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Inconel 718-CoCrMo bimetallic structures through directed energy deposition-based additive manufacturing 利用定向能沉积技术制备Inconel 718-CoCrMo双金属结构
Pub Date : 2022-09-27 DOI: 10.18063/msam.v1i3.18
Cory Groden, V. Champagne, S. Bose, A. Bandyopadhyay
Bimetallic structures and coatings through additive manufacturing (AM) have demonstrated a high degree of freedom for tailoring properties depending on the application. In this study, Inconel 718 and CoCrMo were used as both are common alloys and exhibit unique properties, such as high-temperature oxidation, wear, and fatigue resistance. Using directed energy deposition-based metal AM, bimetallic structures containing these two alloys were manufactured, and the resulting structures exhibited no intermetallic phase formation, cracking, or porosity. Scanning electron microscopy and energy dispersive spectroscopy revealed a smooth elemental transition between the two compositions. Hardness testing showed a linear transition in the interfacial zone, validating no brittle intermetallic phase formation. Compression testing and fracture surface analysis revealed that the failures were not dependent on the interface properties. High-temperature oxidation showed no distinct effect on the interface, a firmly attached chromium oxide layer on the Inconel 718 side and a loosely attached chromium oxide layer on the CoCrMo side. There was also evidence of pit formation on the Inconel 718 surface, but not on the CoCrMo. These findings confirm a stable bimetallic system in which one of the two alloys can be used on the other material to improve the structure’s high-temperature oxidation or wear/corrosion resistance.
通过增材制造(AM)的双金属结构和涂层已经证明了根据应用定制性能的高度自由。在本研究中,使用了Inconel 718和CoCrMo,因为它们都是常见的合金,具有独特的性能,如高温氧化,耐磨和抗疲劳。利用定向能沉积金属增材制造技术,制造出了含有这两种合金的双金属结构,所得到的结构没有金属间相形成、开裂或孔隙。扫描电子显微镜和能量色散光谱显示了两种成分之间的平滑元素转变。硬度测试显示界面区呈线性转变,证实未形成脆性金属间相。压缩试验和断口分析表明,破坏与界面特性无关。高温氧化对界面的影响不明显,在Inconel 718侧形成牢固的氧化铬层,在CoCrMo侧形成松散的氧化铬层。在Inconel 718表面也有凹坑形成的证据,但在CoCrMo上没有。这些发现证实了一种稳定的双金属体系,其中两种合金中的一种可以用于另一种材料上,以提高结构的高温氧化或耐磨损/耐腐蚀性。
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引用次数: 4
Optimizing of chemical admixtures for 3D printable cementitious materials by central composite design 用中心复合设计优化3D打印胶凝材料的化学外加剂
Pub Date : 2022-09-21 DOI: 10.18063/msam.v1i3.16
Mingyang Li, Yiwei Weng, Zhixin Liu, Dong Zhang, T. Wong
Printability of 3D printable cementitious materials is related to material rheological properties, and is affected and controlled by modern concrete chemical admixtures. In this work, the influence of several chemical admixtures including superplasticizer, retarder, and accelerator on the rheological characteristics of printable materials was investigated using central composite design (CCD). Twenty test points with varying dosages of chemical admixtures were performed to evaluate the primary effects of chemical admixtures and their combined interactive effects on the rheological properties. The results indicate that with the increase of retarder or superplasticizer dosage, all rheological parameters decrease while accelerator possesses an opposite impact. The rheological properties are negatively proportional to the combined interactive effect of retarder and accelerator. The combined interactive effect of retarder and superplasticizer positively affects dynamic yield stress, plastic viscosity, and thixotropy, while it negatively impacts static yield stress. The combined interactive effect of accelerator and retarder positively affects the yield stress, whereas it negatively influences the plastic viscosity and thixotropy. The results indicate that the CCD is an efficient method to find the desirable formulation within a given boundary.
