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Langite from Mýtinka near Horní Halže in the Krušné hory Mts. (Czech Republic) 克拉斯内霍里山霍尔尼哈尔泽附近米廷卡的菱镁矿(捷克共和国)
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.09
Jakub Vácha, D. Všianský
Horní Halže – Mýtinka is a mineral occurrence located near Mýtinka in the Krušné hory Mts. In the past, the area was intensively mined for iron (namely hematite in quartz veins). Quartz veins are located on complicated intersections of fault systems in mica schists and migmatites (Urban – Crkal 2021). Recently, Sejkora et al. (2021) described rich Cu mineralization found in the remains of old mine dumps. Sulfide mineralization is represented by pyrite, djurleite, roxbyite, anilite, spionkopite, bornite and covellite, supergene phases by malachite, brochantite, liebethenite and pseudomalachite. The studied material (thin blue coating on a part of a single sulfide grain 3 mm in size; Fig. 1) was found by the first author in 2021 at the old mine dump and matches the material described by Sejkora et al. (2021). The blue phase was identified as langite [Cu4(SO4)(OH)6 · 2H2O] using combination of EDS, Raman and pXRD. Chemical composition of examined mineral coating was analyzed using EDS, which detected presence of Cu, S and O contents only (with Cu significantly higher than S). Raman spectrum of langite from Mýtinka (Fig. 2, Tab. 1) was acquired using a HORIBA LabRam spectrometer and the data were processed using Systat PeakFit software. Proposed spectrum model is in very good agreement with empirical data (r2 = 0.992). Assignment of individual bands according to Martens et al. (2002, 2003) is proposed in Table 1. Raman spectrum of langite is similar to those of posnjakite [Cu4(SO4)(OH)6 · H2O] and wroewolfeite [Cu4(SO4)(OH)6 · H2O]. By combining (poorly and only partially presented) data of Frost et al. (2004) and Martens et al. (2002), following differences among these phases were identified. Bands at 155 and 258 (262 in this work) cm–1 are present in the Raman spectrum of langite but missing in that of posnjakite. The Raman spectrum of wroewolfeite is devoid of bands at 507 and 596 (500 and 598 in this work) cm–1, characteristic of langite, and at 511 and 596 cm–1, characteristic of posnjakite. About 15 fragments of the coating, 20–100 µm in size, were analyzed on Panalytical X’Pert powder XRD diffractometer. Only four diffraction maxima were obtained due to a very small amount of material available. Nevertheless, corresponding d-values are in a good agreement with data for langite (Tab. 2; Galy et al. 1984).
Horní Halže - Mýtinka是位于Krušné hory山Mýtinka附近的一个矿点。 过去,该地区曾大量开采铁矿(即石英脉中的赤铁矿)。石英脉位于云母片岩和岩浆岩断层系统的复杂交汇处(Urban - Crkal,2021 年)。最近,Sejkora 等人(2021 年)描述了在旧矿场遗迹中发现的丰富的铜矿化。硫化物矿化物的代表矿物有黄铁矿、黝帘石、萝斯比岩、黝帘石、榍石、波长石和珂罗石,超生相有孔雀石、锦长石、锂辉石和假孔雀石。所研究的材料(3 毫米大小的单个硫化物晶粒部分上的薄蓝色涂层;图 1)是第一作者于 2021 年在旧矿场发现的,与 Sejkora 等人(2021 年)描述的材料相吻合。通过结合使用 EDS、拉曼和 pXRD,蓝色相被鉴定为兰格石[Cu4(SO4)(OH)6 - 2H2O]。使用 EDS 分析了受检矿物涂层的化学成分,只检测到了铜、S 和 O 的含量(其中铜的含量明显高于 S)。使用 HORIBA LabRam 光谱仪采集了来自 Mýtinka 的兰光石的拉曼光谱(图 2,表 1),并使用 Systat PeakFit 软件对数据进行了处理。提出的光谱模型与经验数据非常吻合(r2 = 0.992)。表 1 列出了根据 Martens 等人(2002 年,2003 年)对各个波段进行的分配。兰格岩的拉曼光谱与 posnjakite [Cu4(SO4)(OH)6 - H2O] 和 wroewolfeite [Cu4(SO4)(OH)6 - H2O] 的拉曼光谱相似。通过综合 Frost 等人(2004 年)和 Martens 等人(2002 年)的数据(数据不全,仅部分呈现),确定了这些物相之间的以下差异。兰格岩的拉曼光谱中存在 155 和 258(本研究中为 262)cm-1 波段,而正长岩的拉曼光谱中却没有这两个波段。钨辉石的拉曼光谱中没有兰格岩特有的 507 和 596(本文中为 500 和 598)cm-1 波段,也没有正长岩特有的 511 和 596 cm-1 波段。在 Panalytical X'Pert 粉末 XRD 衍射仪上分析了约 15 块 20-100 微米大小的涂层碎片。由于材料数量很少,只获得了四个衍射最大值。不过,相应的 d 值与白云石的数据非常吻合(表 2;Galy 等人,1984 年)。
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引用次数: 0
Hydraulic parameters of Submenilite Formation of Ždánice Unit 日丹尼采单元亚芒硝岩层的水力参数
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.13
Ondřej Janíček, Tomáš Kuchovský
This study aims to re-asses hydrodynamic tests of the Submenilite Unit of the Outer Carpathian Flysch Zone sediments, exposed at Přítlucká hora located near Rakvice village in South Moravian region, Czech Republic. We focused on four shallow, 6.0–7.6 m deep hydrogeological wells, drilled by Aqua Enviro s. r. o. company in 2005. The purpose of the drilling was a feasibility study for drainage of western part of Rakvice village. The sediments of the Submenilite Formation of the Ždánice unit that were drilled are dominated by compressed clays, claystones and siltstones, containing thin layers of sand and weathered sandstones. For the purpose of determining hydraulic parameters of underlying aquifer, the company conducted pumping and recovery tests on each of the wells. In this work, we used Jacob’s semilogarithmic method to interpret the measured groundwater level data. Hydraulic conductivity and transmissivity parameters were consequently calculated. The resulting transmissivity values range from 1.6 × 10–2 m2/d to 3.7 × 10–1 m2 /d and hydraulic conductivity value ranges from 3.6 × 10–3 m/d to 1.0 × 10–1 m/d. The calculated index of transmissivity Y corresponds to 4.32–4.57 and index of conductivity Z ranges between 5.80 and 6.27. The values of index of transmissivity Y from this study are generally comparable with results presented by previous authors and demonstrate very low transmissivity of the rocks of this unit mostly built by non-permeable pelitic rocks.
