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Prospects for using lunar soil in the thermal scheme of a nuclear power plant with thermoelectric energy conversion
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-01-23 DOI: 10.1007/s10512-024-01160-1
V. V. Skorlygin

The present paper provides the assessment of the thermal circuit for a lunar nuclear power plant using lunar soil to cool the cold junction of a thermoelectric generator and utilize unconverted heat. A mathematical description of the main processes and calculations were used to demonstrate energy generation and excess heat utilization schemes based on the thermal conductivity of the soil as of little promise given a wide range of soil thermal conductivity coefficients. Most probably, heat engines based on the difference in the temperature on the Moon surface and deep in the lunar soil are also not capable of functioning for any significant amount of time.

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引用次数: 0
Concentration of 72, 74Ge in the additional product of a square cascade
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-01-17 DOI: 10.1007/s10512-024-01165-w
V. A. Palkin

The paper considers the concentration of 72, 74Ge in a square cascade with large stage separation coefficients corresponding to gas centrifuges. Cascades are calculated by varying the sections of partial stage streams with minimal deviation of calculated stage feeding streams from the specified one. The determined random search algorithms rapidly converge the objective function to the minimum. Thus, a single square cascade can effectively concentrate 72, 74Ge isotopes.

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引用次数: 0
Magnesium potassium phosphate matrix for solidification of a spent tributyl phosphate—dodecane simulant
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-01-17 DOI: 10.1007/s10512-024-01163-y
S. A. Fimina, K. Yu. Belova, N. D. Chalysheva, S. E. Vinokurov

Spent extractant in a diluent accumulates of hydrometallurgical fuel reprocessing. Extractant in a diluent classified as liquid radioactive waste, which must be converted into an environmentally safe state. The article presents the results of testing a magnesium potassium phosphate matrix for solidifying a spent tributyl phosphate—dodecane simulant. We examined solidified samples for compressive strength, water stability after 90 days of immersion, resistance to cycling freezing and thawing (30 cycles from −40 to 40 °C), and water resistance in accordance with GOST R 52126–2003. Thus, a magnesium potassium phosphate compound can include up to 20 wt% of aerosil pre-saturated with a tributyl phosphate—dodecane mixture. This corresponds to 17.6 wt% of the extractant in the diluent. Moreover, quality indicators of the studied compound meet the requirements for solidified radioactive waste.

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引用次数: 0
Liquidus temperature study of LiF–NaF–KF-based melts simulating the fuel salt of a molten-salt reactor for Np, Am, Cm transmutation 模拟Np, Am, Cm熔盐堆燃料盐的lif - naf - kf基熔体液相温度研究
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-12-05 DOI: 10.1007/s10512-024-01147-y
M. N. Belonogov, I. A. Volkov, N. D. Dyrda, G. N. Rykovanov, I. V. Sannikov, P. A. Sannikova, R. R. Fazylov, D. V. Khmelnitsky, V. A. Shelan

Experiments were carried out to determine the liquidus temperature of 46.5LiF–11.5NaF–42KF-based melts simulating the fuel salt of a molten-salt burner operating in a Np, Am, Cm transmutation mode without the consumption of plutonium. The liquidus temperature was determined by differential scanning calorimetry; the melt composition was monitored by atomic emission, alpha, and gamma spectrometry. Melts containing PuF3 and UF4, as well as NdF3 and NiF2 simulating the products of fission and corrosion of structural materials were studied. For the actinide fluoride mole fraction of 5–15 mol% in the LiF–NaF–KF-based fuel salt in the presence of fission and corrosion products, the liquidus temperature of the melts was equal to 485–580 °C.

在不消耗钚的情况下,模拟熔盐燃烧器运行在Np、Am、Cm嬗变模式下的燃料盐,对46.5 liff - 11.5 naf - 42kf基熔体的液相温度进行了测定。用差示扫描量热法测定液相温度;用原子发射、α和γ能谱法监测熔体成分。研究了含PuF3和UF4的熔体,以及模拟结构材料裂变和腐蚀产物的NdF3和NiF2熔体。在裂变和腐蚀产物存在的情况下,lif - naf - kf基燃料盐中氟化锕的摩尔分数为5-15 mol%,熔体的液相温度为485-580 ℃。
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引用次数: 0
An analysis of machine learning for the safety justification of VVER reactors 基于机器学习的VVER反应堆安全性论证分析
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-26 DOI: 10.1007/s10512-024-01142-3
M. V. Antipov, M. A. Uvakin, A. L. Nikolaev, I. V. Makhin, E. V. Sotskov

Contemporary approaches to the safety justification of nuclear power plants are characterized by constantly growing requirements for the volume and complexity of a computational analysis. Machine learning provides the ability to analyze large volumes of calculations. The present paper examines the methodology of a multivariate computational safety analysis based on machine learning. The approach proposed in the work will significantly reduce the time spent on labor-intensive calculations of safety justification. The selected learning model is presented with particular attention paid for its properties optimal for the solution of the considered problem. The ways of solving the problems arising during the preparation of a learning sample and model learning are described; the results of the model application for one of the typical problems including the safety justification of VVER reactors during a postulated design-basis accident using the conservative approach are provided. In conclusion, issues requiring further research, as well as the prospects for the development of the proposed methodology are indicated.

