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Optimization of Slag Content and Properties Improvement of Metakaolin-slag Geopolymer Mixes 偏高岭土-矿渣混合料掺渣量优化及性能改善
Pub Date : 2018-07-31 DOI: 10.2174/1874088X01812010040
M. Zawrah, R. A. Gado, R. Khattab
Geopolymers mixes were fabricated from Metakaolin (MK) and Blast Furnace Slag (BFS) waste material in the presence of sodium hydroxide and sodium silicate which were used as alkali activators. To optimize the suitable amount of slag, eleven batches were designed, mixed and homogenized for 30 min.To determine the suitable amount of liquid required for pasting, normal consistency and setting time were determined. The physico-mechanical properties at different curing agesi.e. 3, 7, 28 and 90 days, were determined. X-ray diffraction and scanning electron microscope were used to investigate phase composition and microstructure.To guarantee forming geopolymer gel and to check its amount, HCl extraction test was performed. Salicylic acid/methanol extraction was also performed to verify the presence and amount of Calcium Silicate Hydrate (CSH). The results revealed that calcium-rich slag (BFS) accelerated the hardening process and decreased the alkaline liquid consistency. For geopolymer without BFS, two phases, namely; un-reacted metakaolin and geopolymer gel were formed. For geopolymers with BFS, three phases were formed, namely; un-reacted metakaolin, geopolymer gel and CSH with aluminum substitution (CASH) gel. The bulk density was increased with increasing BFS and curing time. The strength was increased with increasing of BFS, reaching its maximum (about 120 MPa) for the specimen containing 70% slag, cured for 28 days.
以偏高岭土(MK)和高炉渣(BFS)为原料,在氢氧化钠和硅酸钠作为碱活化剂的条件下制备地聚合物混合物。为优化矿渣的适宜用量,设计了11个矿渣批次,进行了搅拌和均质,搅拌时间为30 min。为确定膏体所需的适宜液量,确定了正常稠度和凝结时间。不同龄期下的物理力学性能。3、7、28、90 d。采用x射线衍射和扫描电镜对其相组成和显微组织进行了研究。为保证地聚合物凝胶的形成并检验其含量,进行了盐酸萃取试验。用水杨酸/甲醇萃取法验证水合硅酸钙(CSH)的存在和含量。结果表明,富钙渣加速了钢渣的硬化过程,降低了碱液浓度。对于不含BFS的地聚合物,有两相,即;未反应的偏高岭土和地聚合物凝胶形成。对于含BFS的地聚合物,形成了三个相,即;未反应偏高岭土、地聚合物凝胶和CSH与铝取代(CASH)凝胶。堆积密度随BFS的增加和固化时间的延长而增大。强度随BFS的增加而增加,当含矿渣量为70%时,固化28 d强度最大,约为120 MPa。
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引用次数: 25
Corrosion Inhibition of Mild Steel in 1.0 M HCl Solution by Anhydrous Tricalcium Phosphate 无水磷酸三钙对低碳钢在1.0 M HCl溶液中的缓蚀作用
Pub Date : 2018-07-31 DOI: 10.2174/1874088X01812010068
L. Chafki, E. Rifi, R. Touir, M. Touhami, Z. Hatim
In this study, electrochemical measurements were used to characterize Anhydrous Tricalcium Phosphate (ATP) as a corrosion inhibitor for mild steel in 1.0 M HCl. The potentiodynamic polarization curves indicated that the ATP reacts as an anodic type inhibitor. In addition, it has been found that the electrochemical impedance confirms the inhibitor character of ATP obtained by the potentiodynamic polarization curves where the inhibition efficiency increases by its concentration to reach a maximum of 93.79 % at 10-4 M. The temperature solution influence indicated that the corrosion rate increases with temperature while the inhibitor acts actively. Thermodynamic adsorption and activation parameters indicated that the ATP acts by physical adsorption on the metallic surface with an endothermic process of metal dissolution. Additionally, it was found that the adsorption of ATP molecules obeyed to the Langmuir isotherm. Surface analyses via scanning electron microscopy (SEM) was used to investigate the morphology of mild steel before and after immersion in 1.0 M HCl solution without and with 10-4 M of ATP. It is revealed that the ATP  acted by the formation of a protective layer on the mild steel.
