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INDOOR AIR QUALITY AND COMFORT IN NATIVE AMERICAN SHELTERS: SIMULATION AND ACTUAL DATA ANALYSIS 美国原住民避难所的室内空气质量和舒适度:模拟和实际数据分析
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230301
Paul Fowler, Fernando Del Ama Gonzalo, Anthony Divito, Abigail Carlson, Zachary Lizotte
The wigwam was a Native American shelter built in the north-eastern United States. This study determined if these structures supply comfort to human beings using modern measurement standards and if they provide indoor air quality levels that are healthy. Keene State College faculty and students built a full-size example of a wigwam and monitored data indoors and outdoors. When a fire was introduced into the wigwam to produce comfortable indoor temperatures, the analysis of air temperature and relative humidity, along with CO 2 , VOC, and PM 2.5 levels, determined indoor air quality and comfort. By having a full-size example of a wigwam, the authors were able to compare the accuracy of a digital energy model. Comfort can be accomplished even when using modern standards in this native structure. Temperature, humidity, and rainfall exposure can all be controlled to acceptable levels. Indoor air quality is always at good levels when a fire is not involved because the indoor air in the wigwam is the same as exterior quality levels. However, the particulates and VOC introduced into the environment are at dangerous levels with an open fire. A wood stove with a flue pipe to the exterior was used to reduce the pollutants to acceptable and safe levels.
棚屋是美国东北部印第安人建造的避难所。这项研究用现代测量标准来确定这些建筑是否为人类提供了舒适,以及它们是否提供了健康的室内空气质量水平。基恩州立大学的教师和学生们建造了一个全尺寸的棚屋,并监测了室内和室外的数据。当将火引入棚屋以产生舒适的室内温度时,对空气温度和相对湿度以及CO 2, VOC和PM 2.5水平的分析确定了室内空气质量和舒适度。通过一个全尺寸的棚屋例子,作者能够比较数字能量模型的准确性。即使在这种原生结构中使用现代标准,也可以实现舒适。温度、湿度和降雨暴露都可以控制在可接受的水平。在没有火灾的情况下,室内空气质量总是处于良好水平,因为棚屋内的空气质量与室外空气质量水平相同。然而,在明火中引入的颗粒物和挥发性有机化合物已达到危险水平。在室外使用了一个带有烟道的木火炉,以将污染物减少到可接受和安全的水平。
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引用次数: 0
ZERO-EMISSION SOLUTION FOR A SMART MOBILITY HUB 智能交通枢纽的零排放解决方案
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230351
Markus Sihvonen, Hanna Takala
The road transport industry is facing increasing pressure to reduce its carbon footprint and transition towards eco-friendly solutions. One prominent approach has been the adoption of alternative energy sources for heavy vehicles, with electric trucks emerging as the most promising option due to their reduced emissions, lower fuel costs and improved performance. Concurrently, governments are introducing policies and directives aimed at significantly decreasing CO 2 emissions caused by road transport, often favouring the implementation of smart mobility hubs (SMH) as a means to mitigate the negative impact of road traffic on cities. In line with this movement, the MORE Industrial Park, a major SMH in southern Finland, is pursuing a development strategy to transform into an eco-industrial park with a mission to achieve an emission-free zone. This paper aims to propose a zero-emission first-/last-mile road transportation strategy for the MORE Industrial Park, which serves as a critical SMH for local industries in Hämeenlinna and Janakkala, Finland. The proposed solution suggests utilizing the latest ICT technologies, electric power trains, and the Mobility as a Service concept for sustainable mobility and logistics. The solution seeks to contribute to a greener and more efficient road transport industry in the region.
