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Characterization of Multipurpose Isolate Pseudomonas aeruginosa AMBCD-1 for Biocontrol and Biodegradation Efficiency 多用途铜绿假单胞菌 AMBCD-1 的生物防治和生物降解效率表征
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-26 DOI: 10.1002/tqem.70000
Tanu Singh, Safina Ismail, Kishan Kumar Raj, Anup Kumar Singh, Tapas Chowdhury, Ravindra Soni

The goal of the study was to assess the capability of the bacteria Pseudomonas aeruginosa AMBCD-1 for paddy straw degradation as well as its biological control abilities against the plant wilt pathogen Fusarium. Fourier-transform infrared spectroscopy (FTIR) data showed that AMBCD-1 culture-inoculated treatments dramatically reduced the levels of cellulose, lignin, and hemicelluloses in the deteriorated paddy straw. Additionally, a dual culture technique was utilized to investigate antagonistic activity in vitro using nutritional agar media and potato dextrose agar in equal proportions (1:1) for suppressing the growth of the fungus Fusarium oxysporum and Sclerotium rolfsii in order to assess the biocontrol properties of the chosen bacteria. Following incubation, it was shown that AMBCD-1 exhibited a 66.67% antibacterial activity against the fungus Fusarium oxysporum. Furthermore, the pyocyanin pigment was also extracted from the P. aeruginosa AMBCD-1 strain and confirmed at a mass value of 211.2 using liquid chromatography mass spectrometry (LC-MS), with its standard peak observed at 1.48 min. The results revealed that bacterium P. aeruginosa AMBCD-1 had the ability to biodegrade paddy straw and also inhibit the appearance of the wilt disease caused by Fusarium species in numerous crops.

这项研究的目的是评估铜绿假单胞菌 AMBCD-1 降解稻草的能力及其对植物枯萎病病原体镰刀菌的生物防治能力。傅立叶变换红外光谱(FTIR)数据显示,AMBCD-1 培养液接种处理可显著降低变质稻草中纤维素、木质素和半纤维素的含量。此外,为了评估所选细菌的生物防治特性,还采用了双重培养技术,以等比例(1:1)使用营养琼脂培养基和马铃薯葡萄糖琼脂在体外研究拮抗活性,以抑制真菌镰刀菌(Fusarium oxysporum)和球孢霉(Sclerotium rolfsii)的生长。培养结果表明,AMBCD-1 对真菌 Fusarium oxysporum 的抗菌活性为 66.67%。此外,还从铜绿微囊藻 AMBCD-1 菌株中提取出了焦花青素色素,并通过液相色谱质谱法(LC-MS)确认其质量值为 211.2,其标准峰出现在 1.48 分钟处。结果表明,铜绿微囊藻 AMBCD-1 菌株具有生物降解稻草的能力,还能抑制由镰刀菌引起的多种作物枯萎病的发生。
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引用次数: 0
Presence of Microplastics in Water, Soil, Organic Fertilizer, and Potato Plants on Potato Plantations 马铃薯种植园的水、土壤、有机肥和马铃薯植株中的微塑料含量
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-25 DOI: 10.1002/tqem.70001
Roy Hendroko Setyobudi, Iswahyudi Iswahyudi, Damat Damat, Marchel Putra Garfansa, Diah Hermayanti, Shefa Dwijayanti Ramadani, Zane Vincevica-Gaile, Lira Rizqi Nurfadilah, Evika Sandi Savitri, Zhulvie Meylanzharie

Microplastics (MPs) have become a significant environmental concern, but data on their presence in potato gardens are limited. This study aims to identify and quantify MPs in soil, organic fertilizer, irrigation water, and potato plants in potato gardens. Soil, fertilizer, irrigation water, and potato samples were collected from potato fields. Analysis was carried out using a microscope and Fourier transform infrared spectroscopy (FTIR) to identify the shape, color, quantity, and type of MP polymer. The results indicate significant MPs contamination with the most dominant shape of fibers (86%) and fragments (8%), dominant color black (35%) and blue (27%), abundances of MPs 0.10–9.20 g−1, as well as the presence of polyethylene terephthalate (PET) and high-density polyethylene (HDPE) polymers. These MPs have the potential to harm plant growth and soil quality. MPs are found in significant quantities in potato gardens and have the potential to disrupt agricultural ecosystems. The presence of MPs in potato gardens can affect the quality of agricultural products and human health throughout the food chain.

