N-substituted PANI-ES was obtained from N-phenyl-β-alanine (N-substituted aniline). N-phenyl-β-alanine was synthesized chemically from methyl acrylate and aniline precursor. ESI-MS, H1NMR spectroscopy and FTIR spectroscopy are employed to characterise the N-phenyl-β-alanine for structure elucidation. The structure and properties of corresponding polymers were investigated by X-ray diffraction, FTIR, UV-Visible, H1NMR, FESEM, solubility, and DC conductivity. On the basis of experimental results of prepared N-substituted aniline monomer and its corresponding polymer is proposed. At room temperature, the average DC conductivity of as-prepared PANI polymers was found in semiconducting range, which is 0.153 S/cm for poly (3-methyl (phenyl amino) propionic acid. We also were analysed temperature dependent DC conductivity with and without magnetic field of as prepared PANI polymers to understand the conduction mechanism and it was followed variable-range hopping (VRH) process. In addition, we were discussed the response of liquefied petroleum gas (LPG) with polyaniline based sensor materials.
n -苯基-β-丙氨酸(n -取代苯胺)得到n -取代聚苯胺。以丙烯酸甲酯和苯胺为原料，化学合成了n -苯基β-丙氨酸。采用ESI-MS、H1NMR和FTIR对n -苯基β-丙氨酸进行了表征，并对其结构进行了分析。通过x射线衍射、FTIR、uv -可见、H1NMR、FESEM、溶解度和直流电导率等手段研究了聚合物的结构和性能。在实验结果的基础上，提出了n -取代苯胺单体及其相应的聚合物。室温下制备的聚苯胺聚合物的平均直流电导率在半导体范围内，聚3-甲基苯基氨基丙酸的平均直流电导率为0.153 S/cm。我们还分析了制备的聚苯胺聚合物在有磁场和没有磁场的情况下随温度变化的直流电导率，以了解导电机理，并遵循变范围跳变(VRH)过程。此外，我们还讨论了聚苯胺基传感器材料对液化石油气(LPG)的响应。
{"title":"Acrylic Acid (AA) Based Polyaniline Composite for Liquified Petroleum Gas (LPG) Sensors","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2124","DOIUrl":"https://doi.org/10.34256/ioriip2124","url":null,"abstract":"N-substituted PANI-ES was obtained from N-phenyl-β-alanine (N-substituted aniline). N-phenyl-β-alanine was synthesized chemically from methyl acrylate and aniline precursor. ESI-MS, H1NMR spectroscopy and FTIR spectroscopy are employed to characterise the N-phenyl-β-alanine for structure elucidation. The structure and properties of corresponding polymers were investigated by X-ray diffraction, FTIR, UV-Visible, H1NMR, FESEM, solubility, and DC conductivity. On the basis of experimental results of prepared N-substituted aniline monomer and its corresponding polymer is proposed. At room temperature, the average DC conductivity of as-prepared PANI polymers was found in semiconducting range, which is 0.153 S/cm for poly (3-methyl (phenyl amino) propionic acid. We also were analysed temperature dependent DC conductivity with and without magnetic field of as prepared PANI polymers to understand the conduction mechanism and it was followed variable-range hopping (VRH) process. In addition, we were discussed the response of liquefied petroleum gas (LPG) with polyaniline based sensor materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129483784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Simple in situ chemical oxidation method was employed to prepare different molar of HCl doped DL−PLA/PANI composites using AnHCl as precursor. Surface morphology, ATR−FTIR, UV–Visible, and band gap were studied. PANI nanowires with different diameter and smooth surface were observed for composites. The lowest direct band gap was found to be 1.68 eV for 2 (M) HCl doped DL−PLA/PANI. DC conductivity at room temperature was measured and followed the ohmic behaviour. The calculated highest DC conductivity at room temperature was found to be 0.1628 × 10−2 (S/cm) for 2 (M) HCl doped DL−PLA/PANI. Temperature variation (70−300 K) DC conductivity without magnetic field of as prepared composites was analysed using linear four probe techniques and showed semiconducting nature. The conductivity in the range of temperature (70−300 K) follows 3D VRH hopping mechanism. In kivelson model, the exponents are increased with increasing dopant concentration and was obeyed the power law. MR of the prepared DL−PLA/PANI composite films is strongly dependent on temperature, magnetic field, and concentration of HCl dopant. Negative MR is discussed in terms of a wave function−shrinkage effect on hopping conduction. In addition, we were discussed the response of carbon monoxide (CO) gas with polyaniline-based sensor materials.