当代核电厂安全论证方法的特点是对计算分析的体积和复杂性的要求不断增长。机器学习提供了分析大量计算的能力。本文探讨了一种基于机器学习的多变量计算安全分析方法。工作中提出的方法将大大减少花费在劳动密集型的安全论证计算上的时间。所选择的学习模型被提出,并特别注意其最优的性质,以解决所考虑的问题。描述了在学习样本准备和模型学习过程中出现的问题的解决方法;给出了用保守方法对VVER反应堆在假定设计基础事故中的安全论证这一典型问题进行模型应用的结果。最后,指出了需要进一步研究的问题,以及拟定方法的前景。
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引用次数: 0
Development of a neural-network methodology for the safety justification of VVER reactors in manoeuvring modes 在机动模式下VVER反应堆安全论证的神经网络方法的发展
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-26 DOI: 10.1007/s10512-024-01141-4
M. A. Uvakin, A. L. Nikolaev, M. V. Antipov, I. V. Makhin, E. V. Sotskov

The article considers the advancement of a methodology developed by JSC OKB “Gidropress” for the calculation safety justification of VVER reactors in manoeuvring modes. The main challenge of the methodology in terms of the accident analysis is the selection and justification of initial conditions, which are carried out through expert assessment. To solve the problem, it is proposed to use machine learning for automating expert assessments based on available calculation results. The article proposes methods for constructing elements of a neural network and an algorithm for its learning. The results of the work of these elements and their combinations for the solution to the given problem are analyzed. Conclusions are made about the possibility of advancing the methodology through the development and implementation of a multilayer neural network that takes into account the accident type, manoeuvring algorithm, moment of the campaign, specifics of a particular project, and other factors important for the safety justification.

本文考虑了JSC OKB“Gidropress”开发的一种方法的进步,用于计算VVER反应堆在机动模式下的安全性。该方法在事故分析方面的主要挑战是初始条件的选择和证明,这是通过专家评估进行的。为了解决这个问题,提出了利用机器学习来基于可用的计算结果自动进行专家评估。本文提出了神经网络元素的构造方法及其学习算法。分析了这些元素及其组合的工作结果,以解决给定的问题。通过多层神经网络的开发和实施,考虑到事故类型、机动算法、活动时刻、特定项目的细节以及其他对安全论证重要的因素,得出了关于推进方法的可能性的结论。
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引用次数: 0
Development and testing of methods for extracting and conditioning accident elimination sorbents in the basements of the Fukushima Daiichi NPP 福岛第一核电站地下室中事故消除吸附剂的提取和调理方法的开发和测试
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-25 DOI: 10.1007/s10512-024-01150-3
E. E. Ostashkina, A. E. Savkin, Yu. T. Slastennikov

The present study aimed to select a method for extracting and conditioning sorbents located in the basements of the Fukushima Daiichi NPP (Japan) after the accident elimination. FSUE “RADON” conducted tests of two schemes for extracting and hydraulically unloading sorbents using a pump: directly into a filter trap or a dispenser with pulp overflow into the basement, followed by the transportation of thickened sorbents from the dispenser to the filter trap. The filter trap filling time, which is controlled by the passage of sorbent particles through the inspection window of the flange at the outlet of the flow, does not exceed 1.5 h at a filling degree of more than 95%. The recommended post-treatment mode includes rinsing with water to a chloride ion concentration of less than 30 mg/dm3, dehydration with compressed air, and holding for draining the remaining liquid with periodic pumping.

本研究旨在选择一种提取和调理位于福岛第一核电站(日本)事故消除后地下室的吸附剂的方法。FSUE“RADON”公司对使用泵提取和水力卸载吸附剂的两种方案进行了测试:直接将吸附剂倒入过滤器疏水器或将纸浆溢出到地下室的分配器,然后将加厚的吸附剂从分配器输送到过滤器疏水器。在填充度大于95%时,由吸收剂颗粒通过流量出口处法兰检查窗口控制的过滤器疏水阀填充时间不超过1.5 h。推荐的后处理方式包括用水冲洗至氯离子浓度小于30 mg/dm3,用压缩空气脱水,并定期泵送保持以排出剩余液体。
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引用次数: 0
Formation of intermetallics during the metallization of model nuclear fuel based on uranium dioxide containing oxides of rare earth metals and palladium 含稀土金属和钯氧化物的二氧化铀模型核燃料金属化过程中金属间化合物的形成
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-25 DOI: 10.1007/s10512-024-01151-2
A. V. Shishkin, V. Yu. Shishkin, P. N. Mushnikov, Yu. P. Zaikov

The paper considers the reduction of rare earth metal (REM) oxides and uranium dioxide with lithium produced during the electrolysis of LiCl–Li2O melt with the formation of intermetallics and palladium. At a cathode potential of 0.6–0.8 V relative to (E_{{mathrm{Li}^{+}}/{mathrm{Li}^{0}}}), intermetallic compounds of CePd3, NdPd3, and UPd4 compositions are formed. The formation current for REM intermetallic compounds is significantly greater than that for uranium. Therefore, when they are co-present in samples, REM intermetallics are formed first, followed by intermetallic compounds of uranium in the presence of palladium unbound by REM alloys. This is due to the significantly greater solubility of neodymium and cerium oxides in the salt melt compared to uranium dioxide. At a cathode potential close to or equal to the potential of liquid lithium, intermetallics with palladium, lanthanides, and uranium Ln3Pd4, LnPd, UPd3 are formed. In this case, an important role is played by the ability of lithium and palladium to form alloys that are liquid at 650 °C.

