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Synthesis of zeolites P and evaluation of their activity as new and reusable heterogeneous catalysts in a three-component ABB’ Povarov model reaction 沸石P的合成及其在三组分ABB’Povarov模型反应中作为新的可重复使用的多相催化剂的活性评价
Q2 Multidisciplinary Pub Date : 2020-12-30 DOI: 10.11144/JAVERIANA.SC25-3.SOZP
Jefersson A. López, R. Toro, A. R. Bohórquez, J. H. Quintana, J. Henao
A Na-P zeolite was synthesized and subjected to ion exchange with Ca2+, Cu2+, Al3+, and In3+, and supported with H+/NH4Cl (NH4-P) by in situ reaction of EtOH and NH4Cl. All the exchanged zeolites showed catalytic activity in the ABB’ Povarov reaction. However, zeolite NH4-P promoted a better yield. In all reactions two products were obtained, 2,6-dimethyl-4-(2-oxopyrrolidin-1-yl)-1,2,3,4-tetrahydroquinoline and 1-(1-(4-methylphenylamino)ethyl)pyrrolidin 2-one. Synthesis using zeolite P as catalyst proves to be a simple method with high yields, short reaction times and easy preparation. The catalyst can be recovered by filtration and reused up to three times in good yields.
合成了Na-P沸石,并与Ca2+、Cu2+、Al3+和In3+进行离子交换,并通过EtOH和NH4Cl的原位反应用H+/NH4Cl(NH4-P)负载。所有交换的沸石在ABB的Povarov反应中都显示出催化活性。但是,沸石NH4-P促进了较好的产率。在所有反应中得到2,6-二甲基-4-(2-氧代吡咯烷-1-基)-1,2,3,4-四氢喹啉和1-(1-(4-甲基苯基氨基)乙基)吡咯烷-2-酮。以P沸石为催化剂合成是一种收率高、反应时间短、易于制备的简单方法。催化剂可以通过过滤回收,并以良好的产率重复使用多达三次。
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引用次数: 0
Diurnal physiological behavior of seedlings in the Amazon rainforest: generalist versus specialist species of shade and sun 亚马逊雨林幼苗的昼夜生理行为:遮荫和阳光的多面手与专业物种
Q2 Multidisciplinary Pub Date : 2020-12-30 DOI: 10.11144/JAVERIANA.SC25-3.DPBO
Carolina Ramos-Montaño, L. J. Vanegas-Cano, Nancy Milena Cárdenas-Avella, Karen Lizeth Pulido-Herrera, Sindy Paola Buitrago-Puentes
The regenerative success of generalist and specialist species may be due to differences in their physiology. Measurements of stomatal conductance (gS) provide an efficient way to infer immediate physiological responses of plants to diurnal environment variation. Radiation, air temperature, and relative humidity were measured in the Colombian Amazon rainforest, to identify the extreme environmental conditions that limit the gS of seedlings in three site types: small gap, open forest, and closed forest. We hypothesized that the diurnal physiological performance of generalist species must be plastic in these three environments. Morphological traits, gS, and leaf temperature were evaluated in seedlings of four species: one generalist, common to all sites, and one specialist from each site. The gap site was warmer and more irradiated than the other two sites, which caused several midday physiological depressions, limited seedling survival, and facilitated the specialized strategy. Leaf and air temperatures were strong determinants of overall gS. The generalist species was physiologically plastic and, at some hours of the day, more efficient than the specialists from open forest andclosed forests. This factor interplay could allow the coexistence of both types of plants.
