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Metal dynamics in a tropical watershed: The São Francisco river and its compartments 热带流域的金属动力学:<s:1>弗朗西斯科河及其分区
Pub Date : 2019-03-24 DOI: 10.21715/GB2358-2812.2019332221
I. Torres, A. Horn, Rodrigo Silva Lemos
Water ecosystems are one of the most threaten environments due to anthropogenic pressures, among them the contamination of metals that are toxic to every life form. The main objective of this paper was to investigate the role of each compartment of a river system in metal dynamics using metal sediment concentration. To accomplish the objective sediments from several sites in a tropical river drainage basin were sampled comprising different types of compartments: : the river channel, the dry and wet inundation area and marginal lagoons, as well a pristine site with no anthropogenic impact. A Principal Component Analysis and the calculation of the Enrichment Factor and Index of Geoacummulation were conducted. The results showed that was no great difference of Index of Geoaccumulation among the different compartments. However, the Enrichment Factor was higher in wet inundation areas followed by dry soils from inundation areas and dry lagoons. Principal Component Analysis selected the metals Fe, Cu and Mg in axis 1, while axis 2 selected Mg and Ba. Although there was not a clear separation in the results of the multivariate analysis among sites across a transect, the analysis separated the compartments in relation to the concentration of metals. The results showed that each compartment had its own dynamics in relation to accumulation of metals present in the river basin. The study shows the importance of studying different types of habitats of a drainage basin to stablish best management practices.
由于人为压力,水生态系统是最受威胁的环境之一,其中包括对每一种生命形式都有毒的金属污染。本文的主要目的是利用金属沉积物浓度来研究河流系统中每个隔室在金属动力学中的作用。为了实现这一目标,我们对热带河流流域的几个地点的沉积物进行了采样,这些地点包括不同类型的隔间:河道、干湿淹没区和边缘泻湖,以及一个没有人为影响的原始地点。进行了主成分分析,并计算了富集系数和成藏指数。结果表明,不同隔室的成藏指数差异不大。而湿润淹没区土壤富集系数最高,其次为淹没区干燥土壤和干泻湖土壤。主成分分析在轴1选择了Fe、Cu和Mg,轴2选择了Mg和Ba。虽然在跨样带的多变量分析结果中没有明确的分离,但分析分离了与金属浓度有关的隔室。结果表明,各隔室与流域内金属的积累有其自身的动力学关系。该研究表明,研究流域不同类型的栖息地对于建立最佳管理实践具有重要意义。
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引用次数: 5
Análise isotópica de oxigênio e carbono em microfósseis da Formação Romualdo, cretáceo inferior, bacia do Araripe, Pernambuco, nordeste do Brasil 巴西东北部伯南布哥Ara熟盆地下白垩统Romualdo组微体化石中氧和碳的同位素分析
Pub Date : 2019-03-24 DOI: 10.21715/GB2358-2812.2019332133
Rilda Verônica Cardoso de Araripe, David Holanda de Oliveira, Maria Emília Travassos Rios Tomé, R. M. Mello, A. F. Barreto, A. N. Sial
This work presents the analysis of C and O isotope values behavior in the carapace of ostracodes and foraminifera from the Romualdo Formation, Araripe Basin – PE. The analized samples were collected in three outcrops (Arrojado, Canastra and Cedro) located in the cities of Exu and Araripina. The de δ 18 O values ranged from -10.1‰ to -10.2‰ VPDB and the δ 13 C values ranged between -12,6‰ to +2.7‰ VPDB. The results for oxygen data indicate high temperature of waters and the deposition of marine limestones in all outcrops. For the carbon isotopic data in the Arrojado and Canastra outcrops, the values indicate an anoxic environment with high content of organic matter. In Cedro outcrop, a positive variation occurs indicating an increase in primary production, also associated to an anoxic event, and the positive values are interpreted as a transgressive pulse. These results indicate that Cedro outcrop, located in the middlesouth portion of the basin, has environmental characteristics with greater marine influence than in the Arrojado and Canastra outcrops, located in the southwest portion.
