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Meet Our Editor-in-Chief 认识我们的总编辑
Pub Date : 2020-12-28 DOI: 10.2174/245227320301201202152004
Pei-yuan Li
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引用次数: 0
A Roadmap for the Chalcogenide-graphene Composites Formation Under a Glassy Regime 玻璃态下硫系化合物-石墨烯复合材料形成的路线图
Pub Date : 2020-05-31 DOI: 10.2174/2452273204999200918154642
A. Singh, T. Jen
Nano-composite is an innovative material having nano in which fillers dispersedin a matrix. Typ-ically, the structure is a matrix- filler combination, where the fillers likeparticles, fibers, or fragments are surrounded and bound together as discrete units by the matrix.The term nano-composite encompasses a wide range of materials right from three dimensional metalmatrix composites to two dimensional lamellar composites. Therefore, the physical, chemicaland biological properties of nano materials differ from the properties of individual atoms andmolecules or bulk matter. The chalcogenide – graphene composites in glassy regime is the growingnovel research topic in the area of composite material science. It is obvious to interpret such materialsdifferent physicochemical mechanism.The key objective of this research work to explore the internal physicochemical mechanismof the chalcogenide – graphene composites under the glassy regime. Including the primechalcogen alloying element selenium amorphous atomic structure and their fullerene like bondingnature. By accommodating the essential properties of the stacked layers of bilayer graphene. Thediffusion, compression and dispersion of the bilayer graphene in selenium rich ternary (X(1-x-y)-Y(x)-Z(y) + GF (bilayer graphene); X = Se, Y = Semimetal or metalloid, Z = None metal) alloys underthe complex regime on and after thermal melting process are addressed.To synthesize the composite materials the well-known melt quenchedmethod had adopted. More-over, to interpret the amorphous selenium (Se8) chains and rings molecularstructures we had used vista software with an available CIF data file. While to show thearmchair and zig-zag bonds with bilayer graphene structure the nanotube modeler simulation softwarehas used.Outcomes of this study reveals the chalcogenide -graphene nano composite formation undera glassy regime changes the individual materials structural and other physical properties that isreflecting in different experimental evi-dences, therefore, the modified theoretical concepts for thedifferent properties of such composite materials are interpreted in this study.The dispersion and diffusion of the high stiff graphene bonds in low dimension chalcogenrich alloys has been interpreted based on their quadric thermal expansion behaviour. In additionto this, a possible bond angle modification in the formation of X(1-x-y)-Y(x)-Z(y) + GF compositesare also addressed. To interpret the distinct optical property behavior of the formed X(1-x-y)-Y(x)-Z(y)+ GF composites and parent chalcogenide glassy alloys a schematic model of the energy levels isalso addressed.To make a better understating on the formation mechanism such composites, the diffusionand deformation of high stiff graphene σ and π bonds in a low dimension chalcogenide alloybasic mechanism are discussed on basis of novel “thermonic energy tunneling effect” concept,which could result in quadratic the
纳米复合材料是一种将纳米填料分散在基体上的新型材料。典型的结构是基质-填料组合,其中填料如颗粒、纤维或碎片被基质包围并作为离散单元结合在一起。纳米复合材料涵盖了从三维金属基复合材料到二维片层复合材料的广泛范围。因此,纳米材料的物理、化学和生物特性不同于单个原子、分子或块状物质的特性。玻璃态硫系-石墨烯复合材料是近年来复合材料科学研究的一个新兴课题。很明显,这类材料有不同的物理化学机理。本研究的主要目的是探索硫族化物-石墨烯复合材料在玻璃态下的内部物理化学机制。包括原素元素硒的无定形原子结构及其类富勒烯键合性质。通过容纳双层石墨烯堆叠层的基本特性。富硒三元体系(X(1-x-y)-Y(X)-Z(y) + GF)中双层石墨烯的扩散、压缩和分散X = Se, Y =半金属或类金属,Z =无金属)合金在热熔过程中和之后的复杂制度。复合材料的合成采用了著名的熔体淬火法。此外,为了解释无定形硒(Se8)链和环的分子结构,我们使用了vista软件和可用的CIF数据文件。同时利用纳米管modeler仿真软件来显示具有双层石墨烯结构的扶手键和之字形键。本研究的结果揭示了玻璃态下硫系化物-石墨烯纳米复合材料的形成改变了单个材料的结构和其他物理性质,这些性质反映在不同的实验证据中,因此,本研究解释了这种复合材料不同性质的修正理论概念。基于二次热膨胀行为解释了低维富硫合金中高硬度石墨烯键的分散和扩散。除此之外,本文还讨论了形成X(1-x-y)-Y(X)-Z(y) + GF复合材料时可能的键角修饰。为了解释形成的X(1-x-y)-Y(X)-Z(y)+ GF复合材料和母硫系玻璃合金的独特光学性质行为,还讨论了能级的示意图模型。为了更好地理解这类复合材料的形成机理,基于“热能隧道效应”的新概念,讨论了低维硫系合金中高刚度石墨烯σ键和π键的扩散和变形的基本机理,从而导致石墨烯的二次热膨胀。此外,还从键角的改变和配位缺陷的影响两方面描述了复合材料结构单元的改变。采用外来合金元素的影响和蜂窝带结构中石墨烯层间的表面π等离子体共振的观点,讨论了这种复合材料中的能级抑制和附加亚能级的产生。因此,本研究描述了硫系-双层石墨烯复合材料在玻璃态下形成的各个基本方面。