本研究旨在重新评估出露于捷克共和国南摩拉维亚地区拉克维采村附近的 Přítlucká hora 的外喀尔巴阡山飞地带沉积物亚微粒岩单元的水动力测试。我们重点考察了 Aqua Enviro s. r. o. 公司于 2005 年钻探的四口 6.0-7.6 米深的浅层水文地质井。钻井的目的是对 Rakvice 村西部排水系统进行可行性研究。所钻探的Ždánice单元亚芒硝层沉积物主要是压缩粘土、粘土岩和粉砂岩,其中包含薄层砂和风化砂岩。为了确定下层含水层的水力参数,公司对每口井都进行了抽水和回采试验。在这项工作中,我们采用雅各布半对数法来解释测得的地下水位数据。由此计算出水力传导性和渗透性参数。得出的渗透率值范围为 1.6 × 10-2 m2/d 至 3.7 × 10-1 m2 /d,水力传导率值范围为 3.6 × 10-3 m/d 至 1.0 × 10-1 m/d。计算得出的渗透率指数 Y 介于 4.32-4.57 之间,导流指数 Z 介于 5.80-6.27 之间。这项研究得出的透射率指数 Y 值与前人的研究结果基本相当,表明该单元的岩石透射率非常低,主要由非渗透性的辉绿岩构成。
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引用次数: 0
New occurrences of Paseky Shale near Podlesí NW of Příbram and microfossils from the Nové Podlesí locality (Cambrian, Holšiny-Hořice Formation, Příbram-Jince Basin) 普日布兰西北部 Podlesí 附近 Paseky 页岩的新发现以及来自 Nové Podlesí 地带的微化石(寒武纪,霍尔辛-霍日兹地层,普日布兰-金斯盆地)
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.10
T. Vorel, Vojtěch Kovář
Previously unrecorded occurrences of the Paseky Shale were found in the course of geological mapping at three localities NW of Příbram near Podlesí (Fig. 1). This shale makes a part of the Cambrian Series 2, Holšiny-Hořice Formation in the Příbram-Jince Basin. The shale was documented ca. 250 m S and about 80 m NE of the Malá Dubová hora summit as abundant loose rock fragments (Fig. 2) and soil skeleton (Fig. 3), respectively. An outcrop of the Paseky Shale was found in a small quarry near Nové Podlesí (Figs 4 to 9). The Paseky Shale has a significant position within the geological record of the Barrandian area as it hosts the oldest macrofossil fauna in the Czech Republic, most notably the aglaspid-like arthropod Kodymirus vagans Chlupáč & Havlíček 1965 (Chlupáč – Havlíček 1965, Lamsdell et al. 2013). A microfossil analyses of samples from the quarry near Nové Podlesí has been carried out. The microfossils are relatively sparse and generally rather poorly preserved. The assemblage consists mostly of filaments belonging to the genus Siphonophycus Schopf 1968, emend. Knoll et al. 1991 (Fig. 10 A, D, E, F) ranging from ca. 8 to 50 µm in width. Less common are representatives of Leiosphaeridia minutissima Naumova 1949, emend. Jankauskas in Jankauskas et al. 1989 (Fig. 10 B, C). No other acritarchs were found. Residues further include poorly identifiable fragments of organic-walled microfossils, most likely representing degraded filaments (Fig. 10 G). The studied assemblage is consistent with findings from other localities of the Paseky Shale. However, further relatively rarer components of the microfossil assemblages known from other localities (see Fatka – Konzalová 1995, Kovář – Fatka 2023) are missing. This is most likely due to the low abundance and generally poor preservation of the microfossils at the locality. The general absence of a more diversified acritarch assemblage corresponds to an atypical, restricted marine environment, presumably represented by a lagoonal setting (see Fatka – Konzalová 1995).
