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Failure Analysis of a Reduction Furnace Heat Resistant Roll 还原炉耐热辊失效分析
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c9001712
R. Milner
A failure analysis was conducted in late 1996 on two rolls that had been used in the production of iron and steel powder. The rolls had elongated over their length such that the roll trunnions had impacted with the furnace wall refractory. The result was distortion and bowing of the roll bodies which necessitated their removal from service. The initial analysis found large quantities of nitrogen had been absorbed by the roll shell. Further research indicated nitrogen pickup accounted for 3% volumetric growth for every 1% by weight nitrogen absorption. This expansion was sufficient to account for the dimensional change observed in the failed rolls. This paper details the failure analysis and resulting research it inspired. It also provides recommendations for cast material choice in highly nitriding atmospheres.
1996年年底,对用于生产钢铁粉末的两台轧辊进行了故障分析。轧辊的长度被拉长,使得轧辊耳轴与炉壁耐火材料发生碰撞。其结果是轧辊体的变形和弯曲,这就需要将其从服务中移除。初步分析发现,大量的氮气已被轧辊壳吸收。进一步的研究表明,每1%的重量氮吸收,吸氮量就会增加3%的体积。这种膨胀足以解释在失效轧辊中观察到的尺寸变化。本文详细介绍了失效分析和由此产生的研究启发。它还提供了在高氮化气氛下铸造材料选择的建议。
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引用次数: 0
Intergranular Corrosion of a Type 304 Stainless Steel Fused-Salt Pot Due to Sensitization 304型不锈钢熔盐罐因敏化引起的晶间腐蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0046476
A fused-salt electrolytic-cell pot containing a molten eutectic mixture of sodium, potassium, and lithium chlorides and operating at melt temperatures from 500 to 650 deg C (930 to 1200 deg F) exhibited excessive corrosion after two months of service. The pot was a welded cylinder with 3-mm thick type 304 stainless steel walls and was about 305 mm (12 in.) in height and diam. Analysis (visual inspection and 500x micrographs etched with CuCl2) supported the conclusions that the pot failed by intergranular corrosion because an unstabilized austenitic stainless steel containing more than 0.03% carbon had been sensitized and placed in contact in service with a corrosive medium at temperatures in the sensitizing range. Recommendations included changing material for the pot from type 304 stainless steel to Hastelloy N (70Ni-17Mo-7Cr-5Fe). Maximum corrosion resistance and ductility are developed in Hastelloy N when the alloy is solution heat treated at 1120 deg C (2050 deg F) and is either quenched in water or rapidly cooled in air. An alternative, but less suitable, material for the pot was type 347 (stabilized grade) stainless steel. After welding, the 347 should be stress relieved at 900 deg C (1650 deg F) for 2 h and rapidly cooled to minimize residual stresses.
一个含有钠、钾和锂氯化物的熔融共晶混合物的熔盐电解槽,在500至650摄氏度(930至1200华氏度)的熔体温度下工作两个月后,出现了严重的腐蚀。锅是一个焊接的圆柱体,壁厚3毫米,304型不锈钢,高度和直径约305毫米(12英寸)。分析(目视检查和500倍CuCl2蚀刻显微照片)支持这样的结论:锅是由于晶间腐蚀而失效的,因为含有0.03%以上碳的不稳定奥氏体不锈钢被敏化了,并在敏化范围内的温度下与腐蚀介质接触。建议包括将锅的材料从304型不锈钢改为哈氏合金N (70Ni-17Mo-7Cr-5Fe)。当哈氏合金在1120℃(2050°F)进行固溶热处理,在水中淬火或在空气中快速冷却时,其耐腐蚀性和延展性达到最大。另一种不太合适的材料是347型(稳定级)不锈钢。焊接后,347应在900摄氏度(1650华氏度)下进行2小时的应力释放,并迅速冷却以减少残余应力。
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引用次数: 0
Liquid Erosion of Hydraulic Dynamometer Stator Vanes 水力测功机定子叶片的液体侵蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0046422
Stator vanes (cast from a Cu-Mn-Al alloy) in a hydraulic dynamometer used in a steam-turbine test facility were severely eroded. The dynamometer was designed to absorb up to 51 MW (69,000 hp) at 3670 rpm, and constituted an extrapolation of previous design practices and experience. Its stator was subject to severe erosion after relatively short operating times and initially required replacement after each test program. Although up to 60 cu cm (3.7 cu in.) of material was being lost from each vane, it only reduced the power-absorption capacity by a small amount. Analysis supported the conclusion that the damage was due to liquid erosion, but it could not be firmly established whether it was caused by cavitation or by liquid impact. Recommendations included making a material substitution (to Mo-13Cr-4Ni stainless steel) and doing a redesign to reduce susceptibility to erosion as well as erosion-producing conditions.