{"title":"Inorganic Acid Doped Polyaniline Based Carbon Monoxide (Co) Sensor","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2128","DOIUrl":"https://doi.org/10.34256/ioriip2128","url":null,"abstract":"Simple in situ chemical oxidation method was employed to prepare different molar of HCl doped DL−PLA/PANI composites using AnHCl as precursor. Surface morphology, ATR−FTIR, UV–Visible, and band gap were studied. PANI nanowires with different diameter and smooth surface were observed for composites. The lowest direct band gap was found to be 1.68 eV for 2 (M) HCl doped DL−PLA/PANI. DC conductivity at room temperature was measured and followed the ohmic behaviour. The calculated highest DC conductivity at room temperature was found to be 0.1628 × 10−2 (S/cm) for 2 (M) HCl doped DL−PLA/PANI. Temperature variation (70−300 K) DC conductivity without magnetic field of as prepared composites was analysed using linear four probe techniques and showed semiconducting nature. The conductivity in the range of temperature (70−300 K) follows 3D VRH hopping mechanism. In kivelson model, the exponents are increased with increasing dopant concentration and was obeyed the power law. MR of the prepared DL−PLA/PANI composite films is strongly dependent on temperature, magnetic field, and concentration of HCl dopant. Negative MR is discussed in terms of a wave function−shrinkage effect on hopping conduction. In addition, we were discussed the response of carbon monoxide (CO) gas with polyaniline-based sensor materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"822 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123291040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The background of work carried out highlighting on polyaniline, N-substituted polyaniline and acid-doped polyaniline. The problems associated with this polymer and promises it hold are also discussed. It also provides introduction to the nanocomposites of polyaniline/nanoclays, and polyaniline/polyacrylic acid. As well, we have described the polymer stabilized intrinsically conducting polymer composites. The state of the art polymer stabilised intrinsically conducting composites have been reviewed. At last, we have reviewed on the CH4 gas sensing since it has been recognized as one of the inflammable gas sensors. The main problem on the CH4 gas sensor lies on its room temperature operation and detection of low ppm level concentration.
{"title":"Fundamentals on Polyaniline based Composites","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2121","DOIUrl":"https://doi.org/10.34256/ioriip2121","url":null,"abstract":"The background of work carried out highlighting on polyaniline, N-substituted polyaniline and acid-doped polyaniline. The problems associated with this polymer and promises it hold are also discussed. It also provides introduction to the nanocomposites of polyaniline/nanoclays, and polyaniline/polyacrylic acid. As well, we have described the polymer stabilized intrinsically conducting polymer composites. The state of the art polymer stabilised intrinsically conducting composites have been reviewed. At last, we have reviewed on the CH4 gas sensing since it has been recognized as one of the inflammable gas sensors. The main problem on the CH4 gas sensor lies on its room temperature operation and detection of low ppm level concentration.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131854691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Compacted polyaniline (PANI)/Layered silicate nanocomposites have been successfully prepared by simple in situ, core-shell, and ex situ polymerization routes using AnHCl as a predecessor through chemical oxidation method. The structure, chemical groups, electronic transition and properties were investigated by XRD, SEM, HRTEM, UV Visible, DC electrical conductivity, TGA, and DSC. The XRD results reveals that HCl-treated Cloisite 20A, and PANI-ES/Cloisite 20A nanocomposites are delaminated. Flake-like morphologies were observed in Cloisite 20A and HCl-treated Cloisite 20A, whereas different rate of compacted fibrous morphologies of prepared PANI-ES/Cloisite 20A nanocomposites were observed as evident from SEM images. The Si-O FTIR band position does not change even after HCl treatment of Cloisite 20A, but different FTIR peaks positions of PANI-ES/Cloisite 20A nanocomposites were shifted from pure PANI-ES peaks after using Cloisite 20A nanoclays. UV-Visible spectra indicated the increment of charge carrier within the PANI-ES/Cloisite 20A nanocomposites compared to the pure one. The prepared nanohybrids showed significantly improved thermal property compared to pristine PANI-ES as clear from TGA and DSC analysis. The highest DC electronic conductivity of nanocomposite prepared by core-shell route is found to be 5.12 S/cm using linear four probe techniques. In addition, the charge transport mechanism was understood with and without loading Cloisite 20A in PANI-ES. The conductivity data supported the temperature-dependence relationship σ(T) = σ0.exp[-To/T)1/4] and followed characteristic of three-dimensional variable-range hopping (3D‒VRH) mechanism. In addition, we were discussed the response of Nitrogen dioxide (NO2) gas with polyaniline based sensor materials.
