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Effects of Temperature and Solar Irradiation Variations on The Performances of Photovoltaic Pumping Systems 温度和太阳辐照度变化对光伏抽水系统性能的影响
Pub Date : 2024-06-14 DOI: 10.54963/neea.v3i1.244
Moncef Jraidi, Adnen Cherif
Climate and solar radiation levels are two major environmental elements that affect the operation of photovoltaic (PV) pumping systems. Rising temperatures cause a decrease in PV modules' electrical efficiency because of the fall of fill factor and open-circuit voltage. They may also cause a decrease in motor efficiency because of the growing winding resistance losses. Besides, the increased photocurrent and power production of the PV array are caused by higher levels of solar irradiation, which makes the pump run at higher speeds or flow rates. To quantify these impacts and forecast system performance, precise modeling techniques and control laws are used such as MPPT, PWM and U/F in this paper. This paper presents solar performances and responses such as the flow of the pumped water, the PV power outputs, motor voltages, currents, speed and finally converter controls. However, although MPPT and PWM control laws improve the energy efficiency of the overall system, the simulation results show that the performance of the PV pumping system degrades when the temperature increases and the solar flux decreases, which will affect the autonomy of the PV system.
气候和太阳辐射水平是影响光伏(PV)泵系统运行的两大环境因素。温度升高会导致光伏组件的电气效率降低,因为填充系数和开路电压会下降。由于绕组电阻损耗增加,温度升高还可能导致电机效率下降。此外,太阳辐照度增加也会导致光伏阵列的光电流和发电量增加,从而使泵以更高的速度或流量运行。为了量化这些影响并预测系统性能,本文采用了精确的建模技术和控制法则,如 MPPT、PWM 和 U/F 等。本文介绍了太阳能的性能和响应,如抽水流量、光伏发电输出、电机电压、电流、速度以及最后的变流器控制。然而,尽管 MPPT 和 PWM 控制法提高了整个系统的能效,但仿真结果表明,当温度升高和太阳光通量降低时,光伏抽水系统的性能会下降,这将影响光伏系统的自主性。
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引用次数: 0
Optimization of Matrix Components for Improved Catalytic Activities of Cellulase Immobilized on Biochar-Chitosan Beads 优化基质成分以提高固定在生物炭-壳聚糖珠上的纤维素酶的催化活性
Pub Date : 2024-05-23 DOI: 10.54963/neea.v3i1.249
Egwim Chidi Evans, Oluyemisi Omotayo Omonije, Isaac Poritmwa Gontul
Bioethanol is a renewable energy that is gaining popularity globally. It’s biochemical production requires the use of enzyme, especially cellulase. Cellulase is an enzyme that catalyzes the degradation of cellulose and related polysaccharides which finds applications in food, textiles, detergents, biofuels etc. However, the worldwide use of cellulase is limited by its relatively high production costs and low biological activity. This study was design to locally produce biochar-chitosan beads at optimized conditions to immobilize cellulase for improved thermal and storage stability as well as ensure reusability of the enzyme so as to improve biological activity and avoid the continuous production of free cellulase thereby reducing the production cost. Biochar was produced by pyrolyzing sugarcane bagasse in a local airtight chamber for 1 hour. Beads were formed from different ratios of biochar and chitosan in varying concentrations of calcium chloride solution as generated by design expert software version 13. The beads were dried in an oven at 50 0C for 24 hours and functionalized in 25% glutaraldehyde (GDA). The beads were loaded with enzyme (10.06 µmole/min/mL) at room temperature (27 ± 3 oC). Enzyme activity, thermal stability, storage stability and reusability tests were carried out according to standard procedures. The half-life and activation energy were also evaluated. The result showed that the optimum activity of the loaded enzyme (2.63 µmole/min/mL) was obtained when 2.46 g of porous biochar was mixed with 2.48 g chitosan in 5 % Calcium chloride aqueous solution. The immobilized enzyme was able to maintain thermal stability between 30 oC and 70 oC while the activity for free enzyme started declining after 50 oC. Also, the activation energy for immobilized cellulase enzyme (23.17 KJ/mol) was lower than the activation energy (55.146 KJ/mol) for free cellulase. The half-life, when stored at ambient Temperature (27 ± 3 oC), for free enzyme was 0.4 days while the half-life for immobilized enzyme was 3.59 days. Therefore, cellulase immobilized on support locally produced at optimal conditions had improved catalytic properties when compared to the free enzyme. Hence, more indigenous materials and practices may be employed for a cost effective and cheaper industrial processes.