微塑料(MPs)已成为一个重要的环境问题,但有关其在马铃薯园中存在的数据却很有限。本研究旨在识别和量化马铃薯园中土壤、有机肥、灌溉水和马铃薯植株中的微塑料。研究人员从马铃薯田中采集了土壤、肥料、灌溉水和马铃薯样本。使用显微镜和傅立叶变换红外光谱(FTIR)进行分析,以确定 MP 聚合物的形状、颜色、数量和类型。结果表明,MPs 污染严重,最主要的形状为纤维(86%)和碎片(8%),主要颜色为黑色(35%)和蓝色(27%),MPs 的丰度为 0.10-9.20 g-1,并且存在聚对苯二甲酸乙二酯(PET)和高密度聚乙烯(HDPE)聚合物。这些 MPs 有可能危害植物生长和土壤质量。在马铃薯种植园中发现了大量的 MPs,并有可能破坏农业生态系统。马铃薯种植园中存在的 MP 会影响整个食物链中的农产品质量和人类健康。
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引用次数: 0
Assessment of Groundwater Quality and Fluoride Contamination in Dharmapuri and Krishnagiri Districts, Tamil Nadu, India 印度泰米尔纳德邦 Dharmapuri 和 Krishnagiri 地区地下水质量和氟化物污染评估
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-25 DOI: 10.1002/tqem.70002
M. Kavisri, Meivelu Moovendhan

Fluoride is highly threatening to human health, and it is a serious issue worldwide, especially in India, because several states in India are at high risk of fluoride contamination in drinking water. In this study, the groundwater from Dharmapuri and Krishnagiri districts was chosen for estimation of quality and fluoride level. The 20 samples were collecetd from two districts, water quality and fluoride were estimated using standard protocols. The results showed that in Dharmapur districts, including Dharmapuri and Morappur, the water quality was very poor and the water was in bad condition, and also the water quality and fluoride levels were above the acceptable limits of WHO and TWAD board norms. In Krishnagiri district, such as Hosur, and Larger domestic water samples were highly polluted. The Pochampalli and Hangar, Anjetti, and area ground waters were in poor condition, the rest of the area's water quality and fluoride level are moderate, and may increase in the upcoming years. The quality of water and fluoride levels have crossed the permissible limits of WHO and TWAD board standards in several sites of Krishnagiri and Dharmapuri districts. Frequent monitoring, more awareness programs, fluoride removal advanced eco-friendly, and highly efficient technologies are needed to manage these pollutants issues.

氟对人类健康的威胁很大,这在全世界都是一个严重的问题,尤其是在印度,因为印度的几个邦都是饮用水氟污染的高危地区。本研究选择了达玛普里和克里希纳吉里地区的地下水来评估水质和氟含量。研究人员从两个地区采集了 20 个样本,并采用标准规程对水质和氟含量进行了估算。结果表明,在达玛普尔县(包括达玛普里和莫拉普尔),水质非常差,水质状况不佳,水质和氟含量也超过了世界卫生组织和 TWAD 委员会标准的可接受范围。在 Krishnagiri 区,如 Hosur 和 Larger 的生活用水样本受到严重污染。Pochampalli 和 Hangar、Anjetti 以及该地区的地下水状况较差,其余地区的水质和氟化物水平处于中等水平,并可能在未来几年有所上升。在克里希纳吉里和达玛普里地区的一些地方,水质和氟化物含量已经超过了世界卫生组织和 TWAD 委员会标准的允许范围。要解决这些污染物问题,需要经常进行监测、开展更多宣传计划、采用先进的生态友好型高效除氟技术。
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引用次数: 0
Evaluation of Ruthenium Oxide Nanoparticles as Photocatalysts: Efficiency in Organic Dye Degradation and Environmental Impact Studies 评估作为光催化剂的纳米氧化钌:有机染料降解效率和环境影响研究
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-18 DOI: 10.1002/tqem.22358
S. Arunachalam, R. Siranjeevi, M. Velayutham Pillai, M. Murphy

