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Fracture Toughness Behavior of Welded Service Aged Carbon Steels in Mildly Sour Waters 焊接使用时效碳钢在轻度酸性水域中的断裂韧性行为
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-85807
B. C. Rollins, J. Penso
Cracking of steels in refinery H2S service occurs in two regimes: 1) low pH and 2) high pH. Cracking in the low pH regime (pH < 6 or 7) is associated with ingress of hydrogen from metal dissolution with H2S poisoning the hydrogen recombination reaction. In the high pH regime (pH > 7), cracking requires the presence of species other than just H2S. While this has been a subject of interest since the failure of an amine absorber tower in 1984, limited laboratory testing has been conducted in either regime. The majority of test data that does exist was from studies conducted in more aggressive environments, such as NACE A or NACE B solutions. Additionally, most of the work was conducted on more modern steels rather than service aged of vintage steel. The lack of available data inhibits the ability to perform fitness for service (FFS) assessments without using overly conservative approaches. A recent test program was undertaken to evaluate the fracture toughness properties of the weld heat-affected zone (HAZ) of an ex-service steel in mildly acidic sour water environments more typical of the downstream refining industry. The results of the test program, including the test environment and approach are discussed. In addition to the test program, the current state of understanding sour water cracking is reviewed relative to both the low pH and high pH regimes. The gaps in the current knowledge are discussed.
在炼油厂H2S服务中,钢的开裂发生在两种情况下:1)低pH和2)高pH。在低pH条件下(pH < 6或7)的开裂与氢从金属溶解中进入有关,H2S中毒氢复合反应。在高pH条件下(pH > 7),裂解不仅需要H2S,还需要其他物质的存在。虽然自1984年胺吸收塔发生故障以来,这一直是一个令人感兴趣的问题,但在这两种制度中都进行了有限的实验室测试。现有的大多数测试数据都来自于在更具侵略性的环境中进行的研究,例如NACE A或NACE B解决方案。此外,大部分工作都是在更现代的钢材上进行的,而不是在老式钢材上进行的。可用数据的缺乏限制了在不使用过于保守的方法的情况下进行服务适应性评估的能力。最近进行了一项测试计划,以评估一种退役钢在较典型的下游炼油行业的弱酸性水环境中的焊接热影响区(HAZ)的断裂韧性特性。讨论了测试程序的结果,包括测试环境和测试方法。除了测试程序,了解酸性水裂解相对于低pH和高pH制度的现状进行了回顾。讨论了当前知识的差距。
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引用次数: 0
Fracture in the Ductile-To-Brittle Transition Region of A Narrow-Gap Alloy 52 and Alloy 52 Dissimilar Metal Weld With Buttering 涂油后窄间隙合金52及异种合金52焊缝韧脆过渡区断裂
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-80690
S. Lindqvist, N. Hytönen, L. Sirkiä, P. Arffman, J. Lydman, Yanling Ge, P. Nevasmaa, Z. Que
The fracture toughness in the ductile-to-brittle transition region is determined for the heat-affected zone (HAZ) adjacent to the fusion boundary between a low alloy steel (LAS) and the weld metal of narrow-gap Alloy 52 dissimilar metal weld (DMW) after 15 000 h of thermal aging at 400 °C and of an Alloy 52 DMW with buttering in reference condition. The fracture toughness testing is done according to ASTM E1921, and fractography and cross-section metallography are applied to characterize the crack paths, crack locations and fracture type. The T0 transition temperature for the DMW with buttering is −117 °C, indicating marginally higher toughness compared to the narrow-gap DMW. The cracks close to the fusion boundary (approximately 200 μm) in both DMWs deviate from the HAZ towards the fusion boundary. The thermal aging treatment of the narrow-gap Alloy 52 DMW does not significantly affect the fracture toughness properties of the fusion boundary. Further research is needed to better understand the lower boundary fracture toughness behavior at approximately 300 μm from the fusion boundary. The results contribute to long-term operation assessment of nuclear power plants, and development of analysis and characterization methods for DMWs related to the effect of crack path and location.