3D可打印胶凝材料的可打印性与材料流变特性有关,受现代混凝土化学外加剂的影响和控制。本文采用中心复合设计(CCD)研究了几种化学外加剂(包括高效减水剂、缓凝剂和促进剂)对可印刷材料流变特性的影响。在20个试验点进行了不同剂量的化学外加剂的试验,以评估化学外加剂对流变性能的主要影响及其综合相互作用。结果表明,随着缓凝剂和高效减水剂用量的增加,各流变性参数均降低,而促进剂的影响相反。其流变性能与缓速剂和加速剂的共同作用成反比。缓速剂和高效减水剂的联合作用对动态屈服应力、塑性粘度和触变性有积极影响,而对静态屈服应力有消极影响。促进剂和缓速剂的共同作用对屈服应力有积极影响,而对塑性粘度和触变性有消极影响。结果表明,CCD是在给定边界内寻找理想公式的有效方法。
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引用次数: 0
Biodegradable materials: Foundation of transient and sustainable electronics 可生物降解材料:瞬态和可持续电子学的基础
Pub Date : 2022-09-21 DOI: 10.18063/msam.v1i3.15
M. Monisha, S. Agarwala
Biodegradable materials are designed to degrade in a desired time either through the action of microorganisms or under certain physical conditions. The driving force behind the rise of biodegradable materials is the growing problem of electronic waste (e-waste), low recyclability, and toxicity of electronic materials. Transient response of biodegradable materials has found application in next-generation health-care and biomedical devices. Advances in material science and manufacturing technique have pushed the envelope of innovation further. This review discusses different biodegradable material classes that have emerged to replace the traditional non-biodegradable materials in electronics. Focus has been given to conversion of biodegradable materials to inks and pastes that find use in printed electronics to create flexible, bendable, soft, and degradable devices. Material degradation behavior and dissolution chemistries have been illustrated to understand their impact on electrical performance of devices. Finally, some short-term and long-term challenges are pointed out to overcome the commercialization barrier.
可生物降解材料被设计为通过微生物的作用或在一定的物理条件下在所需的时间内降解。生物可降解材料兴起的驱动力是日益严重的电子垃圾(e-waste)问题、低可回收性和电子材料的毒性。生物可降解材料的瞬态响应在下一代医疗保健和生物医学设备中得到了应用。材料科学和制造技术的进步推动了创新的进一步发展。本文综述了近年来出现的各种生物可降解材料,以取代传统的非生物可降解材料。重点是将生物可降解材料转化为印刷电子产品中使用的油墨和糊状物,以创造柔性,可弯曲,柔软和可降解的设备。材料的降解行为和溶解化学已经说明,以了解他们对设备的电气性能的影响。最后,指出了克服商业化障碍的短期和长期挑战。
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引用次数: 3
Preparation of polyamide 6 and its titanium dioxide photocatalytic composite powders for laser powder bed fusion 激光粉末床熔融用聚酰胺6及其二氧化钛光催化复合粉体的制备
Pub Date : 2022-08-24 DOI: 10.18063/msam.v1i3.14
Peng Chen, Zhaoqing Li, Shengyao Liu, Jin Su, Haoze Wang, Lei Yang, C. Yan, Yusheng Shi
Laser powder bed fusion (LPBF) additive manufacturing is an effective method to prepare three-dimensional ordered network titanium dioxide (TiO2) photocatalytic materials, therefore enhancing the absorption intensity of incident light and improving the photocatalytic efficiency. However, TiO2 is difficult to be directly sintered by LPBF due to the high melting point and brittleness. In this study, we prepared a polyamide 6 (PA6)-coated TiO2 photocatalytic composite powder for LPBF based on the dissolution precipitation polymer coating (DPPC) method and evaluated its LPBF processability. In the precipitation process of PA6, there was a significant crystallization exotherm with temperature recovery. Effective temperature control of this precipitation process had a significant effect on the morphology and particle size distribution of the precipitated powder. The increase of the dissolved concentration of PA6 to 150 g/L produced an obvious temperature gradient of the reactor, resulting in a wide particle size distribution and a powder with a characteristic porous surface. The prepared PA6/TiO2 composite powder presents a near-spherical porous-surfaced morphology, a high specific surface area of 240.5 m2/kg, an appropriate Dv(50) of 48.8 μm, and a wide sintering window of 26.6°C, indicating a good LPBF processability and potential of the photocatalytic application.