生物乙醇是一种可再生能源,在全球越来越受欢迎。生物乙醇的生化生产需要使用酶,尤其是纤维素酶。纤维素酶是一种催化纤维素和相关多糖降解的酶,可应用于食品、纺织品、洗涤剂、生物燃料等领域。然而,由于纤维素酶的生产成本相对较高,生物活性较低,其在全球范围内的使用受到了限制。本研究旨在本地化生产生物炭-壳聚糖珠,在优化条件下固定纤维素酶,以提高热稳定性和储存稳定性,并确保酶的可重复使用性,从而提高生物活性,避免持续生产游离纤维素酶,降低生产成本。生物炭是通过在当地密闭室内热解甘蔗渣 1 小时生产出来的。在不同浓度的氯化钙溶液中加入不同比例的生物炭和壳聚糖,通过设计专家软件 13 版生成珠子。珠子在 50 摄氏度的烘箱中干燥 24 小时,并在 25% 戊二醛(GDA)中进行功能化处理。在室温(27 ± 3 oC)条件下,将珠子装入酶(10.06 µmole/min/mL)。按照标准程序进行了酶活性、热稳定性、储存稳定性和重复使用性测试。还对半衰期和活化能进行了评估。结果表明,当 2.46 克多孔生物炭与 2.48 克壳聚糖在 5 % 氯化钙水溶液中混合时,负载酶的活性达到最佳(2.63 µmole/min/mL)。固定化酶能够在 30 oC 至 70 oC 之间保持热稳定性,而游离酶的活性在 50 oC 之后开始下降。此外,固定化纤维素酶的活化能(23.17 KJ/mol)低于游离纤维素酶的活化能(55.146 KJ/mol)。在环境温度(27 ± 3 oC)下储存时,游离酶的半衰期为 0.4 天,而固定化酶的半衰期为 3.59 天。因此,与游离酶相比,固定在当地以最佳条件生产的支持物上的纤维素酶具有更好的催化特性。因此,可以采用更多的本地材料和做法,以实现具有成本效益和更便宜的工业流程。
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引用次数: 0
Proposing an Approach for the Diffusion of Building Integrated Photovoltaics (BIPVs)—A Case Study 提出推广光伏建筑一体化(BIPV)的方法--案例研究
Pub Date : 2024-02-02 DOI: 10.54963/neea.v3i1.196
Samuel Amo Awuku, Amar Bennadji, F. Muhammad-Sukki, Radhakrishna Prabhu, N. Sellami
Consistent probing into building integrity has led to the exploration of clean energy options such as building integrated photovoltaic (BIPV). BIPV has proven to be aesthetically pleasing, architecturally feasible, and capable of making buildings energy producers instead of mere energy consumers. Despite the enormous benefits of BIPV, its adoption and diffusion have been relatively sluggish and remain far below expectations, especially in developing countries like Ghana. This empirical study aims to assess the impact of advertising on BIPV awareness in Ghana. It also highlights the aesthetic preferences of various respondents. The study uses online surveys to gather quantitative data from 412 respondents across all 16 regions of the country. An initial study conducted on the awareness of BIPV in Ghana indicated a low rate of awareness. Therefore, a sensitisation poster and architectural visualization (AV) were adopted to boost awareness across all 16 regions of the country. Awareness of BIPV increased from 18% to 79.5% after the introduction of the sensitisation poster. Also, 88.8% of the respondents preferred BIPV to Building Applied Photovoltaic (BAPV) mainly because of aesthetics (beauty) and the cost benefits. The respondents indicated that aesthetics is paramount when choosing solar panels for their homes. This study therefore recommends high investment in awareness creation, development of specific design guidelines for BIPV applications and establishment of demo projects in developing countries. The findings of this study contribute to the existing literature on BIPV adoption and may be useful for BIPV manufacturers, marketers, government, and other stakeholders as it provides evidence on the often-neglected approach to BIPV diffusion.
