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Generation and alteration conditions, fluid regime features of the ore-magmatic system of the South Saryshagan granite intrusion (Western Balkhash region) 南萨里沙干花岗岩岩体(西巴尔喀什地区)成矿蚀变条件及流体制度特征
Q4 Earth and Planetary Sciences Pub Date : 2023-11-04 DOI: 10.24930/1681-9004-2023-23-5-887-909
G. Yu. Shardakova, A. V. Korovko, N. A. Antonishin
Research subject . For the first time, the mineral composition, petro- and geochemical features, generation and metasomatic alteration conditions, fluid regime (based on the behavior of F, Sl, and S in apatites), and ore-generating potential of granitoids from the South Saryshagan intrusion (Western Balkhash) were studied. Materials and methods . X-ray fluorescence and atomic emission methods of rock analysis (drilling well core), as well as microprobe (polished sections) studies of mineral composition. Results . The rock composition was found to correspond to moderately alkaline granites, formed at a generation pressure of about 2 kbar and T = 670°C. Subsequent metasomatic transformations were mediumtemperature (313–350°C) and multistage, i.e., phyllitization followed by chloritization. The ferrous composition of chlorite and the confinement of its development area to fracture zones indicate the local scale of the process. Ore mineralization is mainly represented by chalcopyrite, occasionally containing Au. According to the morphology and composition features, apatites from granites can be divided into two groups, i.e., magmatogenic grains and products of their transformations. In a diagram of F-Cl-S ratios, most points of their composition lie in the fields of rocks productive of Cu-porphyry mineralization. Conclusions . Mineral associations and the analysis of F, Cl, and S behavior in apatites indicate changes in the composition of the fluid phase over time under the conditions of an open system. In apatites, sulfur accumulates to the maximum level (0.012 wt % S) simultaneously with an increase in the amount of Cl and a decrease in the amount of F. After S reaches this level, the Cl content in apatites decreases followed by a notable increase in F; as a result, the late portions of the fluid become depleted of F, but enriched with Cl and S. In general, the content of the latter two components is low, compared with that typical of rich Cu–porphyry systems. Since the amount of mobilized copper depends on both the contents of Cl and S in the fluid and the volume of this fluid (determined by the size of the intrusion itself; in our case, it is a small body), the predicted copper reserves in the upper horizons of the South Saryshagan intrusion are small.
研究课题。首次研究了南Saryshagan岩体(西巴尔喀什)花岗岩的矿物组成、岩石地球化学特征、生成和交代蚀变条件、流体状态(基于磷灰石中F、Sl和S的行为)以及成矿潜力。材料和方法。x射线荧光和原子发射方法的岩石分析(钻井岩心),以及微探针(抛光切片)的矿物组成研究。结果。岩石成分为中碱性花岗岩,形成于2 kbar左右的生成压力和670℃的温度下。随后的交代转化是中温(313-350℃)和多阶段的,即千层石化和绿泥石化。绿泥石的含铁成分及其发育区域局限于断裂带表明了该过程的局部规模。矿石成矿以黄铜矿为主,偶含金。根据花岗岩磷灰石的形态和组成特征,可将其分为岩浆成因颗粒和岩浆成因转化产物两大类。在F-Cl-S比值图中,它们的大部分组成点位于产铜斑岩矿化的岩石区。结论。矿物组合和对磷灰石中F、Cl和S行为的分析表明,在开放体系条件下,流体相的组成随时间的变化。在磷灰石中,硫的积累达到最大值(0.012 wt % S)的同时,Cl的量增加,F的量减少。当S达到这一水平后,磷灰石中Cl的含量降低,F的含量显著增加;结果表明,富铜斑岩体系中后两种元素的含量相对较低,富铜斑岩体系中后两种元素的含量相对较低。由于调动铜的量取决于流体中Cl和S的含量以及流体的体积(由侵入体本身的大小决定;在我们的例子中,它是一个小体),预测南Saryshagan侵入体上部层位的铜储量很小。
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引用次数: 0
Trace element composition of zircon from granitoids of the Neoarchean alkaline province of the Kola Peninsula 科拉半岛新太古代碱性省花岗岩类锆石微量元素组成
Q4 Earth and Planetary Sciences Pub Date : 2023-11-04 DOI: 10.24930/1681-9004-2023-23-5-868-886
V. R. Vetrin, S. G. Skublov
Research subject . Zircon from granitoids of the A- and I-types of the Neorchean Kola alkaline province of the Baltic (Fennoscandian) shield. Aim . To determine the trace element composition of zircon in order to characterize the conditions of its formation in different types of granitoids. To use these data, along with the available results of U-Pb dating and Lu-Hf isotope composition of the studied zircon crystals, to assess the amount of mantle and core matter in the protolith composition and the effect of crystallization conditions on the rare element composition of zircon. Materials and Methods . 50 zircon crystals from 5 samples of the main types of granitoids of the province were studied. Concentrations of trace elements were determined using a Cameca IMS-4f ion microprobe (NF FTIAN, Yaroslavl). Points for analysis were selected using optical and cathodoluminescent images. The size of the crater did not exceed 20 µm, the relative measurement error for the predominant part of the elements was set at 10–15%, the threshold for detecting elements was 10 ppb. Results . There are two main types of zircon of Neoarchean age – zircon-1 and zircon-2, formed, respectively, at the magmatic and autometasomatic stages of crystallization, zircon-4 in inclusions in zircon-1, and Paleoproterozoic zircon-3 of metamorphic genesis. The average isotopic composition of Hf in zircon-1 and zircon-2 of different arrays varies slightly, with the amount of mantle component (Xm) ranging from 23 to 30%, which may indicate a relatively constant and significantly core composition of their protoliths. Conclusions . The change in the trace element composition of Neoarchean zircons was controlled mainly by the composition of protoliths and redox crystallization conditions. Under reducing conditions, the greatest chemical activity was acquired by light (La-Nd) lanthanides, for which a direct dependence on the Ce/Ce* value was established. For heavy lanthanides with similar ion sizes relative to Zr+4, crystallochemical factors were more important and a decrease in the dependence of heavy lanthanide concentrations in zircon on Ce/ Ce* was determined.