汽轮机试验用水力测功机定子叶片(铜锰铝合金铸造)腐蚀严重。该测功机在3670 rpm的转速下可吸收高达51 MW (69,000 hp)的功率,是对以往设计实践和经验的推断。它的定子在相对较短的运行时间后受到严重侵蚀,并且在每次测试程序后最初都需要更换。虽然每个叶片的材料损失高达60立方厘米(3.7立方英寸),但它只降低了一小部分的功率吸收能力。分析支持了损伤是由液体侵蚀造成的结论,但无法确定是由空化还是液体冲击造成的。建议包括进行材料替代(Mo-13Cr-4Ni不锈钢),并进行重新设计,以减少对侵蚀的敏感性以及产生侵蚀的条件。
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引用次数: 0
Low-Cycle Thermal Fatigue Failure of a Type 304 Stainless Steel Tee Fitting 304型不锈钢三通接头的低循环热疲劳失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0048361
Several failures occurred in 64-mm schedule 80 type 304 stainless steel (ASME SA-312, grade TP304) piping in a steam-plant heat-exchanger system near tee fittings at which cool water returning from the heat exchanger was combined with hot water from a bypass. Various portions of the piping were subjected to temperatures ranging from 29 to 288 deg C. Each of the failures were revealed to consist of transgranular cracking in and/or close to the circumferential butt weld joining the tee fitting to the downstream pipe leg, where the hot bypass water mixed with the cool return water. The transgranular cracks suggested that thermal fatigue was a more likely cause of failure than SCC. It was concluded by temperature measurements that circumferential temperature gradients, in combination with inadequate flexibility in the piping system as a whole, had caused the failures. The tee fitting was redesigned to alleviate the thermal stress pattern.
在蒸汽装置热交换器系统的三通接头附近,从热交换器返回的冷水与从旁路返回的热水相结合的64毫米表80型304不锈钢(ASME SA-312,等级TP304)管道发生了几次故障。管道的各个部分承受的温度从29℃到288℃不等,每个故障都是在三通接头与下游管腿的周向对接焊缝处或附近发生穿晶裂纹,在那里热旁通水与冷回水混合。穿晶裂纹表明,热疲劳是比SCC更可能的失效原因。通过温度测量得出结论,周向温度梯度以及整个管道系统的灵活性不足是导致故障的原因。t恤配件经过重新设计,以减轻热应力模式。
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引用次数: 0
Failure of a Buried Type 304L Stainless Steel Drain Line by Galvanic Attack 埋地304L型不锈钢排水管道因电蚀而失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0046535
One of five underground drain lines intended to carry a highly acidic effluent from a chemical-processing plant to distant holding tanks failed in just a few months. Each line was made of 304L stainless steel pipe 73 mm (2 in.) in diam with a 5 mm (0.203 in.) wall thickness. Lengths of pipe were joined by shielded metal arc welding. Soundness of the welded joints was determined by water back-pressure testing after several lengths of pipe had been installed and joined. Before completion of the pipeline, a pressure drop was observed during back-pressure testing. An extreme depression in the backfill revealed the site of failure. Analysis (visual inspection, electrical conductivity, and soil analysis) supported the conclusions that the failure had resulted from galvanic corrosion at a point where the corrosivity of the soil was substantially greater than the average, resulting in a voltage decrease near the point of failure of about 1.3 to 1.7 V. Recommendations included that the pipelines be asphalt coated and enclosed in a concrete trough with a concrete cover. Also, magnesium anodes, connected electrically to each line, should be installed at periodic intervals along their entire length to provide cathodic protection.