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引用次数: 0
Withdrawal Notice: New Matter Properties and Applications based on Hybrid Graphene-based Metamaterials 退出公告:基于混合石墨烯基超材料的新物质特性和应用
Pub Date : 2020-05-28 DOI: 10.2174/2452273204999200528141157
A. Bracamonte
The article has been withdrawn at the request of the authors of the journal Current Graphene Science.Bentham Science apologizes to its readers for any inconvenience this may have caused.The Bentham Editorial Policy on Article Withdrawal can be found at https://benthamscience.com/editorial-policies-main.phpIt is a condition of publication that manuscripts submitted to this journal have not been published and will not be simultaneously submitted or published elsewhere. Furthermore, any data, illustration, structure or table that has been published elsewhere must be reported, and copyright permission for reproduction must be obtained. Plagiarism is strictly forbidden, and by submit-ting the article for publication the authors agree that the publishers have the legal right to take appropriate action against the authors, if plagiarism or fabricated information is discovered. By submitting a manuscript, the authors agree that the copyright of their article is transferred to the publishers if and when the article is accepted for publication.
应《当代石墨烯科学》杂志作者的要求,这篇文章已被撤回。《边沁科学》杂志为由此造成的不便向读者道歉。边沁文章撤回编辑政策可以在https://benthamscience.com/editorial-policies-main.phpIt上找到,这是一个发表条件,即提交给本刊的手稿尚未发表,不会同时提交或在其他地方发表。此外,在其他地方发表的任何数据、插图、结构或表格必须报告,并必须获得版权许可才能复制。抄袭是严格禁止的,通过提交文章发表,作者同意出版商有法律权利对作者采取适当的行动,如果发现抄袭或捏造信息。通过提交手稿,作者同意如果文章被接受发表,其文章的版权将转移给出版商。
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引用次数: 1
Recent Advancement in MoS2 for Hydrogen Evolution Reactions 二硫化钼在析氢反应中的研究进展
Pub Date : 2020-03-03 DOI: 10.2174/2452273204666200303124226
R. Gupta, K. Mensah-Darkwa, R. Tabi, M. Owusu, Tenzin Ingsel, P. Kahol
The economic growth of any country depends on certain factors of which energy is a partand even prominent. The global economy has depended heavily on fossil fuels as the main source ofreliable energy for so many decades. Their adverse long-term impact on society has led to a substantialincrease in research activities both in industry and academia. Most of the research has been dominatedby the development of green energy technologies and the expansion of such technologies inorder to meet increasing future demands of energy. Prominent among the research drive is the developmentof fuel cells, whose driving force comes from hydrogen. This is because hydrogen is economicalconsidering its relative abundance, low cost, yet high activity in production. Materials suchas Pt, C, Fe, MoS2 have gained popularity in the production of hydrogen for use in fuel cell devices.The high efficiency of MoS2, amorphous or crystalline, in hydrogen evolution reactions (HER) dependson a suitable architecture that increases the exposure of its edge sites. Such architecture couldbe determined by the design of catalysts in terms of proportions of molybdenum and dopant ions, thecomposite structure between MoS2 and electrically conductive materials, synthesis temperature andthe synthesis method. Therefore, a review is made on recent achievements for different nanoarchitecturesof MoS2 as well as its composite structures for use as electro-catalysts in HER performanceand future prospects.