研究课题。来自波罗的海(芬诺斯坎迪亚)盾区新古纪科拉碱性省A型和i型花岗岩的锆石。的目标。测定不同类型花岗岩中锆石的微量元素组成,以表征其形成条件。利用这些数据,结合已有的锆石晶体U-Pb定年和Lu-Hf同位素组成结果,评估原岩组成中地幔和核物质的含量,以及结晶条件对锆石稀有元素组成的影响。材料与方法。对本省主要花岗岩类5个样品中的50个锆石晶体进行了研究。微量元素浓度测定采用Cameca IMS-4f离子微探针(NF FTIAN,雅罗斯拉夫尔)。利用光学和阴极发光图像选择分析点。陨石坑大小不超过20µm,绝大部分元素的相对测量误差设为10 - 15%,元素检测阈值为10 ppb。结果。新太古代锆石主要有两种类型:锆石-1和锆石-2,分别形成于岩浆和自交代结晶阶段,锆石-1包裹体中的锆石-4和古元古代变质成因的锆石-3。不同阵列锆石-1和锆石-2中Hf的平均同位素组成差异较小,地幔组分(Xm)的含量在23% ~ 30%之间,这可能表明它们的原岩心组成相对稳定且显著。结论。新太古代锆石微量元素组成的变化主要受原岩组成和氧化还原结晶条件的控制。在还原条件下,光系(La-Nd)镧系元素的化学活性最高,其化学活性与Ce/Ce*值直接相关。对于离子大小与Zr+4相似的重镧系元素,晶体化学因素更为重要,锆石中重镧系元素浓度对Ce/ Ce*的依赖性减弱。
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引用次数: 0
First data on rare earth mineralization in acid rock varieties of the Shatak complex (Southern Urals) 南乌拉尔沙塔克杂岩酸性岩类稀土矿化首次资料
Q4 Earth and Planetary Sciences Pub Date : 2023-11-04 DOI: 10.24930/1681-9004-2023-23-5-910-929
S. G. Kovalev, S. S. Kovalev, A. A. Sharipova
Research subject . Acid rock varieties of the Shatak complex were studied. Materials and methods . The reseach object included the previously unknown abundant mineralization represented by rare earth minerals. The concentration of petrogenic oxides was determined by the X-ray fluorescence method at the IG UFRC RAS (Ufa) using a VRA-30 spectrometer (Carl Zeiss, Germany) with an X-ray tube with a W-anode (30 kV, 40 mA). The amount of rare earth elements in the rocks of the studied area was determined by the ICP-MS method at the Central Research Institute of VSEGEI (St. Petersburg). The mineralogy was studied using a Tescan Vega Compact scanning electron microscope equipped with an Xplorer Oxford Instruments energy-dispersive analyzer (IG UFRC RAS, Ufa). Results . The studied rocks were diverse in chemical composition, varying from alkaline varieties (trachydacites) to low-alkaline rhyolites. These rocks belong to a highalumina type characterized by potassium specialization and a low agpaitic coefficient. It is assumed that the felsic varieties are subvolcanic formations, and the term “rhyolites” in this case characterizes the chemical composition of the rocks, but not their genesis. The amount of rare earth elements in the studied rocks is subject to significant fluctuations, varying from 60.81 g/t to 1625.39 g/t; moreover, their distribution is characterized by significant differentiation. In general, the rocks belong to a contrasting basalt-rhyolitic series, and their genesis is due to the differentiation of magma in the intermediate chamber. Numerous rare-earth minerals were found in the rocks, inlcuding allanite-(Ce), monazite-(Ce), monazite-(La), nioboeshinit-(Y), aeschinite-(Y), talena-(Dy), talena-(Nd), synchisite-(Ce) and Ce–La–Fe oxide. Conclusions . The presence of paragenetic associations of rare-earth minerals, such as allanite-(Ce) + aeschinite-(Y) + nioboaeschinite-(Y) and allanite-(Ce) + talena-(Dy) + talena-(Nd), indicate the formation of rare-earth mineralization in the course of a single process. The described type of mineralization has no analogues on the western slope of the Southern Urals, which substantiates the need for further research.