本文研究了LiCl-Li2O熔体电解过程中产生的锂对稀土金属(REM)氧化物和二氧化铀的还原作用,形成金属间化合物和钯。在相对于(E_{{mathrm{Li}^{+}}/{mathrm{Li}^{0}}})的0.6-0.8 V的阴极电位下,形成了CePd3、NdPd3和UPd4组成的金属间化合物。REM金属间化合物的形成电流明显大于铀的形成电流。因此,当它们同时存在于样品中时,首先形成REM金属间化合物,其次是在未被REM合金结合的钯存在下形成的铀金属间化合物。这是由于与二氧化铀相比,钕和铈氧化物在盐熔体中的溶解度要大得多。在接近或等于液态锂电位的阴极电位下,与钯、镧系元素和铀形成金属间化合物Ln3Pd4、LnPd、UPd3。在这种情况下,锂和钯在650 °C时形成液态合金的能力发挥了重要作用。
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引用次数: 0
Self-protection of fast lead-cooled reactors against the partial blockage of the core flow area 快冷堆芯流区部分堵塞的自保护
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-25 DOI: 10.1007/s10512-024-01139-y
V. I. Rachkov, Yu. S. Khomyakov, Yu. E. Shvetsov

An analysis of the consequences for an accident caused by the blockage of the core flow area is of particular importance for the safety of metal-cooled reactors. A blockage may be caused by the release of slag accumulated in the primary circuit due to the violation of the coolant technology. In order to identify the self-protection margins of BREST-OD-300 and BR-1200 reactors, a comparative analysis of the consequences was carried out for an accident caused by the partial blockage of the core flow area. The velocity and temperature of the coolant in the core, as well as the temperature of the fuel and fuel element claddings during the blockage of the fuel assembly inlet was calculated using the SVIR 3D thermal-hydraulic code. Both reactors were demonstrated having high self-protection against the accident caused by the blockage of the most flow area at the core inlet. Thus, BR-1200 and BREST-OD-300 fuel elements maintain gas integrity until the inlet flow areas of 12 and 40 fuel assemblies is blocked, respectively.

分析堆芯流区堵塞引起的事故后果对金属冷却堆的安全具有特别重要的意义。由于违反冷却剂技术,一次回路中积累的炉渣可能会释放出来,造成堵塞。为了确定BREST-OD-300和BR-1200反应堆的自保护裕度,对一起堆芯流区部分堵塞事故的后果进行了对比分析。使用SVIR 3D热工水力程序计算了燃料组件入口堵塞期间堆芯冷却剂的速度和温度,以及燃料和燃料元件包壳的温度。结果表明,在堆芯进口大部分流区堵塞的情况下,两个反应堆都具有较高的自保护能力。因此,BR-1200和BREST-OD-300燃料元件分别保持气体完整性,直到12和40燃料组件的入口流动区域被阻塞。
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引用次数: 0
Combined electrochemical and ultrasonic decontamination of radioactively contaminated metal surfaces 金属表面放射性污染的电化学与超声联合去污
IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-11-25 DOI: 10.1007/s10512-024-01149-w
A. A. Akatov, Yu. S. Koryakovskiy

The paper considers a highly efficient technology of combined electrochemical and ultrasonic decontamination of metals to reduce the volume of waste disposed during the decommissioning of nuclear and/or radiation hazardous facilities. The possibility of a further increase in its efficiency by the use of dilute sulfuric acid as an electrolyte, preliminary exposure of the metal in the electrolyte, and variable polarization, as well as by the reduction in the distance from the treated surface to the emitter is experimentally demonstrated. Laboratory tests with real radioactively contaminated samples of steel from the Leningrad NPP, as well as pilot industrial tests on batches (~100 kg) of metal waste at the Angarsk Electrolysis Chemical Combine JSC were conducted. The obtained results prove high efficiency and productivity of combined decontamination.

本文研究了一种高效的电化学和超声波联合金属去污技术,以减少核和/或辐射危险设施退役过程中处置的废物体积。实验证明,通过使用稀硫酸作为电解液,金属在电解液中的初步暴露,可变极化以及减少从处理表面到发射器的距离,进一步提高其效率的可能性。对来自列宁格勒核电站的受真正放射性污染的钢铁样品进行了实验室测试,并在安加尔斯克电解化学联合公司对批次(~100 kg)金属废物进行了工业试验。实验结果表明,联合除污效率高、生产率高。
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引用次数: 0
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Atomic Energy
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