任何国家的经济增长都依赖于某些因素,能源是其中的一部分,甚至是突出的。几十年来,全球经济严重依赖化石燃料作为可靠能源的主要来源。它们对社会的长期不利影响导致工业界和学术界的研究活动大幅增加。大多数研究都以绿色能源技术的发展和这种技术的扩展为主导,以满足未来日益增长的能源需求。其中最突出的是燃料电池的发展,其动力来自氢。这是因为考虑到氢的相对丰度、低成本和高活动性,它是经济的。Pt、C、Fe、MoS2等材料在生产用于燃料电池装置的氢方面得到了广泛的应用。在析氢反应(HER)中,无定形或结晶二硫化钼的高效率取决于合适的结构,增加其边缘位置的暴露。这种结构可以通过钼和掺杂离子的比例、MoS2与导电材料的复合结构、合成温度和合成方法等因素来决定催化剂的设计。因此,本文综述了近年来不同纳米结构的二硫化钼及其复合结构作为电催化剂在HER性能方面的研究进展和前景。
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引用次数: 2
Recent advances in graphene based nano-composites for automotive and off-highway vehicle applications 用于汽车和非公路车辆的石墨烯基纳米复合材料的最新进展
Pub Date : 2019-11-04 DOI: 10.2174/2452273203666191104150025
R. Kandasamy
Nano-composites comprised of a polymer matrix and various types of nanosized fillers have remained as one of the most important engineering materials and continue to draw great interest in the research community and industry. In particular, graphene based nano-composites with high thermal conductivity, excellent mechanical, electrical and optical properties, becomes important and promising filler for making the next generation, high performance composite materials.Automotive and off-highway machinery industry are extensively viewed as being the industry in which the highest volume of advanced composite materials such as graphene based nano-composites will be used in the future to produce lighter, stronger, more energy-efficient, and safe vehicles. Design, modeling, analyzing and methods for large-scale production of the graphene based nano-composites in automotive and off-highway machinery applications considering it’s mechanical, functional and interface properties between the graphene and polymer matrix under severe loading conditions is challenging, potentially due to nonlinear properties, joining of dissimilar materials and high demand of computations. While graphene based material strategies have been investigated and demonstrated to be effective for structural application in various industries includes electronics, electromechanical and energy systems, currently there is limited research highlighting the specific knowledge available for design engineers and researchers concerned with lightweight and stronger solutions by use of graphene based materials for automotive off-highway vehicle applications.The present review presents, an overview of the latest studies that utilize graphene-based nanomaterials and their composites in automotive and off-highway machinery applications. First, the paper describes the concept of traditional composites used in present engineering industries considering its advantages and limitations, then highlights the key benefits of using nanostructured carbon material, such as graphene through some recent studies available in the literature. Then depicts the various mechanisms of integrating graphene as polymer reinforcements within composite materials, which have been found based on the survey, and their related modeling, designing, and manufacturing capabilities suitable for automotive and off-highway machinery industry. Finally outlines the available experimental evidence for graphene based composites. In order to lay the groundwork for future work in this exciting area, the paper discusses close by several future prospects as well as the current challenges in this field.