道路运输业正面临着越来越大的压力,需要减少碳足迹,向环保解决方案过渡。一种突出的方法是为重型车辆采用替代能源,电动卡车因其减少排放、降低燃料成本和提高性能而成为最有希望的选择。与此同时,各国政府正在出台旨在显著减少道路交通造成的二氧化碳排放的政策和指令,通常倾向于实施智能交通枢纽(SMH),作为减轻道路交通对城市的负面影响的一种手段。与这一运动相一致,芬兰南部的主要SMH MORE工业园区正在实施一项发展战略,将其转变为一个生态工业园区,其使命是实现无排放区。本文旨在为MORE工业园区提出零排放的第一/最后一英里道路运输战略,该园区是Hämeenlinna和芬兰Janakkala当地工业的关键SMH。拟议的解决方案建议利用最新的ICT技术、电力传动系统和移动即服务概念来实现可持续的移动和物流。该解决方案旨在为该地区更环保、更高效的道路运输业做出贡献。
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引用次数: 0
GREEN BUILDING INITIATIVE: A CASE STUDY OF THE SJVN CORPORATE HEADQUARTERS, SHIMLA, INDIA 绿色建筑倡议:印度希姆拉 SJVN 公司总部案例研究
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230291
Rajeev Kumar, Ajay K. Sharma, Gouri Sood
The world is becoming more environmentally conscious and adopting sustainable design practices, thus green building is the need of the hour. The green building is an eco-friendly built environment, as it is based on the fundamental principle of ‘reduce, reuse and recycle’. Similarly, a green building rating system is a method that tests the environmental efficiency of a building through its lifecycle. The paper attempts to create awareness about various green building rating systems prevalent in India and further elaborates the evaluation criterion of most widely used and predominant green building rating systems in India. It has been further explained better with a case study. The Shakti Sadan building is the corporate headquarters of a leading government company and the flag bearer of green architecture and sustainability in the remote hill state of Himachal Pradesh in India. The company that owns this building creates sustainable architecture by adopting techniques like minimum ground coverage, adopting building orientation in a way which allows maximum natural light penetration and ventilation. Also, other green measures taken organisation wide in building construction are renewable energy utilisation, solid waste management, storm and rain water drainage provision, use of sustainable building materials, good air quality, access to daylight and views, pleasant acoustic conditions, low flow fixtures of water, sensor-based indoor lighting to save electricity. The case study has been evaluated on a number of criteria including site parameters, microclimate impact, maintenance and housekeeping, energy, renewable energy utilisation, human health, achieving indoor comfort requirements and social aspects. This is the only building to date in the state of Himachal Pradesh in India to be awarded a four star rating in the year 2022.
世界越来越有环保意识,采用可持续的设计实践,因此绿色建筑是时代的需要。绿色建筑是一个生态友好的建筑环境,因为它基于“减少、再利用和循环”的基本原则。同样,绿色建筑评级系统是一种测试建筑物在其生命周期内的环境效率的方法。本文试图建立对印度流行的各种绿色建筑评级体系的认识,并进一步阐述印度最广泛使用和主导的绿色建筑评级体系的评价标准。通过一个案例对其进行了更好的解释。Shakti Sadan大楼是一家领先的政府公司的总部,也是印度喜马偕尔邦偏远山区绿色建筑和可持续发展的旗手。拥有这座建筑的公司通过采用最小的地面覆盖面积、采用允许最大自然光穿透和通风的建筑朝向等技术来创造可持续的建筑。此外,整个组织在建筑建造方面采取的其他环保措施包括使用可再生能源、固体废物管理、雨水排放、使用可持续建筑材料、良好的空气质量、采光和景观、宜人的声学条件、低流量的水装置、基于传感器的室内照明以节省电力。案例研究已经根据许多标准进行了评估,包括场地参数、小气候影响、维护和内务管理、能源、可再生能源的利用、人体健康、实现室内舒适要求和社会方面。这是迄今为止印度喜马偕尔邦唯一一座在2022年被授予四星评级的建筑。
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引用次数: 0
EXPRESS ENVIRONMENTAL EVALUATION OF THE IMPACT OF BIOGAS PROJECTS ON ATMOSPHERIC AIR 沼气项目对大气影响的环境评估快报
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230231
A. Kiselev, A. Karaeva, E. Magaril
Greening the global energy sector implies the development and implementation of large-scale energy projects around the world. The quality and effectiveness of the environmental assessment plays a central role in achieving the declared results of eco-modernization: the ability to comprehensively and quickly assess the current activities of an energy facility or an investment project planned for implementation allows one to quickly implement environmental and management solutions. The energy sector is the largest emitter of greenhouse gases into the atmosphere and the largest consumer of natural resources; this is what one considers in most of the proposed approaches to environmental assessment in the scientific and methodological literature. However, in addition to greenhouse gas emissions (in particular CO 2 ), energy facilities operating on traditional and alternative fuels consume a significant amount of oxygen as a result of their combustion, which also has a number of negative environmental consequences. The purpose of the study is the development of a methodology for rapid environmental assessment of energy projects, taking into account CO 2 emissions and oxygen consumption. The article presents specific indicators of oxygen consumption and CO 2 emissions per unit of generating capacity for various types of fossil and alternative fuels and their adoption on the example of a biogas project at a regional energy facility.