在绘制地质图的过程中,在普日布兰西北部靠近波德莱西的三个地方发现了以前从未记录过的帕塞基页岩(图 1)。该页岩是普日布兰-金斯盆地寒武系 2 霍尔辛-霍热冰地层的一部分。在马拉杜波瓦山顶南面约 250 米和东北面约 80 米处发现的页岩分别为大量松散的岩石碎片(图 2)和土壤骨架(图 3)。在 Nové Podlesí 附近的一个小采石场发现了 Paseky 页岩的露头(图 4 至图 9)。Paseky 页岩在巴兰迪地区的地质记录中占有重要地位,因为它拥有捷克共和国最古老的大型化石动物群,其中最著名的是鳞翅目节肢动物 Kodymirus vagans Chlupáč & Havlíček 1965(Chlupáč - Havlíček 1965,Lamsdell 等人,2013 年)。对新波得莱西附近采石场的样本进行了微化石分析。微化石的数量相对稀少,保存状况一般也比较差。采集的微化石主要是属于 Siphonophycus Schopf 1968,emend.Knoll 等人,1991 年(图 10 A、D、E、F),宽度从约 8 微米到 50 微米不等。较少见的是 Leiosphaeridia minutissima Naumova 1949,emend.在 Jankauskas 等人 1989 年的 Jankauskas 中发现(图 10 B、C)。没有发现其他刺毛虫。残留物还包括难以辨认的有机壁微小化石碎片,很可能是降解的细丝(图 10 G)。所研究的组合与帕塞基页岩其他地方的发现一致。然而,其他地方已知的微化石组合(见 Fatka - Konzalová 1995 年,Kovář - Fatka 2023 年)中相对罕见的成分却不见了。这很可能是由于该地点的微化石数量较少且保存状况普遍较差。普遍缺乏更多样化的棘皮动物群,这与非典型的、受限的海洋环境相吻合,可能是泻湖环境(见 Fatka - Konzalová 1995 年)。
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引用次数: 0
Indications of volcanic style of the Silurian Nová Ves Volcano (Hemrovy Rocks) 新维斯火山(海姆罗维岩)志留纪火山风格的迹象
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.12
M. Stárková, Š. Mrázová, Stanislava Vodrážková
Studied locality of Hemrovy Rocks belongs to Nová Ves Volcanic Center, one of the Silurian volcanic centers of Prague Basin of Teplá-Barrandien area (lower Wenlock – lower Ludlow age). The aim of this work is to describe details of the volcanic rock structures and to contribute to the interpretation of the Silurian volcanic style. The macroscopic and microscopic structures of basaltic rocks in and close to the abandoned Kační Quarry in the southern part of Prague and at the adjacent locality – ridge of Hemrovy Rocks were studied. At these sites, volcaniclastics dominate over solid volcanic rocks and sediments. The volcanic rocks are represented by basalts, which form thin lava flows overlying both the volcaniclastics and sedimentary rocks. Massive fine-grained basalts pass to pillow lava facies, autobreccia or hyaloclastite breccia in-situ. These brecciated structures evolve into peperites or to unconsolidated volcaniclastic rocks of a previous eruption. Coarse-grained volcaniclastics with oversized subrounded to angular clasts of vesiculated lava or sediments within glassy matrix, sporadically with sediment admixture, are unsorted and thick-bedded. They were probably formed by gravity-driven mass flow. Basalt in the Kační Quarry probably represents a synvolcanic intrusion, as documented by its hyaloclastite rim and presence of clusters of resedimented volcaniclastics in the adjacent fine-grained sediments. Matrix of the volcaniclastics is mostly unsorted, formed mostly by quenched fragments of altered palagonitized and chloritized basaltic glass, locally scoriaceous, and fragments of chilled basaltic lava. Originally highly porous volcaniclastics, resp. hyaloclastites were secondarily cemented by calcite and silica. Secondary chlorite, calcite and silica also fill vesicles and cavities in fragments of glass and lava clasts. Dense vesicularity of lava fragments in volcaniclastics indicates an effective explosive interaction of lava with water. It is probable that much of the wet volcaniclastic material repeatedly slumped back down into the volcano’s crater to be re-ejected by subsequent phreato-magmatic explosions. Hydroclastic fragmentation was iniciated by repeated subaquatic eruptions in shallow subphotic marine zone. Unsorted crinoidal packstones mostly with trilobites, trepostomate bryozoan and volcaniclastic matrix were deposited in the vicinity of the Nová Ves Volcanic Center.
Hemrovy Rocks 的研究地点属于 Nová Ves 火山中心,是 Teplá-Barrandien 地区布拉格盆地志留纪火山中心之一(下温洛克-下鲁德洛时代)。这项工作的目的是描述火山岩结构的细节,并为解释志留纪火山风格做出贡献。研究了布拉格南部废弃的 Kační 采石场及其附近以及邻近地点--Hemrovy 岩石山脊的玄武岩的宏观和微观结构。在这些地点,火山碎屑岩比固体火山岩和沉积物占优势。火山岩以玄武岩为代表,玄武岩形成薄薄的熔岩流,覆盖在火山碎屑岩和沉积岩之上。大量细粒玄武岩在原地形成枕状熔岩面、自生角砾岩或透明角砾岩。这些角砾岩结构演变成花岗岩或以前喷发的未固结火山碎屑岩。粗粒火山碎屑岩的玻璃状基质中含有过大的近圆形至角形疱状熔岩或沉积物碎屑,零星夹杂着沉积物,是未经分选的厚层火山碎屑岩。它们很可能是由重力驱动的大规模流动形成的。卡钦尼采石场的玄武岩可能是同步火山侵入体,其透明闪长岩边缘以及邻近细粒沉积物中存在的再沉积火山碎屑岩群证明了这一点。火山碎屑岩的基质大多是未分类的,主要由淬火的蚀变褐铁矿化和绿铁矿化玄武岩玻璃碎片(局部为蝎尾状)和冷玄武岩熔岩碎片形成。火山碎屑岩原本是高孔隙率的火山碎屑岩,其次由方解石和二氧化硅胶结。次生绿泥石、方解石和二氧化硅也填充了玻璃碎片和熔岩碎块中的囊泡和空腔。火山塑料中熔岩碎块的致密泡状结构表明熔岩与水发生了有效的爆炸作用。许多潮湿的火山碎屑材料很可能反复滑落回火山口,在随后的喷气-岩浆爆炸中再次喷出。水成碎屑是由浅海次生海洋区的多次水下喷发引起的。在新维斯火山中心附近沉积了未经分类的碎屑岩包石,其中大部分都带有三叶虫、三齿贝类和火山碎屑基质。
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引用次数: 0
Supergene mineral assemblage from sediments affected by contact and hydrothermal metamorphism, locality Dobrá – Staré Město near Frýdek-Místek (Czech Republic) 捷克共和国 Frýdek-Místek 附近 Dobrá - Staré Město 地段受接触变质和热液变质影响的沉积物中的超生矿物组合
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.11
D. Matýsek, J. Jirásek