这项工作分析了Ara熟盆地Romualdo组介形虫和有孔虫外壳中的C和O同位素值行为。分析样本采集于Exu和Araripina市的三个露头(Arrojado、Canastra和Cedro)。deδ18O值范围为-10.1‰至-10.2‰VPDB,δ13C值范围为-12.6‰至+2.7‰VPDB。氧气数据的结果表明,海水温度很高,所有露头都有海洋石灰岩沉积。对于Arrojado和Canastra露头的碳同位素数据,这些值表明存在高有机质含量的缺氧环境。在Cedro露头中,出现正变化,表明初级产量增加,这也与缺氧事件有关,正值被解释为海侵脉冲。这些结果表明,位于盆地中南部的Cedro露头具有比位于西南部的Arrojado和Canastra露头更大的海洋影响的环境特征。
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引用次数: 2
Monitoring groundwater chemical composition at an experimental area irrigated with petroleum produced water 石油采出水灌溉试验区地下水化学成分监测
Pub Date : 2019-03-24 DOI: 10.21715/GB2358-2812.2019332197
P. Stein, Germano Melo Júnior, L. C. Souza
Agricultural reuse of the produced water is an efficient means for water resource management. However it is a potentially impacting activity to soil and groundwater, and thus requires environmental monitoring throughout the process. From this perspective, the present work aims at the monitoring of groundwater quality of karstic aquifer, located in the northeast of Brazil, where an irrigation experiment was carried out using PW of the Fazenda Belem oil field, in Ceara State, Brazil. Twelve monitoring wells were evaluated through a four-stage sampling program: the first before the installation of the irrigation experiment (CHA) and the other three, respectively, during (MO1), immediately at the end (MO2) and after the experiment (MO3). The climatic effect was also considered in the evaluation, since sampling events occurred in distinct seasonal periods: the first and the last at the end of the dry season and the second and third at the end of the wet season. Investigations were performed considering two groups of wells: upstream wells and downstream wells in relation to groundwater flow in the experimental area. For Ca 2+ , Mg 2+ , K + , total hardness, HCO 3 - , F - , As, B, Li and P, there was a tendency of increasing concentrations in the Monitoring sampling, in relation to CHA. However, since this scenario was verified in both sets of wells (upstream and downstream), its causes are probably related to natural factors. It was also observed that highest concentrations occur predominantly in the MO1 and MO2 sampling stages, that is, under the influence of the wet season, when water recharges promote dissolution of carbonate constituents present in the aquifer, thus increasing its dissolved concentration. Organic substances analyzed in groundwater were not detected or were detected at very low and dispersed concentrations and without any source specific signatures. Hence, their origin can be attributed to natural or diffuse inputs.
采出水的农业回用是水资源管理的有效手段。然而,它可能会对土壤和地下水产生影响,因此需要在整个过程中进行环境监测。从这个角度来看,本工作旨在监测巴西东北部岩溶含水层的地下水质量,利用巴西塞阿拉州Fazenda Belem油田的PW进行了灌溉实验。通过四阶段采样程序对12个监测井进行了评估:第一个监测井在灌溉实验安装前(CHA),另外三个监测井分别在试验期间(MO1)、试验结束时(MO2)和试验后(MO3)。评估中还考虑了气候影响,因为采样事件发生在不同的季节:第一次和最后一次发生在旱季结束时,第二次和第三次发生在雨季结束时。调查考虑了两组井:与实验区地下水流量有关的上游井和下游井。对于Ca2+、Mg 2+、K+、总硬度、HCO3-、F-、As、B、Li和P,监测采样中的浓度有增加的趋势,与CHA有关。然而,由于这种情况在两组井(上游和下游)中都得到了验证,其原因可能与自然因素有关。还观察到,最高浓度主要出现在MO1和MO2采样阶段,也就是说,在雨季的影响下,充水促进含水层中碳酸盐成分的溶解,从而增加其溶解浓度。地下水中分析的有机物质没有被检测到,或者检测到的浓度非常低且分散,没有任何特定来源的特征。因此,它们的起源可以归因于自然或扩散输入。