纳米复合材料是由聚合物基体和各种纳米尺寸的填料组成的,是最重要的工程材料之一,并继续引起研究界和工业界的极大兴趣。特别是石墨烯基纳米复合材料具有高导热性,优异的机械、电学和光学性能,成为制造下一代高性能复合材料的重要和有前途的填料。汽车和非公路机械行业被广泛认为是未来使用石墨烯纳米复合材料等先进复合材料量最大的行业,以生产更轻、更强、更节能、更安全的车辆。考虑到石墨烯与聚合物基体在恶劣载荷条件下的力学、功能和界面特性,石墨烯基纳米复合材料在汽车和非公路机械应用中的设计、建模、分析和大规模生产方法具有挑战性,这可能是由于非线性特性、不同材料的连接以及高计算需求。虽然石墨烯基材料策略已经被研究并证明在包括电子、机电和能源系统在内的各个行业的结构应用中是有效的,但目前,设计工程师和研究人员关注的是石墨烯基材料在汽车非公路车辆应用中的轻量化和更强的解决方案,这方面的研究有限。本文综述了石墨烯基纳米材料及其复合材料在汽车和非公路机械中的最新研究进展。首先,本文介绍了目前工程行业中使用的传统复合材料的概念,并考虑了其优点和局限性,然后通过最近的一些文献研究,强调了使用纳米结构碳材料(如石墨烯)的主要好处。然后描述了基于调查发现的将石墨烯作为聚合物增强材料集成到复合材料中的各种机制,以及适用于汽车和非公路机械行业的相关建模、设计和制造能力。最后概述了石墨烯基复合材料的现有实验证据。为了为这一激动人心的领域的未来工作奠定基础,本文对这一领域的未来前景和当前面临的挑战进行了详细的讨论。
{"title":"Recent advances in graphene based nano-composites for automotive and off-highway vehicle applications","authors":"R. Kandasamy","doi":"10.2174/2452273203666191104150025","DOIUrl":"https://doi.org/10.2174/2452273203666191104150025","url":null,"abstract":"\u0000\u0000Nano-composites comprised of a polymer matrix and various types of nanosized fillers have remained as one of the most important engineering materials and continue to draw great interest in the research community and industry. In particular, graphene based nano-composites with high thermal conductivity, excellent mechanical, electrical and optical properties, becomes important and promising filler for making the next generation, high performance composite materials.\u0000\u0000\u0000\u0000Automotive and off-highway machinery industry are extensively viewed as being the industry in which the highest volume of advanced composite materials such as graphene based nano-composites will be used in the future to produce lighter, stronger, more energy-efficient, and safe vehicles. Design, modeling, analyzing and methods for large-scale production of the graphene based nano-composites in automotive and off-highway machinery applications considering it’s mechanical, functional and interface properties between the graphene and polymer matrix under severe loading conditions is challenging, potentially due to nonlinear properties, joining of dissimilar materials and high demand of computations. While graphene based material strategies have been investigated and demonstrated to be effective for structural application in various industries includes electronics, electromechanical and energy systems, currently there is limited research highlighting the specific knowledge available for design engineers and researchers concerned with lightweight and stronger solutions by use of graphene based materials for automotive off-highway vehicle applications.\u0000\u0000\u0000\u0000The present review presents, an overview of the latest studies that utilize graphene-based nanomaterials and their composites in automotive and off-highway machinery applications. First, the paper describes the concept of traditional composites used in present engineering industries considering its advantages and limitations, then highlights the key benefits of using nanostructured carbon material, such as graphene through some recent studies available in the literature. Then depicts the various mechanisms of integrating graphene as polymer reinforcements within composite materials, which have been found based on the survey, and their related modeling, designing, and manufacturing capabilities suitable for automotive and off-highway machinery industry. Finally outlines the available experimental evidence for graphene based composites. In order to lay the groundwork for future work in this exciting area, the paper discusses close by several future prospects as well as the current challenges in this field. \u0000","PeriodicalId":294135,"journal":{"name":"Current Graphene Science","volume":"39 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114715004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Graphene-based Nanomaterials for Fabrication of ‘Pesticide’ Electrochemical Sensors 用石墨烯纳米材料制备“农药”电化学传感器
Pub Date : 2019-10-07 DOI: 10.2174/2452273203666191007143008
Manorama Singh, Smita R. Bhardiya, F. Verma, V. Rai, Ankita Rai
At present, graphene is one of the most up-to-date materials and it can be applied for variousenergy conversion devices and sensor technology. In this review article, our main focus is tosummarize the role of graphene and its modified surface leading to develop hybrid nanomaterials andits applications in fabrication of pesticide sensor. Graphene based materials demonstrate exclusiveelectrochemical and optical properties as well as compatibility to absorb a variety of bio-moleculesthrough π-π stacking interaction and/or electrostatics interaction, which make them ideal material tobe employed in sensor application. The role of graphene is very crucial in preparing different uniqueand desirable hybrid functional composites along with nanoparticles, redox mediators, conductingpolymers etc. to improve the performance of the sensors. Therefore, they can be easily used as a suitablematerial applying in fabrication of electrochemical sensors/ biosensors for the detection of organophosphorousand carbamate pesticides. A number of most recent reported works were discussedin which graphene-based hybrid composites show high sensitivity, good catalytic activity, selectivitytowards the determination of pesticide either enzymatically or nonenzymatically. The properties ofgraphene (exceptional charge transport, thermal, optical, mechanical, high surface area, large porevolume and size, an opened ordered structure) play an important role in pesticide detection.