测定了低合金钢(LAS)与窄间隙alloy 52异种金属焊缝(DMW)在400℃热时效15000 h后与参考条件下涂胶的alloy 52 DMW的熔合边界附近的热影响区(HAZ)的韧脆过渡区断裂韧性。根据ASTM E1921进行断裂韧性测试,并应用断口学和断面金相学对裂纹路径、裂纹位置和断裂类型进行表征。涂有黄油的DMW的T0转变温度为- 117℃,与窄间隙DMW相比,韧性略高。在两个DMWs中,靠近熔合边界的裂纹(约200 μm)偏离热影响区向熔合边界方向移动。窄间隙合金52dmw的热时效处理对熔合界断裂韧性的影响不显著。为了更好地了解熔合边界约300 μm处的下边界断裂韧性行为,需要进一步研究。研究结果有助于核电厂的长期运行评估,以及与裂纹路径和位置影响相关的DMWs分析和表征方法的发展。
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引用次数: 2
Thermomechanical Fatigue Initiation in Nuclear Grades of Austenitic Stainless Steel Using Plant Realistic Loading 工厂真实载荷下奥氏体不锈钢核牌号的热机械疲劳引发
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84760
Glenn Trownson, Peter Gill, W. Brayshaw, J. Watson, J. Mann
The effect of a Pressurised Water Reactor (PWR) environment on fatigue life is currently assessed using methods such as NUREG/CR-6909 for initiation and ASME Code Case N809 for crack growth, which may be inherently conservative for certain components, especially when considering plant relevant loading. The thermal shock testing with thick-walled specimens as discussed in this paper allows for more plant relevant loading regimes to be utilised in assessments, incorporating through-wall stress gradients, thick walled test specimens and out-of-phase temperature/strain characteristics. This should lead to improvements in reducing the levels of excess conservatism in current assessment methodologies. The capability of the test facility was first presented in PVP2016-63161 [4]. Since then, significant modifications have been made in order to maximise the achievable strain amplitudes in the thick-walled specimen geometry, alongside minimising typical test durations. This was achieved by maximising the temperature differential between the hot and cold cycles and tuning the cycle length in order to ensure that the cycle is long enough to achieve a target strain amplitude, whilst ensuring that it is not so long as to unreasonably increase test durations. This paper details the results of the thermal shock testing performed to date, the development of accompanying Finite Element Analysis (FEA), preliminary initiation data and the development of the various Non Destructive Testing (NDT) techniques used to detect fatigue crack initiation on the thick-walled specimens. Owing to the long testing times needed to achieve the required cycling, various NDT techniques were developed and employed to confirm the presence of fatigue cracking in the thick-walled test specimens before considering more in-depth characterisation using destructive techniques. Eddy Current Array (ECA) testing has been specifically developed for this testing and uses a 360-degree custom bore probe to conduct non-contact ECA measurements on the inner surface of the test specimens. Calibration blocks containing various sized Electrical Discharge Machining (EDM) notches were used to provide a calibration (amplitude and phase) of eddy current responses for prospective flaw depth sizing from indications. The ECA testing performed has provided indications that fatigue cracking is present within the thick-walled specimens tested and