研究课题。研究了沙塔克杂岩的酸性岩种类。材料和方法。研究对象包括以前未知的以稀土矿物为代表的丰富矿化。在IG UFRC RAS (Ufa)上,使用VRA-30光谱仪(卡尔蔡司,德国)和w阳极(30 kV, 40 mA) x射线管,采用x射线荧光法测定了成岩氧化物的浓度。研究区岩石中稀土元素的含量由VSEGEI中央研究所(圣彼得堡)用ICP-MS法测定。矿物学研究使用Tescan Vega Compact扫描电子显微镜,配备Xplorer Oxford Instruments能量色散分析仪(IG UFRC RAS, Ufa)。结果。所研究的岩石化学成分多样,从碱性品种(粗达英岩)到低碱性流纹岩不等。这些岩石属于高铝型,具有钾特化和低溶染系数的特征。据推测,长英质变种是次火山构造,在这种情况下,“流纹岩”一词表征的是岩石的化学成分,而不是它们的成因。研究岩石中稀土元素的含量波动较大,从60.81 g/t到1625.39 g/t不等;而且,它们的分布具有显著的差异性。岩石总体上属于玄武岩-流纹岩对比系列,其成因是由于岩浆在中间岩浆室中分异所致。在岩石中发现了大量的稀土矿物,包括allanite-(Ce)、monazite-(Ce)、monazite-(La)、nioboeshinit-(Y)、aeschinite-(Y)、talena-(Dy)、talena-(Nd)、synchite -(Ce)和Ce - La - fe氧化物。结论。allanite-(Ce) + aeschinite-(Y) + nioboaeschinite-(Y)、allanite-(Ce) + talena-(Dy) + talena-(Nd)等稀土矿物共生组合的存在,表明稀土成矿作用是在一个单一过程中形成的。所描述的成矿类型在南乌拉尔西坡没有类似的成矿类型,因此需要进一步研究。
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引用次数: 0
Mineral assemblages from chromitites of the Alapaevsk dunite-harzburgite massif (Middle Urals) 中乌拉尔阿拉帕耶夫斯克黑锰矿块体铬铁矿矿物组合
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-740-765
V. V. Murzin, К. N. Malitch, I. Yu. Badanina, D. A. Varlamov, I. S. Chashchukhin
Research subject . Minerals and mineral assemblages of noble elements in chromitites of the Alapaevsk massif. Aim . A systematic mineralogical study of high-chromium (Cr) and alumina-rich (Al) chromitites with the development of a sequence scheme for mineral formation, including platinum-group minerals (PGMs) and gold alloys. Materials and Methods. Samples of high-Cr and Al chromitites from chromite deposits in various parts of the Alapaevsk massif. Scanning electron microscopy (Tescan VEGAII XMU and JSM-6390LV Jeol with EDX INCA Energy 450 X-Max 80 spectrometers) and electron microprobe analysis (Cameca SX 100 with five wave spectrometers) were used. Results . A diagram showing the sequence of mineral formation in chromitites was designed; primary and secondary mineral assemblages were distinguished, with the latter assemblage being divided into early and late mineral associations. Primary assemblages of high-Cr (Cr 2 O 3 > 50 wt %) and Al (Cr 2 O 3 < 50 wt %) ores are represented by similar minerals, including chromespinel, clinopyroxene, and olivine, with characteristically distinct compositions of these minerals in each type of ores. Minerals of the primary assemblage are synchronous with chrome-spinel and are represented by pentlandite, Cu-bearing pentlandite, chalcopyrite, pyrrhotite, bornite, as well as PGMs (laurite RuS 2 , erlichmanite OsS 2 , native osmium) and Cu-rich gold. Minerals of the secondary early association occur in the form of polyphase inclusions within chrome-spinel. Polyphase inclusions are composed of Cr-bearing chlorite, amphibole, garnet, sulfides (millerite, heazlewoodite) and minerals of native elements, including (Ni, Cr)-bearing copper, nickel-bearing copper, (Cu, Fe, Cr)-bearing nickel, awaruite. Noble metal minerals from the secondary early association were found only in Al chromitites and are represented by laurite, Pt- and Pd arsenides and stibnides, Ru-bearing pentlandite, and high-grade native gold. The secondary late mineral association consists of native copper and awaruite, which are intergrown with serpentine in high-Cr ore. The temperature conditions for the formation of secondary assemblages were estimated using a chlorite geothermometer. The formation temperatures of the studied chlorites from chromitites fall within the range of 250–284°C. Conclusions . Noble metal minerals from secondary associations were formed at temperatures below 350°C together with garnet, amphibole, chlorite, and nickel sulfides. Grains of primary Os–Ir–Ru alloys during epigenetic processes underwent sulfurization with the formation of a fine-grained porous mixture of native and sulfide (sometimes with As) phases, and replacement by Ru-pentlandite. The presence of awaruite and native Cu and Ni in both primary and secondary assemblages of chromotites indicates the reducing conditions for the formation of noble metal minerals. The limited occurrence of high-Cr ores, along with the manifested processes of sulfurization for primary
研究课题。阿拉帕耶夫斯克地块铬铁矿中稀有元素的矿物和矿物组合。的目标。对高铬(Cr)和富铝(Al)铬铁矿进行了系统的矿物学研究,并制定了包括铂族矿物(PGMs)和金合金在内的矿物形成序列方案。材料与方法。阿拉帕耶夫斯克地块不同地区铬铁矿床的高铬和高铝铬铁矿样品。使用扫描电子显微镜(Tescan VEGAII XMU和JSM-6390LV Jeol,配备EDX INCA Energy 450 X-Max 80光谱仪)和电子探针分析(Cameca SX 100,配备5台波光谱仪)。结果。设计了铬铁矿矿物形成顺序图;区分了原生矿物组合和次生矿物组合,次生矿物组合分为早期和晚期矿物组合。高Cr (cr2o3 >50 wt %)和Al (cr2o3 <50%的矿石由类似的矿物代表,包括彩晶石、斜辉石和橄榄石,每种矿石中这些矿物的特征组成不同。原生组合矿物与铬尖晶石同步,以镍黄铁矿、含铜镍黄铁矿、黄铜矿、磁黄铁矿、斑铜矿为代表,并以褐铁矿ro_2、黑石o_2、原生锇、富铜金为代表。次生早期结合的矿物以多相包裹体的形式出现在铬尖晶石中。多相包裹体由含Cr绿泥石、角闪孔、石榴石、硫化物(千闪石、绢云石)和含(Ni、Cr)铜、含镍铜、(Cu、Fe、Cr)镍、白钨等天然元素矿物组成。次生早期组合的贵金属矿物仅在铝铬铁矿中发现,以褐铁矿、铂、钯砷化物和辉锑矿、含钌镍黄铁矿和高品位天然金为代表。次生晚期矿物组合由原生铜和青石组成,并与高铬矿石中的蛇纹石共生。利用绿泥石地温计估算了次生组合形成的温度条件。绿泥石的形成温度在250 ~ 284℃之间。结论。次生组合中的贵金属矿物与石榴石、角闪孔、绿泥石和硫化镍在350℃以下形成。初生Os-Ir-Ru合金晶粒在后生过程中经历了硫化,形成了原生相和硫化物(有时含有As)相的细粒多孔混合物,并被Ru-pentlandite取代。黄铜矿原生组合和次生组合中均存在赤铁矿和原生Cu、Ni,说明了贵金属矿物形成的还原条件。由于高cr矿石的有限产状以及Os-Ir-Ru合金初生晶粒的明显硫化过程,导致Alapaevsk地块碎屑PGM的稀缺。