{"title":"Cloisite 20A Based Polyaniline Nanocomposites for Nitrogen Dioxide (No2) Gas Sensors","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2123","DOIUrl":"https://doi.org/10.34256/ioriip2123","url":null,"abstract":"Compacted polyaniline (PANI)/Layered silicate nanocomposites have been successfully prepared by simple in situ, core-shell, and ex situ polymerization routes using AnHCl as a predecessor through chemical oxidation method. The structure, chemical groups, electronic transition and properties were investigated by XRD, SEM, HRTEM, UV Visible, DC electrical conductivity, TGA, and DSC. The XRD results reveals that HCl-treated Cloisite 20A, and PANI-ES/Cloisite 20A nanocomposites are delaminated. Flake-like morphologies were observed in Cloisite 20A and HCl-treated Cloisite 20A, whereas different rate of compacted fibrous morphologies of prepared PANI-ES/Cloisite 20A nanocomposites were observed as evident from SEM images. The Si-O FTIR band position does not change even after HCl treatment of Cloisite 20A, but different FTIR peaks positions of PANI-ES/Cloisite 20A nanocomposites were shifted from pure PANI-ES peaks after using Cloisite 20A nanoclays. UV-Visible spectra indicated the increment of charge carrier within the PANI-ES/Cloisite 20A nanocomposites compared to the pure one. The prepared nanohybrids showed significantly improved thermal property compared to pristine PANI-ES as clear from TGA and DSC analysis. The highest DC electronic conductivity of nanocomposite prepared by core-shell route is found to be 5.12 S/cm using linear four probe techniques. In addition, the charge transport mechanism was understood with and without loading Cloisite 20A in PANI-ES. The conductivity data supported the temperature-dependence relationship σ(T) = σ0.exp[-To/T)1/4] and followed characteristic of three-dimensional variable-range hopping (3D‒VRH) mechanism. In addition, we were discussed the response of Nitrogen dioxide (NO2) gas with polyaniline based sensor materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123051809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Polymer composites synthesized in the present work have been studied extensively. Polymer composites are investigated using sophisticated analytical tools. Electron microscopy was used to study the surface morphology by SEM/FESEM and dispersion of nanoparticles in the polymer matrix by HRTEM. The structural details, i.e., crystallite size, crystallinity, types of nano structure were studied by X-ray diffraction. H1-NMR, ESI-MS and FTIR have been used to elucidate chemical structure of synthesised monomers. The conformational variations in the polymeric materials have been studied using vibrational spectroscopy employing Fourier Transform Infrared (FTIR) spectroscopy. The UV-Visible absorption spectroscopy was used to study the optical properties of the monomers, and as-prepared polymeric samples. The DC conductivity measurement was carried out to study the electronic properties and charge transport mechanisms of the prepared polymeric samples. The gas sensing response was found by electrical measurement. Thermal study has been used to study the stability of prepared materials.