One of the most promising nanoscale materials for photodegradation is ruthenium oxide nanoparticles, which are abbreviated as RuO2 nanoparticles. Ruthenium oxide nanoparticles (RuO2 NPs) are promising nanomaterials for photodegradation. Several research methods have examined their size, phase study, and shape. We also examined RuO2 nanoparticle photocatalysis in rhodamine-B (RhB) and acridine orange (AO) dyes degradation. We discovered that these nanoparticles were highly photocatalytic when exposed to UV light. This non-toxic method uses no solvents. Analyzing synthesized RuO2 nanoparticles required FESEM, XRD, XPS (x-ray photoelectron spectroscopy), FTIR (Fourier transform infrared), and UV-visible spectroscopy. The newly synthesized nanoparticles were evaluated for catalytic activity by degrading RhB and AO dyes. After the first-order reaction, kinetics determined the photocatalytic efficiency against RhB and AO dyes, which degraded at 84% and 82%, respectively. A tamarind plant study found no phytotoxicity in treated effluents. RuO2 catalysts degrade organic dyes in industrial wastewater efficiently and inexpensively. The study shows RuO2 nanoparticles as very effective photocatalysts for degrading organic dyes, exhibiting better performance than conventional materials. In addition, it assesses the phytotoxicity of RuO2 nanoparticles, offering valuable information about their environmental consequences and safety for prospective widespread application.

最有前途的光降解纳米级材料之一是氧化钌纳米颗粒,简称 RuO2 纳米颗粒。氧化钌纳米颗粒(RuO2 NPs)是一种很有前景的光降解纳米材料。有几种研究方法对它们的尺寸、相学和形状进行了研究。我们还研究了 RuO2 纳米粒子在罗丹明-B(RhB)和吖啶橙(AO)染料降解中的光催化作用。我们发现,这些纳米粒子在紫外线照射下具有很强的光催化能力。这种无毒方法不使用溶剂。分析合成的 RuO2 纳米粒子需要使用 FESEM、XRD、XPS(X 射线光电子能谱)、FTIR(傅立叶变换红外光谱)和紫外-可见光谱。通过降解 RhB 和 AO 染料,对新合成的纳米粒子的催化活性进行了评估。在一阶反应后,动力学确定了对 RhB 和 AO 染料的光催化效率,降解率分别为 84% 和 82%。对罗望子树植物的研究发现,处理后的污水没有植物毒性。RuO2 催化剂能高效、低成本地降解工业废水中的有机染料。研究表明,RuO2 纳米粒子是非常有效的降解有机染料的光催化剂,其性能优于传统材料。此外,研究还评估了 RuO2 纳米粒子的植物毒性,为其未来的广泛应用提供了有关环境后果和安全性的宝贵信息。
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引用次数: 0
Upcycling of Beer Industry Wastewater: Biosurfactant Production and Application in Brewery Effluent Treatment 啤酒工业废水的升级再循环:生物表面活性剂的生产及在啤酒厂污水处理中的应用
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-18 DOI: 10.1002/tqem.22361
Tatiana da Silva Sant'Ana, Juliana Machado Latorres, Vilásia Guimarães Martins

The beer processing industry generates large amounts of effluents rich in organic and inorganic material, and complex and expensive systems are commonly used for their treatment. Therefore, new alternatives capable of ensuring sustainable industrial growth through cost-effective solutions are being studied. In this context, biosurfactants stand out due to their ability to degrade and remove contaminants from the environment. Therefore, the objective of this study was to evaluate the potential treatment of effluents from the beer industry using biosurfactants produced from wastewater from the beer industry. The biosurfactants were obtained by submerged cultivation at 30°C for 48 h using the bacterium Corynebacterium aquaticum in a mineral medium added of carbon source. The characterization of the biosurfactants was performed in relation to surface tension, emulsifying activity (EA), pH, and ionic character. The analyses were performed at 0, 24, and 48 h. The efficiency of the effluent treatments was evaluated by characterization in duplicate, before, during and after the treatment, regarding the concentrations of biochemical oxygen demand (BOD), chemical oxygen demand (COD), and total solids (TS). The best biosurfactant results were obtained using C. aquaticum in a medium with 10% (v/v) of brewing industry wastewater (BIW) as a carbon source after 48 h of cultivation, reaching a surface tension of 35.1 ± 0.2 mN/m, EA of 40.9 ± 0.5%, and stability under extreme conditions of temperature (−20°C to 121°C), salt (1% to 10%), and pH (4 to 10). Thus, the biosurfactant was applied for 10 days in an aerated biological treatment system. Best results were observed in biosurfactant concentrations of 0.5 CMD (critical micellar dilution), reaching improvement of up to 55.9% for BOD, 23.8% for COD, and 50.6% for TS. Thus, the biosurfactant produced (10% BIW) shows potential as an accelerator in the brewing industry effluent (BIE) treatment process, without purification and sterilization of the biocompound. Therefore, brewery wastewater proved to be a sustainable and nutritional substrate to obtain biosurfactants.