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引用次数: 0
Avaliação hidrogeoquímica das águas superficiais e subterrâneas na região sudoeste da bacia do rio Subaúma, Bahia 巴伊亚州subauma河流域西南地区地表水和地下水的水文地球化学评价
Pub Date : 2019-03-24 DOI: 10.21715/GB2358-2812.2019332188
Paulo Henrique Prado Stefano, Sillas Alves de Cristo, Ivan Pastro Gomes, Mirna Marierse Nepomuceno Santos
O presente estudo teve como objetivo avaliar as aguas superficiais e subterrâneas da regiao sudoeste da bacia hidrografica do Rio Subauma, que compreende os municipios de Alagoinhas, Aramari e Inhambupe, BA.  Foram amostrados 9 pocos tubulares da regiao, entre eles pocos residenciais e de localidades publicas como escolas e predios da prefeitura. Alem disso, foram analisadas 6 amostras de aguas superficiais ao longo do rio, sendo que a primeira amostra foi coletada proxima a nascente e a ultima a jusante do povoado de Riacho da Guia. Foram analisados parâmetros como pH, cor, turbidez, ferro (Fe), manganes (Mn), amonia (NH 3 ), nitrato (NO 3 -), nitrito (NO 2 - ), solidos totais dissolvidos (STD), dureza, sodio (Na), potassio (K), magnesio (Mg), calcio (Ca) fosforo (P), fluoreto (F - ), sulfato (SO 4 ), cloreto (Cl - ), oxigenio dissolvido (OD), bicarbonato (HCO 3 - ) e carbonato (CO 3 2- ). As aguas subterrâneas foram classificadas em sua maioria como cloretadas sodica, com os ions Na e Cl em maior abundância. As aguas superficiais mostraram uma significante contaminacao antropica a qual aumenta quanto mais a jusante na bacia hidrografica. Os elevados teores de ferro tanto nas aguas superficiais como nas aguas subterrâneas foram atribuidos ao ferro contido na Formacao Barreiras. Por fim, as aguas da bacia podem ser utilizadas para fins de irrigacao sem grandes restricoes.
本研究旨在评估苏巴马河流域西南部地区的地表水和地下水,该地区包括阿拉巴马州阿拉戈尼亚斯市、亚拉马里市和英汉普市。对该地区的九个管状区域进行了采样,包括住宅和公共场所的区域,如学校和市政厅建筑。此外,还对沿河的6个地表水样本进行了分析,第一个样本在源头附近采集,最后一个样本在Riacho da Guia村下游采集。参数如pH、颜色、浊度、铁(Fe)、锰(Mn)、氨(NH3)、硝酸盐(NO3-)、亚硝酸盐(NO2-)、总溶解固体(STD)、硬度、钠(Na)、钾(K)、镁(Mg)、钙(Ca)、磷(P)、氟化物(F-)、硫酸盐(SO4)、氯化物(Cl-)、溶解氧(OD)、碳酸氢盐(HCO3-)和碳酸盐(CO3-)。地下水主要被归类为氯化钠,Na和Cl离子含量更高。地表水显示出明显的人为污染,这在流域下游进一步增加。地表和地下水中的高铁含量归因于屏障地层中所含的铁。最后,该流域的水可以用于灌溉目的,没有重大限制。
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引用次数: 1
Estudo de caracterização geoquímica e das associações de foraminíferos parálicos do sistema estuarino do rio Jequitinhonha, litoral sul da Bahia 巴伊亚州南海岸杰基蒂洪哈河河口系统有孔虫的地球化学特征及组合研究
Pub Date : 2019-03-24 DOI: 10.21715/GB2358-2812.2019332143
I. Azevedo, Simone Souza de Moraes, Antônio Fernando de Souza Queiroz, Ana Carina Matos Silva, N. Escobar, F. Gonzaga