subsequent Visual Testing (VT) was performed to assess the highlighted indications from the ECA testing. The VT methods employed included a video borescope for imaging the inner walls of the specimen. In order to increase the detection capabilities (by improving the contrast) the VT was used in conjunction with fluorescent Dye-Penetrant (fDP) testing, whereby a method was developed for using fDP within the inside bore of the specimen alongside a custom ultraviolet (UV) source to better highlight cracking. This paper discusses the success of the NDT developments and
压水反应堆(PWR)环境对疲劳寿命的影响目前是用NUREG/CR-6909等方法进行评估的,用ASME规范案例N809来评估裂纹扩展,这对某些部件来说可能本质上是保守的,特别是考虑到与工厂相关的负载。本文中讨论的厚壁试样热冲击试验允许在评估中使用更多与工厂相关的加载制度,包括穿壁应力梯度、厚壁试样和相外温度/应变特性。这应导致在减少目前评估方法中过分保守的程度方面有所改进。该测试设施的能力首次在PVP2016-63161中提出[4]。从那时起,为了最大限度地提高厚壁试样几何形状中可实现的应变幅度,同时最小化典型测试持续时间,已经进行了重大修改。这是通过最大化冷热循环之间的温差和调整循环长度来实现的,以确保循环足够长以达到目标应变幅度,同时确保它不会长到不合理地增加测试持续时间。本文详细介绍了迄今为止进行的热冲击试验的结果、伴随的有限元分析(FEA)的发展、初步的起裂数据以及用于检测厚壁试样疲劳裂纹起裂的各种无损检测(NDT)技术的发展。由于需要很长的测试时间来实现所需的循环,在考虑使用破坏性技术进行更深入的表征之前,开发并采用了各种无损检测技术来确认厚壁试件中疲劳裂纹的存在。涡流阵列(ECA)测试是专门为这种测试开发的,它使用360度定制孔探头在测试样品的内表面进行非接触式ECA测量。校准块包含各种尺寸的电火花加工(EDM)缺口,用于根据指示提供涡流响应的校准(幅度和相位),以预测缺陷深度尺寸。进行的ECA测试提供了疲劳开裂的迹象,在测试的厚壁试样中存在疲劳开裂,随后进行视觉测试(VT)来评估ECA测试中突出的迹象。所采用的VT方法包括用于成像标本内壁的视频管镜。为了提高检测能力(通过提高对比度),VT与荧光染料渗透(fDP)测试结合使用,由此开发了一种方法,在样品的内孔内使用fDP和定制的紫外线(UV)源,以更好地突出裂缝。本文讨论了迄今为止NDT开发和测试的成功,并详细介绍了最新的互补裂纹扩展评估工作。
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引用次数: 0
Development of Life Estimation Method for Nozzle Welds in Large Scale Piping of Modified 9Cr-1Mo Steel -Part I: Experimental Study 改性9Cr-1Mo钢大型管道喷嘴焊缝寿命估算方法的发展——第一部分:试验研究
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84220
H. Shigeyama, Yukio Takahashi, K. Tamura, M. Yaguchi, S. Nishinoiri
Type IV creep damage has been frequently reported in longitudinal welds and nozzle welds. Many studies have been conducted on the longitudinal welds, and the applicability of life evaluation by non-destructive testing and numerical analysis has been examined. On the other hand, there are few studies on the nozzle welds, and the applicability of the existing life evaluation method is not clear. In this study, internal pressure creep test and numerical analysis were carried out on a large diameter pipe specimen which has several welded nozzles in order to clarify the applicability of the creep life evaluation method for the nozzle welds. This first report describes the experimental part. The internal pressure creep test at 650°C was performed on the large-diameter pipe specimen of modified 9Cr-1Mo (ASME P91) steel. The test was interrupted three times and nondestructive inspections were performed at each interruption. They included phased array ultrasonic testing, magnetic particle testing and replica observation. The test was completed when the test time reached about 20,000 hours and cross-sectional observations were performed after the specimen was cut into many pieces. Based on these efforts, the location and process of creep damage development in the nozzle welds and the effectiveness of non-destructive inspection were revealed.