啤酒加工业会产生大量富含有机物和无机物的废水,通常采用复杂而昂贵的系统进行处理。因此,人们正在研究能够通过具有成本效益的解决方案确保工业可持续发展的新替代品。在这种情况下,生物表面活性剂因其降解和清除环境中污染物的能力而脱颖而出。因此,本研究的目的是评估使用从啤酒工业废水中提取的生物表面活性剂处理啤酒工业废水的潜力。生物表面活性剂是在添加了碳源的矿物培养基中,通过在 30°C 的温度下浸没培养 Aquaticum 冠状杆菌 48 小时而获得的。生物表面活性剂的表征与表面张力、乳化活性(EA)、pH 值和离子特性有关。在 0、24 和 48 小时内分别进行了分析。污水处理的效率是通过在处理前、处理过程中和处理后对生化需氧量(BOD)、化学需氧量(COD)和总固体(TS)的浓度进行一式两份的表征来评估的。在以 10%(v/v)酿造工业废水(BIW)为碳源的培养基中培养水生藻类,48 小时后获得的生物表面活性剂效果最好,表面张力达到 35.1 ± 0.2 mN/m,EA 达到 40.9 ± 0.5%,并且在温度(-20°C 至 121°C)、盐分(1% 至 10%)和 pH 值(4 至 10)等极端条件下都很稳定。因此,生物表面活性剂在充气生物处理系统中使用了 10 天。生物表面活性剂浓度为 0.5 CMD(临界胶束稀释)时效果最佳,BOD、COD 和 TS 分别提高了 55.9%、23.8% 和 50.6%。因此,生产的生物表面活性剂(10% BIW)在酿造工业废水(BIE)处理过程中具有潜在的促进作用,而无需对生物化合物进行净化和消毒。因此,酿酒废水被证明是一种可持续的营养基质,可用于获得生物表面活性剂。
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引用次数: 0
Modeling Land Use and Land Cover Changes and Its Atmospheric Pollutant Concentration in the Coal Mining Area of Ramgarh District of Jharkhand, India, Using Multi-Layer Perceptron Neural Networks (MLPNN) 利用多层感知器神经网络(MLPNN)模拟印度贾坎德邦拉姆加尔地区煤矿开采区的土地利用和土地覆盖变化及其大气污染物浓度
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-12 DOI: 10.1002/tqem.22351
Shazada Ahmad, Navneet Kaur, Mahammad Shahbaz Badar, Adnan Shakeel, Farid Ahmed

Land use refers to anthropogenic phenomena in the natural environment; humans utilize land resources for their developmental activities. On the other hand, the ecosystems of land use and land cover alter the natural world—the artificial infrastructure leads toward a busted concrete jungle instead of a green footprint. The global green footprint is continually shrinking owing to overutilization of natural resources. The present research examines the land use pattern that changes from 1990 to 2021 and projected projections for 2041 and 2061 in the Ramgarh District. The study also focuses on how artificial modifications alter the concentration level of pollutants in the atmosphere. The Landsat data utilized for 1990, 2000, 2011, and 2021 were incorporated into the LULC map using supervised classification and for analysis of future predictions for 2041 and 2061 using an ANN-based on MLPNNs (multi-layer perceptron neural networks) for Ramgarh District. It also focuses on the trend and patterns of atmospheric pollutants from data using NASA-GIOVANNI MERRA-2. The current study reveals that in 1990, water bodies, coal mining, vegetation, built-up, agriculture, and barren land were 3.01%, 2.24%, 54.07%, 3.64%, 36.85%, and 0.18 %. However, in 2021, water bodies decreased to 1.61%, vegetation to 45.47%, barren land to 0.65%, and an increasing tendency was observed in built-up areas to 6.65%, coal mining to 2.43%, and farmland to 43.19%. A significant trend in atmospheric pollutants, such as CO2, SO2, SO4, NO2, and dust, is observed in the Ramgarh district. The importance of this study is to attain the maximum level of environmental sustainability; it would also encourage the local level planning fitted during the extraction of natural resources.