As associacoes de foraminiferos, alem de serem abundantes e apresentarem ampla distribuicao geografica, aproveitam as peculiaridades intrinsecas desses organismos de armazenarem em suas testas caracteristicas dos locais onde viveram. Nesse contexto, as testas desses organismos foram relacionadas aos teores de metais-traco do sedimento do sistema estuarino do rio Jequitinhonha, litoral sul da Bahia, com o objetivo de avaliar se os niveis desses elementos estao afetando a microfauna. Foram obtidas, para a regiao do canal, 281 testas de foraminiferos na primeira campanha (4,98% dos especimes foram coletados vivos; e nenhuma das testas estavam malformadas) pertencentes a 10 especies, das quais destacam-se Trochammina inflata; Haplophragmoides wilberti e Ammonia beccarii como especies principais. Na segunda amostragem, nao houve registro de foraminiferos, devido as baixas salinidades, impossibilitando a sobrevivencia ate das especies mais resistentes. Na zona de manguezal, na primeira campanha, foram obtidas 116 testas (5,1% de vivos; 0,0% de anomalos) de 10 especies destacaram-se Haplophragmoides wilberti ; Ammonia beccarii ; Quinqueloculina fusca e Q. venusta . Na segunda campanha, foram registradas apenas 143 testas (0,70% de vivos; 0,0% de anomalias) de 10 especies, destacaram-se 4 especies a saber: H. wilberti ; Trochammina inflata e Q. fusca , sendo que, o aumento do numero de testas, deve-se ao aumento da salinidade. Alem disso, foi observado, apenas na primeira campanha do canal do rio Pardo que somente o chumbo (pontos 2, 3, 4, 5 e 6) apresentou valores acima dos limites estabelecidos pelos orgaos de referencia (CONAMA - Brasil, 2012) e Canadian Council of Ministers of the Environment (CCME, 1998).
有孔虫群落除了丰富且具有广泛的地理分布外,还利用了这些生物的内在特性,将它们生活的地方的特征储存在它们的额头上。在这种情况下,这些生物的额头与巴伊亚南部海岸Jequitinhonha河河口系统沉积物中的微量金属含量有关,以评估这些元素的水平是否影响到微型动物。在第一次活动中,共采集到10个物种的281个有孔虫额头(4.98%的标本是活采集的;没有一个额头畸形),其中充气Trochammina尤为突出;主要种为拟单花虫和小氨水。在第二次采样中,由于盐度低,没有有孔虫的记录,即使是最具抵抗力的物种也无法生存。在红树林区,在第一次活动中,10个物种的116个睾丸(5.1%存活;0.0%异常)脱颖而出;贝氏氨;Quinqueloculin fusca和Q.venusta。在第二次活动中,仅记录了10个物种的143个睾丸(0.70%存活;0.0%异常),其中4个物种突出显示:H.wilberti;Trochammin膨胀和Q.fusca,额头数量的增加是由于盐度的增加。此外,据观察,只有在Pardo河河道的第一次战役中,只有铅(第2、3、4、5和6点)的数值超过了参考机构(CONAMA-巴西,2012年)和加拿大环境部长理事会(CCME,1998年)确定的限值。
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引用次数: 0
Estação Ecológica Mata dos Ausentes (EEMA), Senador Modestino Gonçalves/Minas Gerais, e seus desafios: análise da vazão e qualidade dos corpos d'água na região do seu entorno estacao ecologica Mata dos Ausentes (EEMA), Senador Modestino goncalves /Minas Gerais,及其挑战:周边地区水体的流量和质量分析
Pub Date : 2019-03-14 DOI: 10.21715/GB2358-2812.2019332165
S. G. Campos, P. Santos, Luiz Augusto Ferreira-da-Silva, D. M. Pimentel, Igor Brumano Coelho Amaral, Arlete Barbosa dos Reis