At locality Dobrá – Staré Město, series of outcrops occur on both banks of the Morávka River. The river cuts through the sediments on the tectonic contact between the Silesian and Subsilesian units of the Outer Western Carpathians. Clayey facies of the Hradiště Formation (Early Cretaceous, Valanginian to Aptian) contains numerous tectonic fragments reaching hundreds meters in size of strongly altered (carbonatized, smectitized) subaquatic volcanic rocks of the Teschenite Association. These volcanic rocks are dominated by fine-grained to aphanitic rocks, possibly of both effusive and intrusive origin. The host sediments affected by the contact metamorphism (contact adinole) also occur. Framboidal pyrite is abundant in majority of sediments of the studied area, giving rise to efflorescences of gypsum, baryte, celestine, and a mineral of alunite group (Figure 1). A more varied assemblage of supergene minerals was recognized on a small rock outcrop at GPS coordinates N 49° 39.992’ E 018° 23.810’ (Figure 2), where it developed relatively recently after the big floods in 2010 that washed away the previous mineralization. During the first years, only gypsum crusts were detectable, while in 2023, we recognized 4 macroscopic and 5 microscopic minerals forming thin botryoidal crusts. These crusts show faint zoning, with gooey, gel-like X-ray amorphous material in the humid upper part , middle zone with abundant fibroferrite and the lower part dominated by gypsum. Gypsum forms well-developed, but frequently corroded crystals with various habitus (Figure 4A, B). Fibroferrite is present as fibrous aggregates with individual crystals of up to ca. 100–150 µm long and <1 µm thick (Figure 4C). It forms directly from the gel-like substance (Figure 4D). Rhombohedral crystals and rossete aggregates of hydroniumjarosite vary from 2 µm to 5 µm in size (Figure 4E), but the most common are dust-like coatings on rock fissures with particle size <1 µm. Rusty coatings of schwertmannite (Figure 4F), in some places accompanied by gypsum, with Fe/S at. % ratios near 4–5 are common. In some cases, the Al/Fe at. % ratio exceed 1, which might indicate presence of yet undescribed Al-analogue of schwertmannite, ill-defined alumogel, or an amorphous precursor of aluminite. Presence of ferrihydrite is possible but not confirmed. The above-mentioned Fe-rich phases are frequently accompanied by diplobacilli-shaped bacteria (Figure 4F). Slavíkite, pickeringite-halotrichite, alunogen, copiapite group mineral, hexahydrite, and melanterite (Figure 5) were also recognized by EDS and PXRD. Slavíkite and copiapite group minerals seem to be alteration products of fibroferrite. Unit-cell parameters refined from the X-ray powder diffraction are presented for all recognized phases (Table 1). Surprisingly, secondary sulfates are present on the metasediments with abundant calcite (Figure 3), which should serve as a neutralization buffer. The reason is the restricted amount of calcite available on
在 Dobrá - Staré Město 地段,莫拉夫卡河两岸有一系列露头。莫拉夫卡河穿过外西喀尔巴阡山脉西里西亚单元和次西里西亚单元构造接触处的沉积物。赫拉迪什特地层(早白垩世,瓦朗基年至古生代)的粘土层包含大量构造碎片,大小可达数百米,这些碎片为强烈蚀变(碳酸盐化、蜕变)的特申岩协会亚水生火山岩。这些火山岩以细粒至闪长岩为主,可能源于喷出岩,也可能源于侵入岩。受接触变质作用影响的主沉积物(接触沉积物)也有出现。在研究区域的大部分沉积物中,黄铁矿含量丰富,并伴生石膏、重晶石、天青石和一种矾土类矿物(图 1)。在 GPS 坐标 N 49° 39.992' E 018°23.810'(图 2)处的一小块岩石露头上,发现了更为多样的超生矿物组合,这些超生矿物是在 2010 年的大洪水冲走了之前的矿化物之后最近才形成的。在最初几年,只能检测到石膏结壳,而到了 2023 年,我们发现有 4 种宏观矿物和 5 种微观矿物形成了薄薄的植物结壳。这些结壳显示出微弱的分区,上部潮湿,呈凝胶状 X 射线无定形物质,中部有丰富的纤维铁矿,下部以石膏为主。石膏形成发育良好但经常被腐蚀的晶体,具有不同的形态(图 4A、B)。铁素体呈纤维状聚集,单个晶体长约 100-150 微米,厚小于 1 微米(图 4C)。它直接从凝胶状物质中形成(图 4D)。氢化箭石的斜方晶体和锈状聚集体大小从 2 微米到 5 微米不等(图 4E),但最常见的是岩石裂缝上的粉尘状涂层,粒径小于 1 微米。生锈的石英包层(图 4F),有些地方还伴有石膏,Fe/S at.%的比例接近 4-5 是常见现象。在某些情况下,Al/Fe at.%的比率超过 1,这可能表明存在尚未描述的锡华特曼石的铝类似物、不明确的铝凝胶或铝石的无定形前体。可能存在铁水云母,但尚未得到证实。上述富铁相经常伴有二裂杆菌(图 4F)。此外,还通过 EDS 和 PXRD 发现了 Slavíkite、pickeringite-halotrichite、alunogen、copiapite 族矿物、六水铁矿和黑云母(图 5)。Slavíkite 和 copiapite 族矿物似乎是纤维铁氧体的蚀变产物。表 1 列出了根据 X 射线粉末衍射提炼出的所有已识别物相的单胞参数。令人惊讶的是,在方解石含量丰富的基岩上出现了次生硫酸盐(图 3),而方解石应该起到中和缓冲作用。原因是岩石裂隙表面的方解石数量有限,新形成的石膏阻挡了部分水的渗透。由于 Na 离子在超生相中的含量并不高,因此接触金卤石(图 3)中的白云石不受酸性岩排水的影响。由于仍有足够的未变质黄铁矿,我们预计未来的矿物组合将趋于稳定。数量有限的次生硫酸盐不会对环境造成任何重大危害。
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引用次数: 0
Topaz quartzolite (greisen) in North Bohemia – potential source of the natural abrasive 北波希米亚的黄玉石英岩(greisen)--天然磨料的潜在来源
Q4 Earth and Planetary Sciences Pub Date : 2024-01-22 DOI: 10.3140/zpravy.geol.2023.14
Petr Martinec, Petr Hlaváček, L. Sitek, J. Foldyna, J. Klomínský, František Veselovský, Ferry Fediuk