{"title":"Mineral assemblages from chromitites of the Alapaevsk dunite-harzburgite massif (Middle Urals)","authors":"V. V. Murzin, К. N. Malitch, I. Yu. Badanina, D. A. Varlamov, I. S. Chashchukhin","doi":"10.24930/1681-9004-2023-23-5-740-765","DOIUrl":"https://doi.org/10.24930/1681-9004-2023-23-5-740-765","url":null,"abstract":"Research subject . Minerals and mineral assemblages of noble elements in chromitites of the Alapaevsk massif. Aim . A systematic mineralogical study of high-chromium (Cr) and alumina-rich (Al) chromitites with the development of a sequence scheme for mineral formation, including platinum-group minerals (PGMs) and gold alloys. Materials and Methods. Samples of high-Cr and Al chromitites from chromite deposits in various parts of the Alapaevsk massif. Scanning electron microscopy (Tescan VEGAII XMU and JSM-6390LV Jeol with EDX INCA Energy 450 X-Max 80 spectrometers) and electron microprobe analysis (Cameca SX 100 with five wave spectrometers) were used. Results . A diagram showing the sequence of mineral formation in chromitites was designed; primary and secondary mineral assemblages were distinguished, with the latter assemblage being divided into early and late mineral associations. Primary assemblages of high-Cr (Cr 2 O 3 > 50 wt %) and Al (Cr 2 O 3 < 50 wt %) ores are represented by similar minerals, including chromespinel, clinopyroxene, and olivine, with characteristically distinct compositions of these minerals in each type of ores. Minerals of the primary assemblage are synchronous with chrome-spinel and are represented by pentlandite, Cu-bearing pentlandite, chalcopyrite, pyrrhotite, bornite, as well as PGMs (laurite RuS 2 , erlichmanite OsS 2 , native osmium) and Cu-rich gold. Minerals of the secondary early association occur in the form of polyphase inclusions within chrome-spinel. Polyphase inclusions are composed of Cr-bearing chlorite, amphibole, garnet, sulfides (millerite, heazlewoodite) and minerals of native elements, including (Ni, Cr)-bearing copper, nickel-bearing copper, (Cu, Fe, Cr)-bearing nickel, awaruite. Noble metal minerals from the secondary early association were found only in Al chromitites and are represented by laurite, Pt- and Pd arsenides and stibnides, Ru-bearing pentlandite, and high-grade native gold. The secondary late mineral association consists of native copper and awaruite, which are intergrown with serpentine in high-Cr ore. The temperature conditions for the formation of secondary assemblages were estimated using a chlorite geothermometer. The formation temperatures of the studied chlorites from chromitites fall within the range of 250–284°C. Conclusions . Noble metal minerals from secondary associations were formed at temperatures below 350°C together with garnet, amphibole, chlorite, and nickel sulfides. Grains of primary Os–Ir–Ru alloys during epigenetic processes underwent sulfurization with the formation of a fine-grained porous mixture of native and sulfide (sometimes with As) phases, and replacement by Ru-pentlandite. The presence of awaruite and native Cu and Ni in both primary and secondary assemblages of chromotites indicates the reducing conditions for the formation of noble metal minerals. The limited occurrence of high-Cr ores, along with the manifested processes of sulfurization for primary","PeriodicalId":32819,"journal":{"name":"Litosfera","volume":"30 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135874311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Petrographic composition and material sources of Upper Paleozoic rough-clastic rocks in Western Taimyr 塔里木西部上古生界粗碎屑岩的岩石组成及物质来源
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-785-808
S. B. Shishlov, E. Yu. Akimova, K. A. Dubkova
Research subject . Gravelites and conglomerates of the Upper Carboniferous and Permian of Western Taimyr. Aim . To reveal features of the petrographic composition of coarse clastic rocks and, on this basis, to clarify the ideas about the composition and position of the feeding province of the western part of the Taimyr sedimentary basin in the Late Paleozoic. Materials and methods . The analysis of materials collected during a layer-by-layer study of sections and microscopic description of 47 large transparent sections with the count of psephitic (more than 2 mm) fragments of quartzites, felsic and basic igneous, metamorphic and sedimentary rocks was performed. The revealed features of the petrographic composition of psephytoliths, in combination with a generalization of previously published geodynamic and paleogeographic reconstructions, were used to refine the model of the geological development of the Taimyr fold-thrust belt and adjacent areas in the Late Paleozoic. Results . It was established that the sections contain polymictic lithoclastic (83%) and petroclastic (15%) psephytoliths, with occasional inclusions of oligomictic essentially quartz varieties (2%). Minor changes in the composition of clasts over time indicate the existence of a single source of clastic material during the entire Late Paleozoic, which formed the sections of Western Taimyr. It was shown that the maturity of psephytolites increases from the southwest to the northwest and northeast. Numerous fragments of phtanites and lydites with remains of radiolarians of the Middle Devonian – early Early Carboniferous were identified, analogs of which are present in the Lemva zone of the Urals and in the basement of Western Siberia. Conclusions . The material forming the coarse clastic rocks of Western Taimyr was transported by the river for 600–1000 km from the folded structures of the “West Siberian land” located in the southwest (in modern coordinates), which formed in the Visean–Serpukhovian ages of the Early Carboniferous during the collision of the East - European, Kazakhstan and Siberian continental blocks.
