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Metabasites along the Lunvozh river (Middle Timan): petrography, mineralogy, petrochemistry 伦沃日河(中提曼河)沿岸的玄武岩:岩石学、矿物学、岩石化学
Pub Date : 2023-12-08 DOI: 10.19110/geov.2023.10.3
A. Shmakova
A small dike of unknown age was found on the territory of the Kanin-Timan region within the Middle Timan along the Lunvozh river. Our studies revealed that the rocks, composing this intrusive body, corresponded to basaltic andesites according to the content of the main rock-forming elements. They were almost completely recrystallized and composed of chlorite (30—40 %), carbonates (25—40 %), albite (10—15 %), quartz (10—15 %), muscovite (5—8 %) and plagioclase (less than 1 %). Accessory minerals were represented by apatite, monazite and rutile. Ore minerals included pyrite, chalcopyrite, and cobaltine. According to the mineral composition and petrochemical characteristics, the rocks composing the dike body along the Lunvozh river, differed from the basites of the Middle Riphean Middle Timan and Devonian Kanin-Timan complexes identified in the Kanin-Timan region.
在中提曼地区的卡宁-提曼地区,沿着伦沃日河,发现了一个年代不详的小堤坝。根据主要造岩元素的含量分析表明,构成该侵入体的岩石属于玄武岩安山岩。它们几乎完全重结晶,由绿泥石(30 - 40%)、碳酸盐(25 - 40%)、钠长石(10 - 15%)、石英(10 - 15%)、白云母(5 - 8%)和斜长石(不到1%)组成。副矿物以磷灰石、独居石和金红石为代表。矿石矿物包括黄铁矿、黄铜矿和钴矿。根据矿物组成和石油化学特征,构成Lunvozh河沿岸脉体的岩石与卡宁-提曼地区识别的中日番-中提曼和泥盆系卡宁-提曼杂岩的基底不同。
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引用次数: 0
The peculiarities of the framboidal pyrites of the Mikheev porphyry copper deposit (Southern Ural) 米赫耶夫斑岩铜矿床(南乌拉尔)框架黄铁矿的特殊性
Pub Date : 2023-12-06 DOI: 10.19110/geov.2023.9.2
Lyubov' Leonova, O. Azovskova, E. Soroka
Framboids of pyrite were found in bituminized argillic metasomatites of the Mikheev porphyry copper deposit (Southern Urals). A wide occurrence manifestation of low-temperature metasomatism — argillization — is a feature of the rock complex of this deposit. According to the results of thermoweight analysis, the values of organic matter in bituminized argillic metasomatites correspond to kerite. The organic matter support the habitation of microbial communities, including the presence of element-depositing bacteria. The use of high-resolution scanning electron microscopy allowed identifing preserved mineralized biofilms and accumulations of extracellular biopolymers, including seeds of forming pyrites. Such morphological features suggest on a bacteria formation of the framboidal pyrites of the argillizites of the Mikheev deposit.
