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Green Synthesis Approach for Renewable Textile Coating and Their Mechanical and Thermal Properties 可再生纺织涂料的绿色合成方法及其力学和热性能
H. Elsayed, N. Attia
Green, new and renewable smart coating was developed for furniture textile fabrics. Facile and single step method was used for synthesis of green coating based on mandarin peel and chitosan. As, the mandarin peel as fruit waste material was dried, grinded and directly dispersed in chitosan solution producing new green coating composite and then coated on textile fabrics. The mass loadings of green mandarin peel powder was varied on 20-70 wt% and optimized. Thermal stability of coated textile fabrics was enhanced and char yield was improved compared to uncoated one. The charring effect of mandarin peel powder coated samples was significantly enhanced anticipating good flame retardancy effect. The Maximum break loading of the coated textile fabrics was improved achieved 35% improvement compared to uncoated sample reflecting reinforcement of textile fabrics. The interaction between the renewable coating and textile was evaluated. The morphology of uncoated and coated textile fabrics was studied using microscopic technique. Additionally, based on thermal properties of mandarin peel powder it could be promising flame retardant for textile fabrics. This study open new avenues for finishing textile fabrics with enhanced thermal, flame retardancy and mechanical properties with cost-effective and renewable green and effective coating.
开发了绿色、新型、可再生的家具纺织织物智能涂料。采用简单一步法合成了桔皮壳聚糖绿色涂料。将柑桔皮作为果皮废弃物,经干燥、研磨后直接分散在壳聚糖溶液中,制成新型绿色涂料复合材料,涂覆在纺织织物上。对青柑皮粉的质量负荷在20 ~ 70 wt%范围内进行了优化。与未涂覆的织物相比,涂覆后的织物热稳定性增强,炭收率提高。柑桔皮粉末包覆后的炭化效果明显增强,具有良好的阻燃效果。涂层织物的最大断裂载荷比未涂层样品提高了35%,反映了织物的增强。评价了可再生涂料与纺织品的相互作用。用显微技术研究了未涂布和涂布织物的形貌。此外,基于柑桔皮粉的热性能,柑桔皮粉在纺织织物阻燃方面有很大的应用前景。本研究为利用具有成本效益、可再生、绿色高效的涂料对纺织织物进行增温、阻燃和机械性能的整理开辟了新的途径。
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引用次数: 0
Ultrasensitive Detection and Discrimination of Cancer-Related Single Nucleotide Polymorphisms Using Poly-Enzyme Polymer Bead Amplification 利用聚酶聚头扩增技术对癌症相关单核苷酸多态性进行超灵敏检测和鉴别
Lorico D S Lapitan, Yi-hong Xu, Yuan Guo, Dejian Zhou
We report the development of a new ultrasensitive approach for label-free DNA detection using [...]
我们报告了一种新的超灵敏的无标记DNA检测方法的发展[…]
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引用次数: 0
Removal of Nickel and Vanadium from Crude Oil by Using Solvent Extraction and Electrochemical Process 溶剂萃取-电化学法去除原油中的镍和钒
A. Kurbanova, N. Akhmetov, A. Yeshmuratov, Y. Sugurbekov, Ramiz Zulkharnay, G. Demeuova, Murat Baisariyev, G. Sugurbekova
LLP Pavlodar Oil Chemistry Refinery crude oil contain high vanadium and nickel content, which containsmore than 23.09 g/t nickel and 58.59 g/t vanadium. In this study we used two types of metal removing methodssuch as solvent extraction and electrochemical process. The present research is conducted for comparativeanalysis of the deasphalting with organic solvents and electrochemical method. Maximum efficiency ofdeasphalting, with cyclohexane as the solvent, in Soxhlet extractor was 66.4% for nickel and 51.2% forvanadium content from crude oil. Percentage of Ni extraction reached maximum of approximately 20% byusing the electrochemical method in electrolysis cell, which was developed for this research. It consists of threesections: oil and protonating agent (EtOH) solution between two conducting membranes which divides it fromtwo capsules of 10% sulfuric acid and two graphite electrodes which cover all three parts in electrical circuit.Ions of metals’ pass through membranes and remain in acid solutions. The best result was obtained in 60minutes with ethanol to oil ratio of 1 to 3 respectively, current fits in to the range from 0.3A to 0.4A, voltagechanged from 12.8V to 17.3V.