绿色全球能源部门意味着在世界范围内开发和实施大型能源项目。环境评估的质量和有效性在实现生态现代化所宣布的成果方面起着中心作用:全面和迅速评估计划实施的能源设施或投资项目的当前活动的能力使人们能够迅速实施环境和管理解决办法。能源部门是向大气中排放温室气体最多的部门,也是消耗自然资源最多的部门;这是人们在科学和方法论文献中提出的大多数环境评估方法中所考虑的问题。然而,除了温室气体排放(特别是二氧化碳)之外,使用传统和替代燃料的能源设施在燃烧过程中消耗了大量的氧气,这也对环境产生了一些负面影响。这项研究的目的是发展一种方法,以便在考虑到二氧化碳排放和氧气消耗的情况下对能源项目进行快速环境评估。本文介绍了各类化石燃料和替代燃料每单位发电能力的耗氧量和二氧化碳排放量的具体指标,并以某区域能源设施的沼气项目为例加以采用。
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引用次数: 0
CYCLING AS A SUSTAINABLE MOBILITY FORM IN THE MAGNA GRAECIA AREA OF THE CALABRIA REGION, ITALY 在意大利卡拉布里亚地区的马格纳格拉西亚地区,自行车是一种可持续的交通方式
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230361
G. Iiritano, Filomena Tiziana Corallini, G. Petrungaro, Francesco Boccia, M. R. Trecozzi
With the Regional Transport Plan, Calabria Region government has launched several initiatives for sustainability in the transport and logistics sector. Among those, there is the initiative for the promotion of cycling mobility with the aim to also support the realization of the Magna Graecia cycle route. The Magna Graecia cycle route crosses three regions of southern Italy, Basilicata, Calabria and Sicily, for about 1,300 km. It is one of Europe’s long-distance cycle itineraries and represents the final part of Eurovelo 7, which runs through Europe for about 7,700 km, interconnected with the national regional cycle network and the other infrastructures of the regional transport system. The realization of the Magna Graecia cycle route aims to favour forms of sustainable tourism, with particular regard to areas with a strong naturalistic and cultural value. The aim is to promote the development of mobility by bicycle, both as a means of daily transport and for tourist and recreational activities, within the general framework of sustainable mobility. Another aim is to increase the attractiveness of the territory, by trying to reduce the negative effects on health and soil consumption, and job opportunities. This is a study of the role of the regional government in promoting policies to support sustainable mobility with reference to cycle mobility, and on the technical-administrative procedure of Magna Graecia cycle route realization. It is an example of how a regional government works to pursue international sustainability objectives by implementing funding programmes.
根据区域运输计划,卡拉布里亚地区政府在运输和物流领域推出了几项可持续发展举措。其中,有一项促进自行车出行的倡议,旨在支持大希腊自行车路线的实现。大希腊自行车路线横跨意大利南部的三个地区:巴西利卡塔、卡拉布里亚和西西里岛,全长约1300公里。它是欧洲长途自行车路线之一,也是Eurovelo 7的最后一部分,Eurovelo 7贯穿欧洲约7700公里,与国家区域自行车网络和区域交通系统的其他基础设施相互连接。大希腊自行车路线的实现旨在支持可持续旅游的形式,特别是关于具有强烈自然主义和文化价值的地区。其目的是在可持续交通的总体框架内,促进自行车作为日常交通工具以及旅游和娱乐活动的交通工具的发展。另一个目标是通过努力减少对健康和土壤消耗以及就业机会的负面影响来增加领土的吸引力。本文研究了区域政府在促进政策支持可持续交通方面的作用,并参考了自行车交通,以及大希腊自行车路线实现的技术-行政程序。这是一个地区政府如何通过实施资助计划来实现国际可持续发展目标的例子。
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引用次数: 0
COMPARATIVE ANALYSIS OF NATIONAL DECARBONIZATION POLICIES: IS IT POSSIBLE TO ACHIEVE CARBON NEUTRALITY BY 2050? 各国去碳化政策的比较分析:到 2050 年是否有可能实现碳中和?
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230041
A. Karaeva, E. Magaril, Irina Rukavishnikova
The complexity of the task of decarbonizing the global economy requires an integrated and coordinated approach from the governments of developed and developing countries, the organization of effective international cooperation and scientific and technological progress in the field of environmental technologies and alternative energy sources. At present, despite the measures taken, the problem of achieving carbon neutrality is the difficulties of abandoning fossil fuels in countries showing significant economic growth and being the largest CO 2 emitters in recent decades. The purpose of this study is to review and analyse the current state of different energy sources consumption by the leading countries in CO 2 emissions, and the projected changes in the global energy system during the fourth energy transition considering possible decarbonization scenarios. The article presents a comparative analysis of national policies and initiatives for the transition to a low-carbon economy and assesses the prospects for achieving the stated targets for reducing CO 2 emissions by 2050.