研究课题。塔米尔西部上石炭统和二叠统砾岩。的目标。揭示粗碎屑岩的岩相组成特征,并在此基础上阐明晚古生代塔里木盆地西部供养省的组成和位置。材料和方法。对在切片逐层研究中收集的材料进行了分析,并对47个大型透明切片进行了显微描述,并对石英岩、长英质和基性火成岩、变质岩和沉积岩的腐斑(超过2毫米)碎片进行了计数。利用拟植物岩的岩石组成特征,结合已有的地球动力学和古地理重建成果,完善了晚古生代泰米尔褶皱冲断带及邻区地质发育模式。结果。结果表明,该剖面含有多晶岩屑(83%)和岩屑(15%)伪植岩,偶有少晶石英(2%)。随着时间的推移,碎屑成分的微小变化表明,在整个晚古生代,形成了西泰米尔剖面的单一碎屑物质来源。结果表明,伪长晶石的成熟度由西南向西北、东北依次递增。在乌拉尔地区的Lemva带和西伯利亚西部的基底中发现了大量中泥盆世-早石炭世早期放射虫的辉长岩和吕长岩碎片。结论。在早石炭世的visian - serpukhovian时代,在东欧、哈萨克斯坦和西伯利亚大陆块体的碰撞过程中形成的“西西伯利亚陆块”的褶皱构造,将形成西泰米尔粗碎屑岩的物质从位于西南(现代坐标)的“西西伯利亚陆块”的褶皱构造中运送了600-1000公里。
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引用次数: 0
Complex characteristics of suevites at the B. Vanuyta river (Kara astrobleme, Russia) B. Vanuyta河(Kara astrobleme,俄罗斯)岩石的复杂特征
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-844-867
N. I. Maksimenko, T. G. Shumilova, V. V. Ulyashev
Research subject. Suevites from the eastern sector of the Kara astrobleme, located in the basin of the Bolshaya Vanuyta river. Aim. To identify the suevitic type and to clarify the facial features of the suevites from the B. Vanuyta River. Materials . Hand-size samples of suevites collecteed in the basins of B. Vanuyta, Anaroga, Kara, and Sopchayu rivers, as well as samples of siltstones collected outside the Kara crater (rivers Halmeryu, Sayakha, Putyu, Anaroga and the creek Lavovyi). The samples were used for preparing polished thin sections and powder specimens for analytical works. Methods . Field observations, optical and electron scanning microscopy, and silicate analysis by the wet chemical method. Results and conclusions . The structural-textural and petrochemical features of the matrix, fragments of impact glasses, and lithoclasts of suevites from the B. Vanuyta river were characterized. The suevite matrix was found to exhibit an intensely sintered character and to be presented by feldspar, quartz, calcite, chlorite, muscovite, glauconite, and titanite. Lithoclasts include siltstones, sandstones, limestones, mudstones, and shales. Vitroclasts are characterized by angular and irregular morphology with different border patterns, and spotted, fluid, and porous textures. The similarity of the chemical composition of siltstone clusters and similar target rocks confirms the genetic relationship and the leading role of this type of target rocks in the formation of the studied suevites. The proximity in the composition of the impact glasses of the studied suevites and the glasses of type I and II suevites indicates the formation of suevite vitroclasts in the river B. Vanuyta by a similar protolith – siltstones and a clay component of the limestones. The matrix lithification character, morphology and nature of the vitroclast outlines indicate that the suevites from the B. Vanuyta river are the rocks of an aerodynamic facies formed under relatively high-temperature conditions, which structurally lie at the lower part of the detrital impactites sequence of the aerodynamic facies. The studied rocks are close to the type I suevites by the composition of the protolith and differ in the conditions of their formation. With the type II suevites, they have similar facies characteristics, but differ in the composition of the target rocks fragments. It is determined that the leading factor in the typification of suevites from the Kara astrobleme is the chemical composition, at the same time, the types can be subdivided more fractionally based on the specifics of the facies environments of their formation.