Water is a fundamental natural resource for life, for economic development and for social well-being, having a infinity of uses, from the simplest to the most complex. However, it has gradually become a scarce resource that needs to be cared for with discernment. The quantity and quality of fresh water on the planet has always been essential to maintain life cycles, the biodiversity of organisms and the survival of the human species. It is necessary to know the quality of the water to determine what possible uses can be attributed to it. In this context, the present study had as its object the evaluation of the quality of the water that is sent to the environmental reserve, preserved by the State Institute of Forests (SIF), entitled Mata dos Ausentes Ecological Station (MAES). The study was carried out based on the collection of samples during drought and rainy season. The samples were collected at five points in which the study of the flow was carried out, as well as the physico-chemical parameters: Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), pH, Hardness, Turbidity, Nitrates, Chlorides, Manganese and Iron. At the end of the analyzes, a comparison was made of the results obtained with the flow rates at the sample points. It was possible to notice
水是生命、经济发展和社会福祉的基本自然资源,有着从最简单到最复杂的无限用途。然而,它已经逐渐成为一种稀缺资源,需要有洞察力地加以照顾。地球上淡水的数量和质量对于维持生命周期、生物多样性和人类物种的生存始终至关重要。有必要了解水的质量,以确定其可能的用途。在这种情况下,本研究的目的是评估被送往国家森林研究所(SIF)保护的环境保护区的水的质量。该保护区名为Mata dos Ausentes生态站(MAES)。这项研究是在干旱和雨季收集样本的基础上进行的。在进行流量研究的五个点收集样品,以及物理化学参数:化学需氧量(COD)、生化需氧量(BOD)、pH、硬度、浊度、硝酸盐、氯化物、锰和铁。在分析结束时,将获得的结果与采样点的流速进行比较。可以注意到
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引用次数: 0
Flúor nas águas subterrâneas dos municípios de Feira da Mata e Santana (BA): comparação dos teores do fluoreto e seu significado na saúde da população 费拉达马塔市和桑塔纳市地下水中的氟化物:比较氟化物含量及其对人口健康的意义
Pub Date : 2019-03-14 DOI: 10.21715/GB2358-2812.2019332175
Manuel Vitor Portugal Gonçalves, R. Santos, Antônio Ramos-Junnior, Carlos Alberto Machado Coutinho, M. Cruz, Mônica Prisgsheim da Cunha
This research aimed to investigate the chemical composition of the groundwater of the municipalities of Feira da Mata and Santana, in western Bahia, with an emphasis on the distribution of fluoride concentrations. Water was collected in fifteen wells drilled in the pellet-carbonate rocks of the Bambuí Group in the year 2012. The physicochemical variables were measured in situ by means of a multiparameter probe. The analysis of cations given up by ICP-OES and anions by titrimetry, spectrophotometry and colorimetry (SPANSD) (F). In the municipality of Feira da Mata, bicarbonated calcium (87%) and sodium bicarbonate (13%) occurred, in which the fluoride levels exceeded the fluoride potability limit for 13% of the wells. In the municipality of Santana, bicarbonated calcium or mixed calcium (63%) and sodium bicarbonate (23%) waters were representative, in which the fluoride levels exceeded the potability limit for 40% of the wells. The distribution of fluoride levels in the groundwater of the municipalities of Feira da Mata and Santana indicates that the quality monitoring of these and the epidemiological surveillance of dental caries or fluorosis should be prioritized.