全球经济脱碳任务的复杂性要求发达国家和发展中国家政府采取综合和协调的方法,组织有效的国际合作,并在环境技术和替代能源领域取得科技进步。目前,尽管采取了措施,但实现碳中和的问题是,在经济增长显著、近几十年来二氧化碳排放量最大的国家,放弃化石燃料的困难。本研究的目的是回顾和分析二氧化碳排放主要国家的不同能源消费现状,以及在第四次能源转型期间考虑可能的脱碳情景的全球能源系统预测变化。本文对各国向低碳经济转型的政策和举措进行了比较分析,并评估了实现到2050年减少二氧化碳排放的既定目标的前景。
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引用次数: 0
CHALLENGES FOR THE PRACTICAL USE OF RECYCLED CONCRETE AS A SUSTAINABLE ALTERNATIVE IN CONSTRUCTION IN THE MEXICO CITY METROPOLITAN AREA 在墨西哥城大都会地区实际使用再生混凝土作为可持续替代建筑材料所面临的挑战
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230271
Martha Patricia Saldaña Rodea, Gerardo Bernache Pérez, Yasuhiro Matsumoto Kuwabara
Concrete is a building material that generates a large amount of CO 2 and consumes a lot of natural resources. Therefore, people seek to replace it with some type of sustainable concrete (SC). One type of SC is the one made with recycled coarse aggregates (RCA), which come from the demolition and subsequent crushing of concrete elements, commonly used in Mexican construction. This paper analyses the situation of the practical use of this type of concrete in the Mexico City Metropolitan Area, one of the largest and densest cities in the world. Four main challenges to be faced in the application of this type of SC were found: (1) lack of quality control, (2) flexibility in the regulations or their non-existence, (3) time required to safeguard on site, and (4) the social acceptance of the main players in the construction industry. In conclusion, the use of concrete with RCA is a constructively feasible option, however, it requires prior training of the personnel who manage it, in addition to awareness campaigns among the population that increase demand, or else, to be enforced under a mandatory regulation.
混凝土是一种产生大量二氧化碳并消耗大量自然资源的建筑材料。因此,人们寻求用某种类型的可持续混凝土(SC)来取代它。一种类型的SC是由再生粗骨料(RCA)制成的,它来自拆除和随后破碎的混凝土元素,通常用于墨西哥建筑。本文分析了这类混凝土在世界上最大和最密集的城市之一——墨西哥城大都市区的实际应用情况。在应用这种类型的SC时面临的四个主要挑战是:(1)缺乏质量控制,(2)法规的灵活性或不存在,(3)现场维护所需的时间,以及(4)建筑行业主要参与者的社会接受度。总之,将混凝土与RCA一起使用是一种建设性的可行办法,但是,它需要事先对管理它的人员进行培训,此外还需要在人口中开展提高认识的运动,以增加需求,否则必须根据强制性条例加以执行。
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引用次数: 0
TECHNOLOGICAL AND ENERGY CHALLENGES IN THE MOST VULNERABLE COMMUNITIES: A STUDY IN THE STATE OF CHIHUAHUA, MEXICO 最脆弱社区面临的技术和能源挑战:对墨西哥奇瓦瓦州的研究
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230141
Emanuele Giorgi, Camilo Lozoya
Based on the assumption that the technological system is assuming a leading role as a driver of socio-environmental development for contemporary societies, the ‘Design for Vulnerables – Technology Challenge’ research project aims to define strategies to facilitate the adaptation of technological devices in the most vulnerable communities, with the aim of overcoming the socio-environmental threats that contribute to creating situations of vulnerabilities. Defining the most appropriate methodologies to encourage technology adaptation to reduce vulnerabilities remains one of the main challenges for architecture and urban planning. The ‘Design for Vulnerables – Technology Challenge’ research project works with multidisciplinary approaches; there are seven disciplines involved in four communities of the state of Chihuahua, Mexico: Paso del Norte, Chihuahua (urban); Nuevas Delicias, Chihuahua (peri-urban); La Regina, Julimes (rural) and Basaseachic, Ocampo (forestry). With the goal to understand methodologies for technology adaptation and to reduce vulnerabilities, the research group is implementing (together with the residents) tech-based interventions, studying their adaption and evaluating their impact on the built environment. The aim of this article is to: (1) describe the analysis and planning processes conducted with vulnerable communities; (2) describe the projects defined by the communities during the participatory planning process and their relationship with the context; (3) analyse the characteristics of these projects; and (4) observe how these characteristics are related to the technological appropriation and energy limitations of the studied contexts. In the four communities, six ‘hub-oriented’ and ‘tech-based’ projects have been defined together with the residents. All of them had to face energy challenges, trying to demonstrate the possibility of independency and replicability of the projects.