激光粉末床熔融(LPBF)增材制造是制备三维有序网络二氧化钛(TiO2)光催化材料的有效方法,可以增强入射光的吸收强度,提高光催化效率。然而,TiO2由于熔点高、脆性大,很难直接用LPBF烧结。本研究基于溶解沉淀聚合物涂层(DPPC)方法制备了聚酰胺6 (PA6)包被TiO2光催化复合粉末用于LPBF,并对其LPBF的可加工性进行了评价。在PA6的沉淀过程中,存在明显的结晶放热,且温度恢复。有效的温度控制对沉淀粉末的形貌和粒度分布有显著影响。当PA6的溶解浓度增加到150 g/L时,反应器温度梯度明显,粒径分布较宽,粉体表面具有多孔性特征。制备的PA6/TiO2复合粉体具有近球形多孔表面形貌,比表面积高达240.5 m2/kg,合适的Dv(50)为48.8 μm,烧结窗口为26.6℃,具有良好的LPBF加工性能和光催化应用潜力。
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引用次数: 4
Process study for directed energy deposition of 316L stainless steel with TiB2 metal matrix composites TiB2金属基复合材料定向能沉积316L不锈钢的工艺研究
Pub Date : 2022-06-29 DOI: 10.18063/msam.v1i2.13
Yao Ting Ang, S. Sing, J. Lim
In addition to laser powder bed fusion, directed energy deposition (DED) is also gaining interest as an effective metal additive manufacturing technique. Due to its system configuration, it is more efficient and flexible for materials development. Therefore, it can be used for processing of metal matrix composites (MMCs) through the use of powder mixture as feedstock. 316L stainless steel has high corrosion resistance, biocompatibility, and ductility. Several studies have shown the feasibility of using DED to process 316L stainless steel. The material properties of 316L stainless steel can be improved using reinforcement particles such as TiB2 to form MMCs. In this study, the effects of process parameters on microstructure and mechanical properties of 316L stainless steel reinforced with TiB2 (316L/TiB2) MMC were studied. The process parameters, including laser power, scanning speed, and hopper speed, were varied and analyzed using Taguchi L9 array. It was found that the process parameters have insignificant effect on the bulk density of the samples produced. Through this study, it is also found that tumble mixing was not suitable for the powder feedstock preparation for MMCs to be processed by DED. The microstructure of DED 316L/TiB2 MMC samples consists of columnar and equiaxed grains. Columnar grains were located within the layers while equiaxed grains were located at the interlayer zones. Fine sub-grains were also observed within these grains and their boundaries were enriched with molybdenum and chromium segregations. Precipitates containing titanium were also observed to segregate at the sub-grain boundaries. Finally, the Vickers microhardness of the DED 316L/TiB2 MMC was found to be similar to pure 316L stainless steel produced by DED.
