Pub Date : 2020-08-16DOI: 10.31857/s0132344x21120021
Владимир Викторович Шарутин, Татьяна Владимировна Мосунова
On the basis of analysis of the literature published in the period from the end of the 20th century to the beginning of the 21st century, the methods of preparation, some reactions, structure features of organic bismuth compounds, as well as examples of their possible use, have been systematized and described. Over the past ten years, the number of works in the field of bismuth compounds has increased significantly, and their inclusion in this review would substantially enhance the scope of this article. However, some later references have still been included in the review due to their particular importance. In 1950–1952, the Nobel laureate G. Wittig first obtained pentaphenyl compounds of phosphorus, arsenic, antimony, and bismuth and studied some of their reactions. Since then, few foreign researchers continued Wittig's studies in the field of reactivity of pentaphenyl bismuth since the synthesis experiment was quite complex, and its reproduction for many researchers seemed an impossible task. In 1974, one of the authors of the present article synthesized pentaphenyl bismuth for the first time in Russia and published a series of papers on its reactivity. Another Nobel laureate, D. Barton, drew attention to the published works. He was interested in the fascinating results obtained by Russian chemists. In the last years of his life, D. Barton concentrated his efforts in the direction of using organobismuth compounds in fine organic synthesis. A series of remarkable papers were published, the results of which allowed the chemist to be nominated for the second time for the title of Nobel laureate in chemistry, but this did not happen. Research on the reactivity of pentaphenyl bismuth and its derivatives is currently continued in Russia only at the South Ural State University. The following review covers the description of modern achievements in the field of synthesis methods, the study of the reactivity and structural features of bismuth compounds.
{"title":"Синтез, строение и применение органических соединений висмута","authors":"Владимир Викторович Шарутин, Татьяна Владимировна Мосунова","doi":"10.31857/s0132344x21120021","DOIUrl":"https://doi.org/10.31857/s0132344x21120021","url":null,"abstract":"On the basis of analysis of the literature published in the period from the end of the 20th century to the beginning of the 21st century, the methods of preparation, some reactions, structure features of organic bismuth compounds, as well as examples of their possible use, have been systematized and described. Over the past ten years, the number of works in the field of bismuth compounds has increased significantly, and their inclusion in this review would substantially enhance the scope of this article. However, some later references have still been included in the review due to their particular importance. In 1950–1952, the Nobel laureate G. Wittig first obtained pentaphenyl compounds of phosphorus, arsenic, antimony, and bismuth and studied some of their reactions. Since then, few foreign researchers continued Wittig's studies in the field of reactivity of pentaphenyl bismuth since the synthesis experiment was quite complex, and its reproduction for many researchers seemed an impossible task. In 1974, one of the authors of the present article synthesized pentaphenyl bismuth for the first time in Russia and published a series of papers on its reactivity. Another Nobel laureate, D. Barton, drew attention to the published works. He was interested in the fascinating results obtained by Russian chemists. In the last years of his life, D. Barton concentrated his efforts in the direction of using organobismuth compounds in fine organic synthesis. A series of remarkable papers were published, the results of which allowed the chemist to be nominated for the second time for the title of Nobel laureate in chemistry, but this did not happen. Research on the reactivity of pentaphenyl bismuth and its derivatives is currently continued in Russia only at the South Ural State University. The following review covers the description of modern achievements in the field of synthesis methods, the study of the reactivity and structural features of bismuth compounds.","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130518020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-08-16DOI: 10.1134/S0132344X1902004X
А. В. Пискунов, О. Ю. Трофимова, А. В. Малеева, А. В. Черкасов
{"title":"Темплатный синтез комплексов олова(IV) с тридентатными иминопиридиновыми лигандами","authors":"А. В. Пискунов, О. Ю. Трофимова, А. В. Малеева, А. В. Черкасов","doi":"10.1134/S0132344X1902004X","DOIUrl":"https://doi.org/10.1134/S0132344X1902004X","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133109562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.1134/s0132344x19060045
Андрей Анатольевич Павлов, И. А. Никовский, А. В. Полежаев, Д. Ю. Алешин, Е. К. Мельникова, Я. А. Панкратова, Ю. В. Нелюбина