目前,石墨烯是最新的材料之一,它可以应用于各种能量转换装置和传感器技术。本文主要综述了石墨烯及其改性表面在杂化纳米材料开发中的作用及其在农药传感器制造中的应用。石墨烯基材料表现出独特的电化学和光学特性,以及通过π-π堆叠相互作用和/或静电相互作用吸收各种生物分子的相容性,使其成为传感器应用的理想材料。石墨烯在与纳米颗粒、氧化还原介质、导电聚合物等制备不同独特和理想的杂化功能复合材料以提高传感器性能方面的作用是至关重要的。因此,它们可以很容易地作为一种合适的材料应用于制造检测有机磷和氨基甲酸酯类农药的电化学传感器/生物传感器。本文讨论了近年来石墨烯基杂化复合材料在酶和非酶测定农药方面具有较高的灵敏度、良好的催化活性和选择性。石墨烯的特性(特殊的电荷输运、热、光学、机械、高表面积、大孔隙体积和尺寸、开放有序结构)在农药检测中发挥着重要作用。
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引用次数: 5
Recent advances in Photocatalysis for renewable energy production using Microbial Fuel Cell 微生物燃料电池光催化再生能源研究进展
Pub Date : 2019-09-19 DOI: 10.2174/2452273203666190919105313
M. Sohaib, Adeel Ahmed, I. Aslam, M. Sagir, Jawaria Bin Faheem, A. Inayat, H. Talebian
Herein, the recent development and future perspectives of nanophotocatalysis has been discussed for the sustainable and green energy generation through microbial fuel cell (MFC). The artificial photosynthesis and biomass energy production methods have reviewed comprehensively. Further, the fabrication, fundamental aspects and purposes of MFC have been discussed to clearly elaborate the concept of energy production. A lot of effort have been done to convert light energy to biomass energy artificially which is then converted into electric or mechanical energy for further use. Recent age is facing plenty of challenges to convert the light energy to bioenergy.