对建筑完整性的不断探索促使人们开始探索清洁能源方案,如光伏建筑一体化(BIPV)。事实证明,BIPV 不仅美观,在建筑设计上也是可行的,而且能够使建筑物成为能源生产者,而不仅仅是能源消费者。尽管 BIPV 有着巨大的优势,但其采用和推广却相对缓慢,远远低于预期,尤其是在加纳这样的发展中国家。本实证研究旨在评估广告对加纳 BIPV 意识的影响。它还强调了不同受访者的审美偏好。研究采用在线调查的方式,从全国 16 个地区的 412 名受访者那里收集定量数据。对加纳 BIPV 意识的初步研究表明,加纳对 BIPV 的认知率较低。因此,加纳采用了宣传海报和建筑可视化(AV)来提高全国所有 16 个地区的认知度。宣传海报推出后,人们对 BIPV 的认识从 18% 提高到 79.5%。此外,88.8% 的受访者认为 BIPV 比 BAPV 更受青睐,主要原因是美观和成本效益。受访者表示,在选择家用太阳能电池板时,美观是最重要的。因此,本研究建议在提高认识方面投入大量资金,为 BIPV 应用制定具体的设计指南,并在发展中国家建立示范项目。这项研究的结果为现有的有关 BIPV 应用的文献做出了贡献,并为 BIPV 制造商、营销人员、政府和其他利益相关者提供了有用的证据,因为它为 BIPV 的推广提供了经常被忽视的方法。
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引用次数: 0
Proposing an Approach for the Diffusion of Building Integrated Photovoltaics (BIPVs)—A Case Study 提出推广光伏建筑一体化(BIPV)的方法--案例研究
Pub Date : 2024-02-02 DOI: 10.54963/neea.v3i1.196
Samuel Amo Awuku, Amar Bennadji, F. Muhammad-Sukki, Radhakrishna Prabhu, N. Sellami
Consistent probing into building integrity has led to the exploration of clean energy options such as building integrated photovoltaic (BIPV). BIPV has proven to be aesthetically pleasing, architecturally feasible, and capable of making buildings energy producers instead of mere energy consumers. Despite the enormous benefits of BIPV, its adoption and diffusion have been relatively sluggish and remain far below expectations, especially in developing countries like Ghana. This empirical study aims to assess the impact of advertising on BIPV awareness in Ghana. It also highlights the aesthetic preferences of various respondents. The study uses online surveys to gather quantitative data from 412 respondents across all 16 regions of the country. An initial study conducted on the awareness of BIPV in Ghana indicated a low rate of awareness. Therefore, a sensitisation poster and architectural visualization (AV) were adopted to boost awareness across all 16 regions of the country. Awareness of BIPV increased from 18% to 79.5% after the introduction of the sensitisation poster. Also, 88.8% of the respondents preferred BIPV to Building Applied Photovoltaic (BAPV) mainly because of aesthetics (beauty) and the cost benefits. The respondents indicated that aesthetics is paramount when choosing solar panels for their homes. This study therefore recommends high investment in awareness creation, development of specific design guidelines for BIPV applications and establishment of demo projects in developing countries. The findings of this study contribute to the existing literature on BIPV adoption and may be useful for BIPV manufacturers, marketers, government, and other stakeholders as it provides evidence on the often-neglected approach to BIPV diffusion.