在南乌拉尔米赫耶夫斑岩铜矿床的沥青化泥质交代岩中发现了黄铁矿的树状体。低温交代—泥化作用是该矿床岩石杂岩的一大特征。热重分析结果表明,沥青化泥质交代岩有机质值与干酪石相对应。有机物支持微生物群落的生存,包括元素沉积细菌的存在。使用高分辨率扫描电子显微镜可以识别保存的矿化生物膜和细胞外生物聚合物的积累,包括形成黄铁矿的种子。这些形态特征表明,米赫耶夫矿床泥质岩的草莓状黄铁矿是由细菌形成的。
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引用次数: 0
Geochemistry of organic matter of natural bitumen in the section of the Kozhva river (Timan-Pechora province) 科日瓦河段(季曼-佩乔拉省)天然沥青有机物地球化学
Pub Date : 2023-12-06 DOI: 10.19110/geov.2023.9.5
O. Valyaeva, N. Ryabinkina
The results of detailed geochemical studies of natural bitumen in the section of the Kozhva River of the Timan-Pechora province, localized in the dolomites of the Kamensk formation of the Upper Famenian, are presented. It is established that bitumen is allochthonous. This is quite understandable from a geological point of view: the formation of bitumen manifestations is associated with the vertical migration of hydrocarbons (HC) in the zone of the Pripechorsky deep fault, resinous-asphaltene components predominate in the bitumen group composition. Gas chromatography and gas- chromatography-mass spectrometry proved that bitumen underwent intensive bacterial degradation, which led to the loss of n-alkanes and isoprenoids, steranes and partially hopanes. Tricyclanes of composition C19-C25, tetracyclane C24 and «geohopanes» with configuration 17α(H)21β(H) of composition C27 (Ts, Tm) and C29 were identified on mass chromatograms of m/z 191. It was found that tricyclanes predominate. On chromatograms according to m/z 177, 25-norhopane of the composition C28 was identified. Series 25-norhopane series was observed. The isotopic composition of carbon of individual fractions is characteristic of sapropel OM and is similar to the ICC of the previously studied bitumen of the Voya deposit.
本文介绍了对梯曼-佩霍拉省科日瓦河段天然沥青进行详细地球化学研究的结果,这些沥青位于上法门纪卡门斯克组白云岩中。确定沥青是异质的。从地质角度来看,这是可以理解的:沥青表现形式的形成与Pripechorsky深断裂带油气的垂向运移有关,沥青组成分中以树脂沥青质组分为主。气相色谱和气相色谱-质谱分析表明,沥青经过了细菌的强烈降解,导致了正构烷烃、类异戊二烯、甾烷和部分藿烷的损失。在m/z 191质谱上鉴定出了组成为C19-C25的三环、组成为C24的四环和组成为C27 (Ts, Tm)和C29的构型为17α(H)21β(H)的“地藿烷”。发现三环类化合物占主导地位。根据m/ z177谱图,鉴定出化合物C28中的25-去藿烷。观察系列25-去藿烷系列。各组分的碳同位素组成具有砂推体有机质的特征,与先前研究的Voya矿床沥青的碳同位素组成相似。
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引用次数: 0
Fossil bones of the Miocene-Holocene camels of Eurasia (Russia): mineralogical and geochemical properties and ecological reconstructions 欧亚大陆(俄罗斯)中新世-全新世骆驼骨骼化石:矿物学和地球化学特性及生态重建
Pub Date : 2023-12-06 DOI: 10.19110/geov.2023.9.1
V. Silaev, V. Titov, A. Tesakov, V. Filippov, E. Vasil'ev, I. Smoleva, S. Shanina, Dar'ya Kiseleva, A. Khazov, B. Makeev, N. Soloshenko, T. Okuneva
Using a wide complex of mineralogical-geochemical and isotope-geochemical methods we studied, a unique series of samples of fossil camels’ bone remains taken from Eurasian localities from the northwestern Black Sea region to western Transbaikalia and Mongolia, dated in the chronological range from the Late Miocene (6 Ma) until the 14th century AD. The obtained results indicated the mineralogical and geochemical properties of fossil bones as very effective way of ecological and climatic reconstructions and interpretation of the evolutionary history of mammals.
