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2023年度秋季大会プログラム 2023年度秋季大会计划
Q4 Materials Science Pub Date : 2023-09-15 DOI: 10.2497/jjspm.70.mtgpr9_14
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引用次数: 0
2023年度粉末冶金講座 2023年度粉末冶金讲座
Q4 Materials Science Pub Date : 2023-09-15 DOI: 10.2497/jjspm.70.mtg9_2
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引用次数: 0
外場としてのミリ波を援用した高温電気化学デバイスの特性変化 使用毫米波作为外场的高温电化学装置的特性变化
Q4 Materials Science Pub Date : 2023-09-15 DOI: 10.2497/jjspm.23-00013
Takuro FUJIWARA, Takashi TERANISHI, Akira KISHIMOTO, Seiichi SUDA
The characteristics of high-temperature oxide fuel cells and high-temperature steam electrolysis cells under millimeter-wave irradiation were evaluated and compared with those evaluated under conventional electric furnace heating. A reversible high-temperature electrochemical cell was fabricated using alumina-dispersed zirconia as the electrolyte, lanthanum strontium manganate as the air electrode, and nickel-ziconia based cermet as the fuel one. The power generation characteristic of the fuel cell under millimeter wave irradiation was 32% higher than that of a conventional electric furnace temperature heating, and the steam electrolysis efficiency was also 120% higher under millimeter-wave irradiation than that under conventional one. Impedance measurements using an air electrode-electrolyte half-cell showed that the millimeter wave irradiation facilitated the dissociation of oxygen molecule and/or diffusion of oxygen atoms on the surface of the air electrode as well as the oxide ion conduction in the electrolyte.
对高温氧化物燃料电池和高温蒸汽电解电池在毫米波辐照下的性能进行了评价,并与常规电炉加热下的性能进行了比较。以铝分散氧化锆为电解液,锰酸锶镧为空气电极,镍锆基陶瓷为燃料电极,制备了可逆高温电化学电池。毫米波辐照下燃料电池的发电特性比传统电炉温度加热下的发电特性提高32%,毫米波辐照下的蒸汽电解效率也比传统电炉温度加热下的蒸汽电解效率提高120%。利用空气电极-电解质半电池进行的阻抗测量表明,毫米波辐照促进了氧分子的解离和/或氧原子在空气电极表面的扩散以及电解质中氧化离子的传导。
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引用次数: 0
Attempt for Fabrication of Acicular Hexagonal Ferrite Particles Elongated in the c-axis Direction 在c轴方向上拉长的针状六方铁素体颗粒的制备尝试
Q4 Materials Science Pub Date : 2023-09-15 DOI: 10.2497/jjspm.23-00019
Kanpei NISHIOKA, Yu YAMAMOTO, Masakuni TAKAHASHI, Jun KANO, Tatsuo FUJII
Barium ferrite particles were synthesized from acicular α-Fe2O3 particles grown in the c-axis direction. The synthesis was carried out by the flux method, in which acicular α-Fe2O3 particles reacted with BaCO3 in NaCO3 flux. The acicular-shaped BaFe12O19 particles grown in the c-axis direction were obtained. The acicular shape consisted of aggregates of plate-like particles stacked along the c-axis. The platelet-shaped BaFe12O19 particles prepared from spherical α-Fe2O3 under the same synthesis conditions exhibited a smaller coercivity than the acicular BaFe12O19 particles synthesized in this study. Therefore, it can be inferred that the shape anisotropy has an effect on the magnetic properties of the acicular particles.