在这项研究中,电化学测量用于表征无水磷酸三钙(ATP)在1.0 M HCl中作为低碳钢的缓蚀剂。电位极化曲线表明ATP作为阳极型抑制剂发生反应。此外,电化学阻抗证实了电位极化曲线得到的ATP的缓蚀特性,缓蚀效率随其浓度的增加而增加,在10-4 m时达到最大值93.79%。热力学吸附和活化参数表明,ATP在金属表面发生物理吸附,并伴有金属溶解的吸热过程。此外,还发现ATP分子的吸附服从Langmuir等温线。通过扫描电镜(SEM)研究了低碳钢在1.0 M不含ATP和10-4 M含ATP的HCl溶液中浸泡前后的形貌。结果表明,ATP在低碳钢表面形成一层保护层。
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引用次数: 5
Effect oF β-Alanine on The Preparation of 4-Ethoxy-Cinnamic Acid β-丙氨酸对制备4-乙氧基肉桂酸的影响
Pub Date : 2018-07-31 DOI: 10.2174/1874088X01812010058
Nguyen To Hoai, T. Ngoc, N. Nam, T. T. Thuy, C. Trang, N. D. Hai, T. K. Nguyen
Cinnamic acid and its derivatives have a numerous potential applications in many different fields such as pharmacy, organic “building blocks”, and corrosion inhibitors.It is well-known that Verley-Doebner modification is a high efficient method for the preparation of cinnamic acid derivaties, especially with the compounds containing electron-donating subtituents at para position in aromatic ring. In this paper, 4-ethoxy-cinnamic acid was synthesized according to Verley-Doebner reaction with the use of pyrine acting as catalyst and solvent. The effect of the β-alanine concentration on the conversion of the starting material of 4-ethoxy-benzaldehyde was thoroughly investigated using high performance liquid chromatography. The results showed that consuming of 8% of β-alanine would convert 100% of 4-ethoxy-benzaldehyde to 4-ethoxy-cinnamic acid.The structure of the obtained 4-ethoxy-cinnamic acid was also confirmed using Fourier transform infrared spectroscopy, Raman spectroscopy, and Gas chromatography-Mass spectroscopy.Cinnamic acid and its derivatives have numerous potential applications in many different fields such as pharmacy, organic “building blocks”, and corrosion inhibitors. It is well-known that Verley-Doebner modification is a high efficient method for the preparation of cinnamic acid derivaties, especially with the compounds containing electron-donating subtituents at para position in aromatic ring. In this paper, 4-ethoxy-cinnamic acid was synthesized according to Verley-Doebner reaction with the use of pyrine acting as catalyst and solvent. The effect of the β-alanine concentration on the conversion of the starting material of 4-ethoxy-benzaldehyde was thoroughly investigated using high performance liquid chromatography. The results showed that consuming 8% of β-alanine would convert 100% of 4-ethoxy-benzaldehyde to 4-ethoxy-cinnamic acid. The structure of the obtained 4-ethoxy-cinnamic acid was also confirmed using Fourier transform infrared spectroscopy, Raman spectroscopy, and Gas chromatography-Mass spectroscopy.