我们使用了广泛的矿物地球化学和同位素地球化学方法,研究了一系列独特的骆驼骨骼化石样本,这些样本来自欧亚地区,从黑海西北部地区到外贝加尔西部和蒙古,时间范围从晚中新世(6 Ma)到公元14世纪。研究结果表明,化石骨骼的矿物学和地球化学性质是重建哺乳动物生态气候和解释哺乳动物进化史的有效方法。
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引用次数: 0
Comparative characteristics of diaplectic and melt silicate glasses of the Kara astrobleme 卡拉天体二折射玻璃和熔融硅酸盐玻璃的比较特性
Pub Date : 2023-12-06 DOI: 10.19110/geov.2023.9.4
A. Zubov, T. Shumilova, S. Isaenko
The objects of study are diaplectic and melt silicate glasses from vein melt impactites of the Kara astrobleme. Microscopic and spectroscopic characteristics of two glasses with fundamentally different formation mechanisms were obtained, which allowed comparing their structural features. We found that silicate diaplectic and melt impact glasses from high-pressure/high-temperature vein bodies of the Kara astrobleme were characterized by similar structural features — a high degree of polymerization, the presence of four-membered and polymembered SiO4 rings, which was characteristic of all glasses were the SiO2 composition. Diaplectic glasses are characterized by the constant presence of three-membered SiO4 rings; melt glasses were characterized by the absence of this feature, which was determined by more extreme conditions for the glass from melt.
研究对象为卡拉火山脉状熔体撞击形成的硅酸盐玻璃和熔融硅酸盐玻璃。获得了两种形成机理完全不同的玻璃的微观和光谱特征,从而可以比较它们的结构特征。我们发现,来自Kara astrobleme的高压/高温脉体的硅酸盐弹射玻璃和熔融冲击玻璃具有相似的结构特征——高度聚合,存在四元和多元SiO4环,这是所有玻璃的特征,即SiO2成分。偏光玻璃的特点是三元SiO4环的持续存在;熔融玻璃的特点是没有这种特征,这是由更极端的熔融玻璃条件决定的。
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引用次数: 0
The nature of spheroidal gold of the Middle Kyvvozh placer in the Middle Timan 中提曼地区中基伏沃日(Kyvvozh)块状矿床球状金的性质
Pub Date : 2023-12-06 DOI: 10.19110/geov.2023.9.3
M. Sokerin, Yu. Glukhov, Renat Shaybekov, B. Makeev, S. Zorina
A comprehensive mineralogical study of 13 samples of spheroidal gold from schlich concentrates of the Middle Kyvvozh gold placer, which is part of the Kyvvozh gold placer field located in the central part of the Volsk-Vym ridge of the Middle Timan, was carried out. The presence of both natural and technogenic gold in concentrates was established. Natural placer spheroidal gold is characterized by a worn surface with oxide films and the development of a high-grade corrosion rim. Technogenic gold spheroids have a polygonal-mosaic tuberculate-pitted or smooth surface, the presence of aluminosilicate glasses and slags in the form of crusts or inclusions in the matrix, the presence of mineral inclusions and impurities of platinum group metals, tin and lead, which are not characteristic of native gold. Natural spheroids were formed by natural smoothing in the water flow during the formation of the placer. The formation of technogenic spheroids is associated with the impact of high-temperature plasma on the concentrate enriched in placer gold and platinoids, which occurs during electric welding undertaken during the repair work of the flushing devices. The results of the study should help to avoid errors in the interpretation of the genesis of such gold and, as a result, in determining the nature of the primary sources of placers.
对位于中提曼Volsk-Vym脊中部的Kyvvozh金砂矿田的中Kyvvozh金砂矿的施里希精矿的13个球状金样品进行了全面的矿物学研究。精矿中既有天然金,也有工艺金。天然砂矿球金的特点是表面有氧化膜,并形成高级腐蚀边缘。技术金球体具有多边形镶嵌结核状凹坑或光滑的表面,在基体中存在铝硅酸盐玻璃和以结壳或包裹体形式存在的炉渣,存在铂族金属、锡和铅的矿物包裹体和杂质,这些都不是天然金的特征。天然球体是砂矿形成过程中水流的自然平滑形成的。技术球的形成与高温等离子体对富含砂金和铂的精矿的冲击有关,这是在冲洗装置维修期间进行电焊时发生的。这项研究的结果应有助于避免在解释这种金的成因时出现错误,从而在确定砂矿主要来源的性质时避免出现错误。
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引用次数: 0
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