{"title":"Synthesis Methods of Polyaniline Based Composites","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2122","DOIUrl":"https://doi.org/10.34256/ioriip2122","url":null,"abstract":"Polymer composites synthesized in the present work have been studied extensively. Polymer composites are investigated using sophisticated analytical tools. Electron microscopy was used to study the surface morphology by SEM/FESEM and dispersion of nanoparticles in the polymer matrix by HRTEM. The structural details, i.e., crystallite size, crystallinity, types of nano structure were studied by X-ray diffraction. H1-NMR, ESI-MS and FTIR have been used to elucidate chemical structure of synthesised monomers. The conformational variations in the polymeric materials have been studied using vibrational spectroscopy employing Fourier Transform Infrared (FTIR) spectroscopy. The UV-Visible absorption spectroscopy was used to study the optical properties of the monomers, and as-prepared polymeric samples. The DC conductivity measurement was carried out to study the electronic properties and charge transport mechanisms of the prepared polymeric samples. The gas sensing response was found by electrical measurement. Thermal study has been used to study the stability of prepared materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133479150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Inorganic acids (HCl, H2SO4, and H3PO4) doped-PMMA/PANI composites are prepared by in-situ technique via oxidation-polymerization process. Different techniques such as XRD, FTIR, UV-Visible, four-probe method are used to characterize the composite. Presence of different chemical group of the doped composites is analysed by ATR-FTIR spectroscopic analysis. Charge carrier behaviour of the doped composite is analyzed by UV-Visible spectroscopy. Band gap (Eg) of the doped composites is determined from UV-Visible absorption analysis using Tauc expression. The estimated direct band gap energy (Eg) is found to be 1.93 eV (for HCl doped PMMA/PANI composite), 1.19 eV (for H2SO4 doped PMMA/PANI composite), and 1.71 eV (for H3PO4 doped PMMA/PANI composite), respectively. DC-conductivity is measured with and without magnetic field. Temperature dependent DC conductivity is also measured. In addition, we were discussed the response of ammonia (NH3) gas with polyaniline-based sensor materials.
采用原位氧化聚合法制备了无机酸(HCl、H2SO4和H3PO4)掺杂pmma /PANI复合材料。采用XRD、FTIR、uv -可见光、四探针等技术对复合材料进行表征。利用ATR-FTIR光谱分析了掺杂复合材料中不同化学基团的存在。用紫外可见光谱分析了掺杂复合材料的载流子行为。利用Tauc表达，通过紫外可见吸收分析确定了掺杂复合材料的带隙(Eg)。估计的直接带隙能(Eg)分别为1.93 eV (HCl掺杂PMMA/PANI复合材料)、1.19 eV (H2SO4掺杂PMMA/PANI复合材料)和1.71 eV (H3PO4掺杂PMMA/PANI复合材料)。直流电导率是在有和没有磁场的情况下测量的。还测量了与温度相关的直流电导率。此外，我们还讨论了氨(NH3)气体对聚苯胺基传感器材料的响应。
{"title":"Poly Methyl Methacrylate (Pmma) Based Polyaniline Composite for Ammonia (Nh3) Gas Sensors","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2126","DOIUrl":"https://doi.org/10.34256/ioriip2126","url":null,"abstract":"Inorganic acids (HCl, H2SO4, and H3PO4) doped-PMMA/PANI composites are prepared by in-situ technique via oxidation-polymerization process. Different techniques such as XRD, FTIR, UV-Visible, four-probe method are used to characterize the composite. Presence of different chemical group of the doped composites is analysed by ATR-FTIR spectroscopic analysis. Charge carrier behaviour of the doped composite is analyzed by UV-Visible spectroscopy. Band gap (Eg) of the doped composites is determined from UV-Visible absorption analysis using Tauc expression. The estimated direct band gap energy (Eg) is found to be 1.93 eV (for HCl doped PMMA/PANI composite), 1.19 eV (for H2SO4 doped PMMA/PANI composite), and 1.71 eV (for H3PO4 doped PMMA/PANI composite), respectively. DC-conductivity is measured with and without magnetic field. Temperature dependent DC conductivity is also measured. In addition, we were discussed the response of ammonia (NH3) gas with polyaniline-based sensor materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129620153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Polyaniline (PANI) nonofibriles have been successfully synthesised by simple chemical-oxidation polymerization method using aniline as a predecessor at room temperature. It was synthesized using H3PO4 dopants. The structure, chemical groups, and electronic transition were investigated by SEM, FTIR, and UV Visible. We present the methane gas response of as-prepared H3PO4 doped DL−PLA/PANI-ES composite film at different concentration. The percentage (%) methane gas response was found to be 9 % at 500ppm.
