR3R, 11.4 LaR2ROR3R, 2.3 SmR2ROR3R, 0.8 EuR2ROR3R and 3.1 PrR6ROR11R, where the mentioned concentrate was produced after the acid treatment of monazite mineral followed by dissolution with ice water. The produced solution was precipitated with sodium carbonate followed by dissolution in hydrochloric acid and precipitation using oxalic acid to produce yttrium concentrate containing 54.86% YR2ROR3,R 15.53% CeOR2,R 15.29% LaR2ROR3R and 6.90% NdR2ROR3R.
稀土元素(REE)在碳酸盐中的溶解度因元素而异。重稀土元素(HRE)比轻稀土元素更易溶解。它们的溶解度是碳酸盐浓度和钠、钾、铵等碳酸盐种类的函数。本文探讨了碳酸盐对稀土元素的沉淀能力,并利用碳酸钠形成络合物碳酸钇,然后进行草酸沉淀,实现了钇的容易分离。本文的稀土精矿中含有(%)1.8 YR2ROR3R, 1.6 GdR2ROR3R, 23.4 CeOR2R, 7.6 NdR2ROR3R, 11.4 LaR2ROR3R, 2.3 SmR2ROR3R, 0.8 EuR2ROR3R和3.1 PrR6ROR11R,其中所述精矿是在单氮石矿物酸处理后,用冰水溶解得到的。所得溶液用碳酸钠沉淀,盐酸溶解,草酸沉淀,得到YR2ROR3含量为54.86%,CeOR2含量为15.53%,LaR2ROR3R含量为15.29%,NdR2ROR3R含量为6.90%的钇精矿。
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引用次数: 1
Effect of Direct Reduced Iron on Ferrous Oxide Capacity of Slag in Electric Arc Furnace. 直接还原铁对电弧炉炉渣氧化亚铁容量的影响。
Pub Date : 2019-01-01 DOI: 10.21608/tims.2019.191206
H. Abdelwahed, M. Shaheen, G. Megahed, E. Ahmed, M. Meraikib
Slag and the corresponding hot metal samples were collected just before tapping from electric arc furnace of Ezz Flat Steel Company (EFS) and analyzed. The temperature of hot metal was measured before tapping. The analyses of slag and hot metal together with the metal temperature were used to estimate the activity coefficient and activity of total ferrous oxides in slag, also investigate carbon and oxygen activity coefficient in steel according to the statistical theory of regular ionic solutions. The oxides capacity of the slag was also assessed. The variation of carbon and oxygen activity in hot metal with the concentration was also treated. The ratio of activity to concentration of total ferrous oxides is constant and equal to 0.0179. The activity coefficients of oxygen and carbon in steel are 0.810 and 1.0704, respectively. The oxides capacity of the slag increases with increasing carbon concentration in the bath and with increasing DRI proportion in the charge.
对鄂西扁钢公司电弧炉出渣前的炉渣及相应的铁水试样进行了分析。在攻丝前测量了热金属的温度。通过对炉渣和铁水的分析,结合金属温度,估算了炉渣中总氧化亚铁的活度系数和活度,并根据规则离子溶液的统计理论研究了钢中的碳、氧活度系数。并对渣的氧化物容量进行了评价。研究了金属热中碳氧活性随浓度的变化规律。总氧化亚铁的活度与浓度之比是恒定的,等于0.0179。钢中氧和碳的活度系数分别为0.810和1.0704。渣的氧化物容量随熔池中碳浓度的增加和炉料中DRI比例的增加而增加。
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引用次数: 0
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The Bulletin Tabbin Institute for Metallurgical Studies (TIMS)
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