对建筑完整性的不断探索促使人们开始探索清洁能源方案,如光伏建筑一体化(BIPV)。事实证明,BIPV 不仅美观,在建筑设计上也是可行的,而且能够使建筑物成为能源生产者,而不仅仅是能源消费者。尽管 BIPV 有着巨大的优势,但其采用和推广却相对缓慢,远远低于预期,尤其是在加纳这样的发展中国家。本实证研究旨在评估广告对加纳 BIPV 意识的影响。它还强调了不同受访者的审美偏好。研究采用在线调查的方式,从全国 16 个地区的 412 名受访者那里收集定量数据。对加纳 BIPV 意识的初步研究表明,加纳对 BIPV 的认知率较低。因此,加纳采用了宣传海报和建筑可视化(AV)来提高全国所有 16 个地区的认知度。宣传海报推出后,人们对 BIPV 的认识从 18% 提高到 79.5%。此外,88.8% 的受访者认为 BIPV 比 BAPV 更受青睐,主要原因是美观和成本效益。受访者表示,在选择家用太阳能电池板时,美观是最重要的。因此,本研究建议在提高认识方面投入大量资金,为 BIPV 应用制定具体的设计指南,并在发展中国家建立示范项目。这项研究的结果为现有的有关 BIPV 应用的文献做出了贡献,并为 BIPV 制造商、营销人员、政府和其他利益相关者提供了有用的证据,因为它为 BIPV 的推广提供了经常被忽视的方法。
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引用次数: 0
Optimizing Thermal Management: An Evaluation of Embedded Aluminum-Ammonia Heat Pipes Honeycomb Sandwich Panel as a Heat Sink for Satellite Use 优化热管理:对嵌入式铝氨热管的评估 将蜂窝夹芯板用作卫星散热器
Pub Date : 2024-01-27 DOI: 10.54963/neea.v3i1.210
Ho-Chuan Lin, Van Hoan Vu, Alfandy Tansyafri, Meng-Hao Chen
This study presents an innovative approach to enhancing thermal management in satellite applications by utilizing an embedded aluminum-ammonia heat pipes honeycomb sandwich panel (HPA-PNL) as a high-performance heat sink. The study focuses on developing and evaluating this advanced heat sink technology, addressing the challenges associated with assessing its performance and suitability for satellite use. The research explores the selection of materials and testing methodologies, highlighting the significance of overcoming existing limitations in the absence of standardized testing methods. The results of the thermal conductivity in Z-directions (KZ) indicated that the areas on top of the heat pipes show higher thermal conductivity than those on top of the honeycomb core. Also, the effect of background heat sources and different kinds of thermal interface material (TIM) on HPA-PNL performance is insignificant. The heat dissipation through the heat pipe is substantial, emphasizing the effective ability to dissipate heat for an HPA-PNL with many heat sources acting simultaneously. The outcomes of this study reveal promising testing methods for evaluating the KZ of the HPA-PNL, proposing the potential of the embedded aluminum-ammonia heat pipes honeycomb sandwich panel as a highly effective and efficient heat sink for satellite systems, thus contributing to the advancement of satellite technology.
本研究提出了一种创新方法,利用嵌入式铝氨热管蜂窝夹芯板(HPA-PNL)作为高性能散热器,加强卫星应用中的热管理。研究的重点是开发和评估这种先进的散热技术,解决与评估其性能和卫星用途适用性相关的挑战。研究探讨了材料的选择和测试方法,强调了在缺乏标准化测试方法的情况下克服现有限制的重要性。Z 方向(KZ)的热传导率结果表明,热管顶部区域的热传导率高于蜂窝芯顶部区域。此外,背景热源和不同种类的热界面材料(TIM)对 HPA-PNL 性能的影响也不大。通过热导管的散热量很大,强调了同时有多个热源的 HPA-PNL 的有效散热能力。这项研究成果揭示了评估 HPA-PNL KZ 的可行测试方法,提出了嵌入式铝氨热管蜂窝夹层板作为卫星系统高效散热器的潜力,从而为卫星技术的进步做出了贡献。
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引用次数: 0
Victoria’s Energy Transition using n Bottom Line Analysis 维多利亚州的能源转型使用n底线分析
Pub Date : 2023-08-04 DOI: 10.54963/neea.v2i2.116
G. Currie, Riley Cousins, Alexander Diplaris, Sebastian Drimer, M. Foley
To achieve net-zero emissions by 2050, Australia must decarbonise the energy sector and other sectors. The 'energy transition' is driven by policy-led construction of renewable infrastructure and regulation changes. However, no holistic analysis of the path forward currently exists. This research aims to develop a clear plan for Victoria's energy transition by evaluating three scenarios. A Business as Usual (BAU) scenario is compared against two alternative solutions. The alternates emulate two of Victoria's possible trajectories. Alternative 1 (ALT1) focuses on Victoria's reliance on imported interstate renewable energy, while Alternative 2 (ALT2) involves Victoria becoming self-sufficient through renewable generation. Each of the three scenarios is compared across four bottom lines: technical performance, social, economic, and environmental. Interviews among energy experts revealed that economic and social metrics were considered most important. Applying the n-bottom line (nBL) assessment framework delivers a result that finds ALT2 and ALT1 tied as the preferred solution. Hence, the construction of renewable infrastructure in Victoria and increased interstate transmission capacity should be built. Further research could include a deeper understanding of the embodied carbon in infrastructure built for the energy transition.