土地利用是指自然环境中的人为现象;人类利用土地资源进行开发活动。另一方面,土地利用和土地覆盖的生态系统改变了自然世界--人工基础设施导致了破败的水泥森林,而不是绿色足迹。由于过度利用自然资源,全球绿色足迹不断缩小。本研究探讨了拉姆加尔地区从 1990 年到 2021 年的土地利用模式变化以及 2041 年和 2061 年的预测。研究还重点关注人为改变如何改变大气中污染物的浓度水平。利用 1990 年、2000 年、2011 年和 2021 年的大地遥感卫星数据,采用监督分类法将其纳入土地利用、土地利用变化和林业地图,并使用基于 MLPNN(多层感知器神经网络)的 ANN 对拉姆加尔地区 2041 年和 2061 年的未来预测进行分析。本研究还重点研究了利用 NASA-GIOVANNI MERRA-2 数据得出的大气污染物的趋势和模式。目前的研究显示,1990 年,水体、煤矿、植被、建筑、农业和荒地分别占 3.01%、2.24%、54.07%、3.64%、36.85% 和 0.18%。但在 2021 年,水体减少到 1.61%,植被减少到 45.47%,荒地减少到 0.65%,而建筑密集区、煤矿开采区和农田分别增加到 6.65%、2.43%和 43.19%。拉姆加尔地区的二氧化碳、二氧化硫、二氧化硫、二氧化氮和粉尘等大气污染物呈明显上升趋势。这项研究的重要意义在于最大限度地实现环境的可持续发展,同时也将鼓励地方在开采自然资源时进行规划。
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引用次数: 0
Formaldehyde as Preservative for Fish and Seafood: A Boon or a Bane 甲醛作为鱼类和海鲜的防腐剂:是福是祸
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-12 DOI: 10.1002/tqem.22357
Susri Nayak, Pratyusha Nayak, Shubhajit Saha, Lipika Patnaik, Subhashree Nayak, Smruti Prajna Pradhan, Sthitaprajna Nath Sharma, Nishigandha Muduli

Three billion people globally rely on fish and other seafood as a significant source of animal protein. Despite being deemed illegal due to its ability to cause cancer, mutagenesis, and tumor development, formaldehyde is still in use to extend the shelf life of different fish and shellfish, which indicates the failure of awareness among people. Formaldehyde is categorized by the International Agency for Research on Cancer (IARC) as a Group-I human carcinogen. Therefore, we try to summarize the chemistry of formaldehyde, its illegal addition in various food materials leading to adverse health conditions followed by its evaluation at physiological and histological levels in our review with the help of data collected from various research papers, newspaper articles, and online data. We have also highlighted on various environmental factors that play a role in altering the levels of formaldehyde in various food materials. This review also gives an insight into various rules and regulations made to limit the usage of formaldehyde in fish and other seafood at both national and international levels. Our review will help to generate awareness among common people, the establishment of much stronger rules, and regulations on usage of formaldehyde, and finding an alternative for preservation of fish and other food materials.

全球有 30 亿人依赖鱼类和其他海产品作为动物蛋白质的重要来源。尽管甲醛因其致癌、诱变和肿瘤发生的能力而被视为非法,但人们仍在使用甲醛来延长不同鱼类和贝类的保质期,这表明人们的认识还不到位。甲醛被国际癌症研究机构(IARC)列为第一类人类致癌物质。因此,我们试图通过从各种研究论文、报刊文章和在线数据中收集的数据,总结甲醛的化学性质、甲醛在各种食品材料中的非法添加导致的不良健康状况,以及在生理和组织学层面对甲醛的评估。我们还强调了在改变各种食品材料中甲醛含量方面起作用的各种环境因素。本综述还介绍了国家和国际层面为限制鱼类和其他海产品中甲醛的使用而制定的各种规则和规定。我们的综述将有助于提高普通民众的认识,制定更严格的甲醛使用规则和法规,并找到保存鱼类和其他食品材料的替代方法。
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引用次数: 0
Edge Influence in a Semi-Deciduous Tropical Forest: An Investigation of Soil Organic Carbon Fractions 半落叶热带森林的边缘影响:土壤有机碳组分调查
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-11 DOI: 10.1002/tqem.22354
Patrícia Anjos Bittencourt Barreto-Garcia, Francielle da Silva Lopes, Paulo Henrique Marques Monroe, Alessandro de Paula, Kyegla Beatriz da Silva Martins, Marcio Renato Nunes