Topazolite (greisen) is a rock formed essential by quartz and topaz, with accessory white mica, tourmaline, sulphides (molybdenite and arsenopyrite), wolframite and cassiterite. This rock was found in the Krkonoše and Jizera Mountains in the western Sudetes. In Poland, this metasomatic rock occurs at the contact between leucogranite and mica schist (associated with hydrothermal kaolinization) in a narrow zone between the settlements of Rebiszow and Gierałtówek. On Czech territory, similar topaz quartzolite (greisen rock), consisting of up to 65 % quartz and 32 % topaz, was found near the settlements of Růžek and Vítkov near Chrastava in association with orthogneiss. The high content of topaz in this rock offers the possibility of using it as an abrasive in high-speed abrasive water jet technology for cutting and surface treatment of hard metallic and non-metallic materials. In the crushed form, after being concentrated in a treatment plant, topaz could be a natural abrasive with a wide range of applications. However, the results of technological testing of the physical and mineralogical characteristics of the topaz concentrate indicate its unfavorable properties caused by the high fissility of topaz. This leads to losses of topaz during its technological adjustment to the required grain size or during recycling. It has been shown that abrasive concentrates with topaz content above 90 % are promising, especially for special applications of abrasive water jet technology. Mastering the technology for processing of the source raw material, i.e. topaz quartzolite, into a topaz-rich concentrate, and subsequent applied research on the use of topaz abrasives in industry are crucial.
黄玉岩(greisen)是一种主要由石英和黄玉以及白云母、电气石、硫化物(辉钼矿和砷黄铁矿)、黑钨矿和锡石形成的岩石。这种岩石发现于苏台德西部的克尔科诺谢山和吉泽拉山。在波兰,这种变质岩出现在白云岩和云母片岩(与热液高岭土化有关)之间的接触面上,位于雷比肖夫和吉拉乌托韦克定居点之间的狭窄地带。在捷克境内,类似的黄玉石英橄榄岩(灰岩)在 Růžek 和 Chrastava 附近的 Vítkov 居民点附近被发现,其中石英含量高达 65%,黄玉含量为 32%,与正长片麻岩伴生。这种岩石中黄玉的含量很高,可将其用作高速磨料水射流技术中的磨料,用于切割和表面处理坚硬的金属和非金属材料。黄玉在处理厂浓缩后的破碎状态下,可以成为一种用途广泛的天然磨料。然而,对黄玉精矿的物理和矿物学特性进行的技术测试结果表明,黄玉的高易碎性导致了黄玉精矿的不利特性。这导致黄玉在技术调整到所需粒度或回收过程中出现损失。研究表明,黄玉含量超过 90% 的磨料精矿很有前途,特别是在水喷射磨料技术的特殊应用中。掌握将原材料(即黄玉石英岩)加工成富含黄玉的精矿的技术,以及随后在工业中使用黄玉磨料的应用研究至关重要。
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引用次数: 0
Mineralogy of sulfide ores from the Měděná Adit in the Zlaté Hory Ore District zlat<s:1>霍里矿区mvd n<e:1>坑道硫化物矿石矿物学研究
Q4 Earth and Planetary Sciences Pub Date : 2023-05-09 DOI: 10.3140/zpravy.geol.2023.07
Stanislav Staněk, Jiří Zimák
Until 1993, sulfide ores of copper, lead and zinc, as well as native gold were mined in the Zlaté Hory ore district in the Jeseníky Mountains. These deposits occur in the Devonian volcano-sedimentary complex of the Vrbno Group, which consists of quartzites, phyllites, limestones and metamorphic igneous rocks of intrusive and extrusive nature. The main ore bodies are located in a quartzite horizon containing lenses of felsic metavolcanic rocks or in the underlying and overlying rocks (mainly phyllites). Sulfide mineralization of the Měděná Adit in the Zlaté Hory ore district concentrated in greenschists containing three mineral assembblages: i) chlorite + quartz + albite + barian feldspar + siderite + dolomite (ankerite) ± ilmenite, ii) chlorite + phlogopite + quartz + albite + siderite + dolomite (ankerite) ± magnetite ± ilmenite, iii) chlorite + muscovite + quartz + albite + ilmenite ± siderite ± magnetite. Micas have elevated barium contents (2.2 to 5.5 wt. % BaO in phlogopite, 2.6 to 4.6 wt. % BaO in muscovite) and represent the dominant carrier of this element in the rock. In the case that mica is absent in the rock, barium is bound in barian feldspar. When content of quartz in these greenschists is high, they pass into quartzite. Three types of sulfide ore were found in the Měděná Adit: A) banded copper ore in biotite-chlorite greenschist, which is formed dominantly by disseminated pyrite and pyrrhotite, accompanied by a small amount of chalcopyrite (the ore contains approx. 0.7 wt.% Cu), B) disseminated copper mineralization in quartz-rich bands or quartzite intercalations in chlorite greenschist, consisting mainly of pyrrhotite, less voluminous pyrite, and small amounts of chalcopyrite and galena (the ore contains approx. 0.3 wt.% Cu, the lead content is highly variable, up to 0.15 wt.% Pb), C) vein-like copper ore in greenschist with chalcopyrite dominating over pyrrhotite and pyrite (the ore has a very high copper content, 13.6 and 24.7 wt.% Cu in two analyzed samples). With its mineral composition, structural features and the character of the ore-bearing rocks, disseminated copper mineralization is similar to the Cyprus-type ores (so-called Cu-pyrite ores). The vein copper mineralization is probably a result of copper remobilization during regional metamorphism.