为了到2050年实现净零排放,澳大利亚必须使能源部门和其他部门脱碳。“能源转型”是由政策主导的可再生基础设施建设和监管变化推动的。然而,目前还没有对未来道路的全面分析。本研究旨在通过评估三种情景,为维多利亚州的能源转型制定一个明确的计划。将业务照常(BAU)场景与两个备选解决方案进行比较。候补队员模仿了维多利亚的两种可能的轨迹。替代方案1 (ALT1)侧重于维多利亚州对进口州际可再生能源的依赖,而替代方案2 (ALT2)涉及维多利亚州通过可再生能源发电实现自给自足。对这三种方案中的每一种都进行了四个底线的比较:技术性能、社会、经济和环境。对能源专家的采访显示,经济和社会指标被认为是最重要的。应用n-bottom line (nBL)评估框架提供的结果是,ALT2和ALT1作为首选解决方案被捆绑在一起。因此,应该在维多利亚州建设可再生能源基础设施,并增加州际输电能力。进一步的研究可以包括更深入地了解为能源转型而建设的基础设施所隐含的碳。
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引用次数: 0
Token-Based Smart Power Contract for Interoperable Blockchains of Networked Microgrid System 网络化微电网系统互操作区块链的代币式智能电力合约
Pub Date : 2023-07-24 DOI: 10.54963/neea.v2i1.118
D. Sharma
Designing the secure and privacy-protected smart power contract between electricity suppliers and consumers, considered agents, of different microgrids, is a challenging task in the networked- microgrid system. A framework is suggested in which each microgrid implements a heterogeneous or isomorphic blockchain based platform. The blockchain interoperability, inherently, is present in different blockchains implemented by various microgrids. This paper reviews the interoperability issues and smart contract designs in blockchain based systems. The paper proposes new mechanisms to cater blockchain interoperability challenges to facilitate the design of secure and seamless smart contracts among different blockchains of microgrids. A network hub of heterogeneous or isomorphic blockchains of network microgrids has been created. A methodology has been developed to transfer tokens between interoperable blockchains. Distributed identity-based microgrid (DIBM) scheme is incorporated to make the networked microgrid system secure and trustworthy. This paper suggests an effective consensus protocol for cross-chain architecture that improves the tokenization system and smart power contract designs. For simulation purposes, MATLAB and python programming have been used with real-time data of microgrids.
在网络化微电网系统中,在不同微电网的电力供应商和消费者(被视为代理)之间设计安全且保护隐私的智能电力合同是一项具有挑战性的任务。本文提出了一个框架,其中每个微电网都实现了基于区块链的异构或同构平台。区块链的互操作性本身就存在于各种微电网实施的不同区块链中。本文回顾了基于区块链系统的互操作性问题和智能合约设计。本文提出了应对区块链互操作性挑战的新机制,以促进微电网不同区块链之间安全、无缝的智能合约设计。创建了一个网络微电网异构或同构区块链的网络中心。开发了在可互操作区块链之间转移代币的方法。基于分布式身份的微电网(DIBM)方案被纳入其中,以确保网络微电网系统的安全性和可信性。本文为跨链架构提出了一种有效的共识协议,改进了代币化系统和智能电力合约设计。为了进行仿真,本文使用了 MATLAB 和 python 编程,并使用了微电网的实时数据。
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引用次数: 0
Significant Development Potential of the Solid Oxide Fuel Cell for the Technical Progress of the Marine Main Propulsion Plant in the Context of Energy Conservation and Emission Reduction 固体氧化物燃料电池在节能减排背景下促进船舶主推进装置技术进步的巨大发展潜力
Pub Date : 2023-07-10 DOI: 10.54963/neea.v2i1.120
Xiaoyu Wang, Jianzhong Zhu, Minfang Han
The International Maritime Organization (IMO) has proposed a series of strict pollutant emission regulations and carbon emission reduction targets, and the shipping industry is seeking new types of the marine main propulsion plant with advantages of high-efficiency and low-emission. Among the possible alternatives, the marine electric propulsion technology whose electric power source is fuel cell has gained sufficient attentions. At present, the worldwide research of the marine applications for fuel cell supplying propulsion power focuses more on the proton exchange membrane fuel cell (PEMFC) with low power instead of other types of fuel cell, and a series of research projects have achieved concrete results such as the industrialized marine fuel cell system or practical demonstration application. But the development trends of the application of the marine fuel cell supplying propulsion power are from the small boat to the great ship, from the navigating zone with low environmental complexity such as coastal water, inland waters to the ocean with complex navigation conditions. Thus, the power demand of the marine fuel cell in the future will show steady growth, which will create more development opportunities for the solid oxide fuel cell (SOFC) with the advantages of higher power, greater efficiency, long life span and fuel diversity. Although some challenges exist, the solid oxide fuel cell with significant development potential can certainly lead the technical progress of the marine main propulsion plant in the context of energy conservation and emission reduction.
