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Degradation Pathways of Persistent Organic Pollutants (POPs) in the Environment 环境中持久性有机污染物的降解途径
Pub Date : 2019-04-10 DOI: 10.5772/INTECHOPEN.79645
James T. Zacharia
Persistent organic pollutants (POPs) are resistant to most of the known environmental degradation processes. Because of their persistence, POPs bioaccumulate in animal tissues and biomagnify along food chains and food webs with potential adverse impacts on human and wildlife health and the environment. Although POPs are resistant to most of the environmental degradation processes, there are some environmental processes mostly microbial degradation that can degrade POPs to other forms that are not necessarily simpler and less toxic. The Stockholm Convention on Persistent Organic Pollutants adopted in 2001 was meant to restrict the production and use of these toxic chemicals in the environment.
持久性有机污染物(POPs)对大多数已知的环境退化过程具有抗性。由于持久性,持久性有机污染物在动物组织中生物积累,并沿着食物链和食物网进行生物放大,对人类和野生动物的健康及环境产生潜在的不利影响。虽然持久性有机污染物对大多数环境降解过程具有抗性,但有些环境过程(主要是微生物降解)可以将持久性有机污染物降解为不一定更简单和毒性更小的其他形式。2001年通过的《关于持久性有机污染物的斯德哥尔摩公约》旨在限制这些有毒化学物质在环境中的生产和使用。
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引用次数: 25
Introductory Chapter: Persistent Organic Pollutants (POPs) 导论章:持久性有机污染物
Pub Date : 2019-01-11 DOI: 10.5772/INTECHOPEN.82465
S. K. Donyinah
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引用次数: 1
Dissemination of Endosulfan into the Environment 硫丹在环境中的扩散
Pub Date : 2018-12-18 DOI: 10.5772/INTECHOPEN.81094
Claudia Rosales Landeros, Carlos Eduardo Barrera Díaz, B. Bilyeu
Organochlorine pesticide pollution of surface water, groundwater, soil, sediments, and air has been recognized as a major problem in many countries because of the persistence in different environments and the consequent potential adverse health effects. This report presents a review of literature on organochlorine insecticide of endosulfan, which has been used extensively for agricultural purposes. It summarizes information on nomen - clature, physical-chemical properties, production, metabolism, degradation, distribution in the environment, toxicity, regulation, and technologies for the treatment of water and soil contaminated with this pesticide.
有机氯农药污染地表水、地下水、土壤、沉积物和空气已被认为是许多国家的一个主要问题,因为它在不同环境中持续存在,并可能对健康产生不利影响。本文综述了硫丹有机氯杀虫剂的相关文献,对其在农业上的广泛应用进行了综述。综述了该农药的命名、理化性质、生产、代谢、降解、环境分布、毒性、调控和处理技术等方面的研究进展。
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引用次数: 4
The Adaptation Mechanisms of Bacteria Applied in Bioremediation of Hydrophobic Toxic Environmental Pollutants: How Indigenous and Introduced Bacteria Can Respond to Persistent Organic Pollutants-Induced Stress? 细菌在疏水毒性环境污染物生物修复中的适应机制:本地和引进细菌如何应对持久性有机污染物诱导的应激?