五条地下排水管中的一条在短短几个月内就发生了故障,该管道原本打算将一种高酸性废水从一家化学加工厂输送到遥远的储存罐。每条线由直径73毫米(2英寸)的304L不锈钢管制成,壁厚5毫米(0.203英寸)。管道的长度由保护金属弧焊连接。在安装和连接几段管道后,通过水反压试验确定了焊接接头的可靠性。在管道完工之前,在背压测试中观察到压力下降。回填体上的一个极端凹陷显示了失败的地点。分析(目视检查、电导率和土壤分析)支持这样的结论,即故障是由电腐蚀引起的,在土壤的腐蚀性大大大于平均值,导致故障点附近的电压下降约1.3至1.7 V。建议包括将管道涂上沥青,并将其封闭在带有混凝土盖板的混凝土槽中。此外,镁阳极,电连接到每条线路,应定期安装沿其整个长度提供阴极保护。
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引用次数: 0
Torsional-Fatigue Fracture of a Large 4340 Steel Shaft That Was Subject to Cyclic Loading and Frequent Overloads 4340大型钢轴在循环载荷和频繁超载作用下的扭转疲劳断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0091096
A 4340 steel shaft, the driving member of a large rotor subject to cyclic loading and frequent overloads, broke after three weeks of operation. The driving shaft contained a shear groove at which the shaft should break if a sudden high overload occurred, thus preventing damage to an expensive gear mechanism. The rotor was subjected to severe chatter, which was an abnormal condition resulting from a series of continuous small overloads occurring at a frequency of around three per second. Investigation (visual inspection, hardness testing, and hot acid etch images) supported the conclusion that the basic failure mechanism was fracture by torsional fatigue, which started at numerous surface shear cracks, both longitudinal and transverse, that developed in the periphery of the root of the shear groove. These shear cracks resulted from high peak loads caused by chatter. The shear groove in the shaft had performed its function, but at a lower overload level than intended. Recommendations included increasing the fatigue strength of the shaft by shot peening the shear groove to minimize chatter.
4340钢轴是大型转子的驱动部件,由于循环载荷和频繁过载,在运行三周后断裂。传动轴包含一个剪切槽,如果突然发生高过载,轴应在此断裂,从而防止损坏昂贵的齿轮机构。转子受到严重的颤振,这是一种由一系列连续的小过载引起的异常情况,频率约为每秒3次。调查(目视检查、硬度测试和热酸腐蚀图像)支持这样的结论,即基本的破坏机制是由扭转疲劳断裂,扭转疲劳开始于许多纵向和横向的表面剪切裂纹,这些剪切裂纹在剪切槽根部的周围发展起来。这些剪切裂纹是由颤振引起的峰值荷载引起的。轴上的剪切槽发挥了其作用,但其过载水平低于预期。建议包括通过喷丸强化剪切槽来增加轴的疲劳强度,以减少颤振。
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引用次数: 0
Crevice Corrosion on Stainless Steel Tube 不锈钢管的缝隙腐蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0091336
A type 304 austenitic stainless steel tube (0.008 max C, 18.00 to 20.00 Cr, 2.00 max Mn, 8.00 to 10.50 Ni) was found to be corroded. The tube was part of a piping system, not yet placed in service, that was exposed to an outdoor marine environment containing chlorides. As part of the assembly, a fabric bag containing palladium oxide was taped to the tube. The palladium served as a “getter.” Investigation (visual inspection and EDS analysis of corrosion debris) supported the conclusion that chlorides and palladium both contributed to corrosion in the crevice created by the tape on the tube, which was periodically exposed to water. Recommendations included taking steps to prevent water from entering and being trapped in this area of the assembly.
发现304型奥氏体不锈钢管(0.008 max C, 18.00 ~ 20.00 Cr, 2.00 max Mn, 8.00 ~ 10.50 Ni)被腐蚀。该管道是管道系统的一部分,尚未投入使用,暴露在含有氯化物的室外海洋环境中。作为组装的一部分,一个含有氧化钯的布袋被粘在管子上。钯起到“吸气剂”的作用。调查(目视检查和腐蚀碎片的EDS分析)支持这样的结论:氯化物和钯都导致了管道上的胶带形成的裂缝腐蚀,管道定期暴露在水中。建议包括采取措施防止水进入和被困在大会的这个区域。
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引用次数: 0
Corroded Pump Impeller 泵叶轮腐蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c9001165
F. Naumann, F. Spies
After operating for six months, a pump impeller (of nickel-containing cast iron) showed considerable corrosion. Cross sections showed substantial penetration of the wall thickness without loss of material. The observed supercooled structure implied low strength but would not affect corrosion resistance. Etching of the core structure showed a selective form of cast iron corrosion (spongiosis or graphitic corrosion) which lowered the strength of the cast iron enough that a knife could scrape off a black powder (10.85% C, 1.8% S, 1.45% P). Analysis showed that some of the “sulfate” found in the scrubbing water was actually sulfide (including hydrogen sulfide) and was the main cause of corrosion.