通才物种和专才物种的再生成功可能是由于它们生理上的差异。气孔导度(gS)的测量为推测植物对日环境变化的即时生理反应提供了一种有效的方法。通过对哥伦比亚亚马逊雨林的辐射、空气温度和相对湿度的测量,确定了三种样地类型(小林隙、开阔林和闭阔林)中限制幼苗gS的极端环境条件。我们假设,在这三种环境中,多面手物种的日常生理表现一定是可塑的。研究了四种植物幼苗的形态特征、gS和叶温,其中一种是所有站点的通才,另一种是每个站点的特种树。与其他两个地点相比,间隙地温度更高,辐射更强,造成了一些中午生理抑制,限制了幼苗的成活,有利于特化策略。叶片和空气温度是总gS的重要决定因素。多面手物种在生理上具有可塑性,在一天中的某些时间,比来自开放森林和封闭森林的专家更有效率。这种因素的相互作用可能使两种植物共存。
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引用次数: 0
Characterization of antibiotic-resistant Escherichia coli associated with urinary tract infections in Southern Colombia 哥伦比亚南部与尿路感染相关的抗生素耐药性大肠杆菌的特征
Q2 Multidisciplinary Pub Date : 2020-12-22 DOI: 10.11144/JAVERIANA.SC25-3.COAR
Deisy Lorena Guerrero Ceballos, Edith Mariela Burbano Rosero, E. Ibargüen-Mondragón
Bacterial resistance to antibiotics is one of the largest medical concerns worldwide.One of the bacteria of critical priority is E. coli, since it presents different resistance mechanisms and some of its strains have evolved resistance to beta-lactam antibiotics. We characterized 32 antibiotic resistant bacterial isolates from confirmed cases of urinary tract infections from an array of patients in Nariño, southern Colombia. Macro and microscopic descriptions of the 32 clinical isolates were conducted. Resistance profiles, biochemical, and molecular characterization (via 16S rRNA gene sequencing, ERIC-PCR, and resistance genes) were performed. All the isolates were identified as E. coli and had resistance to beta-lactams, aminoglycosides, and fluoroquinolones. This resistance was related to plasmids carryingthebla TEM, blaSHV1, and blaCTXM1genes.There were significant differences between the resistance proportions of the samples (p value:0.0000), mainly to penicillin, cefotoxin, and imipenem. Using ERIC-PCR, four clonal states were evidenced that corroborate a degree of genetic differentiation with in the isolate set.Antibiotic resistance observed in the isolates is associated with resistance genes present in the bacterial chromosome and plasmids.
细菌对抗生素的耐药性是全世界最大的医学问题之一。最重要的细菌之一是大肠杆菌,因为它具有不同的耐药机制,而且它的一些菌株已经进化出对-内酰胺类抗生素的耐药性。我们从哥伦比亚南部Nariño的一系列患者的尿路感染确诊病例中分离出32株抗生素耐药细菌。对32株临床分离株进行了宏观和微观描述。进行抗性谱、生化和分子鉴定(通过16S rRNA基因测序、ERIC-PCR和抗性基因)。所有分离株均为大肠杆菌,对内酰胺类、氨基糖苷类和氟喹诺酮类具有耐药性。这种抗性与携带bla TEM、blaSHV1和blactxm1基因的质粒有关。各样本的耐药比例差异有统计学意义(p值为0.0000),主要是青霉素、头孢毒素和亚胺培南。利用ERIC-PCR,证实了四种克隆状态,证实了分离集中存在一定程度的遗传分化。在分离株中观察到的抗生素耐药性与细菌染色体和质粒中存在的抗性基因有关。
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引用次数: 3
Effect of pH on the growth of three lactic acid bacteria strains isolated from sour cream pH对酸奶油中三株乳酸菌生长的影响
Q2 Multidisciplinary Pub Date : 2020-11-06 DOI: 10.11144/JAVERIANA.SC25-2.EOPO
Madalyd Yurani Vera-Peña, Wendy Lizeth Rodriguez-Rodriguez
Lactic acid bacteria (LAB) have an important role in the food industry because they are used in the production of fermented fo ds. To use these microorganisms in the food industry, it is necessary to obtain a high amount of biomass. One of the most important environmental factors in the growth of LAB is pH. Most of LAB species can tolerate a pH below 5.0, however, a suboptimal pH is expected to limit LAB growth. For this reason, the LAB strains Leuconostoc mesenteroides 67-1, Lactobacillus plantarum 60-1, and Streptococcus infantarius 46-3, isolated from sour cream, were grown in culture media under four different intial pH values to determine their optimal growth pH. Growth was assesed via colony-forming unit (CFU/ml) determination. We found that the growth of each LAB was affected by culture medium pH. We determined that the setpoints of pH for Leuconostoc mesenteroides 67-1, Streptococcus infantarius 46-3, and Lactobacillus plantarum 60-1 were of 4.5 (± 0.5), 5.5 (± 0.5), and 6.0 (± 0.5), respectively. We thus conclude that the growth of these LAB strains is pH-dependent (p < 0.05).