国际海事组织(IMO)提出了一系列严格的污染物排放法规和碳减排目标,航运业正在寻求具有高效、低排放优势的新型船用主推进装置。在可能的替代方案中,以燃料电池为电力来源的船用电力推进技术得到了足够的重视。目前,世界范围内对燃料电池提供推进动力的海洋应用研究更多集中在低功率的质子交换膜燃料电池(PEMFC)上,而非其他类型的燃料电池,一系列研究项目已取得了具体成果,如工业化的海洋燃料电池系统或实际示范应用。但船用燃料电池提供推进动力的应用发展趋势是从小船到大船,从近海、内陆水域等环境复杂度较低的航行区域到航行条件复杂的海洋。因此,未来船用燃料电池的功率需求将呈稳步增长趋势,这将为具有更高功率、更高效率、更长寿命和燃料多样性等优势的固体氧化物燃料电池(SOFC)创造更多的发展机会。尽管还存在一些挑战,但发展潜力巨大的固体氧化物燃料电池必将引领节能减排背景下船舶主推进装置的技术进步。
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引用次数: 0
Hydrogen Safety for Hydrogen Energy Applications and Large-scale Commercialization 氢能应用与大规模商业化的氢安全
Pub Date : 2022-10-09 DOI: 10.54963/neea.v1i3.96
Jichao Hong
The increasing demand for energy in the world and the environmental pollution caused by conventional chemical fuels constantly promote the development and utilization of new energy. As a kind of new energy, hydrogen is favored by countries all over the world because of its diverse sources, convenient storage and transportation, efficient utilization, and environmental friendliness [1] . However, hydrogen is flammable and explosive, which has a wide range of combustion, and deteriorates the mechanical properties of materials. There are hidden dangers such as leakage and explosion in the preparation, storage, transportation, filling, and use of hydrogen, so hydrogen safety is particularly important in the application and large-scale commercial promotion of hydrogen energy. Therefore, it is an important guarantee for the development and safe application of hydrogen energy technology to transition to a more sustainable stage by making clear the danger of hydrogen and conducting basic research on the consequences and prevention of hydrogen safety accidents, to provide a reliable basis for the formulation of relevant standards and regulations. At present, there is little research in the field of hydrogen safety in relevant institutions around the world, and only some milestones have been achieved. At present, the hydrogen safety research is still facing challenges, whose research status is mainly divided into three aspects, such as hydrogen leakage and diffusion [2] , hydrogen combustion and explosion [3] , and the compatibilitybetween hydrogen and metal materials [4] . There is still a need to make appropriate risk assessments for hydrogen safety, hydrogen safety research is still immature, and hydrogen safety issues still face challenges [5] . In the aspect of hydrogen leakage and diffusion, the influence of the shape of the leakage port, hydrogen concentration gradient, and air buoyancy on hydrogen leakage and diffusion still needs further study, and it is still difficult to establish a two-phase leakage model considering the non-ideal characteristics of liquid hydrogen. In terms of hydrogen combustion and explosion, the mechanism of flame acceleration and deflagration detonation transition is still unclear, and the mechanism and experimental study of hydrogen spontaneous combustion still need to be strengthened. As for the compatibility between hydrogen and metal materials, the test data of materials in a high-pressure hydrogen