这项研究的目的是调查巴伊亚州西部费拉达马塔市和桑塔纳市地下水的化学成分,重点是氟化物浓度的分布。2012年,在Bambuí集团的颗粒碳酸盐岩中钻探了15口井,收集了水。用多参数探针原位测量了理化变量。通过滴定法、分光光度法和比色法(SPANSD)对电感耦合等离子体发射光谱法放弃的阳离子和阴离子进行了分析(F)。在费拉达马塔市,出现了碳酸氢钙(87%)和碳酸氢钠(13%),其中13%的井的氟化物含量超过了氟化物饮用限制。在桑塔纳市,碳酸氢钙或混合钙(63%)和碳酸氢钠(23%)水具有代表性,其中40%的井的氟化物含量超过饮用限制。费拉达马塔市和桑塔纳市地下水中氟化物含量的分布情况表明,应优先进行地下水质量监测以及龋齿或氟中毒的流行病学监测。
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引用次数: 0
Modelagem do controle climático nas taxas de erosão mecânica e de intemperismo químico na bacia do Rio Sorocaba (SP) 索罗卡巴河流域机械侵蚀和化学风化速率的气候控制模型(SP)
Pub Date : 2019-02-12 DOI: 10.21715/GB2358-2812.2019331050
A. Fernandes, F. D. Conceição, Eder Paulo Spatti-Junior, Antonio Aparecido Couto-Junior, J. Mortatti
A influencia do controle climatico sobre as taxas de remocao de solos e de intemperismo quimico na bacia do Rio Sorocaba, SP, foi avaliada a partir da caracterizacao fisico-quimica das aguas fluviais e quantificacao do TSS em dois pontos de amostragem (S1 e S2), e dos fluxos fluviais de TSS e TDS, apos a correcao dos aportes atmosfericos e antropicos, no periodo de jun/2009 a jun/2010. Foram estabelecidos de 12 cenarios baseados na variacao das vazoes ao longo do periodo de estudo, associando a cada um deles as respectivas concentracoes de TSS, TDS, SiO 2 e cations dissolvidos. Os fluxos fluviais corrigidos dos aportes atmosfericos e antropicos calculados para S1 e S2 permitiram determinar as taxas de remocao de solos (W M ) e de intemperismo quimico das rochas (W Ch ) na Bacia do Rio Sorocaba, ou seja, 49,5 e 9,6 m/Ma em S1 e de 12,8 e 7,6 m/Ma em S2, respectivamente. O balanco entre estas taxas evidenciou uma maior remocao de solos em S1 (W M ≈ 5,2 W Ch ), em comparacao a S2 (W M ≈ 1,7 W Ch ). O processo de intemperismo quimico de rochas avaliado pelo indice R E indicou tendencia para o dominio da monossialitizacao. Os cenarios propostos corroboraram a influencia do clima nos processos intempericos, com predominio dos processos de intemperismo quimico das rochas nos cenarios relacionados as condicoes climaticas de baixa pluviosidade e temperaturas mais amenas, e o predominio dos processos de remocao dos solos em condicoes mais chuvosas e temperaturas mais elevadas.
climatico控制remocao利率的影响在流域化学风化的土壤和评价,从圣保罗高层物理caracterizacao -quimica河水域和quantificacao TSS在两个采样点(S1和S2)和流河TSS的correcao TDS,后摄入atmosfericos和antropicos拖累君/ 2009 / 2010。根据研究期间流量的变化,建立了12个情景,每个情景都与TSS、TDS、sio2和溶解阳离子的浓度相关联。调整后的流河atmosfericos和antropicos计算摄入的S1和S2使确定土壤remocao利率(W - M)和化学风化的岩石(W - Ch)流域,即5和9,49岁,硕士6米/ 1号7 8 - 12和6米/ S2,硕士学位。这些速率之间的平衡表明,S1 (W M≈5.2 W Ch)的土壤迁移率高于S2 (W M≈1.7 W Ch)。用R指数评价了岩石的化学风化过程,表明岩石具有单硅化主导作用的趋势。所提出的情景证实了气候对风化过程的影响,在与低降雨和温和温度气候条件相关的情景中,岩石的化学风化过程占优势,而在多雨和高温条件下,土壤移动过程占优势。
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引用次数: 0
Estudo preliminar para a remediação de áreas rurais após um acidente nuclear ou radiológico 核或辐射事故后农村地区修复的初步研究
Pub Date : 2019-02-12 DOI: 10.21715/GB2358-2812.2019331098
E. R. Rochedo, D. Silva, Christiano de Luca, Pedro R. R. Rochedo, Maria Angélica Vergara Wasserman, D. Perez
The assessment of protective and remediation measures for rural areas is more complex than that for urban areas, due to the strong influence of large number of parameters and variables associated with climate, diet, eating habits, farming practices and the type of soil in the area. Thus, it is not possible to perform generic studies applicable to any kind of area. Specific studies and surveys should be made in the areas most likely to be contaminated due to a nuclear accident. Considering the Brazilian Nuclear Power Central, the prioritization of areas was based on radiological and economic aspects. This preliminary study demonstrated that the different soil types in Brazil are more relevant to the ingestion dose than the regional differences in the diets. The most relevant product for public dose was identified as the ingestion of milk. The contribution of milk to total ingestion dose depends on the season of the year when the accident occurs. The timing of the application of the measure has an important effect on the percentage dose reduction that can be achieved. In particular for I-131, protective measures related to milk ingestion must be considered within the emergency phase in order to be effective.