基于技术系统作为当代社会社会环境发展驱动力的主导作用这一假设,“脆弱性设计-技术挑战”研究项目旨在确定战略,以促进最脆弱社区对技术设备的适应,以克服造成脆弱性的社会环境威胁。定义最合适的方法来鼓励技术适应以减少脆弱性仍然是建筑和城市规划的主要挑战之一。“脆弱性设计-技术挑战”研究项目采用多学科方法;墨西哥奇瓦瓦州的四个社区有七个学科:帕索德尔北,奇瓦瓦州(城市);Nuevas Delicias,吉娃娃(城郊);拉里贾纳、朱利姆斯(农村)和奥坎波的Basaseachic(林业)。为了了解技术适应的方法并减少脆弱性,研究小组正在实施(与居民一起)基于技术的干预措施,研究它们的适应性并评估它们对建筑环境的影响。本文的目的是:(1)描述对弱势群体进行的分析和规划过程;(2)描述参与式规划过程中社区定义的项目及其与环境的关系;(3)分析这些项目的特点;(4)观察这些特征与研究背景的技术占有和能源限制之间的关系。在四个社区中,与居民一起定义了六个“以中心为导向”和“以技术为基础”的项目。他们都必须面对能源挑战,试图证明项目的独立性和可复制性的可能性。
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引用次数: 0
CARBON FOOTPRINT LIFE CYCLE ASSESSMENT OF MODULAR WOODEN CONSTRUCTION 模块化木结构建筑的碳足迹生命周期评估
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230281
PIN-CHI Chen, CHI-JEN Chen, SZU-TUNG Kuo
Due to the crisis of global warming, the urban development strategy of low-carbon cities has been consistently proposed. The strategy of energy conservation and carbon reduction has become a significant international effort to quantify environmental issues. The construction industries in many countries are predominantly reliant on conventional construction methods and processes characterized by high energy consumption and carbon emissions. This heavy reliance on steel and concrete has resulted in the depletion of land resources and incalculable environmental costs. Among these methods, reinforced concrete (RC) structures constitute the highest proportion. To mitigate the environment impacts caused by RC structures, the adoption of modular timber building systems as a design solution for lightweight buildings proves to be an effective and prudent strategy. The modules building unit created using timber construction offer benefits such as low embodied energy, carbon storage, shorter erection periods, low waste generation, and improved labour productivity. Consequently, modular timber building systems have the potential to be developed as affordable and high-quality building systems. This study uses the life cycle assessment tool to monitor the environmental impacts of modular timber construction systems during the raw material production and construction stages. The main research objectives are as follows: (1) Conduct a carbon inventory analysis of modular timber construction; (2) Estimate the carbon footprint of the production process for modular timber construction; and (3) Estimate the carbon footprint during the construction stage of modular timber construction. The results will be concluded in different stages as follows: (1) material production stage; (2) construction stage; and (3) net carbon emissions of modular wooden building, and will be compared to the existing related cases as well. The findings of this study will contribute to the sustainable development of construction industry in the future.