泵叶轮(含镍铸铁)运行6个月后,出现了相当大的腐蚀。横截面显示了大量的壁厚穿透而没有损失材料。观察到的过冷结构意味着低强度,但不影响耐蚀性。核心结构的蚀刻显示出一种选择性的铸铁腐蚀形式(海海绵腐蚀或石墨腐蚀),这种腐蚀降低了铸铁的强度,足以用刀刮掉黑色粉末(10.85% C, 1.8% S, 1.45% P)。分析表明,在洗涤水中发现的一些“硫酸盐”实际上是硫化物(包括硫化氢),是腐蚀的主要原因。
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引用次数: 0
Ductile Fracture of a Forged Steel Shaft at a Change in Section and at a Stainless Steel Weld 锻钢轴在截面变化和不锈钢焊缝处的韧性断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0047879
The stub-shaft assembly which was part of the agitator shaft in a polyvinyl chloride reactor, fractured in service after a nut that retained a loose sleeve around the smaller-diam section of the shaft had been tightened several times to reduce leakage. The shaft was made of ASTM A105, grade 2 steel, and the larger-diam section was covered with a type 316 stainless steel end cap. The cap was welded to each end using type ER316 stainless steel filler metal. The forged steel shaft was revealed to have fractured at approximately 90 deg to the shaft axis in the weld metal and not in the heat-affected zone of the forged steel shaft. Microscopic investigation and chemical analysis of the steel shaft revealed presence of martensite (offered a path of easy crack propagation) around the fusion line and dilution of the weld metal by the carbon steel shaft. The microstructure was found to be martensitic as the fusion line was approached. The forged steel shaft was concluded to have failed by ductile fracture and possible reasons were discussed. Corrective measures adopted in the replacement shaft were specified.
聚氯乙烯反应器搅拌轴的短轴组件在使用过程中发生断裂,原因是为了减少泄漏,在短轴的小直径部分上拧紧了一根螺母,该螺母保留了一个松散的套筒。轴由ASTM A105 2级钢制成,直径较大的部分覆盖有316型不锈钢端盖。端盖焊接到每端使用ER316型不锈钢填充金属。锻钢轴在焊接金属中与轴轴约90度处断裂,而不是在锻钢轴的热影响区断裂。钢轴的显微检查和化学分析表明,在熔合线周围存在马氏体(提供了一个容易裂纹扩展的路径),并且碳钢轴对焊缝金属的稀释。接近熔合线时,组织为马氏体。认为锻钢轴是由韧性断裂造成的,并对可能的原因进行了讨论。对更换轴所采取的纠正措施进行了说明。
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引用次数: 0
Cavitation Erosion of a Water-Cooled Aluminum Alloy 6061-T6 Combustion Chamber 6061-T6水冷铝合金燃烧室的空化腐蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.modes.c0046418
Equipment in which an assembly of in-line cylindrical components rotated in water at 1040 rpm displayed excessive vibration after less than one hour of operation. The malfunction was traced to an aluminum alloy 6061-T6 combustion chamber that was part of the rotating assembly. Analysis (visual inspection, 100x/500x/800x micrographic examination, spectrographic analysis, and hardness testing) supported the conclusions that, as a result of improper heat treatment, the combustion-chamber material was too soft for successful use in this application. Misalignment of the combustion chamber and one or both of the mating parts resulted in eccentric rotation and the excessive vibration that caused malfunction of the assembly. Irregularities in the housing around the combustion chamber and temperature variation relating to the combustion pattern in the chamber were considered to be possible contributing factors to localization of the cavitation erosion. Recommendations included adopting inspection procedures to ensure that the specified properties of aluminum alloy 6061-T6 were obtained and that the combustion chamber and adjacent components were aligned within specified tolerances. In a similar situation, consideration should also be given to raising the pressure in the coolant in order to suppress the formation of cavitation bubbles.
设备在水中以1040转/分的速度旋转,在运行不到一小时后显示过度振动。故障被追溯到6061-T6铝合金燃烧室,该燃烧室是旋转组件的一部分。分析(目视检查,100倍/500倍/800倍显微检查,光谱分析和硬度测试)支持以下结论:由于热处理不当,燃烧室材料太软,无法成功用于此应用。燃烧室和一个或两个配合部件的不对中导致偏心旋转和过度振动,导致组件故障。燃烧室周围外壳的不规则性以及与燃烧室燃烧模式相关的温度变化被认为是导致空化侵蚀局部化的可能因素。建议包括采用检查程序,以确保获得6061-T6铝合金的规定性能,并确保燃烧室和邻近部件在规定的公差范围内对齐。在类似的情况下,还应考虑提高冷却液中的压力,以抑制空化气泡的形成。
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引用次数: 0
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ASM Failure Analysis Case Histories: Failure Modes and Mechanisms
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