研究课题。来自卡拉阿斯特勒姆东部地区的苏维人,位于Bolshaya Vanuyta河流域。的目标。目的:鉴别瓦努塔河细纹岩类型,厘清其面相特征。材料。在B. Vanuyta河、Anaroga河、Kara河和Sopchayu河流域收集的手大小的suveites样本,以及在Kara陨石坑(Halmeryu河、Sayakha河、Putyu河、Anaroga河和Lavovyi河)外收集的粉砂岩样本。样品用于制备抛光薄片和粉末样品,用于分析工作。方法。现场观察,光学和电子扫描显微镜,和硅酸盐分析湿化学方法。结果和结论。研究了B. Vanuyta河苏维岩的基质、冲击玻璃碎片和岩屑的结构-结构和石化特征。镁铝石基体具有强烈的烧结特征,主要由长石、石英、方解石、绿泥石、白云母、海绿石和钛矿组成。岩屑包括粉砂岩、砂岩、灰岩、泥岩和页岩。玻璃碎屑具有棱角分明、不规则的形态和不同的边缘图案,具有斑点状、流体状和多孔状的结构。粉砂岩簇与相似目标岩化学成分的相似性证实了这类目标岩在研究的镁质岩形成过程中的成因关系和主导作用。所研究的苏伟岩体的冲击玻璃与I型和II型苏伟岩体玻璃的成分接近,表明B. Vanuyta河的苏伟岩体碎屑是由类似的原岩粉砂岩和石灰石中的粘土组分形成的。碎屑岩的基质岩化特征、形态和性质表明,B. Vanuyta河碎屑岩是在相对高温条件下形成的气动力相岩石,在结构上位于气动力相碎屑冲击层序的下部。所研究的岩石在原岩组成上与ⅰ型苏威岩相近,但形成条件不同。与II型榴辉岩相特征相似,但目标岩碎片组成不同。确定了卡拉星闪岩类型的主导因素是其化学成分,同时根据其形成相环境的特殊性,可以对其类型进行更精细的细分。
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引用次数: 0
Hornblende in ultramafic-mafic rocks of the Khudolaz Complex of the Southern Urals: Crystallization conditions and petrological implications 乌拉尔南部Khudolaz杂岩超基性-基性岩中的角闪石:结晶条件及其岩石学意义
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-766-784
I. R. Rakhimov, A. V. Vishnevskiy
Subject research . Morphology and chemical composition of amphiboles from ultramafic-mafic rocks of the Khudolaz complex. Methods . Morphological studies were carried out using optical (Carl Zeiss Axioskop 40A) and electron (Tescan Vega Compact) microscopes. The chemical composition of minerals was determined using CAMECA SX 100 and JEOL JXA-8230 electron probe microanalyzers . Results . The rocks under study are dominated by xenomorphic brown titanium hornblende crystals, formed mainly due to the reaction of clinopyroxene with a residual water-saturated melt at 920–1040°C. Euhedral brown hornblende, which crystallized directly from the residual water-saturated melt in the same temperature range, was found in small amounts. Green hornblende originated along the edges and cracks in brown hornblende crystals during the late magmatic stage and early hydrothermal stage (670–830°C) at the subsolidus transformation. At the hydrothermal stage (620–650°C and below), brown and green hornblende were partially replaced by actinolite and cummingtonite. Conclusions . The nature of changes in the composition of brown hornblende indicates similar petrogenesis conditions at the late magmatic stage in all intrusions of the Khudolaz complex. The process of transition from brown hornblende to green hornblende occurred with a gradual increase in oxygen fugacity (ΔNNO from –0.2…+0.4 to +0.9…+2.5), and was accompanied by decrease of Ti, Fe 2+ , Na and the increase of Si, Al VI , Mg, and K in the mineral structure. The low concentrations of F and Cl in hornblende crystals indicate their formation after migration of halogens from the melt.
课题研究。Khudolaz杂岩超基性-基性岩中角闪石的形态和化学成分。方法。形态学研究采用光学显微镜(Carl Zeiss Axioskop 40A)和电子显微镜(Tescan Vega Compact)进行。采用CAMECA SX 100和JEOL JXA-8230电子探针微量分析仪测定矿物化学成分。结果。所研究的岩石以异型棕色钛角闪石晶体为主,主要由斜辉石与残余水饱和熔体在920 ~ 1040℃反应形成。少量自形棕色角闪石由残余饱和水熔体在同一温度范围内直接结晶。绿色角闪石在岩浆晚期和热液早期(670 ~ 830℃)的亚固相转变中沿棕色角闪石晶体的边缘和裂缝形成。在热液期(620 ~ 650℃及以下),棕色和绿色角闪石部分被放光石和明辉石所取代。结论。棕角闪石组成变化的性质表明,各侵入体在岩浆晚期的成岩条件相似。从褐色角闪石到绿色角闪石的转变过程伴随着氧逸度的逐渐增加(ΔNNO从-0.2…+0.4到+0.9…+2.5),伴随着矿物结构中Ti、Fe 2+、Na的减少和Si、Al VI、Mg、K的增加。角闪石晶体中F和Cl的低浓度表明它们是熔体中卤素迁移后形成的。
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引用次数: 0
Gley catagenesis of Devonian red-colored rocks on the Middle Timan 中提曼泥盆纪红色岩石的闪蚀作用
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-809-819
I. Kh. Shumilov
Research subject . The article presents the results of morphological, mineralogical, and geochemical studies into gley zones in the Devonian red-colored sediments of the Middle Timan. Aim . Determination of the timing of gleization processes in the formation history of the Devonian sedimentary strata; identification of morphological, mineralogical and geochemical features of gley zones. Methods. A macroscopic study of the morphology of gley zones in successive sections of the sediments was carried out in field conditions. Thin sections were studied using a Nikon eclipse LV100 ND polarization microscope with a Nikon DS Fi2 camera; polished samples were characterized using a TESCAN electron microscope VEGA3 with an Oxford instruments X-Max energy dispersion attachment; the chemical composition was determined by an X-ray fluorescent silicate method on a MESA-500W spectrometer; X-ray diffraction analysis was performed using a Shimadzu XRD-6000 diffractometer under the CuKα radiation. Results . In terms of size and morphological features, the gley zones under study are divided into four types: point, veined, lens-shaped, and bed-shaped. The similarity between the forms of gley zones and core organics fragments was established both in plan and vertically. The lithological heterogeneity of rocks (stratification) does not have any effect on the development of gley processes. Changes in the content of rock-forming elements during gleization are confined to intensive iron removal and a slight decrease in the potassium content; the silica content remains almost unchanged. An increase in the content of aluminum, titanium, and magnesium was observed. Among the contents of microelements, trends towards accumulation of Y and Yb, removal of Ga, V, Co, Ni are noticeable. Conclusions . Gleization processes proceeded for a very long time until the sedimentary sequence was completely formed and compacted; the main mechanism of chemical element migration was diffusion.