Recent studies have proven the sensitivity of soil organic carbon (SOC) in responding to variations imposed by tropical forest fragmentation, which may reflect changes in both its quantity and quality. Despite this, studies evaluating soil carbon fractions as an edge effect indicator are still non-existent. We developed this work asking: How do the oxidizable fractions of soil organic carbon (OFSOC) respond to the edge effect in fragments of semi-deciduous seasonal forest? Is this response influenced by the size of the forest fragment? The study was conducted in Vitória da Conquista, Bahia, Brazil, in three forest fragments with different sizes. Thus, three sampling sections were defined in each fragment: edge (0–10 m), transition (40–50 m), and interior. Soil samples were collected at a depth of 0–10 cm. The SOC was divided into three fractions (LC—labile carbon, MLC—moderately labile carbon, and LLC—low labile carbon), adopting the chemical method based on oxidation degrees. Reductions in the SOC (28.2%), LC (17.4%), and MLC content (66.7%) were observed at the edge in the small fragment. There was a reduction of SOC (21.3%) and LLC (39.0%) at the edge in the medium fragment, while MLC showed an increase at the edge (70.4%). The OFSOC were able to respond to the changes imposed by the edge effect, with emphasis on the LC and MLC fractions in smaller fragments. The forest fragment size influenced the level of changes caused by the edge effect in OFSOC, showing greater susceptibility in smaller fragments.

最近的研究证明,土壤有机碳(SOC)对热带森林破碎化带来的变化非常敏感,这可能反映了其数量和质量的变化。尽管如此,将土壤碳组分作为边缘效应指标进行评估的研究仍不存在。我们在这项工作中提出了以下问题:土壤有机碳的可氧化组分(OFSOC)如何对半落叶季节性森林破碎带的边缘效应做出反应?这种反应是否受森林片段大小的影响?这项研究在巴西巴伊亚州维托里亚-达孔奎斯塔(Vitória da Conquista)的三个不同大小的森林片断中进行。因此,在每个片段中定义了三个采样区:边缘(0-10 米)、过渡区(40-50 米)和内部。土壤样本采集深度为 0-10 厘米。采用基于氧化度的化学方法,将 SOC 分成三个部分(LC-易变碳、MLC-中度易变碳和 LLC-低易变碳)。在小碎片的边缘观察到 SOC(28.2%)、LC(17.4%)和 MLC 含量(66.7%)的减少。在中等片段的边缘,SOC(21.3%)和 LLC(39.0%)含量减少,而 MLC 在边缘则有所增加(70.4%)。OFSOC 能够对边缘效应带来的变化做出反应,重点是较小片段中的 LC 和 MLC 部分。森林片段的大小影响了边缘效应对 OFSOC 所造成的变化程度,较小的片段显示出更大的易感性。
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引用次数: 0
Navigating Carbon Peaking and Neutrality in MENA: The Impact of Foreign Direct Investment and Trade Openness Using Panel PCSE and FGLS Techniques 中东和北非地区的碳峰值和碳中性:利用面板 PCSE 和 FGLS 技术分析外国直接投资和贸易开放的影响
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-10 DOI: 10.1002/tqem.22352
Ummar Faruk Saeed, Angelina Kissiwaa Twum, Godfred Etse Klugah

In response to the global challenge of climate change and the drive towards carbon neutrality, this study investigates the effects of foreign direct investment (FDI) and trade openness (TO) on carbon emissions (CEM) within the Middle East and North Africa (MENA) region. The research spans 18 countries from 1990 to 2022, focusing on Sustainable Development Goal 13. Utilizing Porter's hypothesis and the Environmental Kuznets Curve (EKC) theory, the study applies quantitative methods including panel corrected standard errors (PCSE) and feasible generalized least squares (FGLS) to ensure robustness. To address potential endogeneity, two-stage least squares and lagged effect estimations are employed. The findings reveal that both FDI and TO are associated with reduced CEM, indicating positive environmental impacts. Also, the pairwise causality tests show bidirectional causality between FDI, TO, and CEM, while a unidirectional causality is found from industrialization (IND) and energy consumption (EC) to CEM. These results underscore the importance of integrating FDI and TO into strategies for achieving carbon neutrality and advancing sustainable development goals, offering actionable insights for policymakers.