IV型蠕变损伤在纵向焊缝和喷嘴焊缝中经常被报道。对纵向焊缝进行了大量的研究,验证了无损检测和数值分析相结合的寿命评估方法的适用性。另一方面,对喷嘴焊缝的研究较少,现有寿命评估方法的适用性不明确。为了阐明该方法在喷嘴焊缝蠕变寿命评估中的适用性,本研究对一个大直径管试件进行了内压蠕变试验和数值分析。第一份报告描述了实验部分。对改性9Cr-1Mo (ASME P91)钢大直径管材试样进行650℃内压蠕变试验。试验中断了三次,每次中断都进行了无损检测。其中包括相控阵超声检测、磁粉检测和复制品观察。当试验时间达到20000小时左右时,完成试验,并将试件切成若干块后进行截面观察。在此基础上,揭示了喷嘴焊缝蠕变损伤发展的位置和过程,以及无损检测的有效性。
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引用次数: 0
Electric-Field-Assisted Diffusion Welding to Fabricate Alloy 617 Compact Heat Exchangers 电场辅助扩散焊制造617合金紧凑型热交换器
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-83842
Xinchang Zhang, R. Rupp, J. Rufner, M. McMurtrey
Compact heat exchangers are of interest for a number of applications including advanced reactors. Alloy 617 is one of the top candidate materials for the gas-cooled reactor intermediate heat exchanger. Previous endeavors to diffusion weld Alloy 617 utilized hot pressing (HP). It was reported that grain boundary migration across the interface was hindered by extensive precipitation. Bonds of this nature have been observed to reduce the elevated-temperature mechanical properties compared to the wrought-product form. It was hypothesized that the electric current applied during electric-field-assisted sintering (EFAS) can overcome these challenges, resulting in improved diffusion welding (DW). This study investigated DW of Alloy 617 via EFAS. Stacks composed of three sheets that were 20 mm in diameter were welded using EFAS. Specimens were welded with an applied electric current, a pressure of 30 MPa, hold time of 30 min, and temperatures of 1050°C, 1100°C, and 1150°C. DW using HP as the zero-current analog of EFAS was also performed at the most promising EFAS conditions. Results revealed that both the applied electric current and temperature played a key role in precipitation and grain boundary migration in diffusion-welded Alloy 617. Precipitates were observed at the interface of the hot-pressed samples which limited grain boundary migration. Electric current was found to prevent precipitate formation along the interface at 1150°C. The electric current coupled with a temperature of 1150°C during EFAS resulted in significant grain boundary migration across the interface.
紧凑型热交换器对包括先进反应堆在内的许多应用都很感兴趣。617合金是气冷堆中间热交换器的首选材料之一。以前对617合金扩散焊的尝试采用热压(HP)。据报道,广泛的沉淀阻碍了晶界在界面上的迁移。这种性质的键已被观察到与锻造产品形式相比,降低了高温机械性能。假设电场辅助烧结(EFAS)过程中施加的电流可以克服这些挑战,从而改善扩散焊接(DW)。采用EFAS法对617合金的DW进行了研究。使用EFAS焊接由三层直径为20毫米的薄板组成的堆叠。焊接试样时施加电流,压力为30 MPa,保温时间为30 min,温度为1050℃、1100℃和1150℃。在最有希望的EFAS条件下,以HP作为EFAS的零电流模拟进行了DW。结果表明,施加的电流和温度对617扩散焊接合金的析出和晶界迁移起关键作用。在热压试样的界面处存在析出物,限制了晶界迁移。在1150°C时,电流可防止沿界面形成沉淀。电火花放电过程中,电流与1150°C的温度耦合导致晶界在界面上发生了明显的迁移。
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引用次数: 0
Complex Lattice Structure-Based Heat Exchangers Through Additive Manufacturing: Opportunities and Challenges 基于增材制造的复杂晶格结构热交换器:机遇与挑战
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84355
Jerome Wong, A. Qureshi, P. Mertiny
Cellular structures are a class of materials that offer greater stiffness, strength-to-weight ratio, good energy absorption capacity, and high heat transfer capability compared to solid parts. Metallic lattice structures have been applied in different industry sectors, such as in biomedical implants, lightweight components, energy absorbers, and catalytic reactors. With the development of advanced manufacturing techniques, especially additive manufacturing (AM), lattice structures with complicated designs can be produced. Lattice structure-based heat exchangers produced by AM techniques have recently gained significant attention due to their promising performance. Interconnected cavities in lattice structures provide flow of fluid and effective thermal conductivity, which is desirable in heat exchangers. AM methods provide the possibility to promote tortuosity and intricate flow patterns leading to improved performance of heat exchangers. Between different AM techniques, laser powder bed fusion (LPBF) proved to be a suitable method for the manufacture of heat exchangers. Using LPBF methods, the distribution and geometry of cavities in the structure can be controlled with an accuracy that is typically better than for other AM methods. Although LPBF-produced heat exchanger showed enhanced thermal conductance, there are limitations associated with LPBF fabrication, such as surface roughness and need for post processing. In order to bridge this gap, the effects of different process parameters and levels of structural complexity in LPBF processes need to be evaluated. In this context, the present contribution constitutes a position paper that contrasts the opportunities that LPBF may provide for the fabrication of heat exchangers with the challenges that need to be overcome to realize design solutions that meet industry demands.