肉桂酸及其衍生物在许多不同的领域有许多潜在的应用,如制药、有机“构建块”和腐蚀抑制剂。众所周知,Verley-Doebner修饰是制备肉桂酸衍生物的一种高效方法,特别是在芳香环对位上含有给电子取代基的化合物。本文以吡啶为催化剂和溶剂,采用Verley-Doebner反应合成了4-乙氧基肉桂酸。采用高效液相色谱法研究了β-丙氨酸浓度对原料4-乙氧基苯甲醛转化的影响。结果表明,当β-丙氨酸用量为8%时,4-乙氧基苯甲醛可100%转化为4-乙氧基肉桂酸。用傅里叶变换红外光谱、拉曼光谱、气相色谱-质谱等方法对合成的4-乙氧基肉桂酸进行了结构表征。肉桂酸及其衍生物在许多不同的领域有许多潜在的应用,如制药、有机“构建块”和腐蚀抑制剂。众所周知,Verley-Doebner修饰是制备肉桂酸衍生物的一种高效方法,特别是在芳香环对位上含有给电子取代基的化合物。本文以吡啶为催化剂和溶剂,采用Verley-Doebner反应合成了4-乙氧基肉桂酸。采用高效液相色谱法研究了β-丙氨酸浓度对原料4-乙氧基苯甲醛转化的影响。结果表明,当β-丙氨酸用量为8%时,4-乙氧基苯甲醛可100%转化为4-乙氧基肉桂酸。用傅里叶变换红外光谱、拉曼光谱、气相色谱-质谱等方法对合成的4-乙氧基肉桂酸进行了结构表征。
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引用次数: 3
Novel Approach to The Design of Sound Insulating Composites by Means of a Non-linearly Extrapolated Master Curve 用非线性外推主曲线设计隔音复合材料的新方法
Pub Date : 2018-06-29 DOI: 10.2174/1874088X01812010014
Cecchini Federico, Cherubini Valeria, F. Fabbrocino, F. Nanni
Received: April 19, 2018 Revised: May 23, 2018 Accepted: June 02, 2018 Abstract: Background: The increasing use of composite structures with a high stiffness-to-weight ratio in commercial vehicles has brought about a reduction in fuel consumption but, on the other hand, has significantly increased noise transmission particularly in case of thin and lightweight structures. Noise is a primary issue for commercial vehicles, such as airplanes, helicopters and cars. The present research deals with the use of smart materials, as Shear-Thickening Fluids (STF, or dilatants) in view of manufacturing elements with increased sound insulation properties.
摘要:背景:商用车中越来越多地使用高刚度重量比的复合材料结构,这不仅降低了油耗,但另一方面,也显著增加了噪音的传递,尤其是在薄而轻的结构中。噪音是商用交通工具的主要问题,如飞机、直升机和汽车。目前的研究涉及智能材料的使用,如剪切增稠流体(STF,或膨胀剂),以增加隔音性能的制造元件。
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引用次数: 2
Process Optimization for the Synthesis of Silver (AgNPs), Iron Oxide (α-Fe2O3NPs) and Core-Shell (Ag-Fe2O3CNPs) Nanoparticles Using the Aqueous Extract of Alstonia Scholaris: A Greener Approach Alstonia Scholaris水提物合成银(AgNPs)、氧化铁(α-Fe2O3NPs)和核壳(Ag-Fe2O3CNPs)纳米粒子的工艺优化:绿色途径
Pub Date : 2018-06-29 DOI: 10.2174/1874088X01812010029
N. Shimpi, Mujahid S. Khan, Sharda Shirole, S. Sonawane
RESEARCH ARTICLE Process Optimization for the Synthesis of Silver (AgNPs), Iron Oxide (α-Fe2O3NPs) and Core-Shell (Ag-Fe2O3CNPs) Nanoparticles Using the Aqueous Extract of Alstonia Scholaris: A Greener Approach Navinchandra G. Shimpi, Mujahid Khan, Sharda Shirole and Shriram Sonawane Department of Chemistry, University of Mumbai, Sant Cruz (E) 400 098, India University Institute of Chemical Technology, North Maharashtra University, Jalgaon, India Department of Chemical Engineering Visvesvaraya National Institute of Technolog, Nagpur
研究论文:用金耳草水提液合成银(AgNPs)、氧化铁(α-Fe2O3NPs)和核壳(Ag-Fe2O3CNPs)纳米粒子的工艺优化Navinchandra G. Shimpi, Mujahid Khan, Sharda Shirole和Shriram Sonawane孟买大学化学系,圣克鲁兹(E) 400 098,印度大学化学技术研究所,北马哈拉施特拉邦大学,Jalgaon,印度,那格浦尔,Visvesvaraya国家理工学院化学工程系
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引用次数: 7