直到1993年,在Jeseníky山脉的zlat Hory矿区开采了铜、铅和锌的硫化物矿石以及天然金矿。这些矿床产于Vrbno群泥盆系火山-沉积杂岩中,该杂岩由石英岩、千层岩、灰岩和变质火成岩组成,具有侵入和挤压性质。主要矿体位于含长英质变质火山岩透镜体的石英岩层或下伏和上覆岩石(主要为千层岩)中。zlat Hory矿区m d nadit硫化物成矿以绿片岩为主,含3种矿物组合:i)绿泥石+石英+钠长石+钡长石+菱铁矿+白云石(铁白云石)±钛铁矿;ii)绿泥石+云母+石英+钠长石+菱铁矿+白云石(铁白云石)±磁铁矿±钛铁矿;iii)绿泥石+白云石+石英+钠长石+钛铁矿±菱铁矿±磁铁矿。云母的钡含量较高(云母中钡含量为2.2 ~ 5.5 wt. %,白云母中钡含量为2.6 ~ 4.6 wt. %),是岩石中钡元素的主要载体。在岩石中没有云母的情况下,钡被束缚在钡长石中。当绿片岩中石英含量高时,绿片岩就进入石英岩。在马德恩 Adit中发现了3种类型的硫化矿石:A)黑云母-绿泥石绿片岩中的带状铜矿,主要由浸染状黄铁矿和磁黄铁矿组成,并伴有少量黄铜矿(矿石约含黄铜矿)。0.7 wt.% Cu), B)浸染铜矿化在绿泥石绿片岩中富石英带或石英岩插层中,主要由磁黄铁矿、少量黄铁矿和少量黄铜矿、方铅矿组成(矿石含铜量约为0.07 wt.%)。铜含量为0.3 wt.%,铅含量变化很大,可达0.15 wt.% Pb), C)绿片岩中的脉状铜矿,黄铜矿占主导地位,磁黄铁矿和黄铁矿占主导地位(矿石铜含量非常高,两个分析样品中铜含量分别为13.6和24.7 wt.%)。浸染铜矿的矿物组成、构造特征和含矿岩特征与塞浦路斯型铜矿(即铜黄铁矿)相似。脉状铜矿化可能是区域变质作用中铜再活化的结果。
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引用次数: 0
Lower and Middle Miocene sediments southwest of Brno in the light of new findings 根据新发现,布尔诺西南中新世下和中沉积物
Q4 Earth and Planetary Sciences Pub Date : 2023-05-09 DOI: 10.3140/zpravy.geol.2023.08
Oldřich Krejčí
New knowledge on the occurrence of Lower and Middle Miocene sediments in the southwestern surroundings of Brno has been acquired through geological mapping and documentation work during the recent years. Specific work was focused on: • preparation of the publication on the local national history of the cadastral territory of the village of Bohutice; • salvage study of the former reserved bentonite deposit Ivančice – Réna, which is being gradually remediated and turned into a recreational area; • the area in the foreground of the New Ivančice viaduct, which is susceptible to long-term slope instability; • the western edge of the village of Němčičky near Židlochovice, where extensive construction of family houses is underway; • the area between the municipalities of Moravany, Nebovidy and Ostopovice, where the excavations for new extra-high voltage pylons were documented. The detailed mapping, petrographic and biostratigraphic studies allowed to refine the distribution, lithological characteristics and age of Miocene sediments; specifically, a more extensive occurrence of Lower Miocene sediments compared to previous findings was confirmed (localities Ostopovice, Moravské Bránice – locality 5). These findings support earlier results from the area N of the City of Brno, where the known extent of Ottnangian sediments was expanded at the expense of Badenian sediments. The documentation and sampling of the new excavations (for family houses and extra-high voltage pylons) and old mining pits enabled the description and further study of the sediments. The acquired litho- and biostratigraphic data were correlated with engineering geological findings. In a construction pit in Bohutice, a completely new occurrence of tuffitic sediments of the Ottnangian age was discovered and geochemically verified. Furthermore, the Ottnangian gravels in Němčičky were newly discovered. These contain a large proportion of granitoid pebbles probably derived from the Brno Massif. It was found that the weakly consolidated lithologically variable Lower Miocene sediments are prone to landslides. In the case of the New Ivančice viaduct, extensive suffusion doline were identified, resulting from the ingress of rainwater from the wider area of the railway embankment foreground. Biostratigraphy of the sediments was based on micropaleontological analysis of foraminiferas. Ottnangian sediments were usually fossil- free and/or they contained reworked Cretaceous foraminiferas. Lower Badenian sediments are characterized by occurrence of abundant and diversified fauna represented by foraminifera species such as Martinotiella karreri (Cush.), Globigerinoides bisphericus Todd, Vaginulina legumen (L.), etc.