蜂窝结构是一类材料,提供更大的刚度,强度重量比,良好的能量吸收能力,和高传热能力相比,固体部件。金属晶格结构已经应用于不同的工业领域,如生物医学植入物、轻质部件、能量吸收器和催化反应器。随着先进制造技术尤其是增材制造技术的发展,可以制造出具有复杂设计的点阵结构。近年来,基于点阵结构的增材制造换热器因其良好的性能而受到广泛关注。晶格结构中相互连接的空腔提供流体流动和有效的导热性,这在热交换器中是理想的。增材制造方法提供了提高弯曲度和复杂流动模式的可能性,从而提高了热交换器的性能。在不同的增材制造技术中,激光粉末床熔合(LPBF)被证明是一种适合制造换热器的方法。使用LPBF方法,可以以精度控制结构中空腔的分布和几何形状,通常比其他增材制造方法更好。虽然LPBF生产的热交换器表现出增强的导热性,但LPBF制造存在局限性,例如表面粗糙度和后处理的需要。为了弥补这一差距,需要对LPBF工艺中不同工艺参数和结构复杂程度的影响进行评估。在此背景下,本文将对LPBF可能为热交换器制造提供的机会与实现满足工业需求的设计解决方案所需要克服的挑战进行对比。
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引用次数: 0
Development of Predictive Evaluation Methods of Pipe Wall Thinning by Flow Accelerated Corrosion at Drift Region in Junction Piping 结管漂移区流动加速腐蚀减薄管壁预测评价方法的建立
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84566
Shun Watanabe, R. Morita
Flow Accelerated Corrosion (FAC) is a pipe wall thinning phenomenon to be monitored and managed in the power plants with high priority. Its management has been conducted with conservative evaluation of thinning rate, and residual lifetime of piping based on wall thickness measurements. However, noticeable case of the wall thinning occurred in branch and junction piping (T-tube). There is a problem to manage the wall thickness beneath reinforcing plate of the T-tube, because measurement of this area is difficult to be conducted with ordinary ultrasonic testing devices due to the presence of the reinforcing plate. In this study, numerical analysis for the T-tube was conducted, and the wall thinning profile due to the FAC was evaluated by calculating the mass transfer coefficient. It was found that when the flows from the branch pipe and the main pipe merge or diverge, a localized wall thinning distribution occurs in the area where the reinforcement plate of the T-tube exists, and this tendency is affected by Reynolds number. It was suggested that the maximum amount of wall thinning in T-tube can be predicted by the flow rate ratio and the diameter ratio. In the future, we will confirm the effectiveness of the proposed decay function by comparing it with measurements taken in actual plants, and apply it to the management of wall thinning in actual plants.