Crystallographic Features and Nature of Luminescence Centres of the Niobate and Tantalate Compounds with Layered Perovskite-Like Structure 具有层状钙钛矿结构的铌酸盐和钽酸盐化合物的晶体学特征和发光中心性质
Pub Date : 2018-02-28 DOI: 10.2174/1874088X01812010002
O. Chukova, S. Nedilko, Y. Titov, V. Sheludko
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引用次数: 3
Annual Review 2018 of Open Materials Science 开放材料科学2018年度综述
Pub Date : 2018-02-28 DOI: 10.2174/1874088X01812010001
N. Allen
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引用次数: 0
Research on Carrier Correlation in Ballistic Transport Nano-MOSFETs 弹道输运纳米mosfet的载流子相关研究
Pub Date : 2017-09-22 DOI: 10.2174/1874088X01711010038
Xiaofei Jia, Liang He
In this paper,the experiment proved that shot noise is suppressed by Fermi and Coulomb interaction correlation. Meanwhile, the establishment of shot noise suppression factor (Fano) in ballistic transport nano-MOSFETs the Coulomb interaction correlation and the combination of the two effects are derived from separately considering the Fermi interaction correlation. And on this basis the variation of Fano with voltage, doping concentration and temperature are investigated.
实验证明了弹丸噪声被费米和库仑相互作用的关联所抑制。同时,分别考虑费米相互作用的相关性,推导了弹射噪声抑制因子(Fano)在弹道输运纳米mosfet中库仑相互作用的相关性以及两者的组合效应。在此基础上,研究了Fano随电压、掺杂浓度和温度的变化规律。
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引用次数: 0
Corrosion Behavior of Plasma Nitrided SS316L Biomaterial 等离子体氮化SS316L生物材料的腐蚀行为
Pub Date : 2017-07-31 DOI: 10.2174/1874088X01711010029
R. Kartikasari, Sutrisna, I. Aziz
Methods: The plasma nitriding process on the surface of SS316L was performed at 350oC, 400oC, 450oC, 500oC, 550oC and 1.8 mbar nitrogen gas pressure for 3 hours. The surface Nitrogen concentration level distribution from the surface was examined using Energy Dispersive X-ray Spectroscopy, the phases formed after nitriding process were determined using X-ray Diffraction. The corrosion resistance was investigated using three-electrode cell polarization method.
方法:在350℃、400℃、450℃、500℃、550℃、1.8 mbar的氮气压力下,对SS316L表面进行等离子渗氮处理3小时。利用能量色散x射线光谱分析了表面氮的浓度水平分布,利用x射线衍射测定了渗氮后形成的相。采用三电极电池极化法对其耐腐蚀性能进行了研究。
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引用次数: 4
Preparation and Physical Performance of Green Poly(L-lactic acid) Composition by Blending with Starch 绿色聚l -乳酸与淀粉共混复合材料的制备及其物理性能
Pub Date : 2017-07-31 DOI: 10.2174/1874088X01711010022
Yan-Hua Cai, Q. Zheng, Wenjing Guo
To develop more green polymer composites and further know the performance of green composites, the composites based on green poly(L-lactic acid) (PLLA) and starch were fabricated by a counter-rotating mixer. And effect of starch on the fluidity and nucleating performance of PLLA was investigated using melt index instrument, optical depolarizer and wide angle X-ray diffraction instrument, respectively.
为了开发更多的绿色高分子复合材料,进一步了解绿色高分子复合材料的性能,采用反向旋转混合机制备了绿色聚l -乳酸(PLLA)和淀粉复合材料。利用熔融指数仪、光学去偏振仪和广角x射线衍射仪分别研究了淀粉对聚乳酸流动性和成核性能的影响。
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引用次数: 0
期刊
The Open Materials Science Journal
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