通过近年来的地质填图和文献工作,对布尔诺西南地区中新统下、中沉积的产状有了新的认识。具体工作的重点是:•编写关于Bohutice村地籍领土的地方民族历史的出版物;•对前保留的膨润土矿床ivan ice - r纳进行打捞性研究,该矿床正在逐步修复并变成一个休闲区;•新伊万冰高架桥的前景区域,容易受到长期边坡不稳定的影响;•位于Židlochovice附近的n基村的西部边缘,正在大量建造家庭住宅;•莫拉瓦尼、内博维季和奥斯托维茨市之间的地区,在那里有新的特高压塔的挖掘记录。详细的测绘、岩石学和生物地层学研究使中新世沉积物的分布、岩性特征和年龄得以细化;具体来说,与之前的发现相比,下中新世沉积物的分布范围更广(地点Ostopovice, moravsk Bránice -地点5)。这些发现支持了布尔诺市N地区的早期结果,在那里,已知的Ottnangian沉积物范围以巴登尼亚沉积物为代价扩大了。对新挖掘(用于家庭住宅和超高压塔)和旧矿坑的记录和采样使描述和进一步研究沉积物成为可能。获得的岩性和生物地层资料与工程地质发现相吻合。在Bohutice的一个建筑坑中,发现了一种全新的Ottnangian时代的凝灰岩沉积物,并进行了地球化学验证。此外,在肯塔基州新发现了n的Ottnangian砾石。这些岩石含有大量花岗岩类鹅卵石,可能来自布尔诺地块。研究发现,下中新世弱固结岩性变化较大的沉积物易发生滑坡。在新伊万冰高架桥的案例中,由于铁路路堤前景更广阔区域的雨水进入,确定了广泛的漫溢线。沉积物的生物地层学是基于有孔虫的微古生物学分析。Ottnangian沉积物通常不含化石和/或含有经过改造的白垩纪有孔虫。Badenian下沉积区系以Martinotiella karreri (Cush.)、Globigerinoides bisphericus Todd、Vaginulina legumen (L.)等有孔虫为代表,动物种类丰富多样。
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引用次数: 0
Structure of the Kutiště rockslide developed in crystalline rocks of the Hrubý Jeseník Mts. Kutiště滑坡的结构发育在Hrubý Jeseník山的结晶岩中。
Q4 Earth and Planetary Sciences Pub Date : 2023-05-09 DOI: 10.3140/zpravy.geol.2023.06
Martin Kašing, Zuzana Lenďáková, Jakub Jirásek, Michal Goldberger
Slope failures developed in crystalline rocks of the Hrubý Jeseník Mts. (Czechia) are quite sparse phenomenon. So far, only a few deep-seated landslides have been described from areas near Keprník Mt. and Červená hora Mt., while shallow flood- related flows are more frequent. The newly identified Kutiště rockslide (GPS 50.1437297N, 17.0563289E) is located in the village of Jindřichov (Šumperk District, the Olomouc Region, Czechia) about 1 km northeast of Štolný hřbet Mt. (883 m a. s. l.) within the Hrubý Jeseník Mts. The rockslide has been geomorphologically mapped and structural analysis and geophysical measurements using electrical resistivity tomography have been carried out to interpret surface and subsurface structure of the landslide. It is a planar rockslide developed in biotitic orthogneiss of the Keprník Nappe, covering an area of approximately 0.13 km2 (ca. 500 × 250 m) with a total altitude difference of about 140 m. The landslide is dominated by a morphologically very distinct amphitheatre-like headscarp. The approximately 300 m long and relatively compact transport zone of the slide is dissected by several transverse fissures and tension cracks, and it is delimited towards the bedrock by a planar sliding surface at depths of 10–17 m. The accumulation part of the landslide, about 150 m long, has further collapsed by gravity. The resistivity image in this part indicates a sliding surface at a depth of about 25 m. The structural data indicate that the slope failure was structurally predisposed by an orthogonal system of longitudinal (NNW-SSE) and transverse (ENE-WSW) brittle structures, and the hillslope-conformal metamorphic foliation of orthogneiss inclined at an angle of 11° towards N to NNW. The resistivity image of the rockslide does not exclude the presence of deeper sliding surfaces throughout the entire extent of the slope deformation, which would enable its further development. The morphologically fresh appearance of the landslide is not necessarily a result of low age, but rather of the strong resistance of the orthogneiss to weathering.
捷克Hrubý Jeseník山结晶岩中发育的边坡失稳是相当稀疏的现象。到目前为止,在Keprník山和Červená霍拉山附近地区只发现了几次深层滑坡,而浅层洪水则更为频繁。新发现的Kutiště滑坡(GPS 50.1437297N, 17.0563289E)位于Jindřichov村(Šumperk区,捷克奥洛穆茨地区),位于Hrubý Jeseník Mt内Štolný hřbet Mt东北约1公里处(883 ma s.l .)。该滑坡已经进行了地貌学测绘,并使用电阻率断层扫描进行了结构分析和地球物理测量,以解释滑坡的地表和地下结构。它是在Keprník推覆体的生物正形中发育的平面岩崩,面积约0.13 km2(约500 × 250 m),总高差约140 m。该滑坡由一个形态上非常独特的圆形剧场状的头盖骨主导。滑块的运输带长约300 m,相对致密,被若干横向裂缝和张拉裂缝所分割,在10-17 m的深度被一个平面滑动面划向基岩。滑坡的堆积部分,长约150米,在重力作用下进一步坍塌。该部分电阻率图像显示深度约为25 m的滑动面。构造资料表明,坡面破坏是由纵向(NNW- sse)和横向(ENE-WSW)脆性结构的正交体系造成的,坡面-共形变质叶理的正交性向N - NNW倾斜11°。岩石滑坡的电阻率图像不排除在整个边坡变形范围内存在更深的滑动面,这将使其进一步发展。滑坡的形态面貌清新,并不一定是年龄低的结果,而是由于其正长石对风化的抵抗力强。
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引用次数: 0
Petrological diversity of leucocratic rocks at the sodium-potassium feldspar deposit Krásno – Vysoký kámen 钠钾长石矿床白斑岩的岩石学多样性Krásno - Vysoký kámen
Q4 Earth and Planetary Sciences Pub Date : 2023-05-09 DOI: 10.3140/zpravy.geol.2023.03
Karel Breiter, Jaromír Tvrdý, Pavel Jedlička