除了激光粉末床熔合,定向能沉积(DED)作为一种有效的金属增材制造技术也引起了人们的兴趣。由于其系统配置,使得材料开发更加高效和灵活。因此,它可以通过使用粉末混合物作为原料来加工金属基复合材料(MMCs)。316L不锈钢具有很高的耐腐蚀性、生物相容性和延展性。几项研究表明,使用DED加工316L不锈钢是可行的。利用TiB2等增强颗粒形成mmc可以改善316L不锈钢的材料性能。研究了工艺参数对TiB2 (316L/TiB2) MMC增强316L不锈钢组织和力学性能的影响。采用田口L9阵列对激光功率、扫描速度、料斗速度等工艺参数进行了变化分析。结果表明,工艺参数对样品的容重影响不显著。通过本研究还发现,转鼓混合并不适合用于DED处理的mmc的粉末原料制备。DED 316L/TiB2 MMC样品的显微组织由柱状和等轴晶组成。柱状晶粒位于层内,等轴晶粒位于层间。晶粒内部还存在细小的亚晶,其边界富集了钼和铬的偏析。含钛析出物在亚晶界处也有偏析。最后,发现DED 316L/TiB2 MMC的维氏显微硬度与DED生产的纯316L不锈钢相似。
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引用次数: 13
Cold spray additive manufacturing of copper-based materials: Review and future directions 铜基材料的冷喷涂增材制造:回顾与未来方向
Pub Date : 2022-06-27 DOI: 10.18063/msam.v1i2.12
V. Menon, Clodualdo Aranas Jr., G. Saha
The cold gas dynamic spray process is a manufacturing process strategically designed for coatings. The conditions for the deposition of materials to form coatings have evolved over several decades. Copper and copper-based cold spray coatings are an interesting field for investigation, as it has substantial commercial demand and acceptance. Several important works have already been performed in this regard that shows the immense popularity of its applications in power industries. Cold gas dynamic spray, being an economic process, can produce coatings with superior quality and low oxidation. In this paper, a particular focus has been given to copper-based cold spray coatings along with their deposition parameters. The various mechanical, electrical, corrosion, and tribological properties of these copper-based cold spray coatings are commendable and economically lucrative. A good amount of experimental data has also been included in this review article to provide comprehensive information and future scope of research about copper-based cold spray coatings.
冷气体动态喷涂工艺是一种针对涂料设计的工艺。材料沉积形成涂层的条件已经发展了几十年。铜和铜基冷喷涂涂料是一个有趣的研究领域,因为它有大量的商业需求和接受度。在这方面已经进行了几项重要的工作,表明其在电力工业中的应用非常受欢迎。冷气动态喷涂是一种经济的喷涂工艺,可以生产出高质量、低氧化的涂料。本文重点研究了铜基冷喷涂涂层及其沉积参数。这些铜基冷喷涂涂层的各种机械、电气、腐蚀和摩擦学性能是值得称赞的,而且经济上有利可图。本文还介绍了大量的实验数据,为铜基冷喷涂涂料的研究提供了全面的信息和未来的研究方向。
{"title":"Cold spray additive manufacturing of copper-based materials: Review and future directions","authors":"V. Menon, Clodualdo Aranas Jr., G. Saha","doi":"10.18063/msam.v1i2.12","DOIUrl":"https://doi.org/10.18063/msam.v1i2.12","url":null,"abstract":"The cold gas dynamic spray process is a manufacturing process strategically designed for coatings. The conditions for the deposition of materials to form coatings have evolved over several decades. Copper and copper-based cold spray coatings are an interesting field for investigation, as it has substantial commercial demand and acceptance. Several important works have already been performed in this regard that shows the immense popularity of its applications in power industries. Cold gas dynamic spray, being an economic process, can produce coatings with superior quality and low oxidation. In this paper, a particular focus has been given to copper-based cold spray coatings along with their deposition parameters. The various mechanical, electrical, corrosion, and tribological properties of these copper-based cold spray coatings are commendable and economically lucrative. A good amount of experimental data has also been included in this review article to provide comprehensive information and future scope of research about copper-based cold spray coatings.","PeriodicalId":422581,"journal":{"name":"Materials Science in Additive Manufacturing","volume":"2016 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127432417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Multi-objective optimization of intense pulsed light sintering process for aerosol jet printed thin film 强脉冲光烧结气溶胶喷射打印薄膜工艺的多目标优化
Pub Date : 2022-06-22 DOI: 10.18063/msam.v1i2.10
G. L. Goh, Haining Zhang, G. D. Goh, W. Yeong, T. H. Chong
The sintering of printed nanoparticle films is a necessary processing step for most nanoparticle inks to make the printed film functional. The sintering of nanoparticle is usually performed through thermal sintering, photonic sintering, induction sintering, etc. Intense pulsed light (IPL) sintering method is one of the most popular sintering methods for nanoparticle inks due to the fast and effective process, but it may yield mediocre performance if improper sintering parameters are used. In this work, we investigate the correlation between the two factors which are the print passes of aerosol jet printing and the sintering distance of the samples on the effect of the surface morphology and sheet resistance. A contradictory correlation between the two factors was observed and a multi-objective optimization was carried out using machine learning method to identify the most optimum conditions for both factors. We found that multi-objective optimization approach is effective in reducing the conflicting responses, thus the sintered thin film can have low sheet resistance and low surface roughness. This work provides an essential guide for achieving conductive films with electrical conductivity and low surface roughness using IPL sintering process for fast fabrication of multi-layered electronics such as electrochemical electrodes.