{"title":"Спиновое состояние 2,6-ди(5-амино-1H-пиразол-3-ил)пиридиновых комплексов железа(II) и кобальта(II) в растворе и кристалле","authors":"Андрей Анатольевич Павлов, И. А. Никовский, А. В. Полежаев, Д. Ю. Алешин, Е. К. Мельникова, Я. А. Панкратова, Ю. В. Нелюбина","doi":"10.1134/s0132344x19060045","DOIUrl":"https://doi.org/10.1134/s0132344x19060045","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114680470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.1134/S0132344X19050049
Г. Ю. Жигулин, Г. С. Забродина, М. А. Каткова, С. Ю. Кетков
{"title":"Полиядерные глицингидроксиматные металламакроциклические комплексы Cu(II)–Gd(III): галохромные свойства","authors":"Г. Ю. Жигулин, Г. С. Забродина, М. А. Каткова, С. Ю. Кетков","doi":"10.1134/S0132344X19050049","DOIUrl":"https://doi.org/10.1134/S0132344X19050049","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121100709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.31857/s0132344x21080090
А. Н. Усольцев, М. Д. Петров, И. В. Корольков, Максим Николаевич Соколов, В. А. Блатов, С. А. Адонин
{"title":"Бромидные комплексы Sb(III) с 4,4'-диметил-1,1'-бутандиилбиспиридиний-катионом: неожиданное образование полиморфов с комплексными анионами различной ядерности","authors":"А. Н. Усольцев, М. Д. Петров, И. В. Корольков, Максим Николаевич Соколов, В. А. Блатов, С. А. Адонин","doi":"10.31857/s0132344x21080090","DOIUrl":"https://doi.org/10.31857/s0132344x21080090","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121244593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.1134/S0132344X19080024
Г. К. Фукин, Евгений Владимирович Баранов, А. В. Черкасов, Р. В. Румянцев
{"title":"Природа конформационного полиморфизма в кристаллах комплекса Ph\u0000 \u0000 3\u0000 \u0000 Sb(O\u0000 \u0000 2\u0000 \u0000 CCH\u0000 \u0000 2\u0000 \u0000 –CH=CH\u0000 \u0000 2\u0000 \u0000 )\u0000 ","authors":"Г. К. Фукин, Евгений Владимирович Баранов, А. В. Черкасов, Р. В. Румянцев","doi":"10.1134/S0132344X19080024","DOIUrl":"https://doi.org/10.1134/S0132344X19080024","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124764833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.1134/s0132344x19010055
Р. В. Линко, Надежда Полянская, М. А. Рябов, В. С. Сергиенко, П. В. Страшнов, В. В. Давыдов, Г. М. Дрогова
{"title":"Синтез, спектральные исследования и квантово-химическое моделирование строения комплексных соединений Co(II), Ni(II), Cu(II) с (Z)-10-(2-(4-амино-5-тиоксо-4,5-дигидро-1\u0000 \u0000 Н\u0000 \u0000 -1,2,4-триазол-3-ил)гидразоно)-9-фенантроном","authors":"Р. В. Линко, Надежда Полянская, М. А. Рябов, В. С. Сергиенко, П. В. Страшнов, В. В. Давыдов, Г. М. Дрогова","doi":"10.1134/s0132344x19010055","DOIUrl":"https://doi.org/10.1134/s0132344x19010055","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123241828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.31857/s0132344x21080041
М. А. Огиенко, Н. А. Пушкаревский, Д. А. Баширов, Н. В. Куратьева, А. В. Вировец, С. Н. Конченко
{"title":"Комплексы [Fe\u0000 \u0000 2\u0000 \u0000 (μ-S\u0000 \u0000 2\u0000 \u0000 ER\u0000 \u0000 2\u0000 \u0000 )(CO)\u0000 \u0000 6\u0000 \u0000 ] (E = Si, Sn) – реагенты для получения гетерометаллических кластеров: синтез, строение и реакции с галогенсодержащими комплексами металлов","authors":"М. А. Огиенко, Н. А. Пушкаревский, Д. А. Баширов, Н. В. Куратьева, А. В. Вировец, С. Н. Конченко","doi":"10.31857/s0132344x21080041","DOIUrl":"https://doi.org/10.31857/s0132344x21080041","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123763031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.31857/s0132344x22010078
Юй Ван, Д. М. Вахрушева, И. В. Крылова, А. Я. Козьменкова, Е. Н. Николаевская, Б.Н. Манкаев, М. Е. Миняев, М. А. Сыроешкин, М. П. Егоров, В. В. Жуйков
{"title":"1,1'-Дифенил-\u0000 \u0000 бис\u0000 \u0000 -силатран – первый пример структурно-охарактеризованного\u0000 \u0000 бис\u0000 \u0000 -силатрана","authors":"Юй Ван, Д. М. Вахрушева, И. В. Крылова, А. Я. Козьменкова, Е. Н. Николаевская, Б.Н. Манкаев, М. Е. Миняев, М. А. Сыроешкин, М. П. Егоров, В. В. Жуйков","doi":"10.31857/s0132344x22010078","DOIUrl":"https://doi.org/10.31857/s0132344x22010078","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116383860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 1900-01-01DOI: 10.1134/s0132344x19120053
Т. В. Лифинцева, А. С. Бурлов, Валерий Григорьевич Власенко, Ю. В. Кощиенко, Д. А. Гарновский, С. А. Мащенко, С. И. Левченков, Виктор Анатольевич Лазаренко, В. Н. Хрусталев, А. Л. Тригуб
{"title":"Химический и электрохимический синтез, кристаллическая структура, магнитные свойства комплексов Cu(II), Ni(II), Co(II) тетрадентатных азометиновых лигандов","authors":"Т. В. Лифинцева, А. С. Бурлов, Валерий Григорьевич Власенко, Ю. В. Кощиенко, Д. А. Гарновский, С. А. Мащенко, С. И. Левченков, Виктор Анатольевич Лазаренко, В. Н. Хрусталев, А. Л. Тригуб","doi":"10.1134/s0132344x19120053","DOIUrl":"https://doi.org/10.1134/s0132344x19120053","url":null,"abstract":"","PeriodicalId":346974,"journal":{"name":"Координационная химия","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116742541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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