采用c轴方向生长的针状α-Fe2O3颗粒合成了钡铁氧体颗粒。采用通量法合成,针状α-Fe2O3颗粒在NaCO3通量中与BaCO3反应。得到了沿c轴方向生长的针状BaFe12O19颗粒。针状结构由沿c轴堆积的片状颗粒组成。在相同的合成条件下,由球形α-Fe2O3制备的血小板状BaFe12O19颗粒的矫顽力比本研究合成的针状BaFe12O19颗粒小。因此,可以推断形状各向异性对针状颗粒的磁性能有影响。
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引用次数: 0
Short Process for Preparing Long-Lasting SrAl<sub>2</sub>O<sub>4</sub>- and CaAl<sub>2</sub>O<sub>4</sub>-based Phosphors by Spark Plasma Sintering 火花等离子烧结制备长效SrAl&lt;sub&gt;2&lt;/sub&gt; o&gt;4&lt;/sub&gt;-和CaAl&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;4&lt;/sub&gt
Q4 Materials Science Pub Date : 2023-09-15 DOI: 10.2497/jjspm.23-00018
Nao MANABE, Ayako S. SUZUKI, Takuya FUJIMURA, Hiroyuki KITAGAWA
Long-lasting phosphors, SrAl2O4: Eu, Dy and CaAl2O4: Eu, Nd, have been prepared by a short process using the spark plasma sintering method. The raw oxide powders were mixed for 5 min using a high-energy mill. Subsequently, solid-state reaction and sintering were simultaneously performed for approximately 20 min using a spark plasma sintering apparatus. The sintering temperatures were set to 1150–1500°C for SrAl2O4: Eu, Dy and 1100–1400°C for CaAl2O4: Eu, Nd. The X-ray diffraction patterns showed that a sintering temperature of 1400°C or higher was required for single-phase synthesis of SrAl2O4: Eu, Dy, while a sintering temperature of 1200°C was suitable for synthesis of CaAl2O4: Eu, Nd. The sintered SrAl2O4: Eu, Dy and CaAl2O4: Eu, Nd phosphors exhibited bright green and blue emission by ultraviolet irradiation, respectively, and they showed afterglow properties. In particular, SrAl2O4: Eu, Dy prepared at 1500°C and CaAl2O4: Eu, Nd prepared at 1200°C showed good performance in terms of both the initial emission intensity and afterglow properties. Thus, sintered long-lasting SrAl2O4: Eu, Dy and CaAl2O4: Eu, Nd phosphors can be prepared by a short process using spark plasma sintering if the sintering temperatures are properly selected.
采用火花等离子烧结的方法,用短工艺制备了长效荧光粉SrAl2O4: Eu, Dy和CaAl2O4: Eu, Nd。原料氧化物粉末使用高能磨机混合5分钟。随后,使用火花等离子烧结装置同时进行固态反应和烧结约20分钟。SrAl2O4: Eu, Dy的烧结温度为1150 ~ 1500℃,CaAl2O4: Eu, Nd的烧结温度为1100 ~ 1400℃。x射线衍射图表明,单相合成SrAl2O4: Eu, Dy需要1400℃以上的烧结温度,而单相合成CaAl2O4: Eu, Nd需要1200℃的烧结温度。在紫外照射下,烧结的SrAl2O4: Eu, Dy和CaAl2O4: Eu, Nd荧光粉分别呈现亮绿色和亮蓝色,并具有余辉特性。其中,在1500℃下制备的SrAl2O4: Eu, Dy和在1200℃下制备的CaAl2O4: Eu, Nd在初始发射强度和余辉性能方面均表现出良好的性能。因此,只要选择合适的烧结温度,可以在短时间内制备出烧结持久的SrAl2O4: Eu, Dy和CaAl2O4: Eu, Nd荧光粉。
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引用次数: 0
Giant Negative Thermal Expansion Materials: Progress of Research and Future Prospects 巨型负热膨胀材料的研究进展与展望
Q4 Materials Science Pub Date : 2023-08-15 DOI: 10.2497/jjspm.23-00010
K. Takenaka
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引用次数: 0
負膨張材料を分散させた表面層を持つセラミックス積層体の耐熱衝撃性 具有分散有负膨胀材料表面层的陶瓷层叠体的耐热冲击性
Q4 Materials Science Pub Date : 2023-08-15 DOI: 10.2497/jjspm.23-00011
Takaya Ueno, S. Kondo, T. Teranishi, Akira Kishimoto
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引用次数: 0
2023年度秋季大会研究発表講演募集 2023年度秋季大会研究発表講演募集
Q4 Materials Science Pub Date : 2023-08-15 DOI: 10.2497/jjspm.70.mtg8_2
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引用次数: 0
「粉体粉末冶金協会新技術・新製品賞」の募集について 关于“粉末粉末冶金协会新技术、新产品奖”征集
Q4 Materials Science Pub Date : 2023-08-15 DOI: 10.2497/jjspm.70.380
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引用次数: 0
Development of Negative Thermal Expansion Material Utilizing Structural Phase Transition of Zn2P2O7 利用Zn2P2O7结构相变制备负热膨胀材料
Q4 Materials Science Pub Date : 2023-08-15 DOI: 10.2497/jjspm.23-00009
R. Kasugai, Y. Kadowaki, N. Katayama, D. Hirai, K. Takenaka
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引用次数: 0
期刊
Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy
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