打印纳米颗粒薄膜的烧结是大多数纳米颗粒油墨实现打印薄膜功能的必要工艺步骤。纳米颗粒的烧结通常通过热烧结、光子烧结、感应烧结等方式进行。强脉冲光(IPL)烧结工艺快速有效,是纳米颗粒油墨最常用的烧结方法之一,但如果烧结参数选择不当,烧结效果一般。在本工作中,我们研究了气溶胶喷射打印的打印通道和样品的烧结距离两个因素对表面形貌和片材电阻的影响。观察到这两个因素之间的矛盾相关性,并利用机器学习方法进行多目标优化,以确定这两个因素的最优条件。研究发现,多目标优化方法可以有效地减少相互冲突的响应,从而使烧结薄膜具有低片阻和低表面粗糙度。这项工作为利用IPL烧结工艺实现具有导电性和低表面粗糙度的导电膜,用于快速制造多层电子器件(如电化学电极)提供了重要的指导。
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引用次数: 3
Influence of powder morphology on laser absorption behavior and printability of nanoparticle-coated 90W-Ni-Fe powder during laser powder bed fusion 粉末形貌对纳米包覆90W-Ni-Fe粉末激光吸收性能和可打印性的影响
Pub Date : 2022-06-14 DOI: 10.18063/msam.v1i2.11
Jing Sun, M. Guo, Keyu Shi, D. Gu
In this work, mesoscopic simulation and experimental studies were applied to investigate the influence of powder morphology and characteristics on laser absorption behavior and printability of nanoparticle-coated 90W-Ni-Fe powder during laser powder bed fusion (LPBF). The mechanism of laser-material interaction and the thermal behavior of molten fluid during LPBF were revealed, thereby optimizing the powder preparation parameters. It showed that when the powder preparation parameters were optimized (i.e., ball-to-powder weight ratio of 1:2, milling speed of 250 rpm, and milling time of 6 h), the Ni and Fe nanoparticles were uniformly dispersed on W particles and, meanwhile, the sufficiently high sphericity of the W matrix particles was maintained. The nanoparticle-coated 90W-Ni-Fe powder had a sound laser absorption behavior with laser absorptivity of 93.51%, leading to the high LPBF printing quality with a smooth surface free of balling phenomenon and microcracks. Specimen fabricated using optimally prepared powder has a high density of 98% and a low surface roughness of 7.91 μm. The LPBF-processed 90W-Ni-Fe alloys had a uniform hardness distribution with an average value of 439.47 HV1 and significantly enhanced compression properties with compressive strength of 1255.35 MPa and an elongation of 24.74%. The results in this work provided a physical understanding of complex and interdependent laser-powder interaction and melt pool formation mechanisms during LPBF of W-based alloys that are governed by powder characteristics.