{"title":"Inorganic Doped Dl-Polylactide Polyaniline Based Composite for Methane (Ch4) Gas Sensing","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2127","DOIUrl":"https://doi.org/10.34256/ioriip2127","url":null,"abstract":"Polyaniline (PANI) nonofibriles have been successfully synthesised by simple chemical-oxidation polymerization method using aniline as a predecessor at room temperature. It was synthesized using H3PO4 dopants. The structure, chemical groups, and electronic transition were investigated by SEM, FTIR, and UV Visible. We present the methane gas response of as-prepared H3PO4 doped DL−PLA/PANI-ES composite film at different concentration. The percentage (%) methane gas response was found to be 9 % at 500ppm.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"37 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124977215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Different inorganic acids like HCl, HNO3, H2SO4 and H3PO4-doped based DL-PLA/PANI-ES composites were synthesized by in-situ chemical oxidation polymerization technique using liquid aniline as precursors. The doped composite have observed fibril-like morphology with different average sized diameter (178 nm for HCl doped composite, 162 nm (H2SO4 doped composite), 153 nm (H3PO4 doped composite) and 163 nm (HNO3 doped composite), respectively. Analysis of presence of functional groups and other chemical groups of as prepared composites was done by FTIR experiment in ATR mode. The optical (direct) band gap was estimated from UV-Visible absorption spectra. The estimated band gap values are to be 160 eV, 1.37 eV, 1.46 eV, and 1.69 eV for HCl, HNO3, H2SO4 and H3PO4-doped DL-PLA/PANI-ES composite, respectively. The electrical conduction mechanism of HCl-, H2SO4- and H3PO4-doped DL-PLA/PANI-ES composites were taken to study the conduction mechanism in detail in the low temperature regime (77-300 K) with and without applied of the magnetic field. Different models such as variable range hopping (VRH) and Arrhenius model were taken to explain the conduction mechanism of as prepared composites. In the Mott type VRH model, the density of states at the Fermi level, which is constant in the temperature range of 77-300 K were estimated. In the absence of magnetic field, DC conductivity of HCl-, H2SO4- and HNO3-, H3PO4- doped DL-PLA/PANI-ES composite was measured. Also, magnetoresistance (MR) was measured at room temperature for as prepared doped DL-PLA/PANI-ES composites and showed negative MR. In addition, we were discussed the response of hydrogen (H2) gas with polyaniline-based sensor materials.
{"title":"DL-Polylactide (DL-PLA) Based Polyaniline Composite for Hydrogen Gas Sensors","authors":"M. Panigrahi, B. Adhikari","doi":"10.34256/ioriip2125","DOIUrl":"https://doi.org/10.34256/ioriip2125","url":null,"abstract":"Different inorganic acids like HCl, HNO3, H2SO4 and H3PO4-doped based DL-PLA/PANI-ES composites were synthesized by in-situ chemical oxidation polymerization technique using liquid aniline as precursors. The doped composite have observed fibril-like morphology with different average sized diameter (178 nm for HCl doped composite, 162 nm (H2SO4 doped composite), 153 nm (H3PO4 doped composite) and 163 nm (HNO3 doped composite), respectively. Analysis of presence of functional groups and other chemical groups of as prepared composites was done by FTIR experiment in ATR mode. The optical (direct) band gap was estimated from UV-Visible absorption spectra. The estimated band gap values are to be 160 eV, 1.37 eV, 1.46 eV, and 1.69 eV for HCl, HNO3, H2SO4 and H3PO4-doped DL-PLA/PANI-ES composite, respectively. The electrical conduction mechanism of HCl-, H2SO4- and H3PO4-doped DL-PLA/PANI-ES composites were taken to study the conduction mechanism in detail in the low temperature regime (77-300 K) with and without applied of the magnetic field. Different models such as variable range hopping (VRH) and Arrhenius model were taken to explain the conduction mechanism of as prepared composites. In the Mott type VRH model, the density of states at the Fermi level, which is constant in the temperature range of 77-300 K were estimated. In the absence of magnetic field, DC conductivity of HCl-, H2SO4- and HNO3-, H3PO4- doped DL-PLA/PANI-ES composite was measured. Also, magnetoresistance (MR) was measured at room temperature for as prepared doped DL-PLA/PANI-ES composites and showed negative MR. In addition, we were discussed the response of hydrogen (H2) gas with polyaniline-based sensor materials.","PeriodicalId":368918,"journal":{"name":"Polyaniline based Composite for Gas Sensors","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132903840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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