为应对气候变化这一全球性挑战并推动实现碳中和,本研究调查了中东和北非地区外国直接投资(FDI)和贸易开放度(TO)对碳排放(CEM)的影响。研究跨越了 1990 年至 2022 年的 18 个国家,重点关注可持续发展目标 13。利用波特假说和环境库兹涅茨曲线(EKC)理论,研究采用了定量方法,包括面板校正标准误差(PCSE)和可行的广义最小二乘法(FGLS),以确保稳健性。为解决潜在的内生性问题,采用了两阶段最小二乘法和滞后效应估计。研究结果表明,外国直接投资和外商直接投资都与 CEM 的减少有关,表明对环境有积极影响。此外,成对因果检验显示,外国直接投资、外商直接投资和 CEM 之间存在双向因果关系,而工业化(IND)和能源消耗(EC)与 CEM 之间存在单向因果关系。这些结果凸显了将外国直接投资和制造业转移纳入实现碳中和及推进可持续发展目标的战略的重要性,为政策制定者提供了可操作的见解。
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引用次数: 0
Insights Into the Adsorption Behavior of Polyethylene Microplastics Towards Lead(II) Ions 聚乙烯微塑料对铅(II)离子吸附行为的启示
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-08 DOI: 10.1002/tqem.22355
Krishnan Saravanakumar, Manickam Sathyamoorthy, Donipathi Mogili Reddy Prasad, Balakrishna Sankari Naveen Prasad, Ramalingham Senthilkumar, Govindarajan Lakshmanarao

Microplastics and metals represent widespread contaminants which can cause significant damage to aquatic ecosystems and organisms. However, the complex interactions between microplastics and various metals in water environments remains to be understood. This study aims to investigate the interaction dynamics between lead(II) ions and polyethylene in freshwater environments. Adsorption trials were conducted systematically by adjusting operational parameters such as initial Pb(II) concentration, equilibrium pH value, and residence times. An in-depth characterization study using scanning electron microscopy (SEM), x-ray diffraction and Fourier transform infrared (FTIR) analysis was conducted to explain the adsorption mechanism of polyethylene microplastics (PEM). The data indicated the porous surface of PEM, highlighting the presence of diverse functional groups. According to the Langmuir model, the PEM exhibited maximum Pb(II) uptake of 3.69 mg/g at pH 4.5. The pseudo-first-order model demonstrated superior fitting to Pb(II)-PEM kinetics. Desorption trials were performed to assess the release of Pb(II) from Pb(II)-bounded PEM using various chemical agents. It was observed that 0.01 M HNO₃ desorbed Pb(II) ions optimally, achieving a desorption efficiency exceeding 99.9%. Consequently, desorption trials provided evidence that Pb(II)-bounded PEM may release Pb(II) ions in acidic environments, facilitating the transfer of Pb(II) to the digestive tracts of aquatic organisms.

微塑料和金属是广泛存在的污染物,可对水生生态系统和生物体造成重大损害。然而,微塑料和各种金属在水环境中的复杂相互作用仍有待了解。本研究旨在探讨淡水环境中铅(II)离子与聚乙烯之间的相互作用动力学。通过调整初始铅(II)浓度、平衡 pH 值和停留时间等操作参数,系统地进行了吸附试验。为了解释聚乙烯微塑料(PEM)的吸附机理,利用扫描电子显微镜(SEM)、X 射线衍射和傅立叶变换红外(FTIR)分析进行了深入的表征研究。数据表明,PEM 表面多孔,突出显示了不同官能团的存在。根据 Langmuir 模型,在 pH 值为 4.5 时,PEM 对铅(II)的最大吸附量为 3.69 毫克/克。伪一阶模型对 Pb(II)-PEM 动力学的拟合效果更佳。使用各种化学试剂进行了解吸试验,以评估 Pb(II)-PEM 中 Pb(II) 的释放情况。结果表明,0.01 M HNO₃对铅(II)离子的解吸效果最佳,解吸效率超过 99.9%。因此,解吸试验证明,与铅(II)结合的 PEM 可在酸性环境中释放铅(II)离子,促进铅(II)转移到水生生物的消化道中。
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引用次数: 0
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Environmental Quality Management
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