由于与该地区的气候、饮食、饮食习惯、耕作方式和土壤类型有关的大量参数和变量的强烈影响,对农村地区的保护和补救措施的评估比对城市地区的评估更为复杂。因此,不可能进行适用于任何领域的通用研究。应在最可能受核事故污染的地区进行具体的研究和调查。考虑到巴西核电中心,各地区的优先次序是根据放射性和经济方面确定的。这项初步研究表明,巴西不同的土壤类型与摄入剂量的关系比饮食的区域差异更大。与公众剂量最相关的产品被确定为摄入牛奶。牛奶对总摄入剂量的贡献取决于事故发生时一年中的季节。应用该措施的时机对可实现的剂量减少百分比有重要影响。特别是对于碘-131,必须在紧急阶段考虑与牛奶摄入有关的保护措施,以便有效。
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引用次数: 0
Adsorção de Cd(II) por lama vermelha natural e com diferentes ativações 天然赤泥对Cd(II)的吸附及其不同活化作用
Pub Date : 2019-02-12 DOI: 10.21715/GB2358-2812.2019331076
Mariana S. G. Silva, Beatriz Cestaro Pichinelli, F. D. Conceição, Rodrigo Braga Moruzzi, L. N. M. Yabuki, A. A. Menegário, Maria Lúcia Pereira Antunes
Alguns elementos sao considerados toxicos mesmo em baixas concentracoes, causando diversos problemas de saude publica. O cadmio e amplamente utilizado em atividades industriais e pode causar contaminacao do solo e da agua. A lama vermelha foi estudada para uso como adsorvente na remocao de elementos, compostos de aguas residuais e/ou de solo contaminado. No entanto, existem varios compostos e tratamentos que ainda nao foram testados. Neste estudo, o potencial de adsorcao Cd (II) para lama vermelha natural (LV) e lama vermelha ativada por tratamento termico a 400°C (LVT) e tratamento quimico com HCl a 0,05 mol L -1 (LVQ1) e com Ca (NO 3 ) 2 0,1 mol L -1 (LVQ2) foi avaliado. A LV e a LVT apresentaram maior percentual de adsorcao de Cd (II) em solucao aquosa. A isoterma de Freundlich foi mais apropriada para descrever o fenomeno da remocao de Cd (II), a lama vermelha ativada termicamente teve a maior capacidade de adsorcao, 1,04 mmol de g -1 ou 107,52 mg de g -1 . Esses resultados indicam que a LVT tem potencial para uso em aplicacoes que tratam efluentes e/ou solo contaminado da atividade industrial. Palavras-chave: Cd (II), lama vermelha, adsorcao, cinetica, termodinâmica.
一些元素即使在低浓度下也被认为是有毒的,会引发一些公共卫生问题。镉广泛用于工业活动,会造成土壤和水污染。研究了赤泥作为吸附剂去除元素、废水化合物和/或污染土壤。然而,还有一些化合物和治疗方法尚未经过测试。在本研究中,评估了天然赤泥(VL)和经400°C热处理(LVT)和用0.05mol L-1 HCl(LVQ1)和0.1mol L-1 Ca(NO3)2(LVQ2)化学处理活化的赤泥对Cd(II)的吸附潜力。LV和LVT在水溶液中对Cd(II)的吸附率较高。Freundlich等温线更适合描述Cd(II)的去除现象,热活化赤泥的吸附量最高,为1.04mmol g-1或107.52mg g-1。这些结果表明,LVT在处理工业活动的废水和/或污染土壤的应用中具有潜力。关键词:Cd(II),赤泥,吸附,动力学,热力学。
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引用次数: 1
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Geochimica Brasiliensis
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