研究课题。本文介绍了中提曼泥盆纪红色沉积物中泥质带的形态、矿物学和地球化学研究结果。的目标。泥盆纪沉积地层形成史中gleization作用时间的确定泥化带的形态、矿物学和地球化学特征识别。方法。在野外条件下,对连续剖面沉积物的泥质带形态进行了宏观研究。采用尼康DS Fi2相机,使用Nikon eclipse LV100 ND偏光显微镜对薄片进行研究;使用TESCAN电子显微镜(VEGA3)对抛光后的样品进行表征,并用Oxford instruments的X-Max能量色散连接;在MESA-500W光谱仪上用x射线荧光硅酸盐法测定化学成分;在CuKα辐射下,用岛津XRD-6000衍射仪进行x射线衍射分析。结果。根据大小和形态特征,研究的沟带可分为点状、脉状、透镜状和床状四种类型。在平面上和垂直上,建立了沟状带与岩心有机质碎片形态的相似性。岩石的岩性非均质性(分层)对泥化过程的发育没有任何影响。闪化过程中形成岩石元素含量的变化仅限于铁的强烈去除和钾含量的轻微降低;二氧化硅含量几乎保持不变。观察到铝、钛和镁的含量增加。微量元素中,Y、Yb的富集趋势明显,Ga、V、Co、Ni的去除趋势明显。结论。Gleization过程持续了很长时间,直到沉积层序完全形成和压实;化学元素迁移的主要机制是扩散。
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引用次数: 0
Geological structure and Mesozoic-Cenozoic tectonic evolution of the Nenya-Chumysh basin (Southern Salair, southern Western Siberia) 西伯利亚南部Salair南部涅尼亚-丘姆什盆地地质构造与中新生代构造演化
Q4 Earth and Planetary Sciences Pub Date : 2023-11-03 DOI: 10.24930/1681-9004-2023-23-5-820-843
F. I. Zhimulev, A. V. Kotlyarov, I. S. Novikov, N. V. Sennikov, K. K. Kolesov
Research subject . The Nenya-Chumysh basin is a long-term Mesozoic intracontinental sedimentary basin confined to the zone of a regional fault separating the Salair from the structures of Gorny Altai, Gornaya Shoria, and the Kuznetsk basin. Aim . To establish the geological and structural-kinematic characteristics of impulses of intracontinental orogeny that took place during the Mesozoic and Cenozoic in the territory of the northwestern part of the Altai-Sayan Folded Area. Materials and Methods . Geological maps of the area, geophysical data on the position of the base of the Paleozoic basement, satellite images and digital elevation models were used. The sedimentary filling of the basin is considered as a chronicle of tectonic movements in the NW part of the Altai-Sayan Folded Area at the intracontinental stage of development. Results . The Early Jurassic, Early Cretaceous, Late Cretaceous-Paleogene, and Neogene-Quaternary tectonic stages of the development of the Nenya-Chumysh basin were distinguished. In the Early Jurassic, the Nenya-Chumysh basin was a pull-apart basin in a left-hand strike-slip zone. This stage is associated with the accumulation of coal-bearing deposits of the Glushinskaya Formation, the thickness of which in the Nenya-Chumysh basin reaches about 1900 m. In the Early Cretaceous, as a result of changes in the stress field, the Nenya-Chumysh basin was transformed into a thrust basin, composed of terrigenous deposits of the Ilek Formation, forming a wedge-shaped sedimentary basin characteristic of foreland troughs. The neotectonic structure of the Nenya-Chumysh basin, formed in the stress field of the Indo-Eurasian collision, inherits an older structural plan in general terms, although differing in details. A non-inherited structure is the transverse neotectonic uplift of the Sary-Chumysh swell. Conclusions . The Early Jurassic stage is related with the closure of the Paleo-Tethys and the collision of a series of Cimmerian terranes with the southern margin of Eurasia, Early Cretaceous stage is caused with Mongol-Okhotsk collision, and the Cenozoic stage proceeds with the ongoing Indo-Eurasian collision. The geological evolution of continental sedimentary basins controlled by regional faults can be used as a source of information about the intensity and kinematic pattern of impulses of intracontinental orogeny in the geological past.