本文综述了纳米光催化技术在微生物燃料电池(MFC)可持续绿色发电中的研究进展和前景。对人工光合作用和生物质能生产方法进行了综述。此外,讨论了MFC的制造,基本方面和目的,以清楚地阐述能源生产的概念。人工将光能转化为生物质能,然后将生物质能转化为电能或机械能供进一步利用,已经做了很多努力。近年来,将光能转化为生物能源面临着诸多挑战。
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引用次数: 0
Hydrogen Energy Harvesting through nanomaterials under Solar Light Irradiation 太阳能辐照下纳米材料收集氢能的研究
Pub Date : 2019-08-28 DOI: 10.2174/2452273203666190828212038
N. R. Khalid, M. F. Malik, H. Min, S. Abbasi
In this review, the evolution of hydrogen in combined cell system of Photoelectrocatalytic and microbial fuel disused. Hydrogen is used as chemical fuel. Hydrogen is being produced through Photoelectrocatalytic method. The semiconductor material put into the water and irradiated with solar light after which the hydrogen produced by different steps and accumulated. Production of hydrogen also occur in microbial fuel cell system. These are electrochemical devices that initially used to treat the wastewater. But now this cell has entered into very interesting field of research which is Bioelectrochemical (BES). BES produces hydrogen using biomass as a catalyst using small consumption voltage rather than simple electrolysis of water. The first sections explain how hydrogen is produced individually by these two methods. And then we make comprehensive review on the evolution of hydrogen by combined microbial fuel and photoelectrocatalytic cell system, which is our main motive of writing this article. The continuous production of hydrogen by (PEC-MFC) hybrid device, using sunlight and splitting of water and electrohydrogenesis of microbial cell in fusion device (PEC-MFC) were also reported. This method gives continuous production of hydrogen using wastewater under solar light and also gives the treatment of wastewater. It is the clean energy source and also fulfills the today’s demand of energy. At last, a review on production of hydrogen by microbial photoelectrochemical system which is constructed by photocathode of semiconductor material and an anode of microbial. Production of hydrogen was continuously achieved without external voltage under ultraviolet irradiation.
本文综述了废弃的光电催化与微生物燃料组合电池系统中氢的演变。氢被用作化学燃料。利用光电催化法制备氢。将半导体材料放入水中,用太阳光照射,经过不同的步骤产生氢气并积累。氢气的产生也发生在微生物燃料电池系统中。这些是最初用来处理废水的电化学装置。但是现在这种细胞已经进入了一个非常有趣的研究领域——生物电化学(BES)。BES利用生物质作为催化剂,使用小的消耗电压而不是简单的电解水来生产氢气。第一部分解释了如何通过这两种方法分别产生氢。然后对微生物燃料与光电催化电池组合系统的氢气演化进行了全面的综述,这也是本文写作的主要动机。本文还报道了利用阳光和水的分裂以及微生物细胞在融合装置(PEC-MFC)中电制氢的混合装置(PEC-MFC)连续制氢。这种方法使废水在太阳能光照下连续生产氢气,并对废水进行处理。它是清洁能源,也满足了当今的能源需求。最后,对以半导体材料为光电阴极,以微生物为阳极构建的微生物光电化学制氢系统进行了综述。在紫外照射下,无外加电压连续制氢。
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引用次数: 0
Renewable Energy Power for A Sustainable Energy for Future 可再生能源:未来的可持续能源
Pub Date : 2019-08-28 DOI: 10.2174/2452273203666190828163601
M. F. Malik, M. Pervaiz, A. Inayat
Energy is a fundamental aspect in human life. It acts as blood for humans. No energy means no facility and frozen life activities. It needs for agricultural, economics and in domestic level etc. demands of energy is increasing day by day as increases population especially in developing countries. To meet energy requirement renewable energy is more efficient; no greenhouse effect, no emission of CO2, create least amount of resultant wastes, are sustainable base lying on existing and prospect financial and societal desire, no pollution and a safe environment to breathe freely. Mostly renewable energy comes as of ordinary source the same as wind energy, lunar and stellar energy, Bioenergy and hydropower energy etc.
能源是人类生活的一个基本方面。它就像人类的血液。没有能源就意味着没有设施和冻结的生命活动。随着人口的增长,特别是发展中国家对能源的需求日益增加,农业、经济和国内等方面的需求也在不断增加。为满足能源需求,可再生能源效率更高;无温室效应,无二氧化碳排放,产生最少的由此产生的废物,是基于现有和未来的经济和社会需求的可持续基础,无污染和自由呼吸的安全环境。可再生能源大多是普通能源,如风能、月球和恒星能源、生物能源和水力能源等。
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引用次数: 0
Bi-layer Graphene: Structure, Properties, Preparation and Prospects 双层石墨烯:结构、性质、制备及展望
Pub Date : 2019-01-25 DOI: 10.2174/2452273202666181031120115
Yuli Huang, Xiaoyun Li, Huijuan Cui, Zhen Zhou
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引用次数: 2
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Current Graphene Science
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