The presented study aims to reevaluate the geological structure of the Krásno-Vysoký Kámen feldspar deposit and its relationship to the surrounding rocks using chemical and imaging methods. For this purpose, we have documented in detail all the preserved fragments of drill cores from the survey in the 1960s and 1970s years, and 21 exploratory boreholes of the KP series (Fig. 1) realized in 2021, including about 600 chemical XRF bulk-rocks analyzes of rocks from these drillings. The Krásno-Vysoký Kámen open pit is located about 1 km northwest of the Krásno village, western Bohemia. Subject of mining is a complex of leucocratic, feldspar-rich granitoids consisting of predominant medium-grained leucogranite with mainly subhorizontal intercalations of syenite, aplite-pegmatite and feldspar-rich metasomatites. Both the immediate bedrock and the exposed overburden of the leucogranite complex consist of biotite granites. The leucogranite complex forms a lenticular body, the lower boundary of which decreases from N and NW towards E and S (Fig. 5). Especially on the western side of the open pit, the contact of the two rocks is relatively steep, further to the east it flattens. Medium-grained leucocratic granite makes up most of the volume of the deposit. It has a magmatic texture (Fig. 2a) with euhedral, short columnar albite crystals, subhedral orthoclase grains, irregular late quartz grains and low mica content (Tab. 2); apatite and rare topaz and niobium rutile are also present. In the SW edge of the quarry, contact facies of the leucogranite with several layers of oriented crystallization of quartz is exposed. Locally, leucogranite changes to leucosyenite (Fig. 2b). The leucosyenite is still a medium-grained rock with a magmatic texture, but the quartz content decreases (<10%) and the mica is only accessory. Several flat veins of virtually mica-free aplite (Fig. 2c), from several dm to 5 m thick, are lined along the upper contact by a zone of oriented K-feldspar and quartz crystallization (i.e. stockscheider). Alkaline metasomatites (Fig. 2d) are medium to fine grained. Medium-grained varieties are macroscopically hardly distinguishable from igneous syenites; fine-grained varieties are similar to aplites. Feldspars in metasomatites already have a completely irregular worm-like shape, while the ratio of both feldspars fluctuates strongly. The underlying biotite granite is currently well exposed in the NW part of the quarry and was reached by wells KP4, KP5, KP6, and KP7. It is medium-grained granite with Li-biotite and topaz. The contact between this granite and the overlying leucocratic complex was interpreted as rapid transition in old boreholes (Pácal and Pavlů 1979), but sharp contact was found in the borehole KP4. The overlying biotite granite was exposed in the SW parts of the quarry and confirmed by 2 boreholes (KP2, KP3). Both types of biotite granite differ statistically in Fe, Na and K contents. The medians of the chemical composition of all
本文旨在利用化学和成像方法重新评价Krásno-Vysoký Kámen长石矿床的地质构造及其与围岩的关系。为此,我们详细记录了20世纪60年代和70年代调查中保存的所有岩心碎片,以及2021年实现的KP系列的21个勘探钻孔(图1),其中包括对这些钻孔中岩石的约600次化学XRF块状岩石分析。Krásno-Vysoký Kámen露天矿位于波希米亚西部Krásno村西北约1公里处。矿体为富长石的白晶花岗岩复合体,以中粒白花岗岩为主,正长岩、长晶伟晶岩和富长石交代岩为亚水平夹层。浅花岗杂岩的直接基岩和暴露的上覆岩均由黑云母花岗岩组成。浅花岗岩杂岩体呈透镜状体,其下边界由北、北西向东、南逐渐减小(图5),特别是在露天矿西侧,两岩体接触较为陡峭,再往东则趋于平缓。中粒白色花岗岩构成了该矿床的大部分体积。岩浆结构(图2a),含自面体、短柱状钠长石晶体、亚自面体正长石颗粒、不规则晚石英颗粒,云母含量低(表2);磷灰石、稀有黄玉和铌金红石也存在。在采石场的西南边缘,暴露出带有几层石英定向结晶的浅花岗岩接触相。局部浅色花岗岩转变为浅色正长岩(图2b)。浅正长岩仍为岩浆结构的中粒岩,但石英含量下降(10%),云母仅为附属物。几条几乎不含云母的扁平长石脉(图2c),厚度从几厘米到5米不等,沿着上部接触面排列着取向钾长石和石英结晶带(即stockscheider)。碱性交代岩(图2d)为中至细粒。中粒品种在宏观上与火成岩正长岩难以区分;细粒度的品种类似于苹果。交代岩中的长石已经具有完全不规则的蠕虫状形状,而两种长石的比例波动很大。KP4、KP5、KP6和KP7井目前在采石场的NW部分暴露了下伏的黑云母花岗岩。为中粒花岗岩,含锂黑云母和黄玉。该花岗岩与上覆白质杂岩之间的接触被解释为在老钻孔(Pácal and pavllov1979)中的快速过渡,但在KP4钻孔中发现了尖锐的接触。在采石场西南部分暴露上覆黑云母花岗岩,经2孔(KP2、KP3)确认。两种黑云母花岗岩的铁、钠、钾含量差异有统计学意义。上述所有岩石类型的化学成分中位数见表3,部分元素之间的关系见图3。虽然这两种类型的黑云母花岗岩和阿长石具有相对均匀的化学成分,但浅色花岗岩,正长岩和交代岩的组成变化很大,特别是在SiO2和碱方面。当比较这两种碱时,与Na2O(主要是1-6 wt. %,但具有边际值的样品较少)相比,K2O含量(<1 - 9 wt. %)的变异性明显更大。在正长岩、交代岩和浅花岗岩中,可以发现几乎只含有一种长石的极端样品。长石的总含量在浅色花岗岩中主要在40 ~ 70 wt. %,正长岩中在70 ~ 90 wt. %,长石中在50 ~ 70 wt. %,交代岩中在50 ~ 90 wt. %。在KP13和KP14井中,宏观均质白垩系岩石的化学成分发生了显著的垂直变化(图4)。
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