本文采用介观模拟和实验研究方法,研究了粉末形貌和特性对纳米颗粒包覆90W-Ni-Fe粉末激光床熔化过程中激光吸收行为和可打印性的影响。揭示了激光与材料相互作用的机理和LPBF过程中熔融流体的热行为,从而优化了粉末制备参数。结果表明,当粉体制备参数优化(球粉比为1:2,铣削速度为250 rpm,铣削时间为6 h)时,Ni和Fe纳米颗粒均匀地分散在W颗粒上,同时W基颗粒保持了足够高的球形度。纳米颗粒包覆的90W-Ni-Fe粉末具有良好的激光吸收性能,激光吸收率高达93.51%,打印质量高,表面光滑,无球化现象和微裂纹。制备的样品密度高达98%,表面粗糙度仅为7.91 μm。经lpbf处理的90W-Ni-Fe合金硬度分布均匀,平均硬度为439.47 HV1,抗压强度为1255.35 MPa,伸长率为24.74%,抗压性能显著提高。这项工作的结果提供了复杂的和相互依赖的激光粉末相互作用和熔池形成机制的物理理解在w基合金的LPBF过程中,由粉末特性控制。
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引用次数: 10
Flexural behavior of 3D printed bio-inspired interlocking suture structures 3D打印仿生联锁缝合结构的弯曲行为
Pub Date : 2022-05-26 DOI: 10.18063/msam.v1i2.9
S. Wickramasinghe, T. Do, P. Tran
Additive manufacturing has allowed producing various complex structures inspired by natural materials. In this research, the bio-inspired suture structure was 3D printed using the fused deposition modeling printing technique to study its bending response behavior. Suture is one of the most commonly found structures in biological bodies. The primary purpose of this structure in nature is to improve flexibility by absorbing energy without causing permeant damage to the biological structure. An interesting discovery of the suture joint in diabolical ironclad beetle has given a great opportunity to further study the behavior of these natural suture designs. Inspired by the elliptical shape and the interlocking features of this suture, specimens were designed and 3D printed using polylactic acid thermoplastic polymer. A three-point bending test was then conducted to analyze the flexural behavior of each suture design, while digital image correlation and numerical simulation were performed to capture the insights of deformation process.
受天然材料的启发,增材制造可以制造出各种复杂的结构。在本研究中,采用熔融沉积建模打印技术对仿生缝合结构进行3D打印,研究其弯曲响应行为。缝线是生物体内最常见的结构之一。这种结构在自然界中的主要目的是通过吸收能量来提高灵活性,而不会对生物结构造成潜在的损害。一个有趣的发现,在恶魔铁甲甲虫缝合线关节为进一步研究这些自然缝合线设计的行为提供了很好的机会。受椭圆形状和这种缝合线的互锁特征的启发,使用聚乳酸热塑性聚合物设计和3D打印样品。然后进行三点弯曲试验,分析每种缝线设计的弯曲行为,同时进行数字图像相关和数值模拟,以捕捉变形过程的见解。
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引用次数: 8
Editors’ foreword to the inaugural issue of Materials Science in Additive Manufacturing 《增材制造中的材料科学》创刊号的编辑前言
Pub Date : 2022-03-30 DOI: 10.18063/msam.v1i1.2
C. Chua, S. Sing
From rapid prototyping to additive manufacturing (AM), as it is formally known today, the development of these advanced manufacturing techniques has been complemented with rapid research and innovations in materials science. The requirements for appropriate process and the selection of suitable materials that can be processed by this process are critical for AM applications. As AM matures, specific classes of material have become associated with their corresponding AM processes and applications. Conventionally, AM materials include metals[1], polymers[2], and ceramics[3,4] that have been applied to manufacturing functional parts in high-value industries such as biomedical and aerospace. With recent advancements, biomaterials such as living cells and tissues for 3D bioprinting[5,6] and even edible materials for 3D food printing[7,8] have garnered significant attention. Development of these materials are still ongoing, which drives new frontiers in AM, such as multi-material 3D printing[9-12], artificial intelligence for material design[13], and 4D printing, which incorporate the use of smart materials[14,15].
从快速原型制造到增材制造(AM),这些先进制造技术的发展与材料科学的快速研究和创新相辅相成。对于增材制造的应用来说,合适的工艺要求和选择合适的材料是至关重要的。随着增材制造的成熟,特定类别的材料已经与其相应的增材制造工艺和应用相关联。传统上,增材制造材料包括金属[1]、聚合物[2]和陶瓷[3,4],这些材料已应用于制造生物医学和航空航天等高价值行业的功能部件。随着最近的进展,生物材料,如用于3D生物打印的活细胞和组织[5,6],甚至用于3D食品打印的可食用材料[7,8]都受到了极大的关注。这些材料的开发仍在进行中,这推动了增材制造的新领域,如多材料3D打印[9-12],材料设计的人工智能[13],以及包含智能材料使用的4D打印[14,15]。
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引用次数: 0
期刊
Materials Science in Additive Manufacturing
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