Pub Date : 2018-11-05 DOI: 10.5772/INTECHOPEN.79646
Dercová Katarína, Murínová Slavomíra, Dudášová Hana, Lászlová Katarína, Horváthová Hana
The chapter describes the aspects of bioremediation that are related to survival and metabolism of bacterial degraders in the adverse environment contaminated with dangerous hydrophobic chemicals, polychlorinated biphenyls (PCBs). Successful environment decontamination requires bacterial strains that possess appropriate enzymes and are able to degrade particular contaminants. This chapter deals mainly with the adaptation mechanisms that allow bacteria to decrease toxic effects of the dangerous compounds on cytoplasmic membrane as the first contact point of pollutants and the bacterial cell. Many responses have been observed in bacteria that counteract the effects of toxic environmental organic pollutants: saturation-rigidification of cell membrane, cis/trans isomerization of fatty acids, increased content of cyclopropane fatty acids, and changes in branched fatty acids and cardiolipin, production of stress proteins, and elimination of toxic compounds using efflux pump. The study of these mechanisms is the first step in selection of appropriate resistant bacterial strains for bioremediation applications. Next steps should include study of degradation potential and efficacy of the most resistant strains. Setting up suitable experimental systems to examine the cell responses to toxic environmental organic pollutants in the adverse environment and optimal conditions for metabolism of bacterial degraders are important issues in the current bioremediation research agenda. © 2018 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
本章描述了与细菌降解剂在危险疏水化学品多氯联苯(PCBs)污染的不利环境中的生存和代谢有关的生物修复方面。成功的环境净化需要细菌菌株具有适当的酶,能够降解特定的污染物。这一章主要讨论了使细菌减少危险化合物对细胞质膜的毒性作用的适应机制,细胞质膜是污染物和细菌细胞的第一个接触点。在细菌中已经观察到许多对抗有毒环境有机污染物影响的反应:细胞膜的饱和硬化,脂肪酸的顺式/反式异构化,环丙烷脂肪酸含量的增加,支链脂肪酸和心磷脂的变化,应激蛋白的产生,以及使用外排泵消除有毒化合物。这些机制的研究是选择合适的耐药菌株进行生物修复应用的第一步。下一步应包括研究最耐药菌株的降解潜力和功效。建立合适的实验系统来研究细胞在不利环境下对有毒环境有机污染物的反应以及细菌降解物的最佳代谢条件是当前生物修复研究的重要课题。©2018作者。被许可方IntechOpen。本章是在知识共享署名许可(http://creativecommons.org/licenses/by/3.0)的条款下发布的,该许可允许在任何媒体上不受限制地使用、分发和复制,只要原始作品被适当引用。
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引用次数: 14
Lake Sedimentary Environments and Roles of Accumulating Organic Matter in Biogeochemical Cycling Processes and Contaminants Loading Are Invasions of Water Hyacinth in Lake Victoria from 1989 a Concern? 湖泊沉积环境及其有机质在生物地球化学循环过程和污染物负荷中的作用1989年以来维多利亚湖水葫芦入侵值得关注吗?
Pub Date : 2018-11-05 DOI: 10.5772/INTECHOPEN.79395
J. Mwamburi
Sediments accumulated in lake basins consist of various organic and inorganic materials, mostly utilized as proxies for climatic changes and as historical records of the lake con-nectivity to terrestrial ecosystems and anthropogenic activities. In-lake production, aerial wet and dry deposition and transported materials in running water are the main sources of lake deposits, which may be permanently deposited as bottom sediments or remobilized through erosive forces and turbulence, resuspension, tunneling by organisms, and porewater exchanges with the overlying water mass. Examination of the sediment biodiversity, quality, composition, and stratigraphy is part of the approaches in understanding ecological and climatic changes and other anthropogenic impacts in lakes. There are no detailed stud- ies on the spatial distribution of sediment characteristics within the Nyanza Gulf, especially after the establishment of water hyacinth. The first observations on the nature of the bottom of Lake Victoria were made during 1927–1928 survey, with subsequent detailed geochemical core studies concentrated in the main lake. Roles of sediment organic matter are explained, and data from surficial sediments collected, from about 32 sampling sites between 1994 and 2012, are used to characterize the sediments. Lastly, the potential influences from increased urbanization, eutrophication, presence of water hyacinth ( Eichhornia crassipes ), and associated floating macrophytes since 1989 and current cage aquaculture in L. Victoria are explored.
湖盆沉积物由多种有机和无机物质组成,主要作为气候变化的代用物,以及湖泊与陆地生态系统和人类活动连通性的历史记录。湖泊沉积物的主要来源是湖内生产、空中干湿沉积和流动水中的搬运物质,这些沉积物可能作为底部沉积物永久沉积,也可能通过侵蚀力和湍流、再悬浮、生物隧道作用以及与上覆水团的孔隙水交换而重新活化。沉积物的生物多样性、质量、组成和地层学的研究是理解湖泊生态和气候变化以及其他人为影响的方法的一部分。对尼扬扎湾泥沙特征的空间分布,特别是水葫芦建立后,还没有详细的研究。对维多利亚湖底性质的第一次观察是在1927-1928年的调查中进行的,随后详细的地球化学核心研究集中在主湖。分析了沉积物有机质的作用,并利用1994 - 2012年间32个采样点的表层沉积物数据对沉积物进行了表征。最后,探讨了1989年以来城市化、富营养化、水葫芦(Eichhornia crassipes)和相关浮游植物的存在以及目前维多利亚湖网箱养殖的潜在影响。
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引用次数: 5
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Persistent Organic Pollutants
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