乳酸菌(LAB)在食品工业中具有重要的作用,因为它们用于发酵食品的生产。为了在食品工业中使用这些微生物,必须获得大量的生物质。pH是影响乳酸菌生长的最重要的环境因素之一。大多数乳酸菌可以耐受低于5.0的pH值,然而,不理想的pH值预计会限制乳酸菌的生长。为此,从酸奶油中分离的乳酸菌系肠系膜Leuconostoc mesenteroides 67-1、植物乳杆菌60-1和婴儿链球菌46-3在四种不同初始pH的培养基中培养,以确定其最佳生长pH。通过菌落形成单位(CFU/ml)的测定来评估其生长。我们发现每种乳酸菌的生长都受到培养基pH的影响。我们确定肠系膜芽孢杆菌67-1、婴儿链球菌46-3和植物乳杆菌60-1的pH设定点分别为4.5(±0.5)、5.5(±0.5)和6.0(±0.5)。由此可见,这些LAB菌株的生长是ph依赖性的(p < 0.05)。
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引用次数: 3
Product of deferred Cesàro and deferred weighted statistical probability convergence and its applications to Korovkin-type theorems 延迟Cesàro与延迟加权统计概率收敛的乘积及其在Korovkin型定理中的应用
Q2 Multidisciplinary Pub Date : 2020-10-27 DOI: 10.11144/JAVERIANA.SC25-3.PODC
B. Jena, S. K. Paikray
In the present work, we introduce and study the notion of statistical probability convergence for sequences of random variables as well as the idea of statistical convergence for sequences of real numbers, which are defined over a Banach space via the product of deferred Cesàro and deferred weighted summability means. We first establish a theorem presenting aconnection between them. Based upon our proposed methods, we then prove a Korovkin-type approximation theorem with algebraic test functions for a sequence of random variables on a Banach space, and demonstrate that our theorem effectively extends and improves most (if not all) of the previously existing results (in classical as well as in statistical versions). Furthermore, an illustrative example is presented here by means of the generalized Meyer–König and Zeller operators of a sequence of random variables in order to demonstrate that our established theorem is stronger than its traditional and statistical versions. Finally, we estimate the rate of the product of deferred Cesàro and deferred weighted statistical probability convergence, and accordingly establish a new result.
在本文中,我们引入并研究了随机变量序列的统计概率收敛的概念以及实数序列的统计收敛的概念,这些概念是通过延迟Cesàro和延迟加权可和性均值的乘积在Banach空间上定义的。我们首先建立了一个定理来表示它们之间的联系。基于我们提出的方法,我们用代数检验函数证明了Banach空间上随机变量序列的Korovkin型近似定理,并证明了我们的定理有效地扩展和改进了大多数(如果不是全部的话)先前存在的结果(在经典和统计版本中)。此外,本文通过随机变量序列的广义Meyer–König和Zeller算子给出了一个例证,以证明我们建立的定理比其传统和统计版本更强。最后,我们估计了延迟Cesàro和延迟加权统计概率乘积的收敛速度,并据此建立了一个新的结果。
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引用次数: 7
Gut bacteria comparison between wild and captive neotropical otters 野生和圈养新热带水獭肠道细菌的比较
Q2 Multidisciplinary Pub Date : 2020-10-02 DOI: 10.11144/JAVERIANA.SC25-2.GBCB
Johanna Santamaría-Vanegas, L. C. Rodríguez-Rey
The neotropical otter (Lontra longicaudis) is considered a flagship species for the conservation of the ecosystems in which it resides and is currently in a vulnerable state. As a conservation strategy for this species, rehabilitation, breeding, and reintroduction programs of captive individuals have been proposed. However, it is likely that the environment and feeding conditions in captivity result in gut microbial communities that differ from those in wild animals. Gut microbial communities have an important role in the physiological performance of an animal. To determine differences between gut microbial communities of otters in wild and captive living conditions, the structure and diversity of their gut bacterial communities were determined using 16S rDNA molecular markers. Total DNA was isolated from fecal samples of wild animals from the La Vieja River basin and from captive animals in the Cali Zoo. As expected, the gut bacterial communities of captive animals converged to a more similar structure, and their bacterial diversity was significantly lower than that found in wild animals.