世界能源需求的不断增长和常规化学燃料对环境的污染不断推动着新能源的开发利用。氢作为一种新能源,因其来源多样、储运方便、利用高效、环境友好等特点受到世界各国的青睐[1]。但氢气是易燃易爆的,燃烧范围广,使材料的机械性能恶化。氢气的制备、储存、运输、充注、使用等过程中存在泄漏、爆炸等隐患,因此氢能源的应用和大规模商业化推广中氢安全尤为重要。因此,认清氢的危害性,开展氢安全事故后果和预防的基础研究,为制定相关标准和法规提供可靠依据,是氢能技术发展和安全应用向更可持续发展阶段过渡的重要保障。目前,世界各国相关机构在氢安全领域的研究很少,仅取得了一些里程碑式的成果。目前,氢的安全性研究仍面临挑战,其研究现状主要分为氢的泄漏与扩散[2]、氢的燃烧与爆炸[3]、氢与金属材料的相容性[4]三个方面。氢安全仍需要进行适当的风险评估,氢安全研究尚不成熟,氢安全问题仍面临挑战[5]。在氢气泄漏和扩散方面,泄漏口形状、氢气浓度梯度、空气浮力对氢气泄漏和扩散的影响还需要进一步研究,考虑到液氢的非理想特性,建立两相泄漏模型仍然比较困难。在氢气燃烧爆炸方面,火焰加速和爆燃爆轰转捩机理尚不清楚,氢气自燃机理和实验研究仍需加强。关于氢与金属材料的相容性,材料在高压氢环境下的试验数据
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引用次数: 0
Thermochemical property predictions in biomass transformation to fuel components and value-added chemicals 生物质转化为燃料成分和增值化学品的热化学性质预测
Pub Date : 2022-08-01 DOI: 10.54963/neea.v1i3.70
Firdaus Parveen, S. Upadhyayula
Biomass transformation to fuel and platform chemicals is of an immense interest in the world. The thermochemical data for various reactions involved during biomass transformations to fuel components, fuels and platform chemicals has been investigated using highly accurate Gaussian-4 (G-4) method. Glucose to 5-hydroxymethyl furfural (5-HMF) conversion is a two-step pathway, where first step, glucose isomerization to fructose is highly endothermic with high activation energies. 5-HMF upgradation can be carried through hydrogenation, oxidation, condensation and rehydration. Upgradation of HMF to fuel and value-added chemicals (VAC) is industrially important process that can reduce the demand of petrochemical based products. Thermochemical calculations predict the hydrogenation of 5-HMF to 2,5 dimethyl furan (2,5 DMF) is feasible and follow either pathways with dihydroxy methyl furan (DHMF) and methyl furan (MF) as intermediates. The total Gibb’s Free energy difference for the 5-HMF transformation to 2,5 DMF is highly exothermic.  The condensation, rehydration and oxidation reactions of 5- HMF also predicted to be feasible and highly exothermic in nature, that can have potential application in industrial processes. Ethanol is mixed with petrol to run the vehicle on reduced fuel. Ethanol can be obtained from glucose following glycolysis pathway, breaking C-6 sugar to two C-3 sugars. Glyceraldehyde and pyruvic acid are the intermediates in the glycolysis cycle with positive Gibbs free energy change, hence require high temperature. 
生物质转化为燃料和平台化学品在世界上引起了极大的兴趣。利用高精度的高斯-4 (G-4)方法研究了生物质转化为燃料组分、燃料和平台化学品过程中涉及的各种反应的热化学数据。葡萄糖到5-羟甲基糠醛(5-HMF)的转化是一个两步的途径,其中第一步,葡萄糖异构化到果糖是高吸热的,具有高活化能。5-羟甲基糠醛的升级可通过加氢、氧化、缩合和再水合进行。HMF升级为燃料和增值化学品(VAC)是工业上重要的过程,可以减少石油化工产品的需求。热化学计算预测5- hmf加氢生成2,5 -二甲基呋喃(2,5 DMF)是可行的,并遵循以二羟基甲基呋喃(DHMF)和甲基呋喃(MF)为中间体的两种途径。5- hmf转化为2,5 DMF的总吉布自由能差是高度放热的。5-羟甲基糠醛的缩合、再水合和氧化反应是可行的,具有高度放热的性质,在工业生产中具有潜在的应用前景。乙醇与汽油混合,使车辆使用减少的燃料。葡萄糖经糖酵解途径,将C-6糖分解为两个C-3糖,可制得乙醇。甘油醛和丙酮酸是糖酵解循环的中间产物,吉布斯自由能变化为正,因此需要较高的温度。
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New Energy Exploitation and Application
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