流动加速腐蚀(FAC)是电厂管壁变薄现象,是电厂管壁监测和治理的重点问题。其管理一直是基于壁厚测量对管道减薄率和剩余寿命进行保守评估。然而,明显的壁变薄情况发生在分支和连接管道(t管)。t管加强板下面的壁厚管理存在问题,因为有加强板的存在,用普通的超声波检测设备很难测量这个区域。本研究对t管进行了数值分析,通过计算传质系数对FAC引起的壁厚变薄剖面进行了评价。研究发现,当支管与主管流动合并或分流时,在t管加强板存在的区域会出现局部壁厚减薄分布,这种趋势受雷诺数的影响。提出了用流量比和径比可以预测t管最大壁厚减薄量的方法。在未来,我们将通过将所提出的衰减函数与实际植物的测量结果进行比较来确认其有效性,并将其应用于实际植物的壁薄管理。
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引用次数: 0
Fatigue Crack Growth Prediction of a Pipe With a Circumferential Surface Flaw Using ΔJ and Reference Stress Method 利用ΔJ和参考应力法预测含周向表面缺陷的管道疲劳裂纹扩展
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84555
Kiminobu Hojo, S. Kumagai
Fatigue crack growth calculation method beyond ΔK in codes and standards, like ASME Sec. XI or JSME rules for Fitness for Service has not been established even in Mode I. In the FDF-II Subcommittee of the nuclear research committee of the Japan Welding Engineering Society, an evaluation procedure for fatigue crack growth beyond small scale yielding using ΔJ has been investigated for several years. Since the evaluation procedure in the Subcommittee is to be incorporated into codes and standards, it should not be complex. Therefore the reference stress approach was tried to apply to calculate J-integral as a simplified procedure. Several formulae for J-integral calculation based on the reference stress approach were proposed by researchers. The authors joined the Subcommittee and performed finite element analyses for a sample problem to confirm the accuracy of those formulae, which were for a pipe with a circumferential part-through wall flaw subjected by bending load. The reference stress-based J, whose accuracy was confirmed by the authors, was applied to predict crack growth behaviors of pipes with a circumferential surface flaw under cyclic bending load conducted by other researches a decade ago. The difference of the failure cycles between the prediction and the experiment were nearly within a factor of 2. Since the verification of the simplified procedure was performed for just one case, more verification cases were needed to incorporate the procedure into codes and standards.
由于小组委员会的评价程序将纳入守则和标准,因此不应过于复杂。因此,尝试将参考应力法作为一种简化方法应用于j积分的计算。研究人员提出了几种基于参考应力法的j积分计算公式。作者参加了小组委员会,并对一个样品问题进行了有限元分析,以证实这些公式的准确性,这些公式是针对弯曲载荷作用下具有周向穿透壁缺陷的管道。基于参考应力的J,其准确性得到了作者的证实,十多年前已有研究将其应用于含周向表面缺陷的管道在循环弯曲载荷下的裂纹扩展行为预测。预测结果与试验结果的失效周期差值在2倍以内。由于简化程序的验证只针对一个案例,因此需要更多的验证案例来将该程序纳入规范和标准。
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引用次数: 0
Combined Effect of Sustained Load and Harsh Environment on E-Glass/Epoxy Composites: Long Term Exposure 持续负荷和恶劣环境对e -玻璃/环氧复合材料的综合影响:长期暴露
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84669
Amir Hussain Idrisi, Abdel Hamid Ismail Mourad
In this work, the durability of the E-glass/epoxy was investigated in terms of degradation in tensile properties and microstructure. Specimens were conditioned in seawater under sustained load and without load at 23 °C, 45 °C and 65 °C for the period of 15 months. The tensile strength of the E-glass/epoxy reduced gradually with immersion time. It reduced by 11% from 811 MPa to 721 MPa and by 18.2% from 811 MPa to 663 MPa for samples immersed without load and with 15% sustained load respectively. The respective reduction for 23°C and 45°C was 1.1% and 5.5% for samples without load and 6.2% and 11.3% for samples immersion under 15% sustained load after 15 months of exposure. The failure strain of E-glass/epoxy composite was slightly affected for the samples immersed without load during the period of 15 months but it was more noticeable under 15% sustained load at 65°C when the tensile strain reduced to 1.65% after 15 months of immersion. Furthermore, Scanning Electron Microscopy (SEM) analysis was conducted to evaluate the degradation of fiber matrix interface. Results revealed that moisture, temperature and sustained load have a deteriorative impact on the performance of the composite.