新热带水獭(Lontra longicaudis)被认为是保护其所在生态系统的旗舰物种,目前处于脆弱状态。作为该物种的保护策略,已经提出了圈养个体的恢复、繁殖和再引入计划。然而,圈养环境和饲养条件可能导致肠道微生物群落与野生动物不同。肠道微生物群落对动物的生理性能具有重要作用。为了确定野生和圈养条件下水獭肠道微生物群落的差异,采用16S rDNA分子标记测定了水獭肠道细菌群落的结构和多样性。从拉维耶哈河流域野生动物的粪便样本和卡利动物园圈养动物的粪便样本中分离出总DNA。正如预期的那样,圈养动物的肠道细菌群落向更相似的结构趋同,其细菌多样性明显低于野生动物。
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引用次数: 1
Biogenic amines in rainbow trout, tilapia, and cachama fish, available for consumption in Nariño, southern Colombia 虹鳟鱼、罗非鱼和梭鱼中的生物胺,可在哥伦比亚南部Nariño消费
Q2 Multidisciplinary Pub Date : 2020-09-28 DOI: 10.11144/javeriana.sc25-2.bair
J. Lozada-Castro, David Arturo-Perdomo, Angie Pardo-Rueda
Biogenic amines (BAs) are low molecular weight nitrogenous compounds, formed by the breakdown of proteins in highly perishable food products such as fish. BAs can affect human health and are associated with cases of food poisoning. The formation of Bas such as histamine, putrescine, and tyramine were determined, via Process Analytical Chemistry (PAC), in three species of freshwater fish available in markets of city of Pasto in southern Colombia: rainbow trout, tilapia, and cachama. We evaluated the formation of BAs during the fish conservation processes and considered a multifactorial design with two levels. The factors studied were: fish species, slaughter type, storage temperature, and time to purchase. Out of the three fish species studies, tilapia samples revealed the highest average content of putrescine and histamine, with values of 5.4 µg/g and 10.04 µg/g, respectively. Tyramine was not detected in any of the experiments performed. The observed values of BAs in the samples analyzed were below locally tolerated maximal values and the European standard (200 µg/g). However, their presence reveals that factors such as sample storage temperature and time to consumption triggered their formation.
生物胺(BAs)是一种低分子量的含氮化合物,由鱼类等极易腐烂的食品中的蛋白质分解形成。ba会影响人体健康,并与食物中毒有关。通过过程分析化学(PAC)方法,对哥伦比亚南部帕斯托市市场上的三种淡水鱼:虹鳟鱼、罗非鱼和梭鱼的组胺、腐胺和酪胺等Bas的形成进行了测定。我们评估了鱼类保护过程中ba的形成,并考虑了两个水平的多因子设计。研究的因素有:鱼种、屠宰类型、储存温度和购买时间。在三种鱼类中,罗非鱼样本的腐胺和组胺平均含量最高,分别为5.4µg/g和10.04µg/g。在所有的实验中都没有检测到酪胺。分析样品中BAs的观测值低于当地耐受最大值和欧洲标准(200µg/g)。然而,它们的存在表明,样品储存温度和消耗时间等因素触发了它们的形成。
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引用次数: 0
Chemical synthesis and steady state characterization of a nanocrystalline lithium cobalt oxide 纳米晶锂钴氧化物的化学合成及稳态表征
Q2 Multidisciplinary Pub Date : 2020-06-16 DOI: 10.11144/javeriana.sc25-2.csas
J. Gómez-Cuaspud, A. Y. Neira-Guio, E. Vera-López, Luís C. Canaría-Camargo
Lithium cobalt oxide (LiCoO2) is one of the most relevant components in lithium-ion batteries. The array of sought-after features of LiCoO2 depends on its synthesis method. In this work we synthesized and characterized a nanocrystalline LiCoO2 oxide obtained with a wet chemistry synthesis method. The oxide obtained was a homogeneous powder in the nanometric range (5-8 nm) and exhibited a series of improved properties. Characterization by FTIR and UV-Vis techniques led to identifying citrate species as main products in the first step of the synthesis process. X-ray diffraction (XRD), Raman, and transmission electron microscopy (TEM) characterizations led to identifying a pure crystalline phase of the synthesized LiCoO2 oxide. Steady state electrical characterization and solid-state impedance spectroscopy determined the high conductance of the synthesized oxide. All these features are desirable in the design of cathodes for lithium ion batteries.