巴甫洛达尔石油化工炼油厂原油钒镍含量较高,镍含量超过23.09 g/t,钒含量超过58.59 g/t。本研究采用了溶剂萃取法和电化学法两种金属去除方法。本文对有机溶剂法和电化学法脱沥青进行了比较分析。在索氏萃取器中,以环己烷为溶剂,原油中镍和钒的最大脱沥青效率分别为66.4%和51.2%。在为本研究而开发的电解池中,采用电化学方法提取镍的百分比最高可达20%左右。它由三部分组成:两层导电膜之间的油和质子化剂(EtOH)溶液,导电膜将其从两个10%硫酸胶囊和两个覆盖电路中所有三个部分的石墨电极中分离出来。金属离子穿过膜,留在酸性溶液中。当乙醇与油的比例为1:3时,60分钟后得到最佳效果,电流范围为0.3A ~ 0.4A,电压范围为12.8V ~ 17.3V。
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引用次数: 6
Column Studies on Chromium(VI) Adsorption onto Kala Jamun (Syzygium cumini L.) Seed Powder Kala Jamun (Syzygium cumini L.)吸附铬(VI)的色谱柱研究种子粉
S. Deka, K. Bhattacharyya
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引用次数: 1
Self-Assembled Laser-Activated Plasmonic Substrates for High-Throughput, High-Efficiency Intracellular Delivery
Marinna Madrid, Nabiha Saklayen, Marinus Huber, N. Vogel, E. Mazur
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引用次数: 0
Bioleaching of Precious Metals from an Oil-fired Ash Using Organic Acids Produced by Aspergillus niger in Shake Flasks and a Bioreactor 利用黑曲霉在摇瓶和生物反应器中产生的有机酸从燃油灰渣中生物浸出贵金属
P. Rasoulnia, S. Mousavi
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引用次数: 1
Assessment of Adsorption Properties of Neem Leaves Wastes for the Removal of Congo Red and Methyl Orange 印楝叶废弃物对刚果红和甲基橙的吸附性能评价
M. Ibrahim, M. S. Sulaiman, Sadiq Sani
 Abstract— Neem leaves were studied as plant wastes derived adsorbents for detoxification of Congo Red (CR) and Methyl Orange (MO) from aqueous solutions using batch adsorption technique. The objectives involved determining the effects of the basic adsorption parameters namely, agitation time, adsorbent dosage, adsorbents particle size, adsorbate loading concentrations and initial pH, on the adsorption process as well as characterizing the adsorbents by determining their physicochemical properties, functional groups responsible for the adsorption process using Fourier Transform Infrared (FTIR) spectroscopy and surface morphology using scanning electron microscopy (SEM) coupled with energy dispersive X - ray spectroscopy (EDS). The adsorption behaviours of the materials were tested against Langmuir, Freundlich, Temkin, Dubinin Radushkevic and Harkins Jura isotherm models. Percent adsorption increased with increase in agitation time (5 - 240 minutes), adsorbent dosage (100- 500mg), initial concentration (100-300mg/L), and with decrease in particle size (≥75μm to ≤300μm) of the adsorbents. Both processes are dye pH-dependent, increasing or decreasing percent adsorption in acidic (2-6) or alkaline (8-12) range over the studied pH (2-12) range. From the experimental data the Langmuir's separation factor (RL) suggests unfavourable adsorption for all processes, Freundlich constant (nF) indicates unfavourable process for CR and MO adsorption; while the mean free energy of adsorption �� , calculated from Dubinin-Radushkevich equation suggest a physical adsorption. Reduction in band intensities and vibrational changes observed in FTIR spectra indicate possible involvement of carbonyl (-C=O), carboxyl (-COOH) and hydroxyl (-OH) functional groups on the adsorbents' surfaces during the adsorption and interaction with the sulfonic acid groups (-SO3Na) on the dye molecules. The difference in irregular and porous texture surface morphology of fresh and dye- loaded adsorbent characterized the adsorption of the dyes by the adsorbent. While EDS analysis indicates that adsorbent consist of mainly C and O, and small amounts of, Ca, Mg, K, P and S. The result of this study shows that neem leaves are potential alternative low-cost adsorbents for the effective removal of Congo red (CR) and methyl orange (MO), from aqueous solutions. Keywords—Adsorption, Congo red, Methyl orange, Neem Leaves
摘要-采用间歇吸附技术研究了印楝叶作为植物废弃物吸附剂对刚果红(CR)和甲基橙(MO)的脱毒作用。目的包括确定基本吸附参数(即搅拌时间、吸附剂用量、吸附剂粒径、吸附物负载浓度和初始pH值)对吸附过程的影响,以及通过测定吸附剂的物理化学性质来表征吸附剂。利用傅里叶变换红外(FTIR)光谱和扫描电子显微镜(SEM)结合能量色散X射线光谱(EDS)对表面形貌进行分析。根据Langmuir, Freundlich, Temkin, Dubinin Radushkevic和Harkins Jura等温模型测试了材料的吸附行为。随着搅拌时间(5 ~ 240 min)、吸附剂投加量(100 ~ 500mg)、初始浓度(100 ~ 300mg/L)的增加以及吸附剂粒径(≥75μm ~≤300μm)的减小,吸附剂的吸附率均有所增加。这两种工艺都与染料的pH值有关,在研究的pH值(2-12)范围内,在酸性(2-6)或碱性(8-12)范围内增加或减少吸附百分比。实验数据表明,Langmuir分离因子(RL)和Freundlich常数(nF)对CR和MO的吸附均不利;而根据Dubinin-Radushkevich方程计算的平均吸附自由能为物理吸附。在红外光谱中观察到的波段强度降低和振动变化表明,在吸附和与染料分子上的磺酸基(-SO3Na)相互作用过程中,吸附剂表面可能有羰基(-C=O)、羧基(-COOH)和羟基(-OH)官能团参与。新鲜吸附剂和载染料吸附剂的不规则和多孔结构表面形貌的差异表征了吸附剂对染料的吸附作用。而EDS分析表明,该吸附剂主要由C和O组成,以及少量的Ca、Mg、K、P和s组成。本研究结果表明,楝叶是一种潜在的低成本吸附剂,可以有效去除水溶液中的刚果红(CR)和甲基橙(MO)。关键词:吸附,刚果红,甲基橙,印楝叶
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引用次数: 15
Polysaccharides as Pour Point Depressants 多糖作为凝点抑制剂
A. M. El-Soll
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引用次数: 0
Hybrid-Nanoengineering™: A New Platform for Nanomedicine 混合纳米工程™:纳米医学的新平台
Mewa Singh
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引用次数: 0
期刊
World Academy of Science, Engineering and Technology, International Journal of Chemical and Molecular Engineering
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