研究课题。Nenya-Chumysh盆地是一个长期的中生代陆内沉积盆地,局限于将Salair与Gorny Altai、Gornaya Shoria和Kuznetsk盆地的构造分隔开的区域断裂带。的目标。建立阿尔泰-萨延褶皱区西北部中生代和新生代大陆内造山运动的地质和构造运动特征。材料与方法。利用了该地区的地质图、古生代基底基底位置的地球物理数据、卫星图像和数字高程模型。盆地的沉积充填被认为是阿尔泰—萨延褶皱区西北部陆内发育阶段构造运动的编年史。结果。划分了早侏罗世、早白垩世、晚白垩世—古近纪和新近系—第四纪构造发育阶段。早侏罗世,内尼亚-丘米什盆地为左侧走滑带的拉分盆地。这一阶段与Glushinskaya组含煤矿床的聚集有关,该组在涅尼亚-丘姆什盆地的厚度约为1900 m。早白垩世,Nenya-Chumysh盆地受应力场变化的影响,转变为由Ilek组陆源沉积组成的逆冲盆地,形成具有前陆坳陷特征的楔形沉积盆地。内尼亚-丘姆什盆地的新构造构造形成于印欧亚碰撞的应力场中,虽然在细节上有所不同,但总体上继承了较旧的构造格局。Sary-Chumysh隆起的横向新构造隆起为非继承构造。结论。早侏罗世阶段与古特提斯的闭合和一系列西米叠系地体与欧亚大陆南缘的碰撞有关,早白垩世阶段与蒙古-鄂霍次克碰撞有关,新生代阶段与持续的印度-欧亚碰撞有关。受区域断裂控制的陆相沉积盆地的地质演化可以作为地质史上陆内造山运动冲量强度和运动模式的信息来源。
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引用次数: 0
Amphibole peridotite and hornblendite of the Schrisheimite Hill intrusion of the Revdinskiy massif (Ural Platinum Belt) redinskiy地块(乌拉尔铂带)Schrisheimite山侵入岩的角闪孔橄榄岩和角闪岩
Q4 Earth and Planetary Sciences Pub Date : 2023-11-02 DOI: 10.24930/1681-9004-2023-23-5-721-739
P. S. Kozlov, S. V. Berzin, K. S. Ivanov, D. S. Yudin
Research subject . We studied the concentric-zonal massif (≈400 × 400 m) of amphibole-rich ultramafic rocks composed of amphibole peridotite (schriesheimite and amphibole wehrlite) with olivinite schlieren, pyroxenite and hornblendite located among gabbro at the Schrisheimite Hill in the Revdinskiy massif of the Ural Platinum Belt. The scope is characteristic of both of amphibole peridotites, which are extremely rare in the massifs of the Ural Platinum Belt, and the associated amphibole-rich ultramafic rocks. Aim. To expand the understanding of aqueous ultramafic magmatism in Ural Platinum Belt massifs. Materials and methods . To determine the age, we selected monofractions of high-alumina amphibole (pargasite-magnesiohastingsite) from two samples. Amphibole is not significantly altered by the regional metamorphism. 40 Ar/ 39 Ar dating was carried out according to the method described in (Travin et al., 2009; Yudin et al., 2021). The argon isotope composition was measured using a Micromass 5400 mass spectrometer (IGM SB RAS). Results. Amphibole peridotite has a hypidiomorphic (subhedral) or poikilitic texture. It is typical of igneous rocks, which indicates the crystallization of amphibole peridotite was by H 2 O-saturated magmas. Schlieren segregations of fine-grained schriesheimites and fine-grained olivinites are among coarse-grained schriesheimites. Amphibole peridotite, pyroxenite and hornblendite are deficient in high field strength elements (HFSE) and enriched in large ion lithophile elements (LILE) (with contrast concentration of Cs and Rb), which is typical of supra-subduction igneous formations. We obtained a 40 Ar/ 39 Ar age of 437.2 ± 6.7 Ma for an amphibole from hornblendite, which differs significantly from the ages of hornblendite determined earlier. Conclusions . Our new data indicate that hornblendite dikes in different UPB massifs formed over a fairly long time interval from the Early Silurian to the Early Devonian. These data expand modern ideas about the timing and nature of ultramafic water magmatism in the massifs of the Ural Platinum Belt.
研究课题。研究了位于乌拉尔铂带雷夫丁斯基地块中由角闪石橄榄岩(角闪石岩和角闪石)与橄榄岩、辉石岩和角闪石组成的富角闪石超基性岩体(≈400 × 400 m)。范围既具有乌拉尔铂带地块中极为罕见的角闪岩橄榄岩特征,又具有伴生的富含角闪岩的超镁铁质岩特征。的目标。扩大对乌拉尔铂带地块水超镁铁质岩浆作用的认识。材料和方法。为了确定年龄,我们从两个样品中选择了高铝角闪孔(pargasite-magnesiohastingsite)的单组分。角闪孔未受区域变质作用的明显改变。40 Ar/ 39 Ar定年是根据(Travin et al., 2009;Yudin等人,2021)。采用Micromass 5400质谱仪(IGM SB RAS)测定了样品的氩同位素组成。结果。角闪孔橄榄岩具有半自形(半面体)或似晶石结构。具有典型的火成岩特征,表明角闪孔橄榄岩是由饱和h2o岩浆结晶而成。粗粒纹长岩中有细粒纹长岩和细粒橄榄岩的纹影分异。角闪洞橄榄岩、辉石岩和角闪岩缺乏高场强元素(HFSE),而富含大离子亲石元素(LILE) (Cs和Rb的对比浓度),是典型的超俯冲火成岩构造。角闪岩角闪洞的40 Ar/ 39 Ar年龄为437.2±6.7 Ma,与前人测定的角闪岩年龄有明显差异。结论。我们的新数据表明,不同UPB地块的角闪石脉形成于早志留世至早泥盆世的相当长的时间间隔。这些数据扩展了关于乌拉尔铂带地块超镁铁质水岩浆作用的时间和性质的现代观念。
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