在这项工作中,从拉伸性能和微观结构的退化方面研究了e -玻璃/环氧树脂的耐久性。在23°C、45°C和65°C的海水中进行持续加载和无加载,为期15个月。e -玻璃/环氧树脂的抗拉强度随浸泡时间的延长而逐渐降低。在无荷载和15%持续荷载作用下,试样从811 MPa降至721 MPa降低11%,从811 MPa降至663 MPa降低18.2%。在23°C和45°C条件下,无负荷的样品分别减少1.1%和5.5%,在15个月的持续负荷下浸泡的样品分别减少6.2%和11.3%。在15个月的时间里,e -玻璃/环氧复合材料的破坏应变受到了轻微的影响,但在65°C 15%的持续载荷下,这种影响更为明显,15个月的浸渍后拉伸应变降至1.65%。此外,通过扫描电镜(SEM)分析了纤维基体界面的降解情况。结果表明,湿度、温度和持续载荷对复合材料的性能有不利影响。
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引用次数: 1
Mechanical Properties and Metallurgical Examination Results for a Batch of Powder Metallurgy - Hot Isostatically Pressed Low Alloy Steel Grade 508 4N 5084n级热等静压低合金钢粉末冶金机械性能和冶金检验结果
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-85077
D. Stewart, J. Sulley, T. Warner, P. Wallace, G. Jones, D. Thatcher
This paper presents the work conducted by Rolls-Royce to investigate the mechanical and metallurgical properties of a Low Alloy Steel (LAS) grade 508 alloy batch of material. The material was manufactured using the Powder Metallurgy – Hot Isostatic Pressing (PM-HIP) method. The LAS was an ASME 508 4N model alloy. Rolls-Royce has used PM-HIP extensively for the manufacture of nuclear grade components such as valves, piping and pump bowls, and is now investigating its use for the manufacture of LAS pressure vessels in order to provide an alternative sourcing route to forgings to reduce costs and manufacturing lead-times. A key part of this work is to assess whether mechanical properties can be achieved that meet the specification requirements and that are also comparable to the forged equivalent. In this regard, the toughness of the material is of particular interest, with it being extremely important for LAS pressure vessel applications. This paper reports, that for this particular batch of material, the Charpy toughness was significantly below the minimum room temperature specification requirement, but that the tensile properties were well above the minimum specification requirements for proof and ultimate tensile strength. The Charpy toughness at room temperature was only at 38% of the specification requirement, and only at 21% of forged equivalent material. The reason for the poor Charpy results is potentially attributed to prior austenite retention given the highly faceted nature of the fracture faces and the size of the facet faces. Oxides and other precipitates, such as nitrides, are not believed to have significantly contributed to the low Charpy values in this powder batch. This is because inclusion assessments against other powder HIP material, which had exhibited higher Charpy values but produced with higher oxygen content, did not show a significantly different variation in non-metallic inclusion count, and there was no clear evidence of prior particle boundaries being evident in the cross-sectional studies of the microstructure. Hence, it is hypothesised that increased prior austenite formation was due to the increased nitrogen levels in the gas atomised powder.
本文介绍了Rolls-Royce公司为研究低合金钢(LAS) 508合金批次材料的力学和冶金性能所做的工作。该材料采用粉末冶金-热等静压(PM-HIP)法制备。LAS是ASME 508 4N模型合金。罗尔斯·罗伊斯公司已经将PM-HIP广泛用于制造核级部件,如阀门、管道和泵碗,目前正在研究将其用于制造LAS压力容器,以便为锻件提供另一种采购途径,以降低成本和制造交货期。这项工作的一个关键部分是评估机械性能是否可以达到满足规范要求,并与锻造的等效材料相媲美。在这方面,材料的韧性是特别感兴趣的,因为它对LAS压力容器应用非常重要。本文报告说,对于这批特殊材料,夏比韧性明显低于最低室温规范要求,但拉伸性能远远高于证明和极限拉伸强度的最低规范要求。室温下的夏比韧性仅为规范要求的38%,仅为锻造等效材料的21%。Charpy结果不佳的原因可能是由于断裂面的高度多面性和小面尺寸导致先前的奥氏体保留。氧化物和其他沉淀物,如氮化物,被认为对该粉末批次中的低夏比值没有显著贡献。这是因为对其他粉末HIP材料的夹杂物评估,显示出更高的Charpy值,但产生更高的氧含量,在非金属夹杂物数量上没有显着不同的变化,并且在微观结构的横截面研究中没有明确的证据表明先前的颗粒边界是明显的。因此,假设先前奥氏体形成的增加是由于气体雾化粉末中氮含量的增加。
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Volume 4A: Materials and Fabrication
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