锂钴氧化物(LiCoO2)是锂离子电池中最相关的成分之一。LiCoO2备受追捧的特征阵列取决于其合成方法。在本工作中,我们合成并表征了通过湿法化学合成方法获得的纳米晶体LiCoO2氧化物。所获得的氧化物是纳米范围(5-8nm)内的均匀粉末,并表现出一系列改进的性能。通过FTIR和UV-Vis技术进行表征,确定柠檬酸盐物种是合成过程第一步的主要产物。X射线衍射(XRD)、拉曼和透射电子显微镜(TEM)表征导致鉴定合成的LiCoO2氧化物的纯晶相。稳态电学表征和固态阻抗谱确定了合成氧化物的高电导。所有这些特征在锂离子电池阴极的设计中都是合乎需要的。
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引用次数: 0
Existence of local and global solution for a spatio-temporal predator-prey model 一类时空捕食者-猎物模型的局部解和全局解的存在性
Q2 Multidisciplinary Pub Date : 2019-12-06 DOI: 10.11144/javeriana.sc24-3.eola
Ricardo Cano-Macias, Jorge Mauricio Ruiz-Vera
In this paper we prove the existence and uniqueness of weak solutions for a kind of Lotka–Volterra system, by using successive linearization techniques. This approach has the advantage to treat two equations separately in each iteration step. Under suitable initial conditions, we construct an invariant region to show the global existence in time of solutions for the system. By means of Sobolev embeddings and regularity results, we find estimates for predator and prey populations in adequate norms. In order to demonstrate the convergence properties of the introduced method, several numerical examples are given.
本文利用连续线性化技术证明了一类Lotka-Volterra系统弱解的存在唯一性。这种方法的优点是在每个迭代步骤中分别处理两个方程。在适当的初始条件下,构造了一个不变区域来证明系统解在时间上的全局存在性。通过Sobolev嵌入和正则性结果,我们找到了捕食者和猎物种群在适当规范下的估计。为了证明该方法的收敛性,给出了几个数值算例。
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引用次数: 0
A raypath-consistent receiver correction in PS converted wave processing through seismic interferometry: New application for tropical zones 地震干涉测量PS转换波处理中的光路一致性接收器校正:热带地区的新应用
Q2 Multidisciplinary Pub Date : 2019-12-05 DOI: 10.11144/javeriana.sc24-3.arcr
A. Salamanca, Luis Montes-Vides
The estimation of static corrections is an issue still unsolved for PS converted wave processing. Due to the PS converted wave usually arriving at the surface at non-zero angles, the surface consistent approach is no longer valid, and corrections become non-stationary, i.e. the correction is not static. Seismic interferometry is used in receiver gathers transformed to the radial domain to estimate functions that contain the delay caused by the weathered layer, considering the emergence angle of the PS converted wave. Inverse filters, derived from these functions, are applied by convolution to the raw traces to supply traces corrected for weathering layer effects. Seismic interferometry was satisfactorily tested in two synthetic models and then applied to a 2C seismic line from the Llanos Basin (Colombia). This is the first application of the technique in Colombia, initially developed for permafrost zones, with different assumptions and surface complexity; and it resulted in an improved PS converted wave image.
静校正估计是PS转换波处理中尚未解决的问题。由于PS转换波通常以非零角度到达地表,因此地表一致性方法不再有效,校正变得非平稳,即校正不是静态的。考虑PS转换波的出射角,将接收道集变换到径向域,采用地震干涉法估计包含风化层延迟的函数。由这些函数导出的反滤波器通过卷积应用于原始痕迹,以提供对风化层效果进行校正的痕迹。在两个合成模型中对地震干涉测量进行了令人满意的测试,然后将其应用于哥伦比亚Llanos盆地的2C地震线。这是该技术在哥伦比亚的首次应用,最初是为永冻土带开发的,具有不同的假设和地表复杂性;它产生了一个改进的PS转换波图像。
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引用次数: 1
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