由于全球变暖的危机,低碳城市的城市发展战略不断被提出。节能减碳战略已成为量化环境问题的一项重要国际努力。许多国家的建筑工业主要依赖以高能耗和碳排放为特征的传统建筑方法和工艺。这种对钢铁和混凝土的严重依赖导致了土地资源的枯竭和不可估量的环境成本。在这些方法中,钢筋混凝土结构所占比例最高。为了减轻钢筋混凝土结构对环境造成的影响,采用模块化木结构建筑系统作为轻型建筑的设计解决方案被证明是一种有效而谨慎的策略。使用木结构创建的模块建筑单元具有诸如低隐含能源,碳储存,更短的安装周期,低废物产生和提高劳动生产率等优点。因此,模块化木结构建筑系统有潜力发展成为经济实惠的高质量建筑系统。本研究使用生命周期评估工具来监测模块化木结构系统在原材料生产和施工阶段的环境影响。主要研究目标如下:(1)对模块化木结构进行碳清查分析;(2)估算模块化木结构生产过程中的碳足迹;(3)估算模块化木结构施工阶段的碳足迹。结果将在不同阶段得出:(1)材料生产阶段;(2)施工阶段;(3)模块化木结构建筑的净碳排放量,并将与现有的相关案例进行比较。研究结果将有助建造业在未来的可持续发展。
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引用次数: 0
IMPROVING CHAR AND OIL FOR COMMERCIAL APPLICATIONS FROM THE PYROLYSIS OF AUTOMOTIVE SHREDDER RESIDUE THROUGH THE USE OF DIFFERENT TYPES OF CATALYSTS 通过使用不同类型的催化剂,改善汽车破碎机残渣热解产生的木炭和油的商业用途
Q4 Environmental Science Pub Date : 2023-12-04 DOI: 10.2495/esus230121
Peter Bentley, Karl Williams, Ala Khodier
Pyrolysis of automotive shredder residue (ASR) may be a solution for end-of-life vehicles (ELV) to meet legislative targets and to future proof against any reclassification as a hazardous waste. Prior to pyrolysis commercialization, firm markets for all byproducts produced are required. Identified commercial outlets for byproduct char include: (i) activated carbon; (ii) a soil conditioner and (iii) a partial replacement for cement in concrete. Commercialization of pyrolysis treatment for the UK alone would require outlets capable of taking around 100,000 tpa of char, compliant with quality protocols. The challenge for these applications is any retained persistent organic pollutants (POPS) within the matrix of char particles. A solution would be to break these compounds down during the pyrolysis process through the introduction of catalytic material. This paper explores the effectiveness of four catalysts in reducing the organic contamination within pyrolysis byproducts. A purpose-built lab-based pyrolysis unit (30 g of ASR) was used for initial investigations. ASR (pre-shredded to <10mm) was sourced from a UK ELV recycling company using a systematic sampling approach. A control without catalyst was pyrolysed at 500°C for 30 minutes. Each sample was mixed with the catalyst at a ratio of 1:10. The four catalysts used were: (i) 3Å molecular sieve zeolite; (ii) 4Å molecular sieve zeolite; (iii) MCM-41 mesostructured silica and (iv) AL-MCM-41 mesostructured aluminosilicate. Byproducts were collected and chemically analyzed using organic elemental (CHNS) analysis, FT-IR and GC-MS. Findings indicated that all catalysts offered some improvement in reducing the residual organic fractions in char. 4Å was the most effective, increasing the overall carbon percentage by 17.32%. GCMS and FTIR analysis of the oil indicated that catalysts were effective in deoxygenation without reducing the carbon percentage. In conclusion, catalysts may offer a commercial solution to support the uptake of char as a commercial product.
裂解汽车碎纸机残渣(ASR)可能是报废车辆(ELV)的解决方案,以满足立法目标,并在未来防止任何重新分类为危险废物。在热解商业化之前,所产生的所有副产品都需要有稳定的市场。已确定的副产品炭的商业来源包括:(i)活性炭;(ii)土壤改良剂和(iii)混凝土中水泥的部分替代品。仅在英国,热解处理的商业化就需要能够处理约100,000吨/年焦炭的出口,并符合质量协议。这些应用面临的挑战是在炭颗粒基质中残留的持久性有机污染物(POPS)。一种解决方案是在热解过程中通过引入催化材料来分解这些化合物。本文探讨了四种催化剂在减少热解副产物中有机污染方面的效果。初步研究使用专用的实验室裂解装置(30g ASR)。ASR(预粉碎至<10mm)来自英国ELV回收公司,采用系统采样方法。不加催化剂的对照在500℃下热解30分钟。每个样品与催化剂按1:10的比例混合。采用的四种催化剂为:(i) 3Å分子筛分子筛;(二)4Å分子筛分子筛;(iii) MCM-41介结构二氧化硅和(iv) AL-MCM-41介结构铝硅酸盐。收集副产物,采用有机元素分析(CHNS)、红外光谱(FT-IR)和气相色谱-质谱(GC-MS)进行化学分析。结果表明,所有催化剂对炭中残余有机组分的还原效果都有一定的改善。4Å是最有效的,增加了17.32%的总碳百分比。GCMS和FTIR分析表明,催化剂在不降低含碳量的情况下对油进行了有效的脱氧。总之,催化剂可能提供一种商业解决方案,以支持炭作为商业产品的吸收。
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引用次数: 0
期刊